Coin Type Lithium Manganese Dioxide Batteries (CR)
Size:
CR2025
Date of preparation:
Feb 11 2015
Company:
JHIH HONG TECHNOLOGY CO.,LTD.
Telephone Numbers:
+886-2-22989236
Address (Number, Street, City, State, and ZIP Code):
6F, No.15, Wu Chuan Road, Wu-Ku Industrial Park,
New Taipei 248
Fax Numbers:
+886-2-22901657
GHS Risk categories
NA
GHS label element
Image or symbol
NA
Warning:
Warning
Risk information:
1、 into the mouth may be harmful
2、 Do not contact with other metals, stacked, extrusion, may
cause leakage, overheat, explosion, etc.
To guard against :
1、 avoid into the mouth
2、 Single packing or use tray separated place
Incident response:
1、Refer to section 4 emergency measures
The batteries are exempt articles and are not subject to the OSHA Hazard Communication Standard
Requirement. This sheet is provided as technical information only. The information and
recommendations set forth are made in good faith and believed to be accurate as of the date of
preparation. However, JHIH HONG no warranty expressed or Implied.
Evaluation Warning : The document was created with Spire.PDF for .NET.
Reference No.JHT1502
SAFETY DATA SHEET
Section 1-Product and Company Identification
Section 2 – Hazards Identification
2
Ingredient
CAS#
Content(wt%)
Lithium (49mg)
7439-93-2
1.9
Propylene Carbonate
108-32-7
6.0
Manganese dioxide
1313-13-9
2.6
1,2-Dimethoxyethane
110-71-4
3.6
Lithium perchlorate
7791-03-9
1.1
Graphite
7782-42-5、1333-86-4
3.0
Section 3- Composition/Information on Ingredients
Section 4 – First Aid Measures
None unless internal materials exposure. If contents are leaked out, observe following Instructions.
Inhalation: Fumes can cause respiratory irritation . Remove to fresh air and consult a physician.
Skin: Immediately flush skin with plenty of water. If itch or irritation by chemical burn persists,
consult a physician.
Eyes: Immediately flush eye with plenty of water for at least 15 minutes.
Consult a physician immediately
Ingestion: If swallowing a battery, consult a physician immediately.
If contents come into mouth, immediately rinse by plenty of water and consult a physician.
Section 5-Fire Fighting Measures
Extinguishing Media: Extinguisher of alkaline metal fire is effective.
Plenty of cold water is also effective to cool the surrounding area and control the
spread fire. But hydrogen gas may be evolved by the reaction of water and lithium
and it can form an explosive mixture. Therefore in the case that lots of lithium
batteries are burning in a confined space,use a smothering agent.
Fire fighting procedure: Use self-contained breathing apparatus and full protective gear not to inhale harmful
gas .
Section 6-Accidental Release Measures
Accidental Releases: Do not breathe vapors or touch liquid with bare hands (see section 4).
Waste Disposal Methods: Evacuate area. If possible, a trained person should attempt to stop or contain the leak by
neutralizing spill with soda lime or baking soda. A NIOSH Approved Acid Gas Filter Mask or Self-Contained Breathing
Apparatus should be worn. Seal leaking battery and soda lime or baking soda in a plastic bag and dispose of as hazardous
waste.
Other: Follow North American Emergency Response Guide (NAERG)#138 for cells involved in an accident, cells that
have vented, or have exploded.
3
Respiratory Protection
NA
NA
NA
NA
NA
NA
NA
NA
Ventilation
Local Exhaust
Mechanical
Special
Other
Eye Protection
Protective Gloves
Other protective clothing
Section 7-Handling and Storage
1) Handling
Never swallow. Never reverse the positive and negative terminals when mounting . Never short-circuit the battery.
Never heat. Never expose to open flame. Never disassemble. Never weld the terminal or wire to the body of the
battery directly. Never touch the liquid leaked out of battery . Never bring fire close to battery liquid. Never keep in
touch with battery.
2) Storage
Never let the battery contact with water. Never store the battery in hot and high humid place. Don't push the battery
excessively and destroy the battery packaging, often wet and ventilating the dry place to keep in the normal atmospheric
temperature, find the unusual battery is dealt with in time
Section 8 – Exposure Controls, Personal Protection
Section 9 – Physical/Chemical Characteristics
State of matter: Solid state 、Button type
Smell : Tasteless ( At the time of the fullness)
Odor threshold:NA
PH: NA
Melting Point: NA
Boiling Point: 1,2-Dimethoxyethane : 83℃
Evaporation Rate: NA
Flammability (solid, gas):NA
Upper/lower flammability or explosive limits:≧170℃
Vapor Pressure: 1,2-Dimethoxyethane :6.40(20℃)
Vapor Density: 1,2-Dimethoxyethane : 3.11
To the density ( Water =1): NA
Dissolving: NA
Specific Gravity: 1,2-Dimethoxyethane :NA
Spontaneous combustion temperature: NA
Decomposition temperature: NA
Viscosity: NA
4
Reactivity
Stability
Hazardous polymerization
Condition to avoid
Incompatible materials
Hazardous Decomposition or Byproducts
no response
Stable
Will not occur.
See section 7.
Water
Hydrogen
Area
Method
Organization
Special Provision
International
Air
IATA,ICAO
Packing Instruction 968-970
International
Water
IMO
188 & 230
U.S.A
Air, Rail, Highway, Water
DOT
49 CFR Section 173.185
Section 10 – Stability and Reactivity
Section 11 – Toxicological Information
Acute Toxicity:
1,2-Dimethoxyethane:
LC
(Inhalation): N/A
50
LD
: N/A
50
Eye Effects: Corrosive
Skin Effects: Corrosive
Section 12 –Ecological Information
Aquatic Toxicity: Do not let internal components enter marine environments. Avoid releases into
waterways, wastewater or groundwater.
Section 13 – Disposal condition
The battery may be regulated by national or local regulation. Please follow the instructions of Proper
regulation. As electric capacity is left in a discarded battery and it comes into contact With other metals,
it could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-)
terminals with friction tape or some other insulator before disposal.
Section 14 – Transportation Information
Lithium battery model CR2025 is considered as “NotRestricted” cargo because they complied with
IATA Dangerous Goods Regulations 56th Edition of 2015 & Section II of Packing Instruction PI 968.
Shipping Name Lithium Metal Batteries
UN Number UN3090
Hazard Classification Class 9 (Miscellaneous)
Organizations governing the transport of lithium batteries
These regulations are based on the UN Recommendations . Each special provision provides specifications on exceptions
and packaging for shipping lithium batteries. All the Lithium metal cells of JHIH HONG comply in all respects can be
shipped as “ Not Restricted” cargo in accordance with IATA Dangerous Goods Regulations 56 Edition & Section II of
Packing Instruction PI 968.
5
Contents
Lithium metal cells and/or
batteries with a lithium content
not more than 0.3 g
Lithium metal cells and/or
batteries with a lithium content
greater than 0.3 g but not more
than 1 g
Lithium metal cells and/or
batteries with a lithium content
greater than 1 g but not more
than 2 g
Maximum
number of cells /
batteries per
package
No limit
8 pieces per carton
2 pieces per carton
Maximum net
quantity (mass)
per package
2.5 Kg
N/A
N/A
If all of following 3 requirements are satisfied, lithium metal batteries can be transported as “Not Restricted” cargo.
1) Lithium weight or equivalent lithium content must be less than value in table.
Equivalent lithium content (g) is calculated as 0.3 (g/Ah) times the rated capacity (Ah) .
2) Each cell or battery is of the type proven to meet the requirements of each test in the UN Manual of Tests and
Criteria, Part III, section 38.3 Cells
3) Section II of Packing Instruction PI 968:
a) Be marked to indicate that it contains lithium metal cells & batteries, and that special procedures be followed in
the event that the package is damaged.
b) Each package must be labeled with a lithium battery handling label.
c) Be accompanied by a shipping paper explaining that the cells and batteries are excepted from regulations.
d) Packaging requirement following to above 1) Lithium weight or equivalent lithium content must be less than
value in table.
e) Be capable of withstanding a 1.2m drop test in any orientation without shifting of the contents that would allow
short-circuiting, and without release of package contents.
Because the consignor has to take the responsibility, the customer has to confirm the exception conditions when
shipping.
Labeling is not required because batteries are classified as “articles” under the Dangerous Preparations
Directive and as such are exempt from the requirements of the Directive.
Section 16-Other Information
Note:
(1)The symbol in above-mentioned materials " ——"representative consult at present it materials not
relevant, but symbol "NA" represent field the getting more suitable for material.
(2)If you want further information, please contact JHIH HONG sales representative.
6F, NO.15, WU CHUAN RD., WU-KU INDUSTRIAL PARK,
NEW TAIPEI CITY, TAIWAN
Tel:+886-2-2298-9236 Fax:+886-2-2290-1657