Thermo Fisher Scientific pH 560 User Manual

Page 1
Alpha pH 560
pH Controller
pH/mV/ºC meter
Page 2
Preface
This manual serves to explain the use of the Thermo Scientific Alpha pH 560 Controller. The manual functions in
two ways, firstly as a step by step guide to help the user operate the instrument. Secondly, it serves as a handy reference guide. This instruction manual is written to cover many anticipated applications of the Alpha pH 560 Controller. If you have doubts in the use of the instrument, please do not hesitate to contact the nearest Authorised Distributor.
The information presented in this manual is subject to change without notice as improvements are made, and does not represent a commitment on part of Thermo Fisher Scientific.
Thermo Fisher Scientific cannot accept any responsibility for damage or malfunction of the unit due to improper use of the instrument.
Copyright ©2006 All rights reserved. Thermo Fisher Scientific Pte Ltd.
Thermo Scientific Alpha pH 560
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Contents
Chapter 1
Chapter 2
Introduction .....................................................................................................1
Before You Begin ..............................................................................1
Intended Use..................................................................................... 1
Safety Instructions............................................................................. 1
Taking Out of Service .......................................................................2
Correct Disposal of the Unit ............................................................. 2
Getting Started................................................................................................ 3
Description of Instrument.................................................................3
Measurement and Control System ....................................................4
Connection Terminals ......................................................................4
Connectors:................................................................................. 4
Switching Between PT100 & PT1000 Temperature Sensors .........5
Remove Back Cover ....................................................................5
Remove Back PCBA ...................................................................5
Set Jumper J7.............................................................................. 6
Connecting pH/ORP Electrode ........................................................ 7
Connection Terminals ......................................................................7
Connecting Temperature Probe ..................................................7
Connect Potential Matching Pin (PMP) ..................................... 7
Installation ........................................................................................8
Mechanical Dimensions .................................................................8
Wall Mount ................................................................................... 9
Panel Mount ..................................................................................9
Display & Keypad........................................................................... 11
Display Overview......................................................................... 11
Mode Indicators........................................................................... 11
Status Annunciators .....................................................................12
Units of Measurement Indicators ................................................ 12
Key Functions................................................................................. 13
Chapter 3
Chapter 4
Thermo Scientific Alpha pH 560
Operation........................................................................................................14
Measurement Mode ........................................................................ 14
Menu Overview ..............................................................................15
Calibration Mode..........................................................................................16
Preparing the Controller & Electrode for Calibration .....................16
Entering pH/ORP Calibration Mode.............................................. 16
pH Calibration................................................................................ 17
For USA Standard Buffer
1-Point Calibration: ..................................................................17
2-Point Calibration: ..................................................................18
.............................................................17
Page 4
For NIST Buffer ..........................................................................20
1-Point Calibration: ..................................................................20
2-Point Calibration: ..................................................................20
ORP Calibration............................................................................. 22
Temperature Calibration.................................................................23
Chapter 5
Chapter 6
Chapter 7
Chapter 8
Chapter 9
Setup Mode ................................................................................................... 24
Temperature Settings ...................................................................... 26
Configuration Settings ................................................................. 32
Technical Specifications ........................................................................... 36
List of Accessories ...................................................................................... 38
Troubleshooting ........................................................................................... 40
General Information .................................................................................... 41
Appendices ................................................................................................... 42
pH Buffer Values at Various Temperatures .................................. 42
Graphical Representation of the Function of Hysteresis ............... 43
General Instructions Concerning Controller Settings...................43
Abbreviations Used in LCD......................................................... 44
Thermo Fisher Scientific iii
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Chapter 1

Introduction

Before You
Begin

Intended Use

Thank you for purchasing the Alpha pH 560 Controller.
The construction of the pH 560 Controller employs leading edge tech­nology and complies with safety regulations currently in force. Notwithstanding this, improper use could lead to hazards for the user or a third-party, and/or adverse effects on the plant or other equipment. Therefore, the operating instructions must be read and understood by the persons involved before working with the pH Controller.
The instruction manual must always be stored close at hand, in a place accessible to all people working with the pH Controller.
If you have questions, which are not or insufficiently answered in this instruction manual, please contact your authorized supplier. They will be glad to assist you.
Alpha pH 560 Controllers are intended solely for pH or ORP and temperature measurement, as described in this instruction manual.
Any other use, or use not mentioned here, that is incompatible with the technical specifications is deemed inappropriate. The operator is solely responsible for any damage arising from such use.
Other prerequisites for appropriate use include:
Comply with the instructions, notes and requirements set out in
this instruction manual.
Comply with all local safety regulations concerning safety at
work.
Comply with all information and warnings in the
documentation dealing with the products used together with the pH Controller (housings, sensors, etc.).
Comply with local environmental and operational conditions.
Safety
Instructions
Thermo Scientific Alpha pH 560 1
The Alpha pH 560 Controller should be installed and operated
only by personnel familiar with the instrument and who are qualified for such work.
A defective pH Controller must neither be installed nor put
into service.
Page 7
The Alpha pH 560 must only be operated under the specified
operating conditions (see Page 36).
The Alpha pH 560 must not be repaired by the customer.
No modifications to the Alpha pH 560 are allowed. The
manufacturer/supplier accepts no responsibility for damage
caused by unauthorized modifications. The risk is borne entirely
by the user.
Taking Out of
Service
Correct Disposal
of the Unit
First disconnect the unit from the power supply and then undo
all electrical connections.
Remove the unit from the wall / panel.
When the Alpha pH 560 Controller is permanently taken out of service, obey the local environmental regulations for correct disposal or send the instrument to your local distributor, they will take care of proper disposal.
2 Thermo Scientific Alpha pH 560
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Chapter 2

Getting Started

Description of
Instrument
The Thermo Scientific Alpha pH 560 Controller is used for measuring pH and temperature values. The pH values can be measured using industrial combination pH sensors. The temperature values can be measured using 3-wire Pt100 / Pt1000 sensors. The Controller can be used for applications such as water treatment and controlling, galvanic-decontamination, chemical processing, food processing, clean or wastewater control and neutralization processes.
The pH Controller has many user-friendly and safety features which include:
Push-button keypad for calibration and setup
Built-in non-volatile memory to ensure that calibration
and other information are not erased if power supply fails
Menu-driven program that simplifies setup
1 or 2 point calibration with selectable USA or NIST
standard pH buffer set
Automatic temperature compensation (ATC)
Manual temperature compensation setting without the
ATC probe, with independent setting for calibration and process temperature
High resolution ADC for precise measurement
Large dual display LCD for easy reading with clear
multiple annunciators, operational mode indicators and error indicators.
Two switching contacts as set-point relays
Limit (on/off) control mode
Separately adjustable high and low set-point hysteresis
(dead bands) to prevent chattering of relays around the set points
0 to 2000 seconds time delay adjustment on all relays –
minimizes false alarms
Backlight LCD display
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Measurement
and Control
System
A typical measurement system consists of:
A pH process Controller
A pH sensor with integrated or separate Pt100/Pt1000
temperature sensor
An appropriate measurement cable
An immersion, flow or process assembly
A final control element such as pump or valve
Connection
Terminals
Connectors:

Figure 2–1. Measurement and Control System

Remove the screws from the four corners at the back of the pH Controller. Remove the back cover. The connectors are exposed on the back PCBA as shown in the diagram below.
J11 – 24V DC power
J8 – 9V DC power
J9 – Relay connections
J10 – pH electrode & Temperature probe connections (wiring has
to be done in the detachable connector
4 Thermo Scientific Alpha pH 560
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Switching Between
PT100 & PT1000
Temperature
Sensors
Remove Back Cover
Remove Back PCBA
Figure 2–2. Outer Side of Back PCBA
The Controller supports both Pt100 & Pt1000 (2-wire or 3-wire) temperature sensors. The default factory setting is Pt100. If you need to use Pt1000 temperature sensor, you have to change the jumper setting (J7) as described below.
Remove screws from the four corners at the back of the pH Controller. Remove the back cover.
Remove the screw located center of the back PCBA. Detach the back PCBA from the Controller. Turn over the back PCBA. Locate J7 jumper on the inner side of the back PCBA as shown in the figure below.
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Set Jumper J7
Figure 2–3. Inner Side of Back PCBA
Set the J7 jumper to required sensor (Pt100 or Pt1000) type.
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Connecting
pH/ORP
Electrode
1. If the pH/ORP electrode has a BNC connector, remove the BNC
connector from the cable.
NOTE: Oakton Instruments offers an optional ‘BNC to Spade Lug adapter’ (Order code: 05994-90) that can be used with pH/ORP electrode without removing the BNC connector.
2. Strip the insulation of the cable so that the bare wires are exposed
enough for connection as shown in diagram below.
Figure 2–4. pH/ORP Electrode Cable
NOTE: Make sure to strip inner black layer (screen) to expose the clear sheath.
3. Connect pH sensing wire to Pin 1 of J10 connector
4. Connect pH reference wire to Pin 2 of J10 connector
Connection
Terminals
Connecting Temperature
Probe
Connect Potential
Matching Pin (PMP)
For Automatic Temperature Compensated (ATC) pH readings, a 100Ω Pt RTD temperature probe (2-wire or 3-wire) can be connected to the Controller.
3-Wire Probe:
1. Connect PT100 compensate wire to Pin 5 of J10 connector
2. Connect PT100 sense wire to Pin 6 of J10 connector
3. Connect PT100 GND wire to Pin 7 of J10 connector
2-Wire Probe:
1. Short Pin 5 & 6 of J10 connector using a small piece of wire.
2. Connect PT100 sense wire to Pin 6 of J10 connector
3. Connect PT100 GND wire to Pin 7 of J10 connector
If using a pH electrode with a PMP, connect the additional wire (PMP) from the pH electrode to Pin 8 of J10 connector. This liquid electrical reference wire is only used when the pH Controller is configured to ‘Symmetrical mode of operation’. Refer page 14 for details on symmetrical mode of operation.
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Installation

Mechanical
Dimensions
Figure 2–5. Frontal View
Figure 2–6. Side View
8 Thermo Scientific Alpha pH 560
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W
all Mount
Figure 2–7.
Panel Mount
Figure 2–8.
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Figure 2–9.
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Display &
Keypad
Display Overview
The Liquid Crystal Display (LCD) of Alpha pH 560 Controller has two alpha-numerical displays (Upper and a Lower).
Upper display: Measured pH, mV or relative mV value are
displayed when the Controller is in normal operation (measurement) mode.
Lower display: Measured temperature value is displayed when the
Controller is in normal operation (measurement) mode. In pH Calibration mode, standard pH buffer values are displayed here: while measured mV values are displayed in the ORP Calibration mode.
The two displays indicate function names, options & settings in Setup mode. Refer page 24 for more details.
The LCD also consists of various mode indicators, status annunciators and unit of measurement indicators.
Mode Indicators
Figure 2–10. LCD Display
MEAS
SETUP CAL
Measurement mode; blinks in Symmetric mode (Refer Page 14 )
Setup mode (Refer Page 24)
Calibration mode (Refer Page16)
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Status Annunciators
READY
HOLD
ATC
ERR
Appears when the reading is stable
Appears in Setup mode and Calibration mode to indicate that the relay function is frozen
Appears when Automatic Temperature Compensation (ATC) is enabled.
Not visible when Manual Temperature Compensation (MTC) is enabled.
Flashes if the temperature probe is faulty in its ATC mode. (Refer Page 26)
Appears when an error occurs
Electrode annunciator. Appears when viewing electrode properties or during calibration error
Buffer annunciator. Appears in calibration mode
Units of
Measurement
Indicators
mV
R.mV
pH
ºC ºF
Millivolt. Appears in ORP measurement/calibration modes (Refer Page 14 & 22)
Relative Millivolt
Appears in pH measurement/calibration modes (Refer Page 14 & 17)
Temperature in Celsius (Refer Page 26)
Temperature in Fahrenheit (Refer Page 26)
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Key Functions

Figure 2–11.
The Liquid Crystal Display (LCD) of Alpha pH 560 Controller has two alpha-numerical displays (Upper and a Lower).
CAL
Enter Calibration mode
Enter Setup mode
Access sub screens (parameters) within a group of
ENT
settings in Setup mode
Confirm (save) setup parameters and numerical values
Start/Confirm calibration in Calibration mode.
Select a group of settings in Setup mode.
Select parameters and increment/decrement numerical values in Setup and Calibration modes.
(When pressed continuously, speed of value increment/decrement increases)
Returns to Measurement mode when both keys are pressed simultaneously.
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Chapter 3

Operation

Measurement
Mode
When the pH Controller is powered on, the display shows all the LCD segments briefly, and then automatically enters into the Measurement mode.
Figure 3–12.
The mode indicator ‘MEAS’ at the top of the display indicates that the pH Controller is in Measurement mode; ‘MEAS’ blinks when in Symmetric mode. The upper alpha-numerical display shows the measured pH or mV value, while the lower display shows the temperature value. The indicator “pH” or “mV” at the upper right side of the display indicates the current measurement mode. (Refer Page Error! Reference source not found. for switching measurement modes)
NOTE: To guarantee accurate readings, the measuring system (the pH Controller and the sensor) must be calibrated regularly.
From measurement mode you can access:
Calibration mode (by pressing CAL key)
Setup mode (by pressing ENT key)
For more details, refer page 16 for Calibration mode and page 24 for Setup mode.)
14 Thermo Scientific Alpha pH 560
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Menu Overview

Figure 3–13.
Thermo Scientific Alpha pH 560 15
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Chapter 4

Calibration Mode

Preparing the
Controller &
Electrode for
Calibration
Before starting calibration, make sure that the pH Controller is in appropriate measurement mode (pH or ORP). When the Controller is switched on, it starts up with the measurement mode last used. For example, if the pH Controller is switched off in ORP measurement mode, it starts up in ORP mode when it is switched on. (Refer Page 5.7 for switching measurement modes)
Be sure to remove the protective electrode storage bottle or rubber cap of the electrode before calibration or measurement. If the electrode has been stored dry, wet the electrode in tap water for 10 minutes before calibrating or taking readings to saturate the pH electrode surface and minimize drift.
Rinse the electrode in de-ionized water after use, and store in electrode storage solution. If storage solution is not available, use pH 4.01 or 7.00 buffer solution.
Do not reuse buffer solutions after calibration. Contaminants in the solution can affect the calibration, and the accuracy of the measurements.
The pH Controller features two internationally recognized pH buffer standards. Select the buffer standard you require in the setup mode. (Refer Page 5.6) Available buffer options are:
USA buffers --- pH 4.01, 1.68, 7.00, 10.01 and 12.45
NIST buffers --- pH 4.01, 1.68, 6.86, 9.18 and 12.45
Entering pH/ORP
Calibration
Mode
Thermo Scientific Alpha pH 560 16
While in measurement mode, press the CAL key to access calibration mode. LCD indicates ‘CAL PH’ (when measurement mode is pH) or ‘CAL OrP’ (when measurement mode is ORP).
Figure 4–14. Entering Calibration Mode
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NOTES:
To exit calibration mode at any time during calibration, Press
and keys simultaneously (escape). The pH Controller returns to the measurement mode and the old calibration values remain active
The calibration is always carried out in the units of measurement
(pH or mV), selected in setup mode

pH Calibration

For USA Standard
Buffer
The pH Controller is capable of calibration of up to 2 points using USA or NIST pH buffer standards. All new calibration values will automatically override existing calibration data. pH buffer values are referenced to 25 °C. Make sure the measurement mode is set to pH. (Refer Page 5.7 for switching measurement modes). All pH buffer values have window of up to 1 pH tolerance during calibration. Calibration error can be occurred if the measured pH value exceeds this window. If you wish to abort the pH calibration, Press and keys simultaneously and the pH Controller reverts to pH measurement mode.
Make sure that the pH Controller is set to accept USA standard buffer in the Setup mode. (Refer Page 5.6 for Buffer Selection Settings) The factory default is USA standard. It is recommended that you perform 2­point calibration at room temperature (25 °C), starting with the first buffer at pH 7.00 followed by any other buffer value. (pH 4.01, 1.68,
10.01 or 12.45).
1-Point Calibration:
Figure 4–15. USA Buffer Single-Point Calibration
11
Thermo Scientific Alpha pH 560 17
From pH measurement mode press CAL key to enter calibration mode as described in page 16. The LCD shows ‘CAL PH’. Press ENT key to begin calibration.
Page 23
2
Place the electrode in pH 7.00 buffer. Immerse the temperature probe in the buffer solution if ATC mode is enabled. Immerse the potential matching pin in the buffer if
symmetrical mode is enabled. The buffer annunciator appears in LCD. Lower display shows pH 7.00 (USA standard buffer). Upper display shows the current uncalibrated pH reading. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press CAL key to confirm the reading.
3
The calibration is completed. The pH Controller re­calculates electrode properties based on the calibration. The new slope (in mV) is shown in the upper display and pH
reading at 0mV (pH7.00 ± offset) is shown in the lower display.
Press ENT key to exit from the calibration.
4
The pH Controller reverts to pH measurement mode.
2-Point Calibration:
Note: Refer notes at the end of this section for additional information and possible error indicators of calibration process
Figure 4–16. USA Buffer 2-Point Calibration
11
From pH measurement mode press CAL key to enter calibration mode as described in page 16. The LCD shows ‘CAL PH’. Press ENT key to begin first calibration point.
18 Thermo Scientific Alpha pH 560
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2
Place the electrode in pH 7.00 buffer. Immerse the temperature probe in the buffer solution if ATC mode is enabled. Immerse the potential matching pin in the buffer if
symmetrical mode is enabled. The buffer annunciator appears in LCD. Lower display shows pH 7.00 (USA standard buffer). Upper display shows the current uncalibrated pH reading. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press ENT key to confirm the reading.
3
The pH Controller moves to the second calibration point. The lower display shows next standard buffer value (pH
4.01). Use and keys to select your second buffer from one of the preset values: pH 4.01 or 1.68 or 10.01 or 12.45. Remove the electrode from the first buffer, rinse and then immerse it into the second buffer. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press ENT key (or CAL key) to confirm the reading.
4
The calibration is completed. The pH Controller re-calculates electrode properties based on the calibration. The new slope (in mV) is shown in the upper display and pH reading at
0mV (pH7.00 ± offset) is shown in the lower display.
Press ENT key to exit from the calibration.
55
The pH Controller reverts to pH measurement mode.
NOTES:
To exit from pH calibration mode without confirming
calibration, Press and keys together.
When confirming the buffer measurement, if the measured pH
value is not within ±1.00pH from selected buffer value, the
electrode annunciator blinks and ERR indicator appears in the display. This error can also occur if non-standard buffers are used or the electrode has worn out. If this happens, press both and keys together to restart the calibration beginning from Step1.
When calibrating with manual temperature compensation, the
meter automatically changes from the preset ‘process temperature’ to the ‘calibration temperature’. After leaving the
Thermo Scientific Alpha pH 560 19
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calibration mode, the pH Controller reverts back to ‘process
temperature’.
For NIST Buffer
1-Point Calibration:
Make sure that the pH Controller is set to accept NIST standard buffer in the Setup mode. (Refer Page 16) The factory default is USA standard. It is recommended that you perform 2-point calibration at room temperature (25 oC), starting with the first buffer at pH 6.86 followed by any other buffer value. (pH 4.01, 1.68, 9.18 or 12.45)
Figure 4–17. NIST Buffer Single-Point Calibration
11
From pH measurement mode press CAL key to enter calibration mode as described in page 16. The LCD shows ‘CAL PH’. Press ENT key to begin calibration.
2
Place the electrode in pH 6.86 buffer. Immerse the temperature probe in the buffer solution if ATC mode is enabled. Immerse the potential matching pin in the buffer if
symmetrical mode is enabled. The buffer annunciator appears in LCD. Lower display shows pH 6.86 (NIST standard buffer). Upper display shows the current uncalibrated pH reading. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press CAL key to confirm the reading.
3
The calibration is completed. The pH Controller re­calculates electrode properties based on the calibration. The new slope (in mV) is shown in the upper display and pH reading at 0mV (pH7.00 ± offset) is shown in the lower display.
Press ENT key to exit from the calibration.
4
The pH Controller reverts to pH measurement mode.
2-Point Calibration:
20 Thermo Scientific Alpha pH 560
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Figure 4–18. NIST Buffer 2-Point Calibration
11
From pH measurement mode press CAL key to enter calibration mode as described in page 16. The LCD shows ‘CAL PH’. Press ENT key to begin first calibration point.
2
Place the electrode in pH 6.86 buffer. Immerse the temperature probe in the buffer solution if ATC mode is enabled. Immerse the potential matching pin in the buffer if
symmetrical mode is enabled. The buffer annunciator appears in LCD. Lower display shows pH 6.86 (NIST standard buffer). Upper display shows the current uncalibrated pH reading. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press ENT key to confirm the reading.
3
The pH Controller moves to the second calibration point. The lower display shows next standard buffer value (pH
4.01). Use and keys to select your second buffer from one of the preset values: pH 4.01 or 1.68 or 9.18 or
12.45. Remove the electrode from the first buffer, rinse and then immerse it into the second buffer. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press ENT key (or CAL key) to confirm the reading.
4
The calibration is completed. The pH Controller re­calculates electrode properties based on the calibration. The new slope (in mV) is shown in the upper display and pH reading at 0mV (pH7.00 ± offset) is shown in the lower display.
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Press ENT key to exit from the calibration.

ORP Calibration

55
The pH Controller reverts to pH measurement mode.
NOTES:
To exit from pH calibration mode without confirming calibration,
Press and keys together
When confirming the buffer measurement, if the measured pH
value is not within ±1.00pH from selected buffer value, the
electrode annunciator blinks and ERR indicator appears in the display. This error can also occur if non-standard buffers are used or the electrode has worn out. If this happens, press both ▲and ▼ keys together to restart the calibration beginning from Step1
When calibrating with manual temperature compensation, the
meter automatically changes from the preset process temperature to the calibration temperature. After leaving the calibration mode, the pH Controller reverts back to process temperature
The pH Controller allows a single point ORP calibration. ORP calibration process is available only when the measurement mode is set to ORP. (Refer Page 32 for switching measurement modes).
Figure 4–19. ORP Calibration
11
From ORP measurement mode press CAL key to enter calibration mode as described in page 16. The LCD shows ‘CAL OrP’. Press ENT key to begin calibration.
2
Place the electrode in a standard ORP solution of known OPR value. Immerse the temperature probe in the buffer solution if ATC mode is enabled. Immerse the potential matching pin in the buffer if symmetrical mode is enabled.
The buffer annunciator & electrode annunciator appear in LCD. The upper display shows the current mV output of the electrode with offset adjustment (if any). The lower display shows the default (uncalibrated) mV output of the electrode. Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press or key to set the upper display value to the
22 Thermo Scientific Alpha pH 560
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ORP value of the solution. Allowable range: -150mV to 150mV.
Temperature
Calibration
3
4
Calibrate temperature probe only if temperature value displayed on the pH Controller is different from that of a calibrated thermometer. Refer to page 26 for further information temperature settings.
Press ENT key to confirm the value.
The pH Controller reverts to ORP measurement mode.
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Chapter 5

Setup Mode

Enter Setup
Mode
The setup mode allows you to customize the settings of the pH Controller to suite your requirements. While in measurement mode, press the ENT key to access setup mode. LCD shows ‘SETUP’ mode indicator and the first page of setup (OFS – offset settings). Press or key to access other pages of the setup mode.
Figure 5–20. Setup Menu
NOTE:
Thermo Scientific Alpha pH 560 24
To exit setup mode at any time press or keys simultaneously (escape). The pH Controller returns to the measurement mode
Page 30
Electrode Offset
Settings
To Determine the
Offset Value:
NOTE:
In applications where continuous pH measurement is required, it may not be convenient to remove the electrode for calibration. In such cases, an on-line offset adjustment is recommended. The pH Controller allows you set an offset of up to ± 2.00pH to compensate for errors in the pH electrode.
The pH Controller adds or subtracts the offset value from the measured pH value and displays the corrected value. However, if you need to offset the value beyond the average offset you would expect in your application type, consider a full calibration or even electrode replacement.
1. Take a sample from the liquid of pH measurement. Record the pH
reading of the pH Controller at the time the sample was taken.
2. Measure the pH value of your sample using another calibrated pH
meter having its own electrode (pH tester, hand-held meter or bench meter)
‘Electrode Offset Setting’ is not available when the pH Controller is configured for ORP measurement mode. (Refer Page 32 for switching measurement modes)
3. The difference between these two readings is the offset

Figure 5–21. Electrode Offset Settings

11
2
From pH measurement mode press ENT key to enter setup mode as described in page 24. The LCD shows the first screen of setup mode (OFS). Press ENT key to access electrode offset setting (OFS).
The upper display shows the last configured offset value (if any), otherwise zero. The lower display shows currently measured pH reading (including last configured offset value). Allow the reading to stabilize. LCD shows ‘READY’ annunciator when the reading is stable.
Press or key to set the upper display to the newly calculated offset value.
3
Thermo Scientific Alpha pH 560 25
As the upper display value (offset) changes, the pH
Page 31
Controller adjust the lower reading automatically to suit the new offset value. Up to ± 2.00 pH offset is allowed.
Press ENT key to confirm the value. The pH Controller reverts to OFS screen.
Press or key to access other setup screens or press or key simultaneously (escape) to return to measurement mode.
Temperature
Settings
Automatic Temperature Compensation (ATC): The pH values other than pH 7.00 are affected by temperature. Use ATC feature of the pH Controller to compensate for pH changes when the temperature of the sample or process liquid fluctuates. Connect a separate temperature probe (Pt100/pt1000) to the pH Controller if an integrated pH/Temperature probe is not available.
Manual Temperature Compensation (MTC): Set the pH Controller to MTC (disable ATC) when the temperature of sample or process liquid is constant and a temperature probe is not available. If you disable ATC, the pH Controller allows you to set your process temperature (P.ºC) and calibration temperature (C.ºC). This allows calibration at a different temperature other than the process temperature. Example: Setting calibration temperature of 25°C lets you calibrate using standard solutions at 25°C, even if your process temperature is different from 25°C.
Figure 5–22. Customising Temperature Settings
From pH or ORP measurement mode press ENT key to enter
11
setup mode as described in page 24. The LCD shows the first screen of setup mode (OFS). Press or key to select Temperature settings screen (SET ºCF).
Press ENT key to access temperature settings (SET ºCF).
Selecting unit of measurement for temperature: The upper
2
display shows ‘Unit’ and the lower display shows the last configured unit of measurement for temperature.
26 Thermo Scientific Alpha pH 560
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Press or key to select the desired units for temperature (ºC or ºF). Press ENT key to confirm your selection.
Enable/disable ATC: The lower display shows ‘AtC’ and the
3
upper display shows the last configured ATC selection (‘On’ or ‘OFF’).
Press or key to enable (ATC On) or disable (ATC OFF) automatic temperature compensation. Press ENT key to confirm your selection.
If ATC enabled (ATC On):
Selecting temperature offset: The upper display shows
4
the last configured temperature offset value (if any), otherwise the default is zero. The lower display shows currently measured temperature reading (including last configured offset value). LCD shows ‘ATC’ annunciator in lower-right corner.
Place a thermometer, which is known to be accurate, in your sample or process liquid. Make sure your temperature probe is placed in the same liquid. Compare the stabilized temperature reading displayed on the monitor with the thermometer. If there is a difference between the two readings (offset), you can adjust the reading of the monitor. Press or key to adjust the lower display to the correct temperature value.
As the lower display value changes, the pH Monitor
55
adjust the upper display reading automatically to suit the new offset value. Up to ± 10 ºC/ ± 18 ºF offset is allowed.
Press ENT key to confirm the value. The pH Controller reverts to SET ºCF screen.
If ATC disabled (ATC OFF):
Setting process temperature: The lower display shows
6
‘P.ºC’ and the upper display shows the last configured process temperature. Press or key to adjust the upper display to desired process temperature. Allowable range: –10.0 to 125.0°C / 14.0 to 257°F.
Press ENT key to confirm the process temperature.
Setting calibration temperature: The lower display
7
shows ‘C.ºC’ and the upper display shows the last configured calibration temperature. Press or key
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to adjust the upper display to desired calibration temperature. Allowable range: –10.0 to 125.0°C / 14.0 to 257°F.
Press ENT key to confirm the calibration temperature. The pH Controller reverts to SET ºCF screen.
Press ▲ or ▼ key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
To exit from any intermediate steps, press and keys simultaneously (escape). The pH Controller returns to the first screen of temperature settings SET ºCF.
Relay A/Relay B
Setting
NOTE:
The SP1 settings determine the operating parameters for Relay A; while SP2 settings define the operating parameters for Relay B. Since these two settings have identical setup parameters, only SP1 is described here.
The pH Controller allows you to configure two independent sets of operating parameters for each relay (Relay A & B) for each measurement mode (pH & ORP). However, when you switch measurement modes, the relay operating parameters will be reset automatically to their default values for that particular measurement mode.
If Controller type is set to ‘OFF’ (Refer page 32 for Controller settings), the ‘Relay A/Relay B Setting’ is not available.
Figure 5–23. Setting Relays
From pH (or ORP) measurement mode press ENT key to
11
enter setup mode as described in page 38 The LCD shows the first screen of setup mode (OFS). Press or key to select relay A (Set point 1) settings screen (SP1).
Press ENT key to access control relay settings (SP1).
Setting set point value: The upper display shows the last
2
28 Thermo Scientific Alpha pH 560
Page 34
configured set point value, otherwise the default value. Press or key to enter the value for set point 1, at which control function of the pH Controller should activate.
Press ENT key to confirm your set point value.
Select relay function: The upper display shows the last
3
configured relay function (LO = Low or HI=High). Press or key to select the desired function.
Press ENT key to confirm your selection.
NOTE: This parameter lets you choose the relay function.
Select ‘LO’ to activate the relay when the pH reading undershoots the set point (SP1) or select ‘HI’ to activate the relay when the pH reading overshoots the set point (SP1). SP1 and SP2 can be selected as ‘LO/LO’, ‘LO/HI’, ‘HI/LO’, or ‘HI/HI’.
Setting hysteresis value: The lower display shows ‘HYS’. The
4
upper display shows the last configured value, otherwise the default value. Press or key to enter the hysteresis value for set point 1. Allowable range: 0 to 1.00 pH.
Press ENT key to confirm your hysteresis value.
NOTE: Hysteresis prevents rapid relay contact switching if
the pH reading is fluctuating near the set point. Refer to Appendix IV for a graphical representation of the hysteresis.
Setting on-delay time: The lower display shows ‘On.d’. The
55
upper display shows last configured on-delay value. Press or key to enter the on-delay time for set point 1. Allowable
range: 0 to 2000 seconds. When the pH reading is reached the set point 1, the pH Controller delays the relay activation (switch on) by the on-delay time you set here.
Press ENT key to confirm your on-delay time.
Setting off-delay time: The lower display shows ‘OF.d’. The
6
upper display shows last configured off-delay value. Press or key to enter the off-delay time for set point 1. Allowable
range: 0 to 2000 seconds. When the pH reading is reached the set point 1 plus hysteresis value, the pH Controller delays the relay deactivation (switch off) by the off-delay time you set here.
Press ENT key to confirm your off-delay time. The pH Controller reverts to SP1 screen.
Thermo Scientific Alpha pH 560 29
Page 35
Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
Controller
Settings
The controller settings allow you to determine the relay type and relay status of the pH Controller.

Figure 5–24. Controller Settings

From pH (or ORP) measurement mode press ENT key to
11
enter setup mode as described in page 30. The LCD shows the first screen of setup mode (OFS). Press or key to select controller settings screen (Cntr).
Press ENT key to access controller settings (Cntr).
Select the controller type: The lower display shows ‘tyP’. The
2
upper display shows the last configured controller type. (‘OFF’ or ‘L.Ct’). Press or key to select the desired controller type.
OFF: Controller Off
Selecting ‘OFF’, the pH Controller stops functioning as a controller by preventing relay functions. Once the controller type is set to ‘OFF’, the setup mode does not show you the Relay A/Relay B settings.
L.Ct:
Limit value control (Controller On) Selecting ‘L.Ct’, the pH Controller is set to function as a controller. When the controller type is set to ‘L.Ct’, the Relay A/Relay B settings are available in the setup mode for you to configure relay operating
30 Thermo Scientific Alpha pH 560
Page 36
parameters.
Press ENT key to confirm your selection.
If Controller type was set to Off (OFF)
The pH Controller reverts to Cntr screen.
If Controller type was set to On (L.Ct)
Buffer Selection
Settings
EEn: De-energized
En: Energized
Press ENT key to confirm your selection. The pH
Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
NOTE: The buffer selection setting is only available if the Controller is configured for pH measurement mode.
This allows you to set the pH Controller to accept either USA or NIST pH buffer standard group during pH calibration.
Select the relay status under Non-Alarm condition:
3
The lower display shows ‘rEL’. The upper display shows the last configured relay status. (‘dEEn’ or ‘En’). Press or key to select the desired relay status.
Controller reverts to Cntr screen.
Buffer Group pH Buffer Points
USA pH 4.01, 1.68, 7.00, 10.01 & 12.45
NIST pH 4.01, 1.68, 6.86, 9.18 & 12.45

Figure 5–25. Buffer Selection Settings

Thermo Scientific Alpha pH 560 31
Page 37
From pH measurement mode press ENT key to enter setup
11
mode as described in page 24. The LCD shows the first screen of setup mode (OFS). Press or key to select buffer settings screen (bUFF).
Press ENT key to access buffer settings (bUFF).
Selecting buffer group: The lower display shows the last
2
configured buffer group. Press or key to select the required buffer group (‘USA’ or ‘nST’).
Press ENT key to confirm your selection. The pH Controller reverts to bUFF screen.
Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
Configuration
Settings
Configuration settings let you configure the pH Controller to different measurement & operation modes, enable/disable backlight of the LCD & reset the pH Controller to factory defaults.
Asymmetrical Operation Mode (ASY):
This is the default mode of operation of the pH Controller, which is suitable for most applications where sample (or process) liquid is not interfered by adjacent electrical noise.
Symmetrical Operation Mode (SY):
This is mode of operation is recommended for applications where sample (or process) liquid is subjected to high electrical interference and therefore the pH reading becomes unstable. When the pH Controller is set to symmetrical mode, you should immerse the potential matching pin (PMP) in the sample (or process) liquid or use a pH electrode with built-in potential matching pin. The ‘MEAS’ indicator blinks when the pH Controller is set to Symmetric mode.
32 Thermo Scientific Alpha pH 560
Page 38
Figure 5–26. Configuration Settings
From pH (or ORP) measurement mode press ENT key to
11
enter setup mode as described in page 24. The LCD shows the first screen of setup mode (OFS). Press or key to select configuration settings screen (Cnfg).
Press ENT key to access configuration settings (Cnfg).
Enable/disable LCD backlight: The upper display shows
2
‘LitE’. The lower display shows last configured backlight selection (‘On’ or ‘OFF’).
Press or key to enable (LitE On) or disable (LitE OFF) backlight of the LCD.
Press ENT key to confirm your selection.
Select measurement mode: The upper display shows the last
3
configured measurement mode (‘PH’ or ‘OrP’).
Press or key to select your desired measurement mode.
Press ENT key to confirm your selection.
NOTE: When the measurement mode is changed, the relay operation parameters (described in page 28) will be reset back
Thermo Scientific Alpha pH 560 33
Page 39
to their default values.
Select operation mode: The upper display shows the last
4
configured operation mode. (‘ASY’ or ‘SY’).
Press or key to select your desired operational mode.
Press ENT key to confirm your selection.
Reset to factory defaults: The display shows ‘nO dEF’.
55
Press or key to select:
nO
dEF:
Not default reset of the pH Controller. User configured values remain active, when confirmed by pressing ENT key.
FCt
dEF:
CAL
dEF:
Reset all settings of the pH Controller to factory defaults, when confirmed by pressing ENT key.
Reset all calibration settings of the pH Controller to factory defaults, when confirmed by pressing ENT key.
Press ENT key to confirm your selection.
If ‘nO dEF’ was selected, the pH Controller reverts to Cnfg
screen. Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
If ‘FCt dEF’ or ‘CAL dEF’ was selected, the pH Controller
performs the selected reset and returns to measurement mode.
Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
To exit from any intermediate steps, Press and keys simultaneously (escape). The pH Controller returns to the first screen configuration settings (Cnfg).
Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode. To exit from any intermediate steps, Press and keys simultaneously (escape). The pH Controller returns to the first screen configuration settings (Cnfg).
34 Thermo Scientific Alpha pH 560
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Viewing
Electrode
Properties
Each time you calibrate your pH electrode, the pH Controller re­calculates slope & offset of the electrode and shown in the LCD at the end of calibration. The setup mode allows you to view slope & offset values at any time.
NOTE:

Figure 5–27. Viewing Electrode Properties

When the measurement mode is set to ORP, only the offset value of the electrode is displayed.
From pH (or ORP) measurement mode press ENT key to enter
11
setup mode as described in page 24. The LCD shows the first screen of setup mode (OFS). Press or key to select viewing electrode properties screen (CdAt).
Press ENT key to view electrode properties (CdAt).
2
Electrode status: The electrode annunciator appears in the LCD. For pH measurement mode, the slope (in mV) is shown in the upper display and pH reading at 0mV (pH7.00 ± offset) is shown in the lower display.
For ORP measurement mode, the offset value (in mV) of the electrode is shown in the upper display.
Press ENT key to quit from electrode properties screen. The pH Controller reverts to CdAt screen.
Press or key to access other setup screens or Press and key simultaneously (escape) to return to measurement mode.
Thermo Scientific Alpha pH 560 35
Page 41
Chapter 6

Technical Specifications

Product Technical Specification
GENERAL SPECIFICATIONS
(a) pH
Measuring Range 0.00 to 14.00 pH
Resolution 0.01 pH
Accuracy ± 0.01 pH
(b) mV
Measuring Range -1000 to 1000 mV
Resolution 1 mV
Accuracy ± 1 mV
(c) Temperature
Measuring range -10.0 to +125.0 oC or +14.0 to +257
o
F
Resolution 0.1
o
C
o
0.1
F (Resolution is 0.1 oF up to
199.9 oF and 1 oF for 200 oF and above)
Relative accuracy ±0.5 oC
±1.0 oF
Sensor 2 wire / 3 wire - Pt100 or Pt1000
(Jumper Selectable)
Compensation Automatic or Manual
CALIBRATION
(a) pH
Thermo Scientific Alpha pH 560 36
Page 42
Product Technical Specification
Number of calibration
1 or 2 points
points
Number of calibration buffers
USA: 1.68,4.01, 7.00, 0.01,12.45
NIST: 1.68,4.01, 6.86, 9.18 ,12.45
(b) Temperature
Offset Adjustment ± 10 ˚C/ ± 18 ˚F
INPUT / OUTPUT
Input Asymmetrical / Symmetrical
Output 2 SPST Relays
DISPLAY
LCD 7 segments display with symbols for
status information
Back light On/Off selectable
ELECTRICAL DATA AND CONNECTIONS
pH/mV Input Screw Terminal (3.5mm pitch)
Connection terminal 8-pin, 2-pin & 5-pin terminal blocks
OTHERS
Power Input Universal +9 V DC Adaptor and 24V
DC Supply
Dimensions (W x H x D) 96mm x 96mm x 66 mm
Weight (Estimated) 210g
Ambient Temp. operating
0 to 40 oC
range
Maximum Relative Humidity
80% up to 31 oC decreasing linearly to 50% at 40oC
Thermo Scientific Alpha pH 560 37
Page 43
Chapter 7

List of Accessories

Thermo
Scientific
Controller Replacement and Accessories
Item Description Order Code
Alpha-pH 560 Controller TSPHCP0560
Combination pH electrode with 5m cable ECARTSO05B
Combination pH electrode with PMP and 5m cable
Combination pH electrode with PT 100, PMP and 5m cable
Combination pH electrode, submersible, with 5m cable
Combination Gold ORP electrode with PMP and 5m cable
Combination Platinum ORP electrode with PMP and 5m cable
Calibration Solutions
ECARGTSO05B
EC100GTSO05B
ECDA9350605B
ECHTAUTSO05B
ECHTPTTSO05B
Item Description Order Code
pH 4.01 buffer solution, 480 ml bottle EC-BU-4BT
pH 7.00 buffer solution, 480 ml bottle EC-BU-7BT
pH 10.01 buffer solution, 480 ml bottle EC-BU-10BT
pH 4.01 buffer sachets, 20 ml x 20 pcs. EC-BU-4BS
pH 7.00 buffer sachets, 20 ml x 20 pcs. EC-BU-7BS
pH 10.01 buffer sachets, 20 ml x 20 pcs. EC-BU-10BS
pH De-ionized water rinse sachets, 20 ml x 20 pcs EC-RIN-WT
pH sachet assortment pack – 5 each of pH 4.01, pH 7.00, pH 10.01 and de-ionized water sachets per box.
Protein cleaning solution for pH electrode EC-DPC-BT
Storage solution for pH electrode EC-RE-005
EC-AST-PK
Thermo Scientific Alpha pH 560 38
Page 44
NOTE:
pH buffer solutions (480 ml bottle) have ±0.01 pH accuracy at
25 °C
pH buffer sachets are individually sealed, single use pouch
containing 20 ml of fresh, contamination free calibration solution
pH buffer sachets have ±0.01 pH accuracy at 25°C
Eutech
Instruments
Controller Replacement and Accessories
Item Description Order Code
Alpha-pH 560 Controller 56717-32
pH/Temp electrode with PMP and 10-ft cable 35807-20
Platinum ORP electrode with 10-ft cable 35801-21
BNC to spade lug adapter 05994-90
Calibration Solutions
Item Description Order Code
pH 4.01 calibration buffer, 500 mL 00654-00
pH 7.01 calibration buffer, 500 mL 00654-04
pH 10.01 calibration buffer, 500 mL 00654-08
pH 4.01 calibration buffer solution pouches, 20/box
pH 7.00 calibration buffer solution pouches, 20/box
35653-01
35653-02
pH 10.00 calibration buffer solution pouches, 20/box
pH De-ionized water rinse sachets, 20 ml x 20 pcs 35653-00
Assortment pack – 5 each of pH 4.01, pH 7.00 and pH 10.00 solution pouches.
Electrode cleaning solution 00653-06
Electrode storage solution 00653-04
NOTE:
To order Oakton accessories, contact the nearest Oakton
distributor
Thermo Scientific Alpha pH 560 39
35653-03
35653-04
Page 45
Chapter 8

Troubleshooting

Problem Power on, but
no display
Unstable pH reading
Oscillating temperature readings
Slow response a) Dirty / Oily
Cause
a) Loose connections b) Incorrect output
voltage of the power adaptor
a) Dirty electrode b) Electrical noise
interference
a) Electrical noise
interference
electrode
Solution
a) Ensure cables make
good contact
b) Use an power
adaptor with specified output voltage
a) Clean electrode and
recalibrate
b) Switch to Symmetric
mode
a) Ensure shield wire is
properly connected to pin 7
a) Clean electrode
Blinking ATC a) No temperature
probe connection during ATC mode
Blinking electrode annunciator
Or (pH) a) pH electrode is not
Or (Temperature)
a) Error in calibration a) Ensure calibration
connected
a) Temperature probe
is not connected when ATC enabled
a) Ensure temperature
sensing cable makes good contact
standard solution is not contaminated. Ensure electrode is clean.
a) Ensure electrode
makes good contact with Transmitter
a) Ensure electrode
makes good contact with Transmitter
Thermo Scientific Alpha pH 560 40
Page 46
Chapter 9
W

General Information

arranty
Return of Goods
Guidelines for
Returning Unit for
Repair
Thermo Fisher Scientific warrants this product to be free from significant deviations in material and workmanship for a period of one year from the date of purchase. If repair is necessary and not the result of abuse or misuse within the warranty period, please return by freight pre-paid and amendment will be made without any charge. Eutech Instrument Customer Service Dept. will determine if the product problem is due to deviations or customer abuse. Out-of-warranty products will be repaired on an exchange basis at cost.
Before returning goods for any reason whatsoever, the Customer Service Dept. has to be informed in advance. Items must be carefully packed to prevent damage during shipment, and insured against possible damage or loss. Thermo Fisher Scientific/ Oakton Instruments will not be responsible for any damage resulting from careless or insufficient packing.
Warning: Shipping damage as a result of inadequate packaging is the user's/distributor’s responsibility. Please follow the guidelines below before shipment.
Use the original packaging material if possible when shipping the unit for repair. Otherwise wrap it with bubble pack and use a corrugated box for additional protection. Include a brief description of any faults suspected for the convenience of Customer Service Dept., if possible.
Maintenance
and Cleaning
Thermo Scientific Alpha pH 560 41
The Alpha pH 560 Controller contains no user repairable components.
Please contact Thermo Fisher Scientific or its distributor if there is any problem with the unit.
To remove dust, dirt and spots, the external surfaces of the pH Controller may be wiped with a damp, lint-free cloth. A mild household cleaner can also be used if necessary.
Page 47

Appendices

Appendix 1
pH Buffer Values at
Various
Temperatures
The following table shows the various pH values at different temperature of the solution during calibration.
Temperature
(oC)
0 4.01 6.98 7.12 9.47 10.32
5 4.01 6.95 7.09 9.38 10.25
10 4.00 6.92 7.06 9.32 10.18
15 4.00 6.90 7.04 9.27 10.12
20 4.00 6.88 7.02 9.22 10.06
25 4.01 6.86 7.00 9.18 10.01
30 4.01 6.85 6.99 9.14 9.97
35 4.02 6.84 6.98 9.10 9.93
40 4.03 6.84 6.97 9.07 9.89
45 4.04 6.83 6.97 9.04 9.86
50 4.06 6.83 6.97 9.01 9.83
55 4.08 6.83 6.97 8.99 9.81
60 4.10 6.84 6.98 8.96 9.79
pH 4.01 pH 6.86 pH 7.00 pH 9.18 pH 10.01
70 4.12 6.85 6.99 8.92 9.76
80 4.16 6.86 7.00 8.89 9.74
90 4.20 6.88 7.02 8.85 9.73
42 Thermo Scientific Alpha pH 560
Page 48
Index: Error! No text of specified style in document.
t
Appendix 2
Graphical
Representation of
he Function of
Hysteresis
The relay of the pH Controller activates when the set-point is reached (forward direction). In the reverse direction, it does not de-activate when the value reaches the set-point. Instead, it continues to be active till the value reaches the amount set by the Hysteresis band.
Appendix 3
General Instructions
Concerning
Controller Settings
Example: You have set your high set point at pH 10.0 and your hysteresis value at pH 0.5. If your measured value overshoots pH 10.0, the pH Controller’s relay activates. The actions of the external device will cause the solution’s pH to drop. The relay will deactivate, when the pH value drops below 9.5 pH.
Control characteristics of pH Controller used as a limit value switch
Figure 0–28.
Thermo Scientific Alpha pH 560 43
Page 49
Appendix 4
Abbreviations Used
in LCD
Abbreviation Description
ASy
AtC
bUFF
CAL
C.ºC
CdAt
CnFg
Cntr
dEF
dEEn
Asymmetrical mode Automatic Temperature
Compensation Buffer

Calibration

Calibration temperature

Electrode properties

Configuration

Controller

Default values

De-energized

En
FCt
HI
HyS
LitE
LO
OFS
OF.d
On.d
Or
OrP

Energized

Factory (defaults)

High limit

Hysteresis

Backlight

Low limit

Offset

Off delay

On delay

Reading is over range

Oxidation Reduction Potential

P.ºC
PH
44 Thermo Scientific Alpha pH 560

Process temperature

pH
Page 50
Index: Error! No text of specified style in document.
Abbreviation Description
Set
SP1
SP2
Sy
tyP
Ur

Setting

1st Set point

2nd Set point

Symmetrical mode

Type

Reading is under range

Thermo Scientific Alpha pH 560 45
Page 51
46 Thermo Scientific Alpha pH 560
Page 52
Water Analysis Instruments
North America
166 Cummings Center Beverly, MA 01915 USA Toll Free: 1-800-225-1480 Tel: 1-978-232-6000 Dom. Fax: 1-978-232-6015 Int’l Fax: 978-232-6031
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