Teledyne 9110T User Manual
INSTRUCTION MANUAL
Model 9110T
Nitrogen Oxides Analyzer
P/N M9110T
DATE 11/15/13
TELEDYNE ELECTRONIC TECHNOLOGIES
Analytical Instruments
16830 Chestnut Street
City of Industry, CA 91748
Telephone: (626) 934-1500
Fax: (626) 961-2538
Web: www.teledyne-ai.com
Teledyne Analytical Instruments ii
Model 9110T NOx Analyzer
Copyright © 2013 Teledyne Analytical Instruments
All Rights Reserved. No part of this manual may be reproduced, transmitted, transcribed, stored in a retrieval
system, or translated into any other language or computer language in whole or in part, in any form or by any
means, whether it be electronic, mechanical, magnetic, optical, manual, or otherwise, without the prior written
consent of Teledyne Analytical Instruments, 16830 Chestnut Street, City of Industry, CA 91748.
Warranty
This equipment is sold subject to the mutual agreement that it is warranted by us free from defects of material
and of construction, and that our liability shall be limited to replacing or repairing at our factory (without
charge, except for transportation), or at customer plant at our option, any material or construction in which
defects become apparent within one year from the date of shipment, except in cases where quotations or
acknowledgements provide for a shorter period. Components manufactured by others bear the warranty of their
manufacturer. This warranty does not cover defects caused by wear, accident, misuse, neglect or repairs other
than those performed by Teledyne or an authorized service center. We assume no liability for direct or indirect
damages of any kind and the purchaser by the acceptance of the equipment will assume all liability for any
damage which may result from its use or misuse.
We reserve the right to employ any suitable material in the manufacture of our apparatus, and to make any
alterations in the dimensions, shape or weight of any parts, in so far as such alterations do not adversely affect
our warranty.
Important Notice
This instrument provides measurement readings to its user, and serves as a tool by which valuable data can be
gathered. The information provided by the instrument may assist the user in eliminating potential hazards caused
by his process; however, it is essential that all personnel involved in the use of the instrument or its interface be
properly trained in the process being measured, as well as all instrumentation related to it.
The safety of personnel is ultimately the responsibility of those who control process conditions. While this
instrument may be able to provide early warning of imminent danger, it has no control over process conditions,
and it can be misused. In particular, any alarm or control systems installed must be tested and understood, both
as to how they operate and as to how they can be defeated. Any safeguards required such as locks, labels, or
redundancy, must be provided by the user or specifically requested of Teledyne at the time the order is placed.
Therefore, the purchaser must be aware of the hazardous process conditions. The purchaser is responsible for
the training of personnel, for providing hazard warning methods and instrumentation per the appropriate
standards, and for ensuring that hazard warning devices and instrumentation are maintained and operated
properly.
Teledyne Analytical Instruments, the manufacturer of this instrument, cannot accept responsibility for
conditions beyond its knowledge and control. No statement expressed or implied by this document or any
information disseminated by the manufacturer or its agents, is to be construed as a warranty of adequate safety
control under the user’s process conditions.
Trademarks
All trademarks, registered trademarks, brand names or product names appearing in this document are the
property of their respective owners and are used herein for identification purposes only.
Teledyne Analytical Instruments ii
Model 9110TH NOx Analyzer Specific Configuration
INFORMATION ABOUT THE SPECIFIC CONFIGURATION OF YOUR
MODEL 9110T NOX ANALYZER
Note: All instruments must include the standard hardcopy manual.
SELECTED VERSIONS OF THE MODEL 9110T
Model 9110T— Standard Touch Screen Version
This Model 9110E NOx Analyzer is a touch screen version designed for analyzing the NOx
concentration in a background gas specified by the customer. It has a minimum settable range of 0-50
ppb and a maximum settable range of 0-10 ppm. The standard version is designed for ambient pressure
applications. The analyzer may have one or two analysis ranges with or without auto-ranging as listed
below. It includes an internal Moly converter and an external pump. Alarm relays are optional and if
included, that option will be checked below.
Model 9110TH — High Range Touch Screen Version
The Model 9110EH NOx Analyzer is a touch screen version designed for analyzing higher NOx
concentration (from 0-5 ppm to 0-5000 ppm) than the standard model. It includes an internal Hicon
converter and an external pump. Alarm relays are optional and if included, that option will be checked
below. There is no internal zero/span gas/oven option available for this model. The analyzer may have
one or two analysis ranges with or without autoranging as listed below.
This version is available with internal or external Hicon or Moly converters.
Model 9110TM — Mid-Range Touch Screen Version
The Model 9110EA NOx Analyzer is a touch screen version designed for analyzing a mid-range NOx
concentration. It has a minimum settable range of 0-1 ppm and a maximum settable range of 0-200 ppm.
t includes an internal Moly converter and an external pump. Alarm relays are optional and if included,
that option will be checked below. There is no internal zero/span gas/oven option available for this
model. The analyzer may have one or two analysis ranges with or without autoranging as listed below.
This model is similar to the EH version but does not have a sample bypass line. An optional
paramagnetic oxygen sensor is available for oxygen analysis in this version.
Converter Options
The 9110 is equipped with an internal Hicon thermal converter as standard equipment. Other
converters are available for the EH version as follows:
Internal Hicon (standard) External Hicon (2
Internal Moly External Moly (2
nd
set of rack mounts req’d)
nd
set of rack mounts req’d)
Teledyne Analytical Instruments iii
Model 9110T NOx Analyzer Specific Configuration
Power Requirements
This Model 9110E is configured to operate from the following AC Power source:
100-120 VAC 60 Hz 220-240 VAC 60 Hz 100V 60 Hz
100-120 VAC 50 Hz 220-240 VAC 50 Hz 100V 50 Hz
Analog Output Signals
Analog output signals are available at A1, A2, and A3 on the rear panel. This instrument is configured
with the following analog outputs:
A1(NOx): 4-20 mA
A2 (NO): 0-5 V A2(NO): 4-20 mA
A3 (NO
): 0-5 V A2(NO2): 4-20 mA
2
Range Mode
The analyzer can be designed with a single or dual analysis ranges with auto-ranging or dual
independent ranges. This analyzer is configured with the following range mode:
Single Range:
Dual Range/Auto-ranging:
Low Range: Low Range:
High Range: High Range:
Dual Range/Independent:
Gas:
Selected Options for the Model 9110T
Mounting Options
19” rack mounting with 26” sliders with ears
19” rack mounting with ears only
Pump Mounting Options
None
Rack mounting hardware
Rear Panel Gas Fittings
1/4” SS Standard
6 mm SS Optional
Teledyne Analytical Instruments iv
Model 9110TH NOx Analyzer Specific Configuration
Valve Options
No Valves
Internal SS Zero/Span Valves
Second Range Span Valve
Internal Zero/Span Valves with Oven (Not available for 9110EH/EM)
Internal Zero/Span Valves with Oven and Permeation Tube (Not available for 9110EH)
The permeation tube option installed depends on the sample gas and the effusion rate.
The specific permeation tube in this instrument is listed below:
Permeation tube Installed:
Alarm Relay Option
This option includes two concentration alarm relays.
Oxygen Sensor
This analyzer is equipped with a paramagnetic oxygen sensor for measuring the oxygen concentration
over the range of 0-25%
Gas Conditioner
A gas conditioner/dryer permeation gas exchange tube is installed for removing H2O and ammonia
from the sample stream. This item is required for EN certificatation.
Oxygenator
For applications where background gas less than 2% oxygen and using a Moly converter.
Remote Operation for Purged Enclosure
The operator interface is duplicated with switches mounted on the front door of the enclosure allowing
operation without compromising purge integrity.
Background Gas:
Notes:
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Model 9110T NOx Analyzer Specific Configuration
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Model 9110TH NOx Analyzer Safety Messages
SAFETY MESSAGES
Important safety messages are provided throughout this manual for the purpose of avoiding personal
injury or instrument damage. Please read these messages carefully. Each safety message is associated
with a safety alert symbol, and are placed throughout this manual and inside the instrument. The symbols
with messages are defined as follows:
WARNING: Electrical Shock Hazard
HAZARD: Strong oxidizer
GENERAL WARNING/CAUTION: Read the accompanying message for
specific information.
CAUTION: Hot Surface Warning
Do Not Touch: Touching some parts of the instrument without protection or
proper tools could result in damage to the part(s) and/or the instrument.
Technician Symbol: All operations marked with this symbol are to be
performed by qualified maintenance personnel only.
Electrical Ground: This symbol inside the instrument marks the central
safety grounding point for the instrument.
Note
CAUTION
GENERAL SAFETY HAZARD
The T100 Analyzer should only be used for the purpose and in the
manner described in this manual. If you use the T100 in a manner other
than that for which it was intended, unpredictable behavior could ensue
with possible hazardous consequences.
NEVER use any gas analyzer to sample combustible gas(es).
Technical Assistance regarding the use and maintenance of the 9110T or
any other Teledyne product can be obtained by contacting Teledyne’s
Customer Service Department:
Phone: 626-934-1500
Email: ask_tai@teledyne.com
or by accessing various service options on our website at
http://www.teledyne-ai.com/.
Teledyne Analytical Instruments vii
Model 9110T NOx Analyzer Safety Messages
CONSIGNES DE SÉCURITÉ
Des consignes de sécurité importantes sont fournies tout au long du présent manuel dans le but d’éviter des
blessures corporelles ou d’endommager les instruments. Veuillez lire attentivement ces consignes. Chaque
consigne de sécurité est représentée par un pictogramme d’alerte de sécurité; ces pictogrammes se retrouvent
dans ce manuel et à l’intérieur des instruments. Les symboles correspondent aux consignes suivantes :
AVERTISSEMENT : Risque de choc électrique
DANGER : Oxydant puissant
AVERTISSEMENT GÉNÉRAL / MISE EN GARDE : Lire la consigne
complémentaire pour des renseignements spécifiques
MISE EN GARDE : Surface chaude
Ne pas toucher : Toucher à certaines parties de l’instrument sans protection ou
sans les outils appropriés pourrait entraîner des dommages aux pièces ou à
l’instrument.
Pictogramme « technicien » : Toutes les opérations portant ce symbole doivent
être effectuées uniquement par du personnel de maintenance qualifié.
Mise à la terre : Ce symbole à l’intérieur de l’instrument détermine le point central
de la mise à la terre sécuritaire de l’instrument.
MISE EN GARDE
Cet instrument doit être utilisé aux fins décrites et de la manière décrite dans
ce manuel. Si vous utilisez cet instrument d’une autre manière que celle pour
laquelle il a été prévu, l’instrument pourrait se comporter de façon imprévisible
et entraîner des conséquences dangereuses.
NE JAMAIS utiliser un analyseur de gaz pour échantillonner des gaz
combustibles!
Teledyne Analytical Instruments viii
Model 9110TH NOx Analyzer Safety Messages
ABOUT THIS MANUAL
This manual describes operation, specifications, and maintenance for the Model 9110T.
In addition this manual contains important SAFETY messages for this instrument. It is strongly
recommended that you read that operation manual in its entirety before operating the instrument.
ORGANIZATION
This manual is divided among three main parts and a collection of appendices at the end.
Part I contains introductory information that includes an overview of the analyzer, specifications,
descriptions of the available options, installation and connection instructions, and the initial calibration
and functional checks.
Part II comprises the operating instructions, which include initial functional checks and calibration,
basic, advanced and remote operation, advanced calibration, diagnostics, testing, and ends with specifics
of calibrating for use in EPA monitoring.
Part III provides detailed technical information, starting with maintenance, troubleshooting and service
with Frequently Asked Questions (FAQs), followed by principles of operation, and a glossary. It also
contains a special section dedicated to providing information about electro-static discharge and
protecting against its consequences.
The appendices at the end of this manual provide support information such as, version-specific software
documentation, lists of spare parts and recommended stocking levels, and schematics.
CONVENTIONS USED
In addition to the safety symbols as presented in the Important Safety Information page, this manual
provides special notices related to the safety and effective use of the analyzer and other pertinent
information.
Special Notices appear as follows:
ATTENTION
IMPORTANT
COULD DAMAGE INSTRUMENT AND VOID WARRANTY
This special notice provides information to avoid damage to your
instrument and possibly invalidate the warranty.
IMPACT ON READINGS OR DATA
Could either affect accuracy of instrument readings or cause loss of data.
Note Pertinent information associated with the proper care, operation or
maintenance of the analyzer or its parts.
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Model 9110T NOx Analyzer Safety Messages
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Model 9110TH NOx Analyzer Table of Contents
TABLE OF CONTENTS
Information About the Specific Configuration of Your Model 9110T NOX Analyzer ..............................................................iii
Mounting Options .............................................................................................................................................................. iv
Pump Mounting Options .................................................................................................................................................... iv
Rear Panel Gas Fittings.................................................................................................................................................... iv
Safety Messages ....................................................................................................................................................................vii
About This Manual ................................................................................................................................................................. ix
PART I GENERAL INFORMATION .................................................................................................................................... 21
1. Introduction, Features and Options ........................................................................................................................................ 23
1.1. Overview ........................................................................................................................................................................ 23
1.2. Features ......................................................................................................................................................................... 23
1.3. Documentation ............................................................................................................................................................... 24
1.4. Options ........................................................................................................................................................................... 24
2. Specifications, Approvals, & Compliance ............................................................................................................................... 27
2.1. Specifications ................................................................................................................................................................. 27
2.2. EPA Equivalency Designation ........................................................................................................................................ 28
2.3. Approvals and Certifications ........................................................................................................................................... 29
2.3.1. Safety ..................................................................................................................................................................... 29
2.3.2. EMC ........................................................................................................................................................................ 29
2.3.3. Other Type Certifications ........................................................................................................................................ 29
3. Getting Started 31
3.1. Unpacking the 9110T Analyzer ...................................................................................................................................... 31
3.1.1. Ventilation Clearance .............................................................................................................................................. 32
3.2. Instrument Layout ........................................................................................................................................................... 32
3.2.1. Front Panel ............................................................................................................................................................. 33
3.2.2. Rear Panel .............................................................................................................................................................. 37
3.2.3. Internal Chassis Layout .......................................................................................................................................... 38
3.3. Connections and Setup .................................................................................................................................................. 41
3.3.1. Electrical Connections ............................................................................................................................................ 41
3.3.2. Pneumatic Connections .......................................................................................................................................... 55
3.4. Startup, Functional Checks, and Initial Calibration ......................................................................................................... 74
3.4.1. Start Up .................................................................................................................................................................. 74
3.4.2. Warning Messages ................................................................................................................................................. 75
3.4.3. Functional Checks .................................................................................................................................................. 77
3.4.4. Initial Calibration ..................................................................................................................................................... 77
3.4.4.1. Interferents .......................................................................................................................................................... 78
PART II – OPERATING INSTRUCTIONS ............................................................................................................................ 85
4. Overview of Operating Modes ................................................................................................................................................ 87
4.1. Sample Mode ................................................................................................................................................................. 88
4.1.1. Test Functions ........................................................................................................................................................ 88
4.1.2. Warning Messages ................................................................................................................................................. 91
4.2. Calibration Mode ............................................................................................................................................................ 92
4.3. Setup Mode .................................................................................................................................................................... 92
4.3.1. Password Security .................................................................................................................................................. 93
4.3.2. Primary Setup Menu ............................................................................................................................................... 93
4.3.3. Secondary Setup Menu (SETUP MORE) ............................................................................................................ 93
5. Setup Menu 95
5.1. SETUP CFG: Configuration Information .................................................................................................................... 95
5.2. SETUP ACAL: Automatic Calibration Option .............................................................................................................. 95
5.3. SETUP DAS: Internal Data Acquisition System .......................................................................................................... 95
5.4. SETUP RNGE: Analog Output Reporting Range Configuration ................................................................................. 96
5.4.1. 9110T Physical Ranges .......................................................................................................................................... 96
5.4.2. 9110T Analog Output Reporting Ranges ................................................................................................................ 96
5.4.3. SETUP RNGE MODE .................................................................................................................................... 98
5.5. SETUP PASS: Password Protection ........................................................................................................................ 106
5.6. SETUP CLK: Setting the Internal Time-of-Day Clock .............................................................................................. 108
5.6.1. Setting the Time of Day ........................................................................................................................................ 108
5.6.2. Adjusting the Internal Clock’s Speed .................................................................................................................... 109
5.7. SETUP COMM: Communications Ports ................................................................................................................... 110
5.7.1. ID (Machine Identification) .................................................................................................................................... 110
5.7.2. INET (Ethernet) .................................................................................................................................................... 111
5.7.3. COM1[COM2] (Mode, Baude Rate and Test Port) ............................................................................................... 111
5.8. SETUP VARS: Variables Setup and Definition ........................................................................................................ 111
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Model 9110T NOx Analyzer Table of Contents
5.9. SETUP Diag: Diagnostics Functions ........................................................................................................................ 114
5.9.1. Signal I/O .............................................................................................................................................................. 116
5.9.2. Analog Output (DIAG AOUT) ................................................................................................................................ 117
5.9.3. Analog I/O Configuration (DIAG AIO) ................................................................................................................... 117
5.9.4. Test Chan Output (Selecting a Test Channel Function for Output A4) ................................................................. 132
5.9.5. Optic Test ............................................................................................................................................................. 133
5.9.6. Electrical Test ....................................................................................................................................................... 134
5.9.7. Ozone Gen Override ............................................................................................................................................. 134
5.9.8. Flow Calibration .................................................................................................................................................... 134
6. Communications Setup and Operation ................................................................................................................................ 135
6.1. Data Terminal / Communication Equipment (DTE DEC) .............................................................................................. 135
6.2. Communication Modes, Baud Rate and Port Testing ................................................................................................... 135
6.2.1. Communication Modes ......................................................................................................................................... 135
6.2.2. Com Port Baud Rate ............................................................................................................................................. 138
6.2.3. Com Port Testing .................................................................................................................................................. 138
6.3. RS-232 ......................................................................................................................................................................... 139
6.4. RS-485 (Option) ........................................................................................................................................................... 140
6.5. Ethernet ........................................................................................................................................................................ 140
6.5.1. Configuring Ethernet Communication Manually (Static IP Address) ..................................................................... 140
6.5.2. Configuring Ethernet Communication Using Dynamic Host Configuration Protocol (DHCP) ................................ 143
6.6. USB Port for Remote Access ....................................................................................................................................... 147
6.7. Communications Protocols ........................................................................................................................................... 149
6.7.1. MODBUS .............................................................................................................................................................. 149
6.7.2. Hessen ................................................................................................................................................................. 151
7. Data Acquisition System (DAS) and APICOM ..................................................................................................................... 163
7.1. DAS Structure .............................................................................................................................................................. 164
7.1.1. DAS Channels ...................................................................................................................................................... 164
7.1.2. Viewing DAS Data and Settings ........................................................................................................................... 168
7.1.3. Editing DAS Data Channels .................................................................................................................................. 169
7.2. Remote DAS Configuration .......................................................................................................................................... 181
7.2.1. DAS Configuration via APICOM ........................................................................................................................... 181
7.2.2. DAS Configuration via Terminal Emulation Programs .......................................................................................... 183
8. Remote Operation 185
8.1. Computer Mode ............................................................................................................................................................ 185
8.1.1. Remote Control via APICOM ................................................................................................................................ 185
8.2. Interactive Mode ........................................................................................................................................................... 185
8.2.1. Remote Control via a Terminal Emulation Program.............................................................................................. 185
8.3. Remote Access by Modem ........................................................................................................................................... 188
8.4. Password Security for Serial Remote Communications ............................................................................................... 191
9. Calibration Procedures 193
9.1. Before Calibration ......................................................................................................................................................... 194
9.1.1. Required Equipment, Supplies, and Expendables ................................................................................................ 194
9.1.2. Calibration Gases ................................................................................................................................................. 195
9.1.3. Data Recording Devices ....................................................................................................................................... 196
9.1.4. NO2 Conversion Efficiency (CE) ........................................................................................................................... 197
9.2. Manual Calibration Checks and Calibration of the 9110T Analyzer in its Base Configuration ...................................... 197
9.2.1. Setup for Basic Calibration Checks and Calibration of the 9110T analyzer. ......................................................... 197
9.2.2. Performing a Basic Manual Calibration Check ..................................................................................................... 199
9.2.3. Performing a Basic Manual Calibration ................................................................................................................. 199
9.3. Manual Calibration with the Internal Span Gas Generator ........................................................................................... 202
9.3.1. Performing “Precision” Manual Calibration when Internal Span Gas (IZS) Generator Option is Present ............. 202
9.3.2. Setup for Calibration with the Internal Span Gas Generator ................................................................................. 203
9.3.3. CAL On NO2 Feature ............................................................................................................................................ 203
9.3.4. Performing a Manual Calibration Check with the Internal Span Gas Generator ................................................... 205
9.3.5. Performing a Manual Calibration with the Internal Span Gas Generator .............................................................. 206
9.4. Manual Calibration and Cal Checks with the Valve Options Installed .......................................................................... 209
9.4.1. Setup for Calibration Using Valve Options ............................................................................................................ 209
9.4.2. Manual Calibration Checks with Valve Options Installed ...................................................................................... 210
9.4.3. Manual Calibration Using Valve Options .............................................................................................................. 211
9.5. Automatic Zero/Span Cal/Check (AutoCal) .................................................................................................................. 213
9.5.1. SETUP ACAL: Programming and AUTO CAL Sequence ................................................................................ 216
9.6. Calibration Quality Analysis .......................................................................................................................................... 219
9.7. Gas Flow Calibration .................................................................................................................................................... 220
10. EPA Protocol Calibration .................................................................................................................................................... 221
10.1. 9110T Calibration – General Guidelines .................................................................................................................... 221
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Model 9110TH NOx Analyzer Table of Contents
10.2. Calibration Equipment, Supplies, and Expendables ................................................................................................... 222
10.2.1. Spare Parts and Expendable Supplies ............................................................................................................... 222
10.2.2. Calibration Gas and Zero Air Sources ................................................................................................................ 223
10.2.3. Data Recording Device ....................................................................................................................................... 223
10.2.4. Record Keeping .................................................................................................................................................. 223
10.3. Calibration Frequency ................................................................................................................................................ 223
10.4. Level 1 Calibrations versus Level 2 Checks ............................................................................................................... 224
10.5. Gas Phase Titration (GPT) ......................................................................................................................................... 225
10.5.1. GPT Principle of Operation ................................................................................................................................. 225
10.5.2. GPT Calibrator Check Procedure ....................................................................................................................... 225
10.6. GPT Multipoint Calibration Procedure ........................................................................................................................ 228
10.6.1. Set Up for GPT Multipoint Calibration of the 9110T ............................................................................................ 229
10.6.2. Zero Calibration .................................................................................................................................................. 230
10.6.3. Span Calibration ................................................................................................................................................. 230
10.7. GPT NO2 Check ......................................................................................................................................................... 231
10.8. Other Quality Assurance Procedures ......................................................................................................................... 232
10.8.1. Summary of Quality Assurance Checks ............................................................................................................. 232
10.8.2. Short Calibration Checks .................................................................................................................................... 233
10.8.3. Zero/Span Check Procedures ............................................................................................................................ 233
10.8.4. Precision Check .................................................................................................................................................. 234
10.9. Certification of Working Standards ............................................................................................................................. 234
10.10. References ............................................................................................................................................................... 235
PART III – Maintenance and Service .................................................................................................................................. 237
11. Instrument Maintenance ..................................................................................................................................................... 239
11.1. Maintenance Schedule ............................................................................................................................................... 239
11.2. Predictive Diagnostics ................................................................................................................................................ 241
11.3. Maintenance Procedures ............................................................................................................................................ 241
11.3.1. Replacing the Sample Particulate Filter .............................................................................................................. 242
11.3.2. Changing the O3 Dryer Particulate Filter ............................................................................................................. 243
11.3.3. Changing the Ozone Cleanser Chemical ............................................................................................................ 244
11.3.4. Maintaining the External Sample Pump (Pump Pack) ........................................................................................ 247
11.3.5. Changing the Pump DFU Filter ........................................................................................................................... 247
11.3.6. Changing the Internal Span Gas Generator Permeation Tube ........................................................................... 249
11.3.7. Changing the External Zero Air Scrubber (OPT 86C) ......................................................................................... 249
11.3.8. Changing the NO2 Converter .............................................................................................................................. 252
11.3.9. Cleaning the Reaction Cell ................................................................................................................................. 254
11.3.10. Replacing Critical Flow Orifices ........................................................................................................................ 256
11.3.11. Checking for Light Leaks .................................................................................................................................. 257
11.3.12. Checking for Pneumatic Leaks ......................................................................................................................... 258
12. Troubleshooting & Service ................................................................................................................................................. 261
12.1. General Troubleshooting ............................................................................................................................................ 261
12.1.1. Fault Diagnosis with WARNING Messages ........................................................................................................ 262
12.1.2. Fault Diagnosis With Test Functions .................................................................................................................. 266
12.1.3. DIAG SIGNAL I/O: Using the Diagnostic Signal I/O Function ....................................................................... 267
12.2. Using the Analog Output Test Channel ...................................................................................................................... 269
12.3. Using the Internal Electronic Status LEDs .................................................................................................................. 270
12.3.1. CPU Status Indicator .......................................................................................................................................... 270
12.3.2. Relay PCA Status LEDs ..................................................................................................................................... 270
12.4. Gas Flow Problems .................................................................................................................................................... 272
12.4.1. Zero or Low Flow Problems ................................................................................................................................ 272
12.5. Calibration Problems .................................................................................................................................................. 276
12.5.1. Negative Concentrations .................................................................................................................................... 276
12.5.2. No Response ...................................................................................................................................................... 277
12.5.3. Unstable Zero and Span ..................................................................................................................................... 277
12.5.4. Inability to Span - No SPAN Button (CALS) ........................................................................................................ 278
12.5.5. Inability to Zero - No ZERO Button (CALZ) ......................................................................................................... 278
12.5.6. Non-Linear Response ......................................................................................................................................... 279
12.5.7. Discrepancy Between Analog Output and Display ............................................................................................. 280
12.5.8. Discrepancy Between NO and NOX slopes ........................................................................................................ 280
12.6. Other Performance Problems ..................................................................................................................................... 281
12.6.1. Excessive Noise ................................................................................................................................................. 281
12.6.2. Slow Response ................................................................................................................................................... 281
12.6.3. Auto Zero Warnings ........................................................................................................................................... 282
12.7. Subsystem Checkout.................................................................................................................................................. 283
12.7.1. AC Main Power ................................................................................................................................................... 283
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Model 9110T NOx Analyzer Table of Contents
12.7.2. DC Power Supply ............................................................................................................................................... 283
12.7.3. I2C Bus ............................................................................................................................................................... 285
12.7.4. LCD/Display Module ........................................................................................................................................... 285
12.7.5. Relay PCA .......................................................................................................................................................... 285
12.7.6. Motherboard ....................................................................................................................................................... 285
12.7.7. Pressure / Flow Sensor Assembly ...................................................................................................................... 289
12.7.8. CPU .................................................................................................................................................................... 290
12.7.9. RS-232 Communications .................................................................................................................................... 290
12.7.10. NO2 NO Converter ....................................................................................................................................... 291
12.7.11. Simplified GPT Calibration ................................................................................................................................ 296
12.7.12. Photomultiplier Tube (PMT) Sensor Module ..................................................................................................... 300
12.7.13. PMT Preamplifier Board ................................................................................................................................... 302
12.7.14. PMT Temperature Control PCA ........................................................................................................................ 303
12.7.15. O3 Generator .................................................................................................................................................... 304
12.7.16. Internal Span Gas Generator and Valve Options ............................................................................................. 305
12.7.17. Temperature Sensor ......................................................................................................................................... 306
12.8. Service Procedures .................................................................................................................................................... 308
12.8.1. Disk-On-Module Replacement Procedure .......................................................................................................... 308
12.8.2. O3 Generator Replacement ................................................................................................................................ 309
12.8.3. Sample and Ozone (Perma Pure®) Dryer Replacement ..................................................................................... 309
12.8.4. PMT Sensor Hardware Calibration ..................................................................................................................... 310
12.8.5. Replacing the PMT, HVPS or TEC ..................................................................................................................... 312
12.8.6. Removing / Replacing the Relay PCA from the Instrument ................................................................................ 315
12.9. Frequently Asked Questions ...................................................................................................................................... 316
12.10. Technical Assistance ................................................................................................................................................ 318
13. Principles of Operation ....................................................................................................................................................... 319
13.1. Measurement Principle ............................................................................................................................................... 319
13.1.1. Chemiluminescence Creation in the 9110T Reaction Cell .................................................................................. 319
13.1.2. Chemiluminescence Detection in the 9110T Reaction Cell ................................................................................ 320
13.1.3. NOX and NO2 Determination ............................................................................................................................... 321
13.1.4. Auto Zero ............................................................................................................................................................ 322
13.1.5. Measurement Interferences ................................................................................................................................ 323
13.2. Pneumatic Operation .................................................................................................................................................. 326
13.2.1. Sample Gas Flow ............................................................................................................................................... 326
13.2.2. Flow Rate Control - Critical Flow Orifices ........................................................................................................... 330
13.2.3. Ozone Gas Generation and Air Flow .................................................................................................................. 332
13.2.4. Pneumatic Sensors ............................................................................................................................................. 335
13.3. Electronic Operation ................................................................................................................................................... 338
13.3.1. Overview ............................................................................................................................................................. 338
13.3.2. CPU .................................................................................................................................................................... 339
13.3.3. Motherboard ....................................................................................................................................................... 340
13.3.4. Relay PCA .......................................................................................................................................................... 345
13.4. Sensor Module, Reaction Cell .................................................................................................................................... 351
13.5. Photo Multiplier Tube (PMT) ....................................................................................................................................... 352
13.5.1. PMT Preamplifier ................................................................................................................................................ 353
13.5.2. PMT Cooling System .......................................................................................................................................... 355
13.6. Pneumatic Sensor Board ............................................................................................................................................ 356
13.7. Power Supply/Circuit Breaker ..................................................................................................................................... 357
13.7.1. AC Power Configuration ..................................................................................................................................... 358
13.8. Front Panel Touchscreen/Display Interface ................................................................................................................ 363
13.8.1. LVDS Transmitter Board ..................................................................................................................................... 364
13.8.2. Front Panel Touchscreen/Display Interface PCA ............................................................................................... 364
13.9. Software Operation .................................................................................................................................................... 364
13.9.1. Adaptive Filter ..................................................................................................................................................... 365
13.9.2. Temperature/Pressure Compensation (TPC) ..................................................................................................... 365
13.9.3. Calibration - Slope and Offset ............................................................................................................................. 365
14. A Primer on Electro-Static Discharge ................................................................................................................................. 367
14.1. How Static Charges are Created ................................................................................................................................ 367
14.2. How Electro-Static Charges Cause Damage .............................................................................................................. 368
14.3. Common Myths About ESD Damage ......................................................................................................................... 369
14.4. Basic Principles of Static Control ................................................................................................................................ 369
14.4.1. General Rules ..................................................................................................................................................... 369
14.5. Basic anti-ESD Procedures for Analyzer Repair and Maintenance ............................................................................ 371
14.5.1. Working at the Instrument Rack ......................................................................................................................... 371
14.5.2. Working at an Anti-ESD Work Bench ................................................................................................................. 371
Teledyne Analytical Instruments 14
Model 9110TH NOx Analyzer Table of Contents
14.5.3. Transferring Components Between Rack and Bench ......................................................................................... 372
14.5.4. Opening Shipments from TAI Customer Service ................................................................................................ 372
14.5.5. Packing Components for Return to TAI Customer Service ................................................................................. 373
Glossary .............................................................................................................................................................................. 375
APPENDIX A - VERSION SPECIFIC SOFTWARE DOCUMENTATION
APPENDIX B - SPARE PARTS
APPENDIX C - REPAIR QUESTIONNAIRE
APPENDIX D - ELECTRONIC SCHEMATICS
Teledyne Analytical Instruments 15
Model 9110T NOx Analyzer Table of Contents
FIGURES
Figure 3-1: Front Panel Layout....................................................................................................................... 33
Figure 3-2: Display Screen and Touch Control .............................................................................................. 34
Figure 3-3: Display/Touch Control Screen Mapped to Menu Charts ............................................................. 36
Figure 3-4: Rear Panel Layout – Base Unit ................................................................................................... 37
Figure 3-5: Internal Layout – Top View with IZS Option ................................................................................ 39
Figure 3-6: Internal Layout - Top View Showing Other Options .................................................................... 40
Figure 3-7: Analog In Connector .................................................................................................................... 42
Figure 3-8: Analog Output Connector ............................................................................................................ 43
Figure 3-9: Current Loop Option Installed on the Motherboard ..................................................................... 44
Figure 3-10: Status Output Connector ............................................................................................................. 45
Figure 3-11: Energizing the 9110T Control Inputs ........................................................................................... 46
Figure 3-12: Concentration Alarm Relay .......................................................................................................... 47
Figure 3-13 Rear Panel Connector Pin-Outs for RS-232 Mode ...................................................................... 50
Figure 3-14: Default Pin Assignments for CPU COMM Port Connector (RS-232). ......................................... 51
Figure 3-15: Jumper and Cables for Multidrop Mode....................................................................................... 53
Figure 3-16: RS-232-Multidrop PCA Host/Analyzer Interconnect Diagram ..................................................... 54
Figure 3-17: Gas Line Connections from Calibrator – Basic 9110T Configuration .......................................... 59
Figure 3-18: Gas Line Connections from Bottled Span Gas – Basic 9110T Configuration ............................. 60
Figure 3-19: Pneumatics, Basic Configuration ................................................................................................. 62
Figure 3-20: Rear Panel Layout with Z/S Valve Options (OPT 50A) ............................................................... 63
Figure 3-21: Gas Line Connections for 9110T with Z/S Valves Option (OPT 50A) ......................................... 63
Figure 3-22: Pneumatics with Zero/Span Valves OPT 50A ............................................................................. 65
Figure 3-23: Rear Panel Layout with Ambient Zero/Pressurized Span Valves OPT 50B ................................ 66
Figure 3-24: Gas Line Connection w/Ambient Zero/Pressurized Span Valves (OPT 50B) ............................. 67
Figure 3-25: Pneumatics with Ambient Zero/Pressurized Span Valves (OPT 50B) ........................................ 68
Figure 3-26: Rear Panel Layout with Internal Span Source (IZS) OPT 50G ................................................... 70
Figure 3-27: Pneumatics with the Internal Span Gas Generator (OPT 50G) .................................................. 71
Figure 3-28: Pneumatics for Sample Conditioner OPT 86A ............................................................................ 72
Figure 3-29: Pneumatics for External Zero Air Scrubber (OPT 86C) for Z/S Valves ....................................... 73
Figure 4-1: Front Panel Display ...................................................................................................................... 87
Figure 4-2: Viewing 9110T Test Functions .................................................................................................... 90
Figure 5-1: Analog Output Connector Pin Out ............................................................................................... 97
Figure 5-2. SETUP – COMM Menu .............................................................................................................110
Figure 5-3. COMM– Machine ID ..................................................................................................................111
Figure 5-4: Accessing the DIAG Submenus ................................................................................................115
Figure 5-5: Accessing the Analog I/O Configuration Submenus ..................................................................118
Figure 5-6: Setup for Checking / Calibrating DCV Analog Output Signal Levels .........................................123
Figure 5-7: Setup for Checking / Calibration Current Output Signal Levels Using an Ammeter .................125
Figure 5-8: Alternative Setup Using 250Ω Resistor for Checking Current Output Signal Levels ................127
Figure 6-1. COMM – Communication Modes Setup ....................................................................................137
Figure 6-2. COMM – COMM Port Baud Rate ..............................................................................................138
Figure 6-3. COMM – COM1 Test Port .........................................................................................................139
Figure 6-4. COMM - LAN /Internet Manual Configuration ............................................................................142
Figure 6-5. COMM – LAN / Internet Automatic Configuration (DHCP) ........................................................145
Figure 6-6. COMM – Change Hostname ....................................................................................................146
Figure 7-1: Default DAS Channels Setup ....................................................................................................167
Figure 7-2: APICOM Remote Control Program Interface ............................................................................181
Figure 7-3: Sample APICOM User Interface for Configuring the DAS .........................................................182
Figure 7-4: DAS Configuration Through a Terminal Emulation Program ....................................................183
Figure 8-1: Remote Access by Modem ........................................................................................................189
Figure 9-1: Set up for Manual Calibrations/Checks of 9110T’s in Base Configuration w/ a Gas Dilution
Calibrator ...................................................................................................................................198
Figure 9-2: Set up for Manual Calibrations/Checks of 9110T’s in Base Configuration w/ Bottled Gas .......198
Figure 9-3: Pneumatic Connections for 9110T Precision Calibration when IZS Generator Present ...........202
Figure 9-4: Pneumatic Connections for Manual Calibration/Checks with the Internal Span Gas Generator203
Teledyne Analytical Instruments 16
Model 9110TH NOx Analyzer Table of Contents
Figure 10-1: GPT Calibration System ............................................................................................................229
Figure 11-1 Replacing the Particulate Filter ..................................................................................................242
Figure 11-2: Particle Filter on O3 Supply Air Dryer ........................................................................................243
Figure 11-3: Ozone Cleanser Assembly ........................................................................................................245
Figure 11-4: Zero Air Scrubber Assembly ......................................................................................................251
Figure 11-5: NO2 Converter Assembly ...........................................................................................................253
Figure 11-6: Reaction Cell Assembly .............................................................................................................255
Figure 11-7: Critical Flow Orifice Assembly ...................................................................................................256
Figure 12-1: Example of Signal I/O Function .................................................................................................268
Figure 12-2: CPU Status Indicator .................................................................................................................270
Figure 12-3: Relay PCA Status LEDS Used for Troubleshooting ..................................................................271
Figure 12-4: Location of DC Power Test Points on Relay PCA .....................................................................284
Figure 12-5: Typical Set Up of Status Output Test ........................................................................................287
Figure 12-6: Pressure / Flow Sensor Assembly .............................................................................................289
Figure 12-7: Setup for determining NO2 NO Efficiency – 9110T Base Configuration ...............................293
Figure 12-8: Pre-Amplifier Board Layout ........................................................................................................311
Figure 12-9: 9110T Sensor Assembly ............................................................................................................313
Figure 12-10: Relay PCA with AC Relay Retainer In Place .............................................................................315
Figure 12-11: Relay PCA Mounting Screw Locations .....................................................................................316
Figure 13-1: Reaction Cell with PMT Tube and Optical Filter ........................................................................321
Figure 13-2: 9110T Sensitivity Spectrum .......................................................................................................321
Figure 13-3: NO2 NO Conversion ...............................................................................................................322
Figure 13-4: Pneumatic Flow During the Auto Zero Cycle .............................................................................323
Figure 13-5: Internal Gas Flow for Basic 9110T with External Pump ............................................................327
Figure 13-6: Basic Internal Gas Flow for Basic 9110T with Internal Pump ...................................................328
Figure 13-7. Vacuum Manifold, Standard Configuration ................................................................................329
Figure 13-8: Flow Control Assembly & Critical Flow Orifice ..........................................................................330
Figure 13-9: Location of Flow Control Assemblies & Critical Flow Orifices ...................................................331
Figure 13-10: Ozone Generator Principle ........................................................................................................333
Figure 13-11: Semi-Permeable Membrane Drying Process ............................................................................334
Figure 13-12: 9110T Perma Pure® Dryer .........................................................................................................334
Figure 13-13: 9110T Electronic Block Diagram ...............................................................................................338
Figure 13-14: CPU Board .................................................................................................................................340
Figure 13-15: Relay PCA Layout (P/N 045230100) .........................................................................................345
Figure 13-16: Relay PCA P/N 045230100 with AC Relay Retainer in Place ...................................................346
Figure 13-17: Status LED Locations – Relay PCA ...........................................................................................348
Figure 13-18: Heater Control Loop Block Diagram. .........................................................................................349
Figure 13-19: Thermocouple Configuration Jumper (JP5) Pin-Outs ................................................................351
Figure 13-20: 9110T Sensor Module Assembly ...............................................................................................352
Figure 13-21: Basic PMT Design .....................................................................................................................353
Figure 13-22: PMT Preamp Block Diagram .....................................................................................................354
Figure 13-23: Typical Thermo-Electric Cooler .................................................................................................355
Figure 13-24: PMT Cooling System Block Diagram .........................................................................................356
Figure 13-25: Power Distribution Block Diagram .............................................................................................358
Figure 13-26: Location of AC power Configuration Jumpers ...........................................................................359
Figure 13-27: Pump AC Power Jumpers (JP7) ................................................................................................360
Figure 13-28: Typical Set Up of AC Heater Jumper Set (JP2) ........................................................................361
Figure 13-29: Typical Jumper Set (JP2) Set Up of Heaters ............................................................................362
Figure 13-30: Front Panel and Display Interface Block Diagram .....................................................................363
Figure 13-31: Basic Software Operation ..........................................................................................................364
Figure 14-1: Triboelectric Charging ................................................................................................................367
Figure 14-2: Basic anti-ESD Workbench .......................................................................................................370
Teledyne Analytical Instruments 17
Model 9110T NOx Analyzer Table of Contents
TABLES
Table 1-1. Analyzer Options .......................................................................................................................... 24
Table 2-2: Software Settings for EPA Equivalence....................................................................................... 28
Table 3-1: Ventilation Clearance ................................................................................................................... 32
Table 3-5: Analog Output Pin Assignments .................................................................................................. 43
Table 3-6: Status Output Pin Assignments ................................................................................................... 45
Table 3-7: Control Input Pin Assignments .................................................................................................... 46
Table 3-8: NIST-SRM's Available for Traceability of NOx Calibration Gases ................................................ 57
Table 3-9: Zero/Span Valves Operating States OPT 50A ............................................................................ 65
Table 3-10: Valve Operating States OPT 50B installed .................................................................................. 69
Table 3-11: Internal Span Gas Generator Valve Operating States OPT 50G ................................................ 71
Table 3-12: Possible Warning Messages at Start-Up ..................................................................................... 76
Table 4-1: Analyzer Operating Modes .......................................................................................................... 88
Table 4-2: Test Functions Defined ................................................................................................................ 88
Table 4-3: Warning Messages Defined ......................................................................................................... 91
Table 4-4: Primary Setup Mode Features and Functions ............................................................................. 93
Table 4-5: Secondary Setup Mode Features and Functions ........................................................................ 93
Table 5-1: IND Mode Analog Output Assignments ....................................................................................... 99
Table 5-2: Password Levels ........................................................................................................................106
Table 5-3: Variable Names (VARS) ............................................................................................................112
Table 5-4: Diagnostic Mode (DIAG) Functions ...........................................................................................114
Table 5-5: DIAG - Analog I/O Functions .....................................................................................................117
Table 5-6: Analog Output Voltage Range Min/Max ....................................................................................119
Table 5-7: Voltage Tolerances for the TEST CHANNEL Calibration ..........................................................123
Table 5-8: Current Loop Output Check .......................................................................................................127
Table 5-9: Test Channels Functions available on the 9110T’s Analog Output ...........................................132
Table 6-1: COMM Port Communication Modes ..........................................................................................135
Table 6-2: Ethernet Status Indicators .........................................................................................................140
Table 6-4: RS-232 Communication Parameters for Hessen Protocol ........................................................151
Table 6-5: Teledyne's Hessen Protocol Response Modes .........................................................................154
Table 6-6: Default Hessen Status Flag Assignments .................................................................................159
Table 7-1: Front Panel LED Status Indicators for DAS ...............................................................................163
Table 7-2: DAS Data Channel Properties ...................................................................................................164
Table 7-3: DAS Data Parameter Functions ................................................................................................172
Table 8-1: Terminal Mode Software Commands ........................................................................................186
Table 8-2: Teledyne API's Serial I/O Command Types ..............................................................................186
Table 9-1: IZS Option Valve States with CAL_ON_NO2 Turned ON ..........................................................203
Table 9-2: AUTOCAL Modes ......................................................................................................................213
Table 9-3: AutoCal Attribute Setup Parameters ..........................................................................................214
Table 9-4: Example AutoCal Sequence ......................................................................................................215
Table 9-5: Calibration Data Quality Evaluation ...........................................................................................219
Table 10-1: Activity Matrix for EPA Calibration Equipment and Supplies .....................................................222
Table 10-2: Definition of Level 1 and Level 2 Zero and Span Checks .........................................................224
Table 10-3: Activity Matrix for Data Quality ...................................................................................................233
Table 11-1: 9110T Maintenance Schedule ...................................................................................................240
Table 11-2: Predictive Uses for Test Functions ............................................................................................241
Table 12-1: Front Panel Warning Messages ................................................................................................264
Table 12-2: Test Functions - Indicated Failures ............................................................................................266
Table 12-3: Test Channel Outputs as Diagnostic Tools ...............................................................................269
Table 12-4: Relay PCA Watchdog LED Failure Indications ..........................................................................270
Table 12-5: Relay PCA Status LED Failure Indications ................................................................................271
Table 12-6: DC Power Test Point and Wiring Color Codes ..........................................................................284
Table 12-7: DC Power Supply Acceptable Levels ........................................................................................284
Table 12-8: Relay PCA Control Devices .......................................................................................................285
Table 12-9: Analog Output Test Function - Nominal Values Voltage Outputs .............................................286
Table 12-10: Status Outputs Check ................................................................................................................288
Table 12-11: 9110T Control Input Pin Assignments and Corresponding Signal I/O Functions ......................288
Teledyne Analytical Instruments 18
Model 9110TH NOx Analyzer Table of Contents
Table 13-1: List of Interferents ......................................................................................................................325
Table 13-2: 9110T Valve Cycle Phases ........................................................................................................329
Table 13-3: 9110T Gas Flow Rates ..............................................................................................................331
Table 13-4: Relay PCA Status LED’s ...........................................................................................................347
Table 13-5: Thermocouple Configuration Jumper (JP5) Pin-Outs ................................................................350
Table 13-6: AC Power Configuration for Internal Pumps (JP7) ....................................................................360
Table 13-7: Power Configuration for Standard AC Heaters (JP2) ................................................................361
Table 13-8: Power Configuration for Optional Heaters (JP6) .......................................................................362
Table 14-1: Static Generation Voltages for Typical Activities .......................................................................367
Table 14-2: Sensitivity of Electronic Devices to Damage by ESD ................................................................368
Teledyne Analytical Instruments 19
Model 9110T NOx Analyzer Table of Contents
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Teledyne Analytical Instruments 20
Model 9110TH NOx Analyzer Part I
PART I
GENERAL INFORMATION
Teledyne Analytical Instruments 21
Model 9110T NOx Analyzer Part I
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Teledyne Analytical Instruments 22
Model 9110TH NOx Analyzer Introduction
1. INTRODUCTION, FEATURES AND OPTIONS
1.1. OVERVIEW
The Model 9110T Nitrogen Oxides Analyzer uses chemiluminescence detection, coupled with
state-of-the-art microprocessor technology to provide the sensitivity, stability and ease of use
needed for ambient or dilution CEM monitoring requirements of nitric oxide (NO), nitrogen
dioxide (NO2) and the total nitrogen oxides (NOx). The instrument:
Calculates the amount of NO present by measuring the amount of chemiluminescence given off
when the sample gas is exposed to ozone (O3).
Uses a catalytic-reactive converter to convert any NO2 in the sample gas to NO, which is then
measured as above (including the original NO in the sample gas) and reported as NOx.
Since the density of the sample gas effects the brightness of the chemiluminescence reaction, the 9110T
software compensates for temperature and pressure changes.
Stability is further enhanced by an Auto-Zero feature which periodically redirects the gas flow through
the analyzer so that no chemiluminescence reaction is present in the sample chamber. The analyzer
measures this “dark” condition and uses the results as an offset, which is subtracted from the sensor
readings recorded while the instrument is measuring NO and NO
and dependable performance under the harshest operating conditions.
. The result gives a sensitive, accurate,
X
The 9110T analyzer’s multi-tasking software gives the ability to track and report a large number of
operational parameters in real time. These readings are compared to diagnostic limits kept in the
analyzers memory and should any fall outside of those limits the analyzer issues automatic warnings.
Built-in data acquisition capability, using the analyzer's internal memory, allows the logging of multiple
parameters including averaged or instantaneous concentration values, calibration data, and operating
parameters such as pressure and flow rate. Stored data are easily retrieved through the rear panel serial
or Ethernet ports via our APICOM software or from the front panel, allowing operators to perform
predictive diagnostics and enhanced data analysis by tracking parameter trends. Multiple averaging
periods of one minute to 365 days are available for over a period of one year.
1.2. FEATURES
Some of the other exceptional features of your 9110T Nitrogen Oxides Analyzer are:
Ranges, 0-50 ppb to 0-20 ppm, user selectable
Independent ranges and auto ranging
Large, vivid, and durable graphics display with touch screen interface
Microprocessor controlled for versatility
Multi-tasking software to allow viewing test variables while operating
Continuous self checking with alarms
Permeation dryer on ozone generator
Bi-directional RS-232, optional USB and RS-485, and 10/100Base-T Ethernet ports for remote
operation
Front panel USB ports for peripheral devices and firmware upgrades
Digital status outputs to provide instrument operating condition
Adaptive signal filtering to optimize response time
Teledyne Analytical Instruments 23
Model 9110T NOx Analyzer Introduction
Temperature and pressure compensation
Converter efficiency correction software
Catalytic ozone destruct
Comprehensive internal data logging with programmable averaging periods
Ability to log virtually any operating parameter
8 analog inputs (optional)
Internal zero and span check (optional)
1.3. DOCUMENTATION
In addition to this operation manual, two other manuals are available for download from Teledyne’s
website at http://www.teledyne-api.com/manuals/, to support the operation of the instrument:
APICOM Software Manual, part number 03945
DAS Manual, part number 02837
1.4. OPTIONS
The options available for your analyzer are present in with name, option number, a description and/or
comments, and if applicable, cross-references to technical details in this manual, such as setup and
calibration. To order these options or to learn more about them, please contact Teledyne Sales
Department at:
Option
Pumps
Rack Mount
Kits
TOLL-FREE: 888-789-8168
PHONE: +1 626-934-1500
FAX: +1 626-961-2538
EMAIL: ask_tai@teledyne.com
WEBSITE: http://www.teledyne-ai.com/
Table 1-1. Analyzer Options
Option
Number
11A Ship without pump N/A
11B Pumpless Pump Pack N/A
12A Internal Pump 115V @ 60 Hz N/A
12B Internal Pump 220V @ 60 Hz N/A
12C Internal Pump 220V @ 50 Hz N/A
Options for mounting the analyzer in standard 19” racks
20A Rack mount brackets with 26 in. (660 mm) chassis slides N/A
20B Rack mount brackets with 24 in. (610 mm) chassis slides N/A
21 Rack mount brackets only (compatible with carrying strap, Option 29) N/A
23 Rack mount for external pump pack (no slides) N/A
Description/Notes Reference
Pumps meet all typical AC power supply standards while exhibiting same
pneumatic performance.
Teledyne Analytical Instruments 24
Model 9110TH NOx Analyzer Introduction
Option
Carrying Strap/Handle Side-mounted strap for hand-carrying analyzer
29
Option
Number
Description/Notes Reference
Extends from “flat” position to accommodate hand for carrying.
Recesses to 9mm (3/8”) dimension for storage.
Can be used with rack mount brackets, Option 21.
Cannot be used with rack mount slides.
CAUTION – GENERAL SAFETY HAZARD
THE 9110T ANALYZER WEIGHS ABOUT 18 KG (40 POUNDS).
TO AVOID PERSONAL INJURY WE RECOMMEND THAT TWO PERSONS LIFT AND CARRY THE
ANALYZER. DISCONNECT ALL CABLES AND TUBING FROM THE ANALYZER BEFORE MOVING IT.
Analog Input and USB port
64B
Current Loop Analog
Outputs
41
Parts Kits Spare parts and expendables
42A
43
45
Calibration Valves
50A
50B
50G
NO2 Permeation Tubes Replacement tubes; identical size/shape; different permeation rates.
Used for connecting external voltage signals from other instrumentation (such as
meteorological instruments).
Also can be used for logging these signals in the analyzer’s internal
DAS
Adds isolated, voltage-to-current conversion circuitry to the analyzer’s analog
outputs.
Can be configured for any output range between 0 and 20 mA.
May be ordered separately for any of the analog outputs.
Can be installed at the factory or retrofitted in the field.
Expendables Kit includes a recommended set of expendables for
one year of operation of this instrument including replacement
sample particulate filters.
Expendables Kit with IZS includes the items needed to refurbish
the zero air scrubber.
Spare Parts Kit includes spares parts for one unit.
Used to control the flow of calibration gases generated from external sources,
rather than manually switching the rear panel pneumatic connections.
AMBIENT ZERO AND AMBIENT SPAN VALVES
Zero Air and Span Gas input supplied at ambient pressure.
Gases controlled by 2 internal valves; SAMPLE/CAL & ZERO/SPAN.
AMBIENT ZERO AND PRESSURIZED SPAN VALVES
Span Gas input from external, pressurized source;
Span Gas flow rate maintained at 1 ATM by critical flow orifice & vented
through Vent port.
Shutoff valve stops flow of Span Gas when in sample mode to preserve
pressurized gas source.
Zero Air created via 2-stage scrubber & dry filter unit (DFU).
Gases controlled by 2 internal valves; SAMPLE/CAL & ZERO/SPAN.
ZERO SCRUBBER AND INTERNAL SPAN SOURCE (IZS)
Span Gas generated from internal NO
Zero Air created by 2-stage scrubber & DFU.
Gases controlled by 2 internal valves: Sample/Cal & Zero/Span
permeation tube
2
.
N/A
Sections 3.3.1.2,
and 7
Sections 3.3.1.4
and 5.9.3.7
Appendix B
Appendix B
Appendix B
Section 3.3.2.3
Section 3.3.2.4
Sections 3.3.2.5
and 3.3.2.6
52B
52G
Each tube comes with a calibration certificate, traceable to a NIST standard,
specifying its actual effusion rate of that tube to within ± 5% @ 0.56 liters per
Permeation Rate
( 25%)
421 ng/min
842 ng/min
Approximate NO2 Concentration @ 50°C
300ppb – 500 ppb 25%
0600 – 1000 ppb 25%
N/A
N/A
Section 3.3.2.5
Teledyne Analytical Instruments 25
Model 9110T NOx Analyzer Introduction
Option
Communication Cables For remote serial, network and Internet communication with the analyzer.
Type Description
60A RS-232
60B RS-232
60C Ethernet
60D USB
USB Port For remote connection
64A
Concentration Alarm Relays Issues warning when gas concentration exceeds limits set by user.
61
RS-232 Multidrop Enables communications between host computer and up to eight analyzers.
62
Other Gas Options Second gas sensor and gas conditioners
65A Oxygen (O2) Sensor Figure 3-6
86A Ammonia removal sample conditioner (required for EN Certification) 3.3.2.6, 3.4.4.1
86C External zero air scrubber
Special Features Built in features, software activated
N/A
N/A
N/A
Option
Number
minute, calibration performed at a tube temperature of 50°C.
Description/Notes Reference
Shielded, straight-through DB-9F to DB-25M cable, about
1.8 m long. Used to interface with older computers or
code activated switches with DB-25 serial connectors.
Shielded, straight-through DB-9F to DB-9F cable of about
1.8 m length.
Patch cable, 2 meters long, used for Internet and LAN
communications.
Cable for direct connection between instrument (rear
panel USB port) and personal computer.
For connection to personal computer. (Separate option only when
Option 64B, Analog Input and USB Com Port not elected).
Four (4) “dry contact” relays on the rear panel of the instrument. This
relay option is different from and in addition to the “Contact Closures”
that come standard on all TAPI instruments.
Multidrop card seated on the analyzer’s CPU card.
Each instrument in the multidrop network requres this card and a
communications cable (Option 60B).
Maintenance Mode Switch, located inside the instrument, places
the analyzer in maintenance mode where it can continue sampling,
yet ignore calibration, diagnostic, and reset instrument commands.
This feature is of particular use for instruments connected to
Multidrop or Hessen protocol networks.
Call Customer Service for activation.
Second Language Switch activates an alternate set of display
messages in a language other than the instrument’s default
language.
Call Customer Service for a specially programmed Disk on Module containing
the second language.
Dilution Ratio Option allows the user to compensate for diluted
sample gas, such as in continuous emission monitoring (CEM) where
the quality of gas in a smoke stack is being tested and the sampling
method used to remove the gas from the stack dilutes the gas.
Call Customer Service for activation.
Section 3.3.1.8
Section 3.3.1.8
Section 3.3.1.8
Section 3.3.1.8
Sections 3.3.1.8
and 6.6
Section 3.3.1.7
Section 3.3.1.8
Figure 3-29,
Sections 3.3.2.6,
9.1.2.1, 11.3.7, and
11.3.7.1, Table 11-1
N/A
N/A
Section 5.4.3.5
Teledyne Analytical Instruments 26
Model 9110TH NOx Analyzer Specifications, Approvals, & Compliance
2. SPECIFICATIONS, APPROVALS, & COMPLIANCE
This section presents specifications for the 9110T, Agency approvals, EPA designation, and CE mark
and safety compliance..
2.1. SPECIFICATIONS
Table 2-1 presents the instrument’s parameters and the specifications that each meets.
Table 2-1: 9110T Basic Unit Specifications
Parameter
Min/Max Range
(Physical Analog Output)
Measurement Units ppb, ppm, µg/m3, mg/m3 (selectable)
Zero Noise1 < 0.2 ppb (RMS)
Span Noise1 < 0.5% of reading (RMS) above 50 ppb or 0.2 ppb, whichever is greater
Lower Detectable Limit 2 0.4 ppb
Zero Drift < 0.5 ppb (at constant temperature and voltage) /24 hours
Span Drift < 0.5% of Full Scale (at constant temperature and voltage) /24 hours
Lag Time
Rise/Fall Time1 <60 seconds to 95%
Linearity 1% of full scale / 24 hours
Precision 0.5% of reading above 50 ppb
Sample Flow Rate 500 cm3/min ± 10%
AC Power 100-120 V, 60 Hz (3.0 A); 220-240 V, 50 Hz (2.5 A)
Power, Ext Pump
Analog Output Ranges
Analog Output Resolution 1 part in 4096 of selected full-scale voltage
Recorder Offset
Standard I/O 1 Ethernet: 10/100Base-T
Optional I/O 1 USB com port
Dimensions H x W x D 7" x 17" x 23.5" (178mm x 432 mm x 597 mm)
Weight Analyzer: 40 lbs (18 kg)
1
Min: 0-50 ppb Full Scale
Max: 0-20,000 ppb Full Scale (selectable, independent NO, NO
auto ranges supported)
20 seconds
100 V, 50/60 Hz (3.25 A); 115 V, 60 Hz (3.0 A);
220-240 V, 50/60 Hz (2.5 A)
10V, 5V, 1V, 0.1V (selectable)
All Ranges with 5% Under/Over Range
± 10%
2 RS-232 (300 – 115,200 baud)
2 USB device ports
8 opto-isolated digital status outputs (7 defined, 1 spare)
6 opto-isolated digital control inputs (4 defined, 2 spar)
4 analog outputs
1 RS485
8 analog inputs (0-10V, 12-bit)
4 digital alarm outputs
Multidrop RS232
3 4-20mA current outputs
Specification
, NOx ranges and
2
Teledyne Analytical Instruments 27
Model 9110T NOx Analyzer Specifications, Approvals, & Compliance
Parameter
External Pump Pack: 15 lbs (7 kg)
Operating Temperature Range
Humidity Range 0-95% RH non-condensing
Environmental Conditions Installation Category (Over voltage Category) II Pollution Degree 2
1
As defined by the US EPA.
2
Defined as twice the zero noise level by the US EPA.
5 - 40 C (with EPA equivalency)
Specification
2.2. EPA EQUIVALENCY DESIGNATION
TAI’s 9110T nitrogen oxides analyzer is designated as a reference method (Number RFNA-1104-099)
for NO
Range: Any full-scale range between 0-0.05 and 0-1.0 ppm (parts per million).
Ambient temperature range of 5 to 40°C.
With 1-micron PTFE filter element installed in the internal filter assembly.
Equipped with ozone supply air filter
Gas flow supplied by External vacuum pump capable of 10 in-Hg-A at 2 standard liters per minute
measurement, as defined in 40 CFR Part 53, when operated under the following conditions:
2
(slpm) or better.
Software Settings, see Table 2-2:
Table 2-2: Software Settings for EPA Equivalence
Parameter Setting
Dynamic Zero OFF or ON
Dynamic Span OFF
CAL-on-NO2 OFF
Dilution Factor 1.0 or OFF
Temp/Pres compensation ON
AutoCal ON or OFF
Independent range ON or OFF
Auto range ON or OFF
Under the designation, the Analyzer may be operated with or without the following options:
Rack mount with or without slides.
Rack mount for external pump.
4-20mA isolated analog outputs.
Zero/Span Valves option.
Internal Zero/Span (IZS) option with:
NO
NO
permeation tube - 0.4 ppm at 0.7 liter per minute; certified/uncertified.
2
permeation tube - 0.8 ppm at 0.7 liter per minute; certified/uncertified.
2
Teledyne Analytical Instruments 28
Model 9110TH NOx Analyzer Specifications, Approvals, & Compliance
Note Under the designation, the IZS option cannot be used as the source of
calibration.
2.3. APPROVALS AND CERTIFICATIONS
The TAI Model 9110T analyzer was tested and certified for Safety and Electromagnetic Compatibility
(EMC). This section presents the compliance statements for those requirements and directives.
2.3.1. SAFETY
IEC 61010-1:2001, Safety requirements for electrical equipment for measurement,
control, and laboratory use.
CE: 2006/95/EC, Low-Voltage Directive
North American:
cNEMKO (Canada): CAN/CSA-C22.2 No. 61010-1-04
NEMKO-CCL (US): UL No. 61010-1 (2nd Edition)
2.3.2. EMC
EN 61326-1 (IEC 61326-1), Class A Emissions/Industrial Immunity
EN 55011 (CISPR 11), Group 1, Class A Emissions
FCC 47 CFR Part 15B, Class A Emissions
CE: 2004/108/EC, Electromagnetic Compatibility Directive
2.3.3. OTHER TYPE CERTIFICATIONS
MCERTS: Sira MC 050068/05
For additional certifications, please contact Customer Service:
Toll-free Phone:
Phone:
Email:
800-324-5190
858-657-9800
Fax:
858-657-9816
api-customerservice@teledyne.com
Teledyne Analytical Instruments 29
Model 9110T NOx Analyzer Specifications, Approvals, & Compliance
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Teledyne Analytical Instruments 30
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