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Document Number: Alkaline_Dry_CH_SDS_01_15
SAFETY DATA SHEET
In Accordance with OSHA Standard 1910.1200 App D (USA)
1. Identification
(a) Product identifier used on the label:
LR03(GD) / AAA / 1.5V
LR6(GD) / AA / 1.5V
(b) Other means of identification:
Alkaline
(c) Recommended use of the chemical and restrictions on use:
Do not throw in fire! Not rechargeable!
(d) Name, address, and telephone number of the chemical manufacturer, importer, or other
responsible party:
Supplier:
Address: Unit Nos 03B-06, 13/Fl., No 909 Cheung Sha Wan Road, Cheung Sha Wan,
Kowloon, Hong Kong.
Tel: 852-2730-9243
Fax: 852-2735-6250
(e) Date of preparation: 1-Jan-2015
Hitachi Maxell Global Limited
2. Hazard(s) identification
(a) Classification of the chemical in accordance with paragraph (d) of §1910.1200
Chemical power source
(b) Signal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with
paragraph (f) of §1910.1200. (Hazard symbols may be provided as graphical reproductions in
black and white or the name of the symbol, e.g., flame, skull and crossbones)
N/A
(c) Describe any hazards not otherwise classified that have been identified during the classification
process
The chemical materials concluded in the Product is sealed up, thus being stable, safe and
eco-friendly under common conditions, may not cause physical / chemical hazards.
(d) Where an ingredient with unknown acute toxicity is used in a mixture at a concentration ≥1%
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Document Number: Alkaline_Dry_CH_SDS_01_15
LR03
LR6
SAFETY DATA SHEET
and the mixture is not classified based on testing of the mixture as a whole, a statement that X%
of the mixture consists of ingredient(s) of unknown acute toxicity is required
No such an ingredient is contained in the product.
3. Composition/information on ingredients
Except as provided for in paragraph (i) of §1910.1200 on trade secrets:
For Substances:
(a) Chemical name
(b) Common name and synonyms
(c) CAS number and other unique identifiers
(d) Impurities and stabilizing additives which are themselves classified and which contribute to the
classification of the substance
Chemical Name
Manganese dioxide MnO2 1313-13-9 38 % 38 %
Graphite C 7782-42-5 4 % 4 %
Zinc Zn 7440-66-6 15 % 15 %
Potassium hydroxide KOH 1310-58-3 5 % 5 %
Steel (shell) Fe 7439-89-6 30 % 29%
Brass (pin) Cu 7440-50-8 4 % 4 %
Nylon (gasket) Nylon 66 32131-17-2 3.2 % 4 %
Polyethylene
terephthalate (label)
Mercury Hg 7439-97-6 Not detected (≤ 1ppm) Not detected (≤ 1ppm)
Cadmium Cd 7439-92-1 Not detected (< 5ppm) Not detected (< 5ppm)
Lead Pb 7440-43-9 Not detected (< 20ppm) Not detected (<20ppm)
Common Name
and Synonyms
PET 25038-59-9
CAS #
0.8 % 1%
Content (Wt %)
For Mixtures
In addition to the information required for substances:
(a) The chemical name and concentration (exact percentage) or concentration ranges of all
ingredients which are classified as health hazards in accordance with paragraph (d) of
§1910.1200 and
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SAFETY DATA SHEET
(1) Are present above their cut-off/concentration limits; or
(2) Present a health risk below the cut-off/concentration limits.
No such an ingredient is contained in the product.
(b) The concentration (exact percentage) shall be specified unless a trade secret claim is made in
accordance with paragraph (i) of §1910.1200, when there is batch-to-batch variability in the
production of a mixture, or for a group of substantially similar mixtures (See A.0.5.1.2) with
similar chemical composition. In these cases, concentration ranges may be used.
No such a situation would happen during the production from batch to batch.
For All Chemicals Where a Trade Secret is claimed
Where a trade secret is claimed in accordance with paragraph (i) of §1910.1200, a statement that
the specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret is required.
4. First-aid measures
(a) Description of necessary measures, subdivided according to the different routes of exposure, i.e.,
inhalation, skin and eye contact, and ingestion
Inhalation: Not applicable.
Skin Contact: Wash with clean water immediately once leakage happens and the inner liquid
splashes onto skin.
Eye contact: Rinse eyes immediately with running water for at least ten minutes. Consult an
ophthalmologist.
Ingestion: Seek medical assistance or treatment immediately.
(b) Most important symptoms/ effects, acute and delayed
The liquid if leaked from the product may be smelly, mild irritant to skin, etc.
(c) Indication of immediate medical attention and special treatment needed, if necessary
Wash with clean water immediately.
5. Fire-fighting measures
(a) Suitable (and unsuitable) extinguishing media.
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SAFETY DATA SHEET
Carbon dioxide (CO2), foam, or dry chemical powder extinguishing media is suitable.
(b) Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products).
The product is not inflammable; the liquid, if leaked from the product, may cause corrosion to
paper, plastic, or any other tender material(s) near by.
(c) Special protective equipment and precautions for fire-fighters.
The fire-fighters are suggested wearing full protective clothing and using self contained
breathing apparatus.
6. Accidental release measures
(a) Personal precautions, protective equipment, and emergency procedures.
Wear protective clothing. Keep unprotected persons away.
(b) Methods and materials for containment and cleaning up.
Collect spilled material with an insert standard absorbent like sand or silica.
Care for well-Ventilated conditions. Recycle or dispose of the materials in an appropriate way.
7. Handling and storage
(a) Precautions for safe handling.
Obey the common known rules and precautions for handling with chemical power sources.
(b) Conditions for safe storage, including any incompatibilities.
Store product in clean, cool and ventilated place with a temperature between 10℃ and 30℃
(no higher than 40℃ in the ordinary course of events) and a relative humidity no higher than
65%; the storage time should not be too long; the batteries should be well-arranged, and do
avoid sort-circuit caused by the contact of the positive and negative electrodes.
8. Exposure controls/personal protection
(a) OSHA permissible exposure limit (PEL), American Conference of Governmental Industrial
Hygienists (ACGIH) Threshold Limit Value (TLV), and any other exposure limit used or
recommended by the chemical manufacturer, importer, or employer preparing the safety data
sheet, where available.
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SAFETY DATA SHEET
N/A
(b) Appropriate engineering controls.
Do not disassemble the product without professional basis.
(c) Individual protection measures, such as personal protective equipment.
No special equipment is required for handling, carrying or using the product.
The chemical materials concluded in the Product is sealed up, thus being stable, safe and
eco-friendly under common conditions.
9. Physical and chemical properties
(a) Appearance (physical state,
color, etc.)
(b) Odor
(c) Odor threshold
Cylindrical battery with PET label in white, blue,
:
golden and black colours, etc.
not applicable
:
:
not applicable
(d) pH
(e) Melting point/ freezing point
(f) Initial boiling point and
boiling range
(g) Flash point
(h) Evaporation rate
(i) Flammability (solid, gas)
(j) Upper/lower flammability or
explosive limits
not applicable
:
: not applicable
not applicable
:
:
not applicable
not applicable
:
: not applicable
not applicable
:
(k) Vapor pressure
(l) Vapor density
(m) Relative density
(n) Solubility(ies)
(o) Partition coefficient:
n-octanol/ water
:
not applicable
not applicable
:
: not applicable
not applicable
:
:
not applicable
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SAFETY DATA SHEET
(p) Auto-ignition temperature
(q) Decomposition temperature
(r) Viscosity
10. Stability and reactivity
(a) Reactivity
N/A
(b) Chemical stability
Stable.
The chemical materials concluded in the Product are sealed up, thus being stable, safe and
eco-friendly under common conditions.
(c) Possibility of hazardous reactions
No.
not applicable
:
: not applicable
not applicable
:
(d) Conditions to avoid (e.g., static discharge, shock, or vibration)
Environmental temperature higher than 40℃, relative humidity below 45% or higher than 65%
is recommended to be avoided for product storage or working.
(e) Incompatible materials
N/A
(f) Hazardous decomposition products
No.
11. Toxicological information
Description of the various toxicological (health) effects and the available data used to identify those
effects, including
(a) Information on the likely routes of exposure (inhalation, ingestion, skin and eye contact)
The chemical materials concluded in the Product are sealed up, thus being stable, safe and
eco-friendly under common conditions;
The liquid (alkaline solution), if leaked from the product, may cause corrosion to paper, plastic,
or any other tender material(s) near by, but not toxicological.
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SAFETY DATA SHEET
(b) Symptoms related to the physical, chemical and toxicological characteristics
People might feel itching, if the inner liquid splashes onto skin.
(c) Delayed and immediate effects and also chronic effects from short- and long-term exposure
N/A
(d) Numerical measures of toxicity (such as acute toxicity estimates)
N/A
(e) Whether the hazardous chemical is listed in the National Toxicology Program (NTP) Report on
Carcinogens (latest edition) or has been found to be a potential carcinogen in the International
Agency for Research on Cancer (IARC) Monographs (latest edition), or by OSHA
No.
12. Ecological information (Non-mandatory)
(a) Ecotoxicity (aquatic and terrestrial, where available): N/A
(b) Persistence and degradability: N/A
(c) Bio-accumulative potential: N/A
(d) Mobility in soil: N/A
(e) Other adverse effects (such as hazardous to the ozone layer) : No.
13. Disposal considerations (Non-mandatory)
Description of waste residues and information on their safe handling and methods of disposal,
including the disposal of any contaminated packaging.
The used product (waste) is recommended to be disposed-of in separate collection, so as to
avoid improper disassembly or recycling method that may lead to pollution or corrosion caused
by the alkaline solution inside it.
14. Transport information (Non-mandatory)
In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a
safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that
batteries be packaged in a manner that prevents short circuits and be contained in “strong outer
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Document Number: Alkaline_Dry_CH_SDS_01_15
Regulatory Body
SAFETY DATA SHEET
packaging” that prevents spillage of contents. All original packaging for Maxell alkaline batteries has
been designed to be compliant with these regulatory concerns.
Alkaline batteries (sometimes referred to as “Dry cell” batteries) are not listed as dangerous goods
under the ADR European Agreement Concerning the International Carriage of Dangerous Goods by
Road, the IMDG International Maritime Dangerous Goods Code, UN Dangerous Good Regulations,
IATA Dangerous Goods Regulations 56th edition, ICAO Technical Instructions and the U.S.
hazardous materials regulations (49 CFR). These batteries are not subject to the dangerous goods
regulations provided they meet the requirements contained in the following special provisions
.
ADR Not regulated
IMDG Not regulated
UN Not regulated
US DOT 49 CFR 172.102 Provision 130
IATA A123 (56th Edition)
ICAO Not regulated
All Maxell alkaline batteries are packed in such a way to prevent short circuits or the generation
dangerous quantities of heat and meet the special provisions listed above. In addition, the IATA
Dangerous Goods Regulations and ICAO Technical Instructions require the words “not restricted”
and the Special Provision number A123 be provided on the air waybill, when an air waybill is issued.
Special Provisions
(a) UN number: N/A
(b) UN proper shipping name: N/A
(c) Transport hazard class(es) : N/A
(d) Packing group, if applicable: N/A
(e) Environmental hazards (e.g., Marine pollutant (Yes/No)) No.
(f) Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code)
The product can be treated as ordinary goods in transportation;
Products in bulk shall be packed in inner packaging in such a manner that can prevent
movement or short-circuit effectively.
(g) Special precautions which a user needs to be aware of, or needs to comply with, in connection
with transport or conveyance either within or outside their premises
Avoid high-temperature, high-humidity condition.
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SAFETY DATA SHEET
15. Regulatory information (Non-mandatory)
Safety, health and environmental regulations specific for the product in question
The product is eco-friendly and in accordance with the safety regulations in ANSI C18.1M_
Part2 Standard, and complying with the environmental requirements in EU Directives
2006/66/EC (Battery Directive).
16. Other information, including date of preparation or last revision
The date of preparation of the SDS or the last change to it
This Safety Date Sheets (SDS) is issued on 1-Jan-2015 as a first version according to
requirements of the USA’s OSHA Standard 1910.1200 App D.
For any other question, please contact the manufacturer for further information.
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