Prepare on 2017/04/18
Revised on 2018/07/03
Version: 2.1
Material Safety Data Sheet
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product Name: UV CURABLE RESIN_CASTABLE (F1)
Product Use: Printing material for 3d printers
Company: XYZprinting, Inc.
Address: No.147, Sec. 3, Beishen Rd., Shenkeng Dist., New Taipei City, Taiwan (R.O.C.)
Information Phone No.: 886-2-7705 8001
Emergency Phone No.: 886-2-7705 8001
SECTION 2: Hazards identification
EMERGENCY OVERVIEW
Color: Yellow
Physical State: Liquid
Odor: Low odor
Classification of the substance or mixture:
Skin corrosion/irritation: Category 2
Skin sensitisation: Category 1
Serious eye damage/eye irritation: Category 2
GHS LABELLING
Hazard pictograms:
Signal word: Warning
Hazard substance:
Methacrylate monomer
Hazard statements:
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H413: May cause long lasting harmful effects to aquatic life.
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash contact place thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
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Identification name
CAS No./EC No.
Hazard Statement(s)
Weight % content (or range)
Methacrylate monomer
Proprietary/
H315; H317; H319
80~90
Acrylate Oligomer
Proprietary/
H319
10~20
Phenylbis(2,4,6-trimethyl
benzoyl)-phosphine oxide
162881-26-7/423-340-5
H317;H413
0~5
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards
PBT / vPvT: ─
SECTION 3: Composition/information on ingredients
SECTION 4: First aid measures
Description of first aid measures
Inhalation:
If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as
needed. Obtain emergency medical attention. Prompt action is essential.
Skin contact:
Remove contaminated clothing as needed. Wash skin thoroughly with mild soap/water. Flush with lukewarm
water for 15 minutes. If sticky, use waterless cleaner first. Seek medical attention if ill effect or irritation
develops.
Eyes contact:
In case of eye contact, immediately rinse with clean water for 20-30minutes. Retract eyelids often. Obtain
emergency medical attention if pain, blinking, tears or redness persists.
Ingestion:
If large quantity swallowed, give lukewarm water (pint) if victim completely conscious/alert. Do not induce
vomiting/risk of damage to lungs exceeds poisoning risk. Obtain emergency medical attention.
The most important symptoms and hazardous effects:
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Harmful in contact with skin and causes skin irritation. May cause an allergic skin reaction. Causes serious
eye irritation.
The protection of first-aiders:
Wear C class protective equipment and first aid in safety area.
Notes to physicians:
Harmful in contact with skin and causes skin irritation. May cause an allergic skin reaction. Causes serious
eye irritation.
SECTION 5: Firefighting measures
Suitable fire extinguishing media:
Water spray, dry powder, foam, carbon dioxide, or appropriate foam.
Specific hazards may be encountered during fire-fighting:
High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause
spontaneous polymerizing reaction generating heat/pressure. Closed containers may rupture or explode
during runaway polymerization. Harmful vapors evolution of fumes/fog. The substances/groups of
substances mentioned can be released in case of fire.
Specific fire-fighting methods:
Full protective equipment, including self contained breathing apparatus is needed to protect fire
fighters from exposure.
Special equipment / instructions for the protection of firefighters:
Chemical splash goggles and/or face shield, respiratory protection equipment, protective gloves, apron,
boot.
SECTION 6: Accidental release measures
Personal precautions:
Wear proper protective equipment, avoid raw material contact and vapor inhalation.
Environmental precautions:
Extinguish all ignition sources and ventilate area. Dispose/report per regulatory requirements. Contain
contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.
Clean-up procedures:
Avoid contact spilled or released material. Reduce spill or release in safety condition. Soak up small
spill with inert solids (such as vermiculite, clay) and sweep/shovel into vented disposal container. Dike
and recover large spill. Obtain emergency help by fire or emergency unit.
SECTION 7: Handling and storage
Handling procedures:
Avoid direct contact with the substance. This product is inhibited to prevent uncontrolled
polymerization. A polymerization can generate heat and pressure and may cause product container to
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Component
TWA*
STEL*
CEILING*
BEIs*
Methacrylate monomer
/ / /
/
Acrylate Oligomer
/ / /
/
Phenylbis(2,4,6-trimethyl
benzoyl)-phosphine oxide
/ / /
/
rupture.
Storage procedures:
Maintain head space in storage containers to support oxygen requirements of the inhibitor(s). Do not
blanket or mix with oxygen free gas, and prevent material from freezing (inhibitor can separate from
product as a solid). Store the products above 10℃/50℉ and below 32℃/90℉. Store the products
away from heat sources, strong oxidizers, radiation and other initiators. Use product within three
months of receipt for optimum results. If material freezes, heat and mix to redistribute the inhibitor.
Product may also be heated to facilitate handling. Heat product container slowly to 40℃/104℉ for not
more than 24 hours. Convection ovens or warm water bath (preferred due to more efficient heat
transfer) are recommended for heating. Do not use drum heater. An air space, preferably an air bubble
flow, should be provided for at all times during heating.
SECTION 8: Exposure controls/personal protection
Control parameters:
*TWA - 8 hours time weighted average exposure limits
*STEL - Short-term exposure limits
*CEILING - Maximum exposure limits
*BEIs - Biological standards
Exposure controls:
Appropriate engineering controls
1. Using no spark, grounding ventilation system, and separate from general ventilation system.
2. Exhaust waste gas to outdoor, and take applicable measure to protect environment.
3. Using local exhaust ventilation and closed processing system when mass production.
4. Complement exhaust air by ventilation system with supply plenty fresh air.
Personal protective equipment
Respiratory protection:
If this material is handled at elevated temperature or under mist forming conditions, NIOSH/MSHA
approved respiratory protection equipment should be used.
Hand protection:
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Appearance (physical state, color, etc.)
Yellow liquid at 25°C
Odor
Low odor
Odor threshold
─
Melting point/freezing point
─
pH value
AP 6.8 - 7.2
Boiling point/boiling range
─
Flammability (solid, gas)
─
Lower flammability or explosive limits
─
Upper flammability or explosive limits
─
Flash point
100°C Test Method: Closed cup
Decomposition temperature
─
Auto ignition temperature
─
Oxidising properties
─
Explosive properties
─
Explosion limits
─
Vapor pressure
─
Vapor density
─
Density
1.00 - 1.10g/cm3
Do not use natural rubber gloves. Products without solvents added: wear nitrile gloves. Products used
with solvents: wear thick (>0.5 mm) nitrile gloves. Replace gloves immediately when torn or any
change in appearance (dimension, color, flexibility, etc) is noticed.
Eye / face protection:
Eye protection such as chemical splash goggles and/or face shield must be worn when possibility
exists for eye contact due to splashing or spraying liquid, airborne particles, or vapor. Contact lenses
should not be worn.
Skin and body protection:
Depending on the conditions of use, protective gloves, apron, boots, head and face protection should
be worn. This equipment should be cleaned thoroughly after each use.
Hygiene measures:
1. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of
any potential exposure.
2. Use good personal hygiene practices. Wash hands before eating, drinking, smoking, or using toilet
facilities.
3. Promptly remove soiled clothing/wash thoroughly before reuse. Shower after work using plenty of
soap and water.
SECTION 9: Physical and chemical properties
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Solubility
Insoluble in water
Partition coefficient of n-octanol/water
─
Viscosity
─
Evaporation rate
─
Relative density
─
SECTION 10: Stability and Reactivity
Chemical Stability:
Stable on normal condition.
Possible hazardous reactions occurring under specific conditions:
Heat and pressure generation when polymerization and result in closed container broken and cracked.
Conditions to be avoided:
High temperatures, localized heat sources (i.e., drum or band heaters), oxidizing conditions, freezing
conditions, direct sunlight, ultraviolet radiation, inert gas blanketing.
Materials to avoid:
Strong oxidizers, strong reducers, free radical initiators, inert gases, oxygen scavengers.
Hazardous decomposition products:
Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps other toxic vapors may be released
during a fire involving this product.
SECTION 11: Toxicological information
Routes of exposure:
Skin, inhalation, ingestion, eyes.
Symptoms:
After inhalation:
No significant signs or symptoms indicative of any adverse health hazard are expected to occur at
standard conditions due to the low volatility of this material.
However, aerosols, or vapors which may be generated at elevated processing temperatures, may
cause respiratory tract irritation. Symptoms of irritation may include coughing, mucous production and
shortness of breath.
After skin contact:
Although no appropriate human or animal health effects data are known to exist, this material is
expected to be a skin irritant. Symptoms of irritation may include redness or rash, swelling of the
affected area and blistering. Repeated or prolonged skin contact may cause a more severe skin
response such as ulcers and scarring. Symptoms of skin exposure may be delayed 24-48 hours.
Although no appropriate human or animal health effects data is known to exist, this material may cause
an allergic skin reaction (sensitization) in susceptible individuals upon repeated exposure.
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After eye contact:
Although no appropriate human or animal health effects data are known to exist, this material is
expected to cause eye irritation. May cause moderate irritation with symptoms including burning
sensation, tearing, redness or swelling.
After ingestion:
Although no appropriate human or animal health effects data are known to exist, this material is
expected to be a slight ingestion hazard.
Acute toxicity: ─
Chronic toxicity or long term toxicity: ─
SECTION 12: Ecological information
Ecological toxicity: ─
Persistence and degradability: ─
Bio-accumulative potential: ─
Mobility in soil: ─
Other adverse effects: ─
SECTION 13: Disposal considerations
Waste treatment methods:
1. Residues and spilled material may be hazardous waste due to potential for internal heat generator.
Disposal must be in accordance with applicable federal, state, or local regulations.
2. The container for this product can present explosion or fire hazards, even when emptied. To avoid
risk of injury, do not cut, puncture, or weld on or near this container. Since the emptied containers
retain product residue, follow label warnings even after container is emptied. This product is only for
industrial application. The packing container must be disposed properly according to the local
environmental protection law and regulation.
SECTION 14: Transport Information
United nations number (UN No): /
UN Proper shipping name: /
Transport hazard class(es): /
Packing group number: ─
Marine pollutant: No
Specific transport measures and precautionary conditions: ─
SECTION 15: Regulatory information
EU Regulation
EINEC/ELINCS/NLP: All materials are listed
Page 7 of 8
REACH Annex XVII: None listed
Hazard Symbols: Xi
WGK: (Water Danger/Protection)
US Federal
TSCA: All materials are listed on the TSCA Inventory or are not subject to TSCA requirements
SARA 302 EHS List (40 CFR355 Appendix A): None listed
SARA 313 (40 CFR 327.65): None Listed
CERCLA (40 CFR 302.4): None Listed
SECTION 16: Other information
Remark:
“ – “ = not available ; “ / “ = not applicable
Legal disclaimer:
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. This company shall not be held liable for any damage resulting from handling or from
contact with the above product.
While XYZprinting, Inc. believed that data contained herein are accurate and derived from qualified
sources the data are not be taken as a warranty or representation for solely for your consideration,
investigation and verification. Any use of these data and information must be determined by the user to be
in accordance with applicable federal, state and local and regulation.
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