Product Name：
Lithium Manganese Dioxide Batteries
CHEMICAL SYSTEM:
Lithium Manganese Dioxide
Volts:
3 V
Size:
CR2032
Trade Mark:
JHT
Approximate Weight:
3.2 g
Designed for Recharge:
NO
Date of preparation:
Jan 01 2017
Company:
JHIH HONG TECHNOLOGY CO.,LTD.
Telephone Numbers:
+886-2-22989236
Address (Number, Street, City, State, and ZIP Code):
6F, No.15, Wu Chuan Road, Wu-Ku Industrial Park,
New Taipei 248
Fax Numbers:
+886-2-22901657
Ingredient
CAS NO.
Content (wt%)
Lithium
7439-93-2
2.25 (0.072 gram)
Propylene Carbonate
108-32-7
6.1
Manganese dioxide
1313-13-9
30.0
1,2-Dimethoxyethane
110-71-4
4.2
Lithium perchlorate
7791-03-9
0.9
Graphite
7782-42-5、1333-86-4
3.4
Polypropylene
9003-07-0
4.1
Stainless steel
7439-89-6
49.05
The batteries are exempt articles and are not subject to the OSHA Hazard Communication Standard
Requirement. This sheet is provided as technical information only. The information and
recommendations set forth are made in good faith and believed to be accurate as of the date of
preparation. However, JHIH HONG makes no warranty expressed or Implied.
MATERIAL SAFETY DATA SHEET
Section 1-Product and Company Identification
Section 2- Composition/Information on Ingredients
Section 3 – Hazards Identification
This contains lithium, organic solvent, and other combustible materials. For this reason, Improper handling
of the battery could lead to distortion, leakage*, overheating, explosion of fire and cause human injury or
equipment trouble. Please strictly observe safety instruction.
(*Leakage is defined as an unintended escape of liquid from a battery.)
Section 4 – First Aid Measures
None unless internal materials exposure. If contents are leaked out, observe following
Instructions
Inhalation Fumes can cause respiratory irritation . Remove to fresh air and consult a physician.
Skin Immediately flush skin plenty of water. If itch or irritation by chemical bum persists, consult a
physician.
Eyes Immediately flush eye with plenty of water for at least 15 minutes.
Consult a physician immediately
Ingestion If swallowing a battery, consult a physician immediately.
If contents come into mouth, immediately rinse by plenty of water and consult a physician.
Section 5-Fire Fighting Measures
Extinguishing Media Extinguisher of alkaline metal fire is effective.
Plenty of cold water is also effective to cool the surrounding area and control the spread
fire. But hydrogen gas may be evolved by the reaction of water and lithium and it can
form an explosive mixture. Therefore in the case that lots of lithium batteries are burning
in a confined space ,use a smothering agent.
Fire fighting procedure Use self-contained breathing apparatus and full protective gear not to inhale harmful
gas .
Section 6-Accidental Release Measures
Accidental Releases: Do not breathe vapors or touch liquid with bare hands (see section 4).
Waste Disposal Methods: Evacuate area. If possible, a trained person should attempt to stop or contain the leak by neutralizing
spill with soda lime or baking soda. A NIOSH Approved Acid Gas Filter Mask or Self-Contained Breathing Apparatus should
be worn. Seal leaking battery and soda lime or baking soda in a plastic bag and dispose of as hazardous waste.
Other: Follow North American Emergency Response Guide (NAERG)#138 for cells involved in an accident, cells that
have vented, or have exploded.
Section 7-Handling and Storage
1) Handling
Never swallow. Never reverse the positive and negative terminals when mounting . Never short-circuit the battery.
Never heat. Never expose to open flame. Never disassemble. Never weld the terminal or wire to the body of the battery
directly. Never touch the liquid leaked out of battery . Never bring fire close to battery liquid. Never keep in touch with
battery.
2) Storage
Never let the battery contact with water. Never store the battery in hot and high humid place. Don't push the battery
excessively and destroy the battery packaging, often wet and ventilating the dry place to keep in the normal atmospheric
temperature, find the unusual battery is dealt with in time
Respiratory Protection
NA
NA
NA
NA
NA
NA
NA
NA
Ventilation
Local Exhaust
Mechanical
Special
Other
Eye Protection
Protective Gloves
Other protective clothing
Stability
Incompatibility
Hazardous polymerization
Condition to avoid
Hazardous Decomposition or Byproducts
Stable
Water
Will not occur.
See section 7.
Hydrogen
Boiling Point:
1,2-Dimethoxyethane : 83℃
Vapor Pressure:
1,2-Dimethoxyethane :6.40(20℃)
Vapor Density:
1,2-Dimethoxyethane : 3.11
Solubility in Water:
1,2-Dimethoxyethane : :diffluence contact with water
Specific Gravity:
1,2-Dimethoxyethane :1.63
Melting Point:
1,2-Dimethoxyethane :-67℃
Evaporation Rate:
N/A
Water Reactive:
1,2-Dimethoxyethane : :diffluence contact with water
Appearance & Odor:
1,2-Dimethoxyethane : achromatism liquid; slight aether odor.
Section 8 – Exposure Controls, Personal Protection
Section 9 – Physical/Chemical Characteristics
State of matter: Solid state
Form : Button type
Color: True quality of stainless steel
Smell : Tasteless ( At the time of the fullness)
Resolve temperature: NA
Spontaneous combustion temperature: NA
Explosion demarcation line : Higher than 170 degrees Centigrade of batteries will be burnt
To the density ( Water =1): NA
Dissolving: NA
Section 10 – Stability and Reactivity
Area
Method
Organization
Special Provision
International
Air
IATA,ICAO
Packing Instruction PI968~970
International
Water
IMO
188 & 230
U.S.A
Air, Rail, Highway, Water
DOT
49 CFR Section 173.185
Contents
Lithium metal cells and/or
batteries with a lithium content not
more than 0.3 g
Lithium metal cells and/or
batteries with a lithium content
greater than 0.3 g but not more
than 1 g
Lithium metal cells and/or
batteries with a lithium content
greater than 1 g but not more than
2 g
Maximum number of
cells / batteries per
package
No limit
8 pieces per carton
2 pieces per carton
Section 11 – Toxicological Information
Acute Toxicity:
1,2-Dimethoxyethane:
LC
(Inhalation): N/A
50
LD
: N/A
50
Eye Effects: Corrosive
Skin Effects: Corrosive
Section 12 –Ecological Information
Aquatic Toxicity: Do not let internal components enter marine environments. Avoid releases into waterways,
wastewater or groundwater.
Section 13 – Disposal condition
The battery may be regulated by national or local regulation. Please follow the instructions of Proper
regulation. As electric capacity is left in a discarded battery and it comes into contact With other metals, it
could lead to distortion, leakage, overheating, or explosion, so make sure to cover the (+) and (-) terminals
with friction tape or some other insulator before disposal.
Section 14 – Transportation Information
Lithium battery model CR2032 is complied with IATA Dangerous Goods Regulations 58th Edition of 2017
& Section IB of Packing Instruction PI 968.
Shipping Name(UN Number) Lithium metal batteries(UN3090)
Lithium metal batteries packed with equipment(UN3091)
Lithium metal batteries contained in equipment(UN3091)
Hazard Classification Class 9 (Miscellaneous)
Organizations governing the transport of lithium batteries
These regulations are based on the UN Recommendations. Each special provision provides specifications on exceptions and
packaging for shipping lithium batteries. All the Lithium metal cells of JHIH HONG comply in all respects can be shipped in
accordance with IATA Dangerous Goods Regulations 58th Edition & Section IB of Packing Instruction PI 968
If all of following 3 requirements are satisfied, lithium metal batteries can be transported as “Dangerous Goods” cargo.
1) Lithium weight or equivalent lithium content must be less than value in table.
Maximum net
quantity (mass) per
package
2.5 Kg
N/A
N/A
Equivalent lithium content (g) is calculated as 0.3 (g/Ah) times the rated capacity (Ah) .
2) Each cell or battery is of the type proven to meet the requirements of each test in the UN Manual of Tests and Criteria,
Part Ⅴ, section 38.3 Cells
3) Section IB of Packing Instruction PI 968:
a) Be marked to indicate that it contains lithium metal cells & batteries, and that special procedures be followed in the
event that the package is damaged.
b) Each package must be labeled with a lithium battery handling label.
c) Be accompanied by a shipping paper explaining that the cells and batteries are excepted from regulations.
d) Packaging requirement following to above 1) Lithium weight or equivalent lithium content must be less than value
in table.
e) Be capable of withstanding a 1.2m drop test in any orientation without shifting of the contents that would allow
Because the consignor has to take the responsibility, the customer has to confirm the exception conditions when shipping.
short-circuiting, and without release of package contents.
Section 15-Regulatory Information
EC Labeling : None
Risk Phrases :None
Safety Phrases : None
Labeling is not required because batteries are classified as “articles” under the Dangerous Preparations
Directive and as such are exempt from the requirements of the Directive.
Section 16-Other Information
Major environmental regulations are as follows:
1) EU BATTERY DIRECTIVE(2006/66/EC)
2) California Code of regulations ,Title 22,Division 4.5,Chapter 33:Best Management Practices for
Perchlorate Materials
Note:
1) The symbol in above-mentioned materials " ——"representative consult at present it materials not relevant,
but symbol "NA" represent field the getting more suitable for material.
2) If you want further information, please contact JHIH HONG sales representative.
6F, NO.15, WU CHUAN RD., WU-KU INDUSTRIAL PARK,
NEW TAIPEI CITY, TAIWAN
Tel:+886-2-2298-9236 Fax:+886-2-2290-1657
E-mail: service@jht-energy.com http://www.jht-energy.com
Last data revised 2017.01.01
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