Page 1
Prepare on 2016/05/52
Revised on 2018/07/02
Version: 3.0
Material Safety Data Sheet
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product Name: UV CURABLE RESIN_FLEXIBLE
Product Use: Printing material for 3d printers
Company: XYZprinting, Inc.
Address: No.147, Sec. 3, Beishen Rd., Shenkeng Dist., New Taipei City, Taiwan (R.O.C.)
Information Phone No.: 886-2-7705 8001
Emergency Phone No.: 886-2-7705 8001
SECTION 2: Hazards identification
GHS classification
PHYSICAL HAZARDS
Explosives: /
Flammable gases : /
Flammable aerosols: /
Oxidizing gases: /
Gases under pressure: /
Flammable liquids: /
Flammable solids: /
Self-reactive substances and mixture: Classification not possible
Pyrophoric liquids : /
Pyrophoric solids: /
Self-heating substances and mixture: Classification not possible
Substances and mixture which, in contact with water, emit flammable gases: Classification not possible
Oxidizing liquids: Classification not possible
Oxidizing solids: /
Organic peroxides: Classification not possible
Corrosive to metals: Classification not possible
HEALTH HAZARDS
Acute toxicity (oral): Category 4
Acute toxicity (skin): Not classified
Acute toxicity (inhalation: gas): /
Acute toxicity (inhalation: vapour): Classification not possible
Acute toxicity (inhalation: dust): Classification not possible
Acute toxicity (inhalation: mist): Classification not possible
Skin corrosion / irritation: Category 2
Page 1 of 8
Page 2
Serious eye damages / eye irritation: Category 1
Respiratory sensitization: Classification not possible
Skin sensitization: Category 1B
Germ cell mutagenicity: Classification not possible
Carcinogenicity: Classification not possible
Reproductive toxicity: Classification not possible
Specific target organ toxicity / single exposure: Classification not possible
Specific target organ toxicity / repeated exposure: Category 2
Aspiration hazard: Classification not possible
ENVIRONMENTAL HAZARDS
Hazardous to the aquatic environment (acute): Category 2
GHS LABELLING
Hazard pictograms:
Signal word: Danger
Hazard substance:
Trimethylolpropane Triacrylate
Phenylbis(2,4,6-trimethyl benzoyl)-phosphine oxide
Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H318: Causes serious eye damage.
H373: May cause damage to organs through prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.
Precautionary statements:
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response
P301 + P330: IF SWALLOWED: rinse mouth.
Page 2 of 8
Page 3
Identification name
CAS No./EC No.
Weight % content
(or range)
Acrylate monomer
16969-10-1
85%
Polyurethane acrylate
82116-59-4
< 12%
Diphenyl(2,4,6-trimethylbenzoyl)phosphine
oxide
75980-60-8
> 3%
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Contact physician immediately.
P314: Get medical advice/attention if you feel unwell.
P320: Specific treatment is urgent (refer to Section 4).
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
Other hazards
Nothing in particular.
SECTION 3: Composition/information on ingredients
SECTION 4: First aid measures
Description of first aid measures
Inhalation:
In case of adverse exposure to vapors produced by excessive heating, immediately remove to fresh air. And
refer to medical attention.
Skin contact:
Remove/Take off immediately all contaminated clothing. Wipe with cloth. Wash with soap and water. If skin
irritation or a rash occurs, get medical advice/attention.
Eyes contact:
If in eyes: Rinse cautiously with water for at least 15 minutes. Remove contact lenses if present and easy to
do. Continue rinsing. And Contact physician immediately.
Ingestion:
Rinse mouth with water. Do not induce vomiting, if possible, induce vomiting and refer to medical attention.
Page 3 of 8
Page 4
SECTION 5: Firefighting measures
Suitable fire extinguishing media:
Water (for first aid), chemical powder, carbon dioxide, foam, and dry sand.
Unsuitable fire extinguishing media:
In case of large fires, do not use water.
General fire hazards:
Oxides carbon and other toxic gases will form upon combustion and thermal cracking. In case of large
fires, do not water to avoid hot water or molten material splattering and spreading. In case, foam
extinguisher will help to shut off air.
Specific fire-fighting methods:
Shut off all sources of ignition. Wear proper protective equipment. After extingusihing, keep personal
out by roping round until inside of material cools.
Special equipment / instructions for the protection of firefighters:
The fire-fighting should be done from the windward, with suitable respiratory protective devises.
SECTION 6: Accidental release measures
Personal precautions:
When handling material, wear protective goggles, gloves and long-sleeved clothing.
Environmental precautions:
Avoid release of this material into sewer, watercourse or river.
Clean-up procedures:
Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8
"Exposure controls / Personal protective equipment" prior to clean up.
SECTION 7: Handling and storage
Handling procedures:
Prevent contact with eyes, skin and clothing. Do not breathe vapour and mist. Wash thoroughly after
handling. Do not taste or swallow. DO NOT heat or spray. Use only with adequate ventilation. Keep
container closed. Refer to Section 8.
Storage procedures:
Store at 10～32℃, 40～80%RH in the place away from direct sunlight. Keep container tightly closed,
well-ventilated place away from incompatible materials. Store away from heat, sparks, flames, or other
sources of ignition. Use product within three months of receipt for optimum results.
Page 4 of 8
Page 5
Component
TWA*
STEL*
CEILING*
BEIs*
Acrylate monomer
/ / /
/
Polyurethane acrylate
/ / /
/
Diphenyl(2,4,6-trimethylbenzoyl)phosphi
ne oxide
/ / /
/
Appearance (physical state, color, etc.)
Yellowish translucent Liquid at 25°C
Odor
Mild odor
Odor threshold
─
Melting point/freezing point
─
pH value
/
Boiling point/boiling range
─
Flammability (solid, gas)
─
Lower flammability or explosive limits
─
Upper flammability or explosive limits
─
SECTION 8: Exposure controls/personal protection
Control parameters:
*TWA - 8 hours time weighted average exposure limits
*STEL - Short-term exposure limits
*CEILING - Maximum exposure limits
*BEIs - Biological standards
Exposure controls:
Appropriate engineering controls
Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne
contamination below occupational exposure limits.
Personal protective equipment
Respiratory protection:
Use suitable respirator if there is potential to exceed exposure limit. If this material is handled at
elevated temperature or under mist forming conditions, a suitable respirator must be used.
Eye / face protection:
Safety goggles or safety glasses with side shields.
Skin protection:
Use impermeable gloves, protective shoes and anti-static long-sleeved clothing as necessary to
prevent skin contact.
SECTION 9: Physical and chemical properties
Page 5 of 8
Page 6
Flash point
>120°C
Decomposition temperature
─
Auto ignition temperature
─
Oxidising properties
─
Explosive properties
─
Explosion limits
─
Vapor pressure
─
Vapor density
─
Density
1.1 - 1.3g/cm3
Solubilities
Insoluble in water
Partition coefficient of n-octanol/water
─
Viscosity
─
Evaporation rate
─
Relative density
─
SECTION 10: Stability and Reactivity
Chemical Stability:
Stable on normal condition.
Possible hazardous reactions occurring under specific conditions:
May occur.
Conditions to be avoided:
Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Avoid
direct sunlight, freezing conditions, UV light, Inert gas blanketing.
Materials to avoid:
Oxidizing agents, reducing agents, free radical initiators, oxygen scavengers, acids and bases, alkalis,
amines, other polymerization initiators.
Hazardous decomposition products: ─
SECTION 11: Toxicological information
Acute Toxicity: ─
Skin Corrosion/Irritation: ─
Serious eye damage/eye irritation: ─
Respiratory sensitization/skin sensitization: ─
Germ cell mutagenicity: ─
Carcinogenicity: ─
Reproductive toxicity: ─
Specific target organ toxicity-single exposure: ─
Page 6 of 8
Page 7
Specific target organ toxicity-repeated exposure: ─
Aspiration hazard: ─
Others: ─
SECTION 12: Ecological information
Ecological toxicity: ─
Persistence and degradability: ─
Bio-accumulative potential: ─
Mobility in soil: ─
Other adverse effects: ─
SECTION 13: Disposal considerations
Waste treatment methods:
Disposal must be in accordance with applicable federal, state, or local regulations.
SECTION 14: Transport Information
International regulations
UN class: 9
UN number: 3082
UN shipping name: Environmentally hazardous substance, liquid, n.o.s.
(This product includes 2-Propenoic acid, 2-hydroxy-3-phenoxypropyl ester)
Packing Group: 3
Marine pollution material: P
Domestic regulations: Follow all regulation on the transport in your country or region.
Safety measure and condition on transportation:
Protect against tumble, fall, physical damage and direct sunlight during loading to avoid shift in transit.
Emergency response guideline number: ─
SECTION 15: Regulatory information
The Fire Services Act: Category IV Class III petroleums
Industrial Safety and Health Act: ─
SECTION 16: Other information
Remark:
“ – “ = not available ; “ / “ = not applicable
References
JIS Z 7253(2012)
ACGIH2000TLVsandBEIs（2000）
Page 7 of 8
Page 8
Japan Society For Occupational Health (JSOH) Recommendations for allowable concentrations (1999)
GHS(rev.4) Annex3(2011)
Legal disclaimer:
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. This company shall not be held liable for any damage resulting from handling or from
contact with the above product.
While XYZprinting, Inc. believed that data contained herein are accurate and derived from qualified
sources the data are not be taken as a warranty or representation for solely for your consideration,
investigation and verification. Any use of these data and information must be determined by the user to be
in accordance with applicable federal, state and local and regulation.
Page 8 of 8
Loading...