Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
! SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Name of product
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended intended purpose(s)
Technical Aerosols
1.3. Details of the supplier of the safety data sheet
Distributor
Advice Produktsicherheit / Product-Safety-Department
W 44 T Multi-Spray
Code-Nr. 112510
WEICON GmbH & Co. KG
Königsberger Str. 255, DE-48157 Münster
Postbox 48045, DE-8460 Münster
Phone ++49(0)251 / 9322 - 0, Fax ++49(0)251 / 9322 - 244
E-Mail : msds@weicon.de
Internet : www.weicon.de
Phone ++49(0)251 / 9322 - 0
E-mail (competent person):
msds@weicon.de
1.4. Emergency telephone number
GIZ Bonn (German, English) Tel: ++49(0)228-19 240
TRANSPORT: Consultank Lutz Harder GmbH Tel: +49(0)178
433 7434 (24h Emergency Contact)
Manufacturer
1.4. Emergency telephone number
Emergency advice -
WEICON GmbH & Co. KG
Königsberger Str. 255, DE-48157 Münster
Phone GIZ Bonn (Medizinische Auskunft in Deutsch und Englisch)
Tel: ++49(0)228-19 240
TRANSPORT: Consultank Lutz Harder GmbH Tel: +49(0)178
433 7434 (24h Emergency Contact)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]
Hazard classes and Hazard
categories
Aerosol 1 H222, H229
STOT SE 3 H336
Hazard Statements Classification procedure
Hazard Statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H336 May cause drowsiness or dizziness.
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 1/10
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
2.2. Label elements
Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]
GHS02 GHS07
Signal word
Danger
Hazard Statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H336 May cause drowsiness or dizziness.
Precautionary Statements
P102 Keep out of reach of children.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F.
P501 Dispose of contents/container to hazardous or special waste collection point.
Supplemental Hazard information (EU)
Repeated exposure may cause skin dryness or cracking.
2.3. Other hazards
Information pertaining to special dangers for human and environment
In extensive use, formation of flammable / explosive vapour-air mixture is possible.
Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
SECTION 3: Composition/ information on ingredients
3.1. Substances
not applicable
3.2. Mixtures
Description
Mixture of active ingredients with propellant
Hazardous ingredients
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 2/10
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
Hazardous ingredients (continued)
CAS No EC No Name [%
weight]
95-63-6 202-436-9 1,2,4-trimethylbenzene 0,1 - 0,29 Flam. Liq. 3, H226 / Acute Tox. 4, H332 / Eye
106-97-8 203-448-7 butane 10 - 24,99 Flam. Gas 1, H220 / Press. Gas
64742-48-9 265-150-3 Naphtha (petroleum), hydrotreated heavy 25-49.99 Flam. Liq. 3, H226 / Asp. Tox. 1, H304 / STOT
polymer Alkaryl polyether 0,3 - 0,99 Eye Irrit. 2, H319 / Skin Irrit. 2, H315 / Aquatic
74-98-6 200-827-9 propane 3 - 9,99 Flam. Gas 1, H220 / Press. Gas
Mineral Oil 3 - 9,99 Asp. Tox. 1, H304
REACH
CAS No Name REACH registration number
64742-48-9 Naphtha (petroleum), hydrotreated heavy 01-2119463258-33
Classification according to Regulation (EC)
No 1272/2008 [CLP/GHS]
Irrit. 2, H319 / STOT SE 3, H335 / Skin Irrit. 2,
H315 / Aquatic Chronic 2, H411
SE 3, H336 / , EUH066
Chronic 2, H411
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
Remove contaminated soaked clothing immediately.
In case of inhalation
Ensure of fresh air.
In the event of symptoms refer for medical treatment.
In case of skin contact
In case of contact with skin wash off with water.
Consult a doctor if skin irritation persists.
In case of eye contact
In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice.
In case of ingestion
Do not induce vomiting.
Refer to medical treatment.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
No information available.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Alcohol-resistant foam
Dry powder
Carbon dioxide
water mist
Unsuitable extinguishing media
Full water jet
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 3/10
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
5.2. Special hazards arising from the substance or mixture
Danger of bursting
In case of fire formation of dangerous gases possible.
5.3. Advice for firefighters
Special protective equipment for fire-fighters
Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done
with breathing apparatus.
Additional information
Cool endangered containers with water spray jet.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Ensure adequate ventilation.
Use personal protective clothing.
6.2. Environmental precautions
Inform pollution control authorities if product gets into the sewerage systems or open waters.
Do not discharge into the drains or bodies of water..
Do not discharge into the drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
Take up with absorbent material.
After taking up the material dispose according to regulation.
6.4. Reference to other sections
Safe handling: see section 7
Disposal: see section 13
Personal protection equipment: see section 8
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
Ventilate closed rooms at ground level.
Care for thoroughly room ventilation, if necessary use in well ventilated area with local exhaust ventilation at workplace.
General protective measures
Avoid contact with eyes and skin
Do not inhale gases/vapours/aerosols.
Hygiene measures
At work do not eat, drink and smoke.
Wash hands before breaks and after work.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking
Do not spray on a naked flame or any incandescent material.
Pressurized container.
Do not pierce or burn even after use.
Vapours can form an explosive mixture with air.
Take precautionary measures against static discharges.
Avoid effect of heat.
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 4/10
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep in closed original container.
Adhere to administrative regulations relating to storage of compressed gas cylinders / containers.
Further information on storage conditions
Protect from heat and direct solar radiation.
Storage temperature may not exceed 50°C (=122°F).
Store container at cool and aired place.
7.3. Specific end use(s)
Recommendation(s) for intended use
See section 1.2
! SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Ingredients with occupational exposure limits to be monitored
CAS No Name Code [mg/m3] [ppm] Remark
106-97-8 Butane 8 hours 1450 600
Short-term 1810 750
EH40/2005
Indicative occupational exposure limit values (91/322/EEC, 2000/39/EC, 2006/15/EC or 2009/161/EU)
CAS No Name Code [mg/m3] [ppm] Remark
95-63-6 1,2,4-trimethylbenzene 8 hours 100 20
Additional advice
The statutory local and national regulations have to be observed.
8.2. Exposure controls
Respiratory protection
In case of insufficient ventilation or long-term effect use breathing apparatus.
Short term: filter apparatus, Filter A/P2
!
Hand protection
Gloves (solvent-resistant)
In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the
gloves.
Glove material specification: Nitile rubber
Chemical protective gloves must be chosen carefully in view of their design and depending on the dependence on the
concentration and amounts of dangerous goods used in the specific working tasks.
Eye protection
tightly fitting goggles
Other protection measures
protective clothing
Appropriate engineering controls
Sufficient ventilation and exhaustion.
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 5/10
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
aerosol
Odour threshold
not determined
Important health, safety and environmental information
Value Temperature at Method Remark
pH value
not determined
Colour
amber
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
Odour
characteristic
boiling range
decomposition point
Flash point
Vapourisation rate
Flammable (solid)
Flammability (gas)
Ignition temperature
Self ignition temperature
Lower explosion limit
Upper explosion limit
Vapour pressure
Relative density
Vapour density
not applicable
not determined
not applicable Aerosol
not determined
not applicable
not determined
270 °C
The product is not
self-igniting.
0,6 Vol-%
10,9 Vol-%
2100 hPa 20 °C
0,715 g/cm3 20 °C
not determined
Solubility in water
Solubility/other
Partition coefficient n-
not determined
not determined
No or low immiscibility
octanol/water (log P O/W)
Decomposition
not determined
temperature
Viscosity
Solvent content
Solids content
not determined
67,1 %
7,4 %
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 6/10
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
Oxidising properties
No information available.
Explosive properties
The product is considered non-explosive ; nevertheless explosive vapour/air mixtures can be generated .
9.2. Other information
No information available.
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
No information available.
10.3. Possibility of hazardous reactions
No dangerous reactions known.
10.4. Conditions to avoid
Keep away from heat.
Formation of inflammable vapour-air mixtures.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
Thermal decomposition
Remark No decomposition if used as directed.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity/Irritation/Sensitization
Value/Validation Species Method Remark
LD50 acute oral
LD50 acute dermal
LC50 acute
inhalation
> 5000 mg/kg rat Naphtha
> 5000 mg/kg rabbit Naphtha
4951 mg/m3 (4 h) rat Naphtha
Skin irritation
Eye irritation
Skin sensitization
Additional information
The product is to be handled with the caution usual with chemicals.
Other hazardous properties may not be excluded.
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 7/10
non-irritant
non-irritant
non-sensitizing
SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicological effects
Value Species Method Validation
Fish
LL/EL/IL50 > 1000 mg/l (96 h) Oncorhynchus mykiss Naphtha
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
Daphnia
Algae
12.2. Persistence and degradability
No information available.
12.3. Bioaccumulative potential
No information available.
12.4. Mobility in soil
No information available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
General regulation
Even in the event of low quantities penetration into the underground drinking water is contaminated.
Do not allow uncontrolled leakage of product into the environment.
Product is not allowed to be discharged into aquatic environment, drains or sewage treatment plants.
EL0 1000 mg/l (48 h) Daphnia magna Naphtha
LL/EL/IL50 > 1000 mg/l (72 h) Pseudokirchneriella
subcapitata
Naphtha
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste code No. Name of waste
15 01 04 metallic packaging
15 01 10* packaging containing residues of or contaminated by hazardous substances
Wastes marked with an asterisk are considered to be hazardous waste pursuant to Directive 2008/98/EC on hazardous waste.
Recommendations for the product
Remove in accordance with local official regulations.
Recommendations for packaging
Dispose of according to the local waste regulations.
Recommended cleansing agent
E.g white spirit.
General information
Assignment to a waste code number / waste identification according to the EWC is to be carried out on a sector or
process-specific basis.
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 8/10
! SECTION 14: Transport information
ADR/RID IMDG IATA-DGR
14.1. UN number
1950 1950 1950
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
14.2. UN proper shipping
name
14.3. Transport hazard
class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
Caution: Gases
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable
Land and inland navigation transport ADR/RID
Hazard label(s) 2.1
tunnel restriction code D
Classification code 5F
transport in "limited quantities" according to 3.4 ADR is possible
!
Transport/further information
24h EMERGENCY CONTACT (TRANSPORT) +49(0)178 433 7434 (Consultank Lutz Harder GmbH)
AEROSOLS AEROSOLS Aerosols, flammable
2.1 2.1 2.1
-- -
No No No
! SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
! VOC standard
VOC content
VOC value
15.2. Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.
67,11 %
480 g/L
SECTION 16: Other information
Recommended uses and restrictions
National and local regulations concerning chemicals shall be observed.
For industrial use only.
Further information
Each user is responsible for the implementation of the national special regulations.
The information contained herein is based on the state of our knowledge. It characterizes the product with regard to the
appropriate safety precautions. It does not represent a guarantee of the properties of the product.
Please observe the following disclaimer! --- Our safety data sheets have been compiled according to effective EUdirectives, WITHOUT taking into account the special national directives concerning the handling of hazardous
substances.
Danish MAL Code 5-3
Indication of changes: "!" = Data changed compared with the previous version. Previous version: 8.3
EUH066 Repeated exposure may cause skin dryness or cracking.
H220 Extremely flammable gas.
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 9/10
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Safety Data Sheet according to Regulation (EC)
No. 1907/2006 (REACH)
Printed 11.01.2016
revision 18.06.2015 (GB) Version 8.4
W 44 T Multi-Spray
WEICON GmbH & Co. KG Königsberger Straße 255 D-48157 Münster / Federal Republic of Germany Page 10/10
Loading...