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Teledyne Analytical Instruments, 16830 Chestnut Street, City of Industry, CA 91749-1580.
Warranty
This equipment is sold subject to the mutual agreement that it is warranted by us free
from defects of material and of construction, and that our liability shall be limited to
replacing or repairing at our factory (without charge, except for transportation), or at
customer plant at our option, any material or construction in which defects become
apparent within one year from the date of shipment, except in cases where quotations or
acknowledgements provide for a shorter period. Components manufactured by others bear
the warranty of their manufacturer. This warranty does not cover defects caused by wear,
accident, misuse, neglect or repairs other than those performed by Teledyne or an authorized service center. We assume no liability for direct or indirect damages of any kind and
the purchaser by the acceptance of the equipment will assume all liability for any damage
which may result from its use or misuse.
We reserve the right to employ any suitable material in the manufacture of our
apparatus, and to make any alterations in the dimensions, shape or weight of any parts, in
so far as such alterations do not adversely affect our warranty.
Important Notice
This instrument provides measurement readings to its user, and serves as a tool by
which valuable data can be gathered. The information provided by the instrument may
assist the user in eliminating potential hazards caused by his process; however, it is
essential that all personnel involved in the use of the instrument or its interface, with the
process being measured, be properly trained in the process itself, as well as all instrumentation related to it.
The safety of personnel is ultimately the responsibility of those who control process
conditions. While this instrument may be able to provide early warning of imminent danger,
it has no control over process conditions, and it can be misused. In particular, any alarm or
control systems installed must be tested and understood, both as to how they operate and
as to how they can be defeated. Any safeguards required such as locks, labels, or redundancy, must be provided by the user or specifically requested of Teledyne at the time the
order is placed.
Therefore, the purchaser must be aware of the hazardous process conditions. The
purchaser is responsible for the training of personnel, for providing hazard warning
methods and instrumentation per the appropriate standards, and for ensuring that hazard
warning devices and instrumentation are maintained and operated properly.
Teledyne Analytical Instruments, the manufacturer of this instrument, cannot
accept responsibility for conditions beyond its knowledge and control. No statement
expressed or implied by this document or any information disseminated by the manufacturer or its agents, is to be construed as a warranty of adequate safety control under the
user’s process conditions.
ii
Teledyne Analytical Instruments
Trace Oxygen Analyzer
Specific Model Information
The instrument for which this manual was supplied may incorporate one or
more options not supplied in the standard instrument. Commonly available
options are listed below, with check boxes. Any that are incorporated in the
instrument for which this manual is supplied are indicated by a check mark in the
box.
Instrument Serial Number: _______________________
Options Included in the Instrument with the Above Serial Number:
G Ultra Trace 3000-V: Instrument configured for Vacuum Service
G 19" Rack Mnt:The 19" Relay Rack Mount units are available with one
Ultra Trace 3000 series analyzers installed in a standard
19" panel and ready to mount in a standard rack.
A-5 Application Notes on Pressures and Flow..................... A-5
Teledyne Analytical Instruments
v
Model Ultra Tace 3000
COMBUSTIBLE GAS USAGE WARNING
This is a general purpose instrument designed for use in a
nonhazardous area. It is the customer's responsibility to ensure
safety especially when combustible gases are being analyzed
since the potential of gas leaks always exist.
D ANGER
The customer should ensure that the principles of operation of
this equipment is well understood by the user . Misuse of this
product in any manner, tampering with its components, or unauthorized substitution of any component may adversely affect
the safety of this instrument.
Since the use of this instrument is beyond the control of
Teled yne, no responsibility b y Teled yne, its affiliates, and agents
for damage or injury from misuse or neglect of this equipment is
implied or assumed.
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Teledyne Analytical Instruments
Ultra Trace Oxygen AnalyzerIntroduction 1
Introduction
1.1Overview
The Teledyne Analytical Instruments Model 3000 Ultra Trace Oxygen
Analyzer is a versatile microprocessor-based instrument for detecting oxygen
at the parts-per-billion (ppb) level in a variety of gases. This manual covers
the Model Ultra Trace 3000 General Purpose flush-panel and/or rack-mount
units only. These units are for indoor use in a nonhazardous environment.
1.2Typical Applications
A few typical applications of the Model Ultra Trace 3000 are:
•Monitoring inert gas blanketing
•Air separation and liquefaction
•Chemical reaction monitoring
•Semiconductor manufacturing
•Petrochemical process control
•Quality assurance
•Gas analysis certification.
1.3Main Features of the Analyzer
The Model 3000 Ultra Trace Oxygen Analyzer is sophisticated yet
simple to use. The main features of the analyzer include:
•A 2-line alphanumeric vacuum fluorescent display (VFD) screen,
driven by microprocessor electronics, that continuously prompts
and informs the operator.
•High resolution, accurate readings of oxygen content from low
ppm levels through 25%. Large, bright, meter readout.
•Stainless steel cell block (wetted surfaces).
Teledyne Analytical Instruments
1-1
1 Introduction Model Ultra Trace 3000
•Advanced Micro-Fuel Cell, designed for trace analysis, has a 0250 ppb low range with less than a 100 ppb offset and six
months warranty and an expected lifetime of one year.
•Versatile analysis over a wide range of applications.
•Microprocessor based electronics: 8-bit CMOS microprocessor
with 32 kB RAM and 128 kB ROM.
•Three user definable output ranges (from 0-250 ppb through 01000 ppm) allow best match to users process and equipment, plus
a fixed 1000 ppm over range.
•Auto Ranging allows analyzer to automatically select the proper
preset range for a given measurement. Manual override allows
the user to lock onto a specific range of interest.
•Two adjustable concentration alarms and a system failure alarm.
•Extensive self-diagnostic testing, at startup and on demand, with
continuous power-supply monitoring.
•Two way RFI protection.
•RS-232 serial digital port for use with a computer or other digital
communication device.
•Four analog outputs: two for measurement (0–1 V dc and
Isolated 4–20 mA dc) and two for range identification.
•Convenient and versatile, steel, flush-panel or rack-mountable
case with slide-out electronics drawer.
1.4Model Designations
Ultra Trace 3000:Standard model for sample under pressure
Ultra Trace 3000-V: Instrument configured for Vacuum Service
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Teledyne Analytical Instruments
Ultra Trace Oxygen AnalyzerIntroduction 1
1.5Front Panel (Operator Interface)
The standard Ultra Trace 3000 is housed in a rugged metal case with all
controls and displays accessible from the front panel. See Figure 1-1. The
front panel has thirteen buttons for operating the analyzer, a digital meter, an
alphanumeric display, and a window for viewing the sample flowmeter.
Function Keys: Six touch-sensitive membrane switches are used to
change the specific function performed by the analyzer:
Digital Meter
Alphanumer ic
Display
Door Latc h
S
S
E
E
T
T
F
F
L
L
O
O
W
W
Sample System
Flow Indicator
Standby Switch
Data Entry Buttons
Function Buttons
Figure 1-1: Model Ultra Trace 3000 Front Panel
•AnalyzePerform analysis for oxygen content of a sample gas.
•SystemPerform system-related tasks (described in detail in
chapter 4, Operation.).
•SpanSpan calibrate the analyzer.
•ZeroZero calibrate the analyzer.
Teledyne Analytical Instruments
1-3
1 Introduction Model Ultra Trace 3000
•AlarmsSet the alarm setpoints and attributes.
•RangeSet up the 3 user definable ranges for the instrument.
Data Entry Keys: Six touch-sensitive membrane switches are used to
input data to the instrument via the alphanumeric VFD display:
•Left & Right ArrowsSelect between functions currently
displayed on the VFD screen.
•Up & Down ArrowsIncrement or decrement values of
functions currently displayed.
•EnterMoves VFD display on to the next screen in a series. If
none remains, returns to the
•Escape Moves VFD display back to the previous screen in a
series. If none remains, returns to the
Digital Meter Display: The meter display is a Light Emitting Diode
(LED) device that produces large, bright, 7-segment numbers that are legible
in any lighting. It produces a continuous readout from 0-999 ppb and then
switches to a continuous ppm readout from 0-9999.9 ppm. It is accurate
across all analysis ranges without the discontinuity inherent in analog range
switching.
Analyze
screen.
Analyze
screen.
Alphanumeric Interface Screen: The VFD screen is an easy-to-use
interface from operator to analyzer. It displays values, options, and messages
that give the operator immediate feedback.
NeedleValve: To adjust flow of gas sample
Flowmeter: Monitors the flow of gas past the sensor. Readout is 0.2 to
2.4 standard liters per minute (SLPM) of nitrogen
Standby Button: The Standby turns off the display and outputs,
but circuitry is still operating.
CAUTION: The power cable must be unplugged to fully
disconnect power from the instrument. When
chassis is exposed or when access door is open
and power cable is connected, use extra care to
avoid contact with live electrical circuits .
Access Door: For access to the Micro-Fuel Cell, the front panel
swings open when the latch in the upper right corner of the panel is pressed
1-4
Teledyne Analytical Instruments
Ultra Trace Oxygen AnalyzerIntroduction 1
all the way in with a narrow gauge tool. Accessing the main circuit board
requires unfastening rear panel screws and sliding the unit out of the case.
1.6Rear Panel (Equipment Interface)
The rear panel, shown in Figure 1-2, contains the gas and electrical
connectors for external inlets and outlets. Some of those depicted are optional and may not appear on your instrument. The connectors are described
briefly here and in detail in chapter 3 Installation.
Teledyne A nalytical Instrum e n ts
Figure 1-2: Model Ultra Trace 3000 Rear Panel
•Power ConnectionUniversal AC power source.
•Gas Inlet and OutletOne inlet and one exhaust out.
•Analog Outputs0–1 V dc oxygen concentration plus 0-1
V dc range ID, and isolated 4–20 mA dc
oxygen concentration plus 4-20 mA dc
range ID.
•Alarm Connections2 concentration alarms and 1 system
alarm.
Teledyne Analytical Instruments
1-5
1 Introduction Model Ultra Trace 3000
•RS-232 PortSerial digital concentration signal output
and control input.
•Remote ProbeUsed in the Ultra Trace3000 for
controlling external solenoid valves
only.
•Remote Span/ZeroDigital inputs allow external control of
analyzer calibration.
•Calibration ContactTo notify external equipment that
instrument is being calibrated and
readings are not monitoring sample.
•Range ID ContactsFour separate, dedicated, range relay
contacts. Low, Medium, High, Cal.
•Network I/OSerial digital communications for local
network access. For future expansion.
Not implemented at this printing.
Note: If you require highly accurate Auto-Cal timing, use external
Auto-Cal control where possible. The internal clock in the
Model Ultra Trace 3000 is accurate to 2-3 %. Accordingly,
internally scheduled calibrations can vary 2-3 % per day.
1-6
Teledyne Analytical Instruments
Ultra Trace Oxygen Analyzer Operational Theory 2
Operational Theory
2.1Introduction
The analyzer is composed of three subsystems:
1. Micro-fuel Cell Sensor
2. Sample System
3. Electronic Signal Processing, Display and Control
The sample system is designed to accept the sample gas and transport it
through the analyzer without contaminating or altering the sample prior to
analysis. The Micro-fuel Cell is an electrochemical galvanic device that
translates the amount of oxygen present in the sample into an electrical
current. The electronic signal processing, display and control subsystem
simplifies operation of the analyzer and accurately processes the sampled
data. The microprocessor controls all signal processing, input/output and
display functions for the analyzer.
2.2Micro-Fuel Cell Sensor
2.2.1 Principles of Operation
The oxygen sensor used in the Model Ultra Trace 3000 series is a
Micro-fuel Cell, Model B-2CXL designed and manufactured by Analytical
Instruments. It is a sealed plastic disposable electrochemical transducer.
The active components of the Micro-fuel Cell are a cathode, an anode,
and the aqueous KOH electrolyte in which they are immersed. The cell
converts the energy from a chemical reaction into an electrical current in an
external electrical circuit. Its action is similar to that of a battery.
There is, however, an important difference in the operation of a battery
as compared to the Micro-fuel Cell: In the battery, all reactants are stored
within the cell, whereas in the Micro-fuel Cell, one of the reactants (oxygen)
Teledyne Analytical Instruments
2-1
2 Operational Theory Model Ultra Trace 3000
comes from outside the device as a constituent of the sample gas being
analyzed. The Micro-Fuel Cell is therefore a hybrid between a battery and a
true fuel cell. (All of the reactants are stored externally in a true fuel cell.)
2.2.2 Anatomy of a Micro-Fuel Cell
The Micro-Fuel Cell is a cylinder only 1¼ inches in diameter and 1¼
inches thick. It is made of an extremely inert plastic, which can be placed
confidently in practically any environment or sample stream. It is effectively
sealed, although one end is permeable to oxygen in the sample gas. The
other end of the cell is a contact plate consisting of two concentric foil rings.
The rings mate with spring-loaded contacts in the sensor block assembly and
provide the electrical connection to the rest of the analyzer. Figure 2-1
illustrates the external features.
Figure 2-1: Micro-fuel Cell
Refer to Figure 2-2, Cross Section of a Micro-Fuel Cell, which illustrates the following internal description.
Figure 2-2. Cross Section of a Micro-Fuel Cell (not to scale)
At the top end of the cell is a diffusion membrane of Teflon, whose
thickness is very accurately controlled. Beneath the diffusion membrane lies
2-2
Teledyne Analytical Instruments
Ultra Trace Oxygen Analyzer Operational Theory 2
the oxygen sensing element—the cathode—with a surface area almost 4 cm2.
The cathode has many perforations to ensure sufficient wetting of the upper
surface with electrolyte, and it is plated with an inert metal.
The anode structure is below the cathode. It is made of lead and has a
proprietary design which is meant to maximize the amount of metal available
for chemical reaction.
At the rear of the cell, just below the anode structure, is a flexible
membrane designed to accommodate the internal volume changes that occur
throughout the life of the cell. This flexibility assures that the sensing membrane remains in its proper position, keeping the electrical output constant.
The entire space between the diffusion membrane, above the cathode,
and the flexible rear membrane, beneath the anode, is filled with electrolyte.
Cathode and anode are submerged in this common pool. They each have a
conductor connecting them to one of the external contact rings on the contact
plate, which is on the bottom of the cell.
2.2.3 Electrochemical Reactions
The sample gas diffuses through the Teflon membrane. Any oxygen in
the sample gas is reduced on the surface of the cathode by the following
HALF REACTION:
O2 + 2H2O + 4e
––
–
––
→ 4OH
––
–
––
(cathode)
(Four electrons combine with one oxygen molecule—in the presence of
water from the electrolyte—to produce four hydroxyl ions.)
When the oxygen is reduced at the cathode, lead is simultaneously
oxidized at the anode by the following HALF REACTION:
Pb + 2OH
––
–
––
→ Pb+2 + H2O + 2e
––
–
––
(anode)
(Two electrons are transferred for each atom of lead that is oxidized.
Therefore it takes two of the above anode reactions to balance one cathode
reaction and transfer four electrons.)
The electrons released at the surface of the anode flow to the cathode
surface when an external electrical path is provided. The current is proportional to the amount of oxygen reaching the cathode. It is measured and used
to determine the oxygen concentration in the gas mixture.
The overall reaction for the fuel cell is the SUM of the half reactions
above, or:
2Pb + O2 → 2PbO
Teledyne Analytical Instruments
2-3
2 Operational Theory Model Ultra Trace 3000
(These reactions are specific to oxygen as long as no gaseous components
capable of oxidizing lead—such as iodine, bromine, chlorine and fluorine—are
present in the sample.)
In the absence of oxygen, no current is generated.
2.2.4 The Effect of Pressure
In order to state the amount of oxygen present in the sample in ppb or
parts-per-million of the gas mixture, it is necessary that the sample diffuse into
the cell under constant pressure.
If the total pressure increases, the rate that oxygen reaches the cathode
through the diffusing membrane will also increase. The electron transfer, and
therefore the external current, will increase, even though the oxygen concentration of the sample has not changed. It is therefore important that the sample
pressure at the fuel cell (usually vent pressure) remain relatively constant
between calibrations.
2.2.5 Calibration Characteristics
Given that the total pressure of the sample gas on the surface of the
Micro-Fuel Cell input is constant, a convenient characteristic of the cell is that
the current produced in an external circuit is directly proportional to the rate at
which oxygen molecules reach the cathode, and this rate is directly proportional to the concentration of oxygen in the gaseous mixture. In other words it
has a linear characteristic curve, as shown in Figure 2-3. Measuring circuits do
not have to compensate for nonlinearities.
In addition, since there is zero output in the absence of oxygen, the
characteristic curve has close to an absolute zero (less than ± 0.1 ppm oxygen).
Depending upon the application, zeroing may still be used to compensate for
the combined zero offsets of the cell and the electronics.
2.2.6 TEC Cooling System
Ultra Trace 3000 analyzers include an advance Thermal Electric
Cooler (TEC) system. This system enhances the performance of the Micro-fuel
Cell by cooling it and regulating its operating temperature. The TEC system
includes a TEC module, a temperature control PCB, a separate power supply,
a thermistor, and a special insulated cellblock. The system is used to regulate
the cell temperature at 11 degrees C. Operating the Micro-fuel Cell at a low
2-4
Teledyne Analytical Instruments
Ultra Trace Oxygen Analyzer Operational Theory 2
temperature minimizes the cell offset (typically less than 75 PPB). A second
benefit of the TEC system is that by regulating the cell temperature the
analyzer becomes tolerant of thermal transients.
The TEC module is a solid-state semiconductor heat – pump. Passing
DC current through the TEC module produces heat flow though the device.
One side of the device will become hot and the other side will become cold.
The TEC module is attached to a heat-sink which is cooled by a fan. This is
required to maintain the hot side at an acceptable temperature. The hot side
temperature limits the overall performance of the TEC module. The fan
draws air into the bottom of the analyzer, this air is forced over the heat sink
and exits through the left side of the analyzer. The power for the TEC device
is supplied by a Pulse Width Modulated (PWM) proportional switching
temperature controller. The temperature controller PCB supplies a 12 volt
pulse whose duty cycle is proportional to the cooling required. The temperature controller PCB uses a thermistor to monitor the temperature of the of cell
block. Power for the fan, and the temperature controller PCB is supplied by
a separate 12VDC power supply.
Figure 2-3. Characteristic Input/Output Curve for a Micro-Fuel Cell
Teledyne Analytical Instruments
2-5
2 Operational Theory Model Ultra Trace 3000
2.3Sample System
The sample system delivers gases to the Micro-Fuel Cell sensor from
the analyzer rear panel inlet. Depending on the mode of operation either
sample or calibration gas is delivered.
The Model Ultra Trace 3000 sample system is designed and fabricated
to ensure that the oxygen concentration of the gas is not altered as it travels
through the sample system.
The sample system for the standard instrument incorporates 1/4" VCR
for sample inlet and outlet tube connections at the rear panel. The sample or
calibration gas that flows through the system is monitored by a flowmeter
downstream from the cell. Figure 2-4 shows the piping layout and flow
diagram for the standard model.
2-6
Figure 2-4: Piping Layout
Teledyne Analytical Instruments
Ultra Trace Oxygen Analyzer Operational Theory 2
Figure 2-5: Flow Diagram-Sample Under Pressure
-Standard Model Ultra Trace 3000
-Do not exceed 10" Hg Vacuum-
Figure 2-5-1: Flow Diagram-Sample at Zero Pressure
-Model Ultra Trace 3000-V
Teledyne Analytical Instruments
2-7
2 Operational Theory Model Ultra Trace 3000
Figure 2-5 is the flow diagram for the sampling system. In the standard
instrument, calibration gases can be connected directly to the Sample In port
by teeing to the port with appropriate valves.
2.4Electronics and Signal Processing
The Model Ultra Trace 3000 Oxygen Analyzer uses an 8031 microcontroller with 32 kB of RAM and 128 kB of ROM to control all signal processing, input/output, and display functions for the analyzer. System power
is supplied from a universal power supply module designed to be compatible
with any international power source. Figure 2-6 shows the location of the
power supply and the main electronic PC boards.
The signal processing electronics including the microprocessor, analog
to digital, and digital to analog converters are located on the motherboard at
the bottom of the case. The preamplifier board is mounted on top of the
motherboard as shown in the figure. These boards are accessible after removing the back panel. Figure 2-7 is a block diagram of the Analyzer
electronics.
Power Supply
Front Panel
Display Board
Preamplifier
PCB
Figure 2-6: Electronic Component Location Inside the Model Ultra Trace 3000
Universal
TEC Power Supply
Slide-out
Electronics
Drawer
Temperature
Controller
Board
Motherboard
2-8
Teledyne Analytical Instruments
Ultra Trace Oxygen Analyzer Operational Theory 2
Sensor
Thermistor
T E C
FAN
Temperature
Controller
HEAT
SINK
Current
to V oltage
Amplifier
Auto
Range
Second
Stage
Amplifier
Power
Supply
System
Failure
Alarm
A to D
Converter
Micro-
Processor
0-1 V
4-20 mA
0-1 V
4-20 mA
Displays
Processing
Self Test
Signal
Concentration
D to A
Converter
Range
Figure 2-7: Block Diagram of the Model Ultra Trace 3000 Electronics
Teledyne Analytical Instruments
2-9
2 Operational Theory Model Ultra Trace 3000
In the presence of oxygen the cell generates a current. A current to
voltage amplifier converts this current to a voltage, which is further amplified
in the second stage amplifier.
The output from the second stage amplifier is sent to an 18 bit analog
to digital converter controlled by the microprocessor.
The digital concentration signal along with input from the control panel
is processed by the microprocessor, and appropriate control signals are
directed to the display, alarms and communications port. The same digital
information is also sent to a 12 bit digital to analog converter that produces
the 4-20 mA dc and the 0-1 V dc analog concentration signal outputs, and
the analog range ID outputs.
Signals from the power supply are also monitored, and through the
microprocessor, the system failure alarm is activated if a malfunction is
detected.
2-10
Teledyne Analytical Instruments
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