SAFETY DATA SHEET
Propylene Glycol
1.1 Product identifier
Product Name: Propylene Glycol
Product Codes(s):
Synonyms:
REACH Registration Number:
1.2 Relevant identified uses of the substance or mixture and uses advised against
General Use:
Uses advised against:
1.3 Details of the supplier and of the safety data sheet
Manufacturer/Distributor
Allan Chemical Corporation
Allan Chemical Corporation
235 Margaret King Avenue
235 Margaret King Avenue
Ringwood, NJ 07456 USA
Ringwood, NJ 07456 USA
+1-973-962-4014
1.4 Emergency telephone number
Chem Tel Contract # MIS0000288
+1-813-248-0585
+1-800-255-3924
Propylene Glycol
1,2-Dihydroxypropane; Methylene glycol; Monopropylene glycol; 1,2-Propylene glycol; 1,2-Propanediol; 2-Hydroxypropanol.
Material for use in industrial and commercial formulation applications
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
No data available
None known
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Product definition:
Classification (Regulation (EC) No 1272/2008)
None allocated
2.2 Label Elements
Labeling (Regulation (EC) No 1272/2008)
Hazard Symbol(s):
Signal Word:
Hazard Statement(s):
Substance
None allocated
None allocated
None allocated
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
% by Weight
>99
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified
as hazardous to the health or the environment and hence require reporting in this section.
3.2 Mixtures
Chemical characterization (preparation)
Not applicable
Ingredient
Propylene Glycol
CAS Number
57-55-6
EC Number
200-338-0
Index Number
------------
EC Classification
------------
SECTION 4 - FIRST AID MEASURES
4.1 Description of first aid measures
Inhalation:
difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Loosen tight fitting clothing
such as a collar, tie, belt or waistband. If symptoms persist, seek medical attention.
Eyes: Immediately flush eyes with large amounts of water for 15 minutes, occasionally lifting the upper and lower lids. Remove contact lenses,
if present and easy to do, after the first 2 minutes and continue rinsing. If irritation persists seek medical attention, preferably from an
ophthalmologist.
Skin:
contaminated clothing and shoes thoroughly before reuse. If irritation occurs or persists, seek medical attention.
Ingestion:
do so by medical personnel. Never give anything by mouth to an unconscious person. If victim feels unwell, obtain medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Potential health symptoms and effects
Eyes:
Skin:
If product mist or vapor causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is
Flush skin with large amounts of water while removing contaminated clothing and continue rinsing for at least 15 minutes. Wash
Rinse mouth thoroughly with water if the victim is conscious. Remove dentures, if present. Do not induce vomiting unless directed to
May cause mild, transient eye irritation. Mist may cause eye irritation.
Not expected to cause skin irritation.
Propylene Glycol
ALLAN CHEMICAL CORPORATION
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Inhalation:
Ingestion:
Chronic:
4.3 Indication of any immediate medical attention and special treatment needed
Advice to Doctor and Hospital Personnel:
Not expected to cause irritation of the respiratory tract.
Very low toxicity if swallowed. May cause digestive upset when ingested in large quantities with nausea, vomiting and diarrhea.
None known
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishable media
Suitable methods of extinction:
Unsuitable methods of extinction:
5.2 Special hazards arising from the substance or mixture
Closed containers may explode due to the buildup of pressure when exposed to extreme heat. During emergency conditions overexposure to
decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention.
Explosion hazards:
5.3 Advice for firefighters
Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent
pressure buildup and possible autoignition or explosion when exposed to extreme heat. Burning liquids may be moved by flushing with water to
protect personnel and minimize property damage. If possible, water contaminated by this material should be contained from being discharged to
any waterway, sewer or drain to prevent environmental contamination.
Not considered to be explosion hazard.
Water fog, water spray, carbon dioxide, dry chemical and alcohol-resistant foam.
Water jets or direct water streams may spread fire.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Wear all appropriate protective equipment designated in Section 8. Remove all sources of ignition. Ventilate the area.
6.2 Environmental precautions
Avoid dispersal of spilled material or runoff and prevent contact with soil and entry into drains, sewers or waterways.
6.3 Methods and materials for containment and cleaning up
Cover drains and contain spill. Cover with a large quantity of inert absorbent. Do not use combustible material such as saw dust. Shovel or
sweep up product and place into an approved container for proper disposal. Observe possible material restrictions (Sections 7.2 and 10.5).
Dispose of waste via a licensed waste disposal contractor.
6.4 Reference to other sections
See Section 13 for additional waste treatment information.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for safe handling
Wear all appropriate personal protective equipment specified in Section 8. Do not get in eyes or on skin or clothing. If normal use of material
presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Wash contaminated clothing and shoes before
reuse.
Advice on protection against fire and explosion
Material does not present a fire or explosion hazard.
7.2 Conditions for safe storage, including any incompatibilities
Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10.5), food and drink. Store away from direct sunlight
or ultraviolet light. Transfer only to approved containers having correct labeling. Keep container tightly closed to prevent moisture absorption.
Protect containers against physical damage. Containers that have been opened must be carefully resealed and kept upright to prevent leakage.
Containers may be hazardous when empty as they contain product residues. Use appropriate containment to avoid environmental contamination.
Ventilate closed areas. Do not take internally. Keep out of reach of children.
7.3 Specific end uses
Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1 Control parameters
CAS Number
57-55-6
8.2 Exposure controls
Engineering Measures:
equipment. Use adequate ventilation. Local exhaust is preferable. Refer to Section 7.1 for additional data.
Individual protection measures:
selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance
of the protective equipment should be enquired at the representative supplier.
Hygiene measures:
clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking or using the lavatory.
Eye/face protection:
ANSI Z87.4 or Standard EN 166.
Ingredient
Propylene Glycol
Technical measures and appropriate working operations should be given priority over the use of personal protective
Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be
Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminated
Wear protective goggles or safety glasses with non-perforated side shields and a face shield. Refer to 29 CFR 1910.133,
10 mg/m3 TWA (aerosol only);
50 ppm; 155 mg/m3 TWA (aerosol & vapor)
OSHA PEL
ACGIH TLV
------------
NIOSH
------------
Propylene Glycol
ALLAN CHEMICAL CORPORATION
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Eye/face protection:
ANSI Z87.4 or Standard EN 166.
Hand Protection:
supplier. Gloves should be impermeable to chemicals and oil. Breakthrough time of gloves must be greater than the intended use period.
Other protective equipment:
Respiratory Protection:
assessment shows air-purifying respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK
(EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Wear protective goggles or safety glasses with non-perforated side shields and a face shield. Refer to 29 CFR 1910.133,
Chemical protective gloves should not be needed when handling this material. If needed, wear gloves recommended by glove
Protective clothing. Protective boots, if the situation requires.
None required with normal use. Always use an approved respirator when vapor/aerosols are generated. Where risk
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance Clear, colorless liquid
Odor
Odor Threshold No data available
Molecular Weight 76.09
Chemical Formula
pH ~7
Freezing/Melting Point, Range
Initial Boiling Point
Evaporation Rate <1 (n-BuOAc = 1)
Flammability (solid, gas) Non-flammable
Flash Point 99 °C (210 °F) Open cup
Autoignition Temperature 371 °C (700 °F)
Decomposition Temperature No data available
Lower Explosive Limit (LEL) 2.6
Upper Explosive Limit (UEL) 12.6
Vapor Pressure
Vapor Density 2.6 (Air = 1)
Specific Gravity
Viscosity 48.6 cps @ 25 °C
Solubility in Water 100%
Partition Coefficient: n-octanol/water -0.92
Volatiles by Volume @ 70 ºF 100%
9.2 Other data
No data available
Odorless
C3H8O2
-60 °C (-76 °F)
188 °C (370 °F)
0.08 mm Hg @ 20 °C
1.04 @ 20 °C
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
No dangerous reactivity known under conditions of normal use.
10.2 Chemical stability
This product is stable under recommended storage conditions, handling and use. Hygroscopic (may absorb moisture from the air).
10.3 Possibility of hazardous reactions
None known
Hazardous polymerization does not occur.
10.4 Conditions to avoid
Temperature extremes; contact with incompatible materials. Avoid direct sunlight or ultraviolet light.
10.5 Incompatible materials
Strong oxidizing agents, strong bases
10.6 Hazardous decomposition products
Thermal decomposition products include oxides of carbon.
SECTION 11 - TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute Oral Toxicity
LD50, rat: >20,000 mg/kg
Acute inhalation toxicity
LC50, rabbit: 317 mg/l - 2h, aerosol. No deaths occurred at this concentration.
Acute dermal toxicity
LD50, rabbit: 20,800 mg/kg
Skin irritation/corrosion
Prolonged skin exposure is not likely to cause significant skin irritation.
Eye irritation/corrosion
May cause mild, transient eye irritation.
Sensitization
Negative
Propylene Glycol
ALLAN CHEMICAL CORPORATION
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Sensitization
Negative
Genotoxicity in vitro
Negative
Mutagenicity
Negative
Specific organ toxicity - single exposure
No data available
Specific organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Further information
This material is not listed as a carcinogen by IARC, ACGIH, NTP or OSHA. No data is available regarding the mutagenicity or teratogenicity of
this material in humans, nor is there available data that indicates that it causes adverse developmental or fertility effects in humans.
Handle in accordance with good industrial hygiene and safety practice.
SECTION 12 - ECOLOGICAL INFORMATION
12.1 Toxicity
Material is practically non-toxic to aquatic organisms on an acute basis (LD50/EC50/EL50/LL50 >100 mg/l in the most sensitive species tested).
Acute and prolonged toxicity to fish:
Acute toxicity to aquatic invertebrates:
Acute toxicity to aquatic invertebrates:
12.2 Persistence and degradability
Material is readily biodegradable.
12.3 Bioaccumulation potential
Bioaccumulation potential is low.
12.4 Mobility in soil
Potential for mobility in soil is very high.
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
Additional ecological information
Do not allow material to run into surface waters, wastewater or soil.
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
LC50 - Oncorhynchus mykiss (Rainbow trout), 96 h, static: 51,600 mg/l
LC50 - Pimephales promelas (Fathead minnow), 96 h, static: 51,400 mg/l
EC50 - Daphnia magna (Water flea), 48 h: 1,000 mg/l
EC50 - Pseudokirchneriella subcapitata (Green algae), 96 h: 19,000 mg/l
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Methods of disposal:
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff
and contact with soil, waterways, drains and sewers.
Hazardous waste:
The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some
The classification of this product may meet the criteria for a hazardous waste.
SECTION 14 - TRANSPORT INFORMATION
Note:
Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations
TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials
and methods of shipping.
NOT REGULATED FOR TRANSPORT
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for substance or mixture
U. S. Federal Regulations
OSHA Hazard Communication Standard: This material is not classified as hazardous in accordance with OSHA 29 CRF 1910.1200.
OSHA Process Safety Management Standard:
EPA Risk Management Planning Standard:
EPA Federal Insecticide, Fungicide and Rodenticide Act:
TSCA Status: All components of this product are listed on the Toxic Substance Control Act (TSCA) Inventory. This product is not subject to
TSCA 12(b) Export Notification.
Chemicals in this product are not regulated under OSHA PSM Standard 29 CFR 1910.119.
Chemicals in this product are not regulated under EPA RMP Standard (RMP) 40 CFR Part 68.
This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150.
Propylene Glycol
ALLAN CHEMICAL CORPORATION
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Superfund Amendments and Reauthorization Act (SARA)
SARA 313 Information:
None of the chemicals in this product are subject to reporting requirements of Section 313 of the Emergency Planning
and Community Right-to Know Act of 1986.
SARA Section 311/312 Hazard Categories:
SARA 302/304 Extremely Hazardous Substance:
None
None of the chemicals in this product are subject to reporting requirements of these sections
of Title III of SARA.
SARA 302/304 Emergency Planning & Notification:
None of the chemicals in this product are subject to reporting requirements of these
sections of Title III of SARA.
Comprehensive Response Compensation and Liability Act (CERCLA):
This product contains no CERCLA reportable substances.
Clean Air Act (CAA)
This product does not contain any substances listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b).
This product does not contain any Class 1 Ozone depletors.
This product does not contain any Class 2 Ozone depletors.
Clean Water Act (CWA)
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
U.S. State Regulations
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986:
This product contains no chemical(s) known to the State of California to cause cancer or other reproductive harm.
Other U.S. State Inventories:
Propylene Glycol (CAS #57-55-6) is not listed on any State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air
Pollutants lists.
Canada
WHMIS Hazard Symbol and Classification:
Canadian Controlled Products Regulations (CPR):
None allocated
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations, and the MSDS contains all the information required by the Controlled Products Regulations.
Canadian Ingredient Disclosure List (IDL):
Canadian National Pollutant Release Inventory (NPRI):
Propylene /glycol (CAS #57-55-6) is listed on the IDL.
None of the substances in this product are listed on the NPRI.
European Economic Community
Labeling (67/548/EEC to 1999/45/EC):
WGK, Germany (Water danger/protection):
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.
1
Global Chemical Inventory Lists
Country
Canada
Canada
Europe
United States
Australia
New Zealand
China
Japan
Korea
Philippines
Inventory Name
Domestic Substance List (DSL).
Non-Domestic Substance List (NDSL)
Inventory of New and Existing Chemicals (EINECS)
Toxic Substance Control Act (TSCA)
Australian Inventory of Chemical Substances (AICS)
New Zealand Inventory of Chemicals (NZIoC)
Inventory of Existing Chemical Substances in China (IECSC)
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Inventory Listing*
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
*"Yes" indicates that all components of this product are in compliance with the inventory requirements administered by the governing country.
*"No" indicates that one or more components of this product are not on the inventory and are not exempt from listing.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out.
SECTION 16 - OTHER INFORMATION
Hazardous Material Information System (HMIS)
Health
Flammability
Physical Hazard
Personal Protection
THE INFORMATION PRESENTED IN THIS SAFETY DATA SHEET (SDS/MSDS) WAS PREPARED BY A TECHNICAL PROFESSIONAL BASED ON DATA THAT THEY BELIEVE IN THEIR
GOOD FAITH JUDGEMENT IS ACCURATE. HOWEVER, THE INFORMATION PROVIDED HEREIN IS PROVIDED "AS IS", AND ALLAN CHEMICAL CORPORATION MAKES AND GIVES NO
REPRESENTATIONS OR WARRANTIES WHATSOEVER, AND EXPRESSLY DISCLAIMS ALL WARRANTIES REGARDING SUCH INFORMATION AND THE PRODUCT TO WHICH IT RELATES,
WHETHER EXPRESS, IMPLIED, OR STATUTORY, INCLUDING WITHOUT LIMITATION, WARRANTIES OF ACCURACY, COMPLETENESS, MERCANTABILITY, NON-INFRINGEMENT,
PERFORMANCE, SAFETY, SUITABILITY, STABILITY, AND FITNESS FOR A PARTICULAR PURPOSE, AND ANY WARRANTIES ARISING FORM COURSE OF DEALING, COURSE OF
PERFORMANCE, OR USAGE OF TRADE.
Propylene Glycol
0
1
0
C
HMIS & NFPA Hazard Rating Legend
* = Chronic Health Hazard
0 = INSIGN IFICANT
1 = S LIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
ALLAN CHEMICAL CORPORATION
National Fire Protection Association (NFPA)
Flammability
1
Health
0
Special
Instability
0
Page 5 of 6
THIS SDS/MSDS IS INTEDNED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PROPERLY TRAINED PERSON USING THIS PRODUCT,
AND IS NOT INTENDED TO BE COMPREHENSIVE AS TO THE MANNER AND CONDITIONS OF USE, HANDLING, STORAGE, OR DISPOSAL OF THE PRODUCT. INDIVIDUALS RECEIVING
THIS SDS/MSDS MUST ALWAYS EXERCISE THEIR OWN INDEPENDENT JUDGEMENT IN DETERMINING THE APPROPRIATENESS OF SUCH ISSUES. ACCORDINGLY, ALLAN CHEMICAL
CORPORATION ASSUMES NO LIABILITY WHATSOEVER FOR THE USE OF OR RELIANCE UPON THIS INFORMATION. NO SUGGESTIONS FOR USE ARE INTENDED AS, AND NOTHING
HEREIN SHALL BE CONSTRUED AS, A RECOMMENDATION TO INFRINGE ANY EXISTING PATENTS OR TO VIOLATE ANY FEDERAL, STATE, OR FOREIGN LAWS. ALLAN CHEMICAL
CORPORATION REMINDS YOU THAT IT IS YOUR LEGAL DUTY TO MAKE ALL INFORMATION IN THIS SDS/MSDS AVAILABLE TO YOUR EMPLOYEES.
Version 1
Preparation Date: 14 August 2014
Propylene Glycol
ALLAN CHEMICAL CORPORATION
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