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)
Safety Data Sheet
According to OSHA 29 CFR 1910.1200 HCS & Canada WHMIS
SECTION 1: Identification
1.1. Product identifier
Product Name : Xstamper Refill Ink Color : (Black)
CS-10N, CS-20N, CS-60N
Xstamper Products
Dyestuff type Xstamper Color : (Black)
CX-AN,CX-BN,CX-GN,CX-FN,CA-2N,CA-3N,etc.
1.2. Recommended use of the chemical and restrictions on use
Recommended use : Stamp ink
1.3. Details of the supplier of the safety data sheet
Supplier Company Name : Shachihata Inc.
Address : 1661 W 240th Street Harbor City CA 90710
Telephone : 310-530-4445
Fax : 310-530-2892
Contact (e-mail) : customerservice@xstamper.com
Manufacturer Company Name : Shachihata Inc.
Address : 4-69,Amazuka-cho,Nishi-ku,Nagoya City,451-0021,Japan
Telephone : +81-52-521-3600
Fax : +81-52-521-3899
Contact (e-mail) : chem-analysis@ngy.shachihata.co.jp
1.4. Emergency telephone number
Telephone : 800-541-9719 ext. 6466
Revision Date : 02.10.2013
SECTION 2: Hazard(s) identification
United States (US
2.1.1 Classification of the substance or mixture
Flammable liquids, Category 3 H226 : Flammable liquid and vapour
Serious eye damage /eye irritation, Category 2B H320 : Causes eye irritation
2.1.2 Label elements
Hazard pictograms :
Signal word : Warning
Hazard statement : Flammable liquid and vapour (H226)
Precautionary statement
【Prevention】
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. (P210)
Take precautionary measures against static discharge. (P243)
Wear protective gloves/protective clothing/eye protection/face protection. (P280)
Wash hands thoroughly after handling. (P264)
【Response】
In case of fire : Use dry chemical powder,form or carbon dioxide for extinction. (P370+P378)
IF INHALED : Remove victim to fresh air and keep at rest in a position comfortable for breathing. (P304+P340)
IF IN EYES
If eye irritation persists : Get medical advice/attention. (P337+P313)
: According to OSHA 29 CFR 1910.1200 HCS 2012
Causes eye irritation (H320)
: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
(P305+P351+P338)
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IF SWALLOWED : Get medical advice/attention if you feel unwell.Rinse mouth. (P301+P314+P330)
【Storage】
Store in a well-ventilated place. Keep container tightly closed. (P403+P233)
【Disposal】
Dispose of contents/container to waste in accordance with (P501)
local/regional/ national/international regulation (to be specified).
2.1.3 Other hazards
Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard),
this product is considered hazardous.
Canada
: According to WHMIS
2.2.1 Classification of the substance or mixture
Class B2 : Flammable Liquids
Class D2B : Eye irritation
2.2.2 Label elements
2.2.3 Other hazards
In Canada, the product mentioned above is considered hazardous
under the Workplace Hazardous Materials Information System (WHMIS)
2.3 Other information
FLAMMABILITY
NFPA
2
HEALTH REACTIVITY
1 0
INSTABILITY/
HMIS
SECTION 3: Composition/information on ingredients
Substance/Mixture
Ingredients
Ethanol 1 ~ 10
: Mixture
:
64-17-5
Xstamper Refill Ink CS-20N
HEALTH
FLAMMABILITY
PHYSICAL HAZARD
PERSONAL
PROTECTION
Classification (OSHA HCS 2012)Chemical Name / Composition CAS
Hazard Class
Flam.Liq. 2
1
2
0
Hazard statementGeneric name weight % Registry No.
H225
Derivative of vegetable oil 40 ~ 50 Confidential none
1,2-Propylene glycol 5 ~ 15
57-55-6
none
2-(2-butoxyethoxy)ethanol 5 ~ 15 112-34-5 Eye Irrit.2A
Vegetable oil 5 ~ 15
Synthetic resin 5 ~ 15 none
Confidential
Confidential
none none
Dyestuff 5 ~ 15 Confidential none none
total 100
SECTION 4: First-aid measures
4.1. Description of first aid measures
IF INHALED : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Consult a doctor if symptoms persist.
IF ON SKIN : Remove/Take off immediately all contaminated clothing.Wash with soap and water.
If skin irritation/rash occurs or feel unwell, consult a doctor for medical advice.
IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do.Continue rinsing.If eye irritation persists, get medical advice/attention.
IF SWALLOWED : After rinse mouth immediately, give about 250 ml of water or milk and thin in the stomach,
and do not vomit forcibly.Moreover, do not give anything from the mouth to the patient
when not conscious.Receive the doctor's treatment (stomach pump) promptly.
none
none
H319
none
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Note to Physicians :
All treatments should be based on observed signs and symptoms of distress in the patient.
Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media : Dry chemical powder, foam or carbon dioxide
Unsuitable extinguishing media : Water jet
5.2. Special hazards arising from the substance or mixture
For initial stage extinction, carbon dioxide or dry chemical powder.
When a fire extends, fire is extinguished by a large amount of water spray.
Do not discharge extinguishing waters into the aquatic environment.
5.3. Advice for firefighters
In the extinction work, an appropriate protective equipment (gloves, glasses, and mask) has to be worn.
Because during a fire, hazardous gases may be generated, fire-fighters have to wear self-contained breathing
apparatus and other protective equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate personnel to safe area. Shut off all sources of ignition.
No Flares, smoking or flame in area. Put on protective equipment. Ensure adequate ventilation.
6.2. Environmental precautions
Do not throw the leakage thing directly into environment
6.3. Methods and material for containment and cleaning up
In case of a small spill, absorb with dry sand, soil, sawdust, cloth, etc.,
then place in a chemical waste containers.
In case of large spills, dike and prevent overflow, cover spills with foam,
then place in a chemical container using non-sparking tools.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling : Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage : Keep containers tightly closed and store in a cool and dry place.
areas and containers Keep away from heat and flame,ignition source and sunlight.
Keep out of the reach of children.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
ACGIH (2013)
Ethanol STEL 1000ppm
2-(2-butoxyethoxy)ethanol TWA 10ppm
OSHA PEL
Ethanol TWA 1000ppm
Canada Ontario Provincial
Ethanol STEL 1000ppm
1,2-Propylene glycol TWA 50ppm
Canada Quebec Provincial
Ethanol TWA 1000ppm
8.2. Exposure controls
Personal protective equipment
Respiratory Protection : Use with local exhaust ventilation, when in long use.
Avoid breathing vapours. Wear mask to prevent organic gas, if necessary.
Hand Protection : Avoid contact with hands. Wear safety gloves, if necessary.
Eye Protection : Avoid contact with eyes. Wear safety glasses, if necessary.
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g
g/kg
g
Skin Protection : Avoid skin contact. Wear personal protection apron,boots,if necessary.
Environmental exposure controls
General advice : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance : black liquid
Odor : none
pH : Not applicable
Boiling point : No data available
Flash point : 104 °F (40 °C) (closed cup)
Relative Density (at 77 °F , 25 °C) :
Solubility in Water : Insoluble
1.0 ( g/cm
3
)
SECTION 10: Stability and reactivity
10.1. Reactivity
No dangerous reaction known under conditions of normal use.
10.2. Possibility of hazardous reactions
Under normal conditions of storage and use, hazardous reactions will not occur.
10.3. Chemical stability
The product is stable.
10.4. Conditions to Avoid
High temperature, Direct sunlight, Fire
10.5. Incompatible Materials
No data available
10.6. Hazardous decomposition products
CO, CO
2
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : LD/LC50 values that are relevant for classification
[Ethanol]
Oral-rat LD50 7,060mg/k
Inhalation-rat LC50 20,000ppm/10h
[2-(2-butoxyethoxy)ethanol]
Oral-rat LD50 5,660m
Dermal-rabbit LD50 2,700mg/k
Serious eye damage /eye irritation : Category 2B Causes eye irritation
Carcinogenicity : This product does not contain any component that is considered
a human carcinogen by IARC, ACGIH, OSHA or NTP .
SECTION 12: Ecological information
12.1. Ecotoxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Other adverse effects
: No data available
: No data available
: No data available
: No data available
: No known significant effects or critical hazards.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Disposal must be made according to official regulations.
Comply with all Federal, State, and Local regulations regarding disposal.
Do not allow product to reach ground, any water course or sewage system.
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SECTION 14: Transport information
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
DOT, TDG, IMO / IMDG, IATA / ICAO : UN1210
DOT, TDG, IMO / IMDG, IATA / ICAO : PRINTING INK,flammable
DOT, TDG, IMO / IMDG, IATA / ICAO :
· Class 3 (Flammable liquids.)
· Label 3
DOT, TDG, IMO / IMDG, IATA / ICAO : III
Marine pollutant : No
EMS Number : F-E,S-D
14.7. Transport in bulk according to Annex II of
MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
< USA Information >
OSHA STATUS : This product is hazardous under 29 CFR 1910.1200.
TSCA inventory : All components of this product are listed in the TSCA Inventory.
TSCA Hazard Communication Program (40 CFR Part 721) (SNUR) : not Listed
EPCRA Section 302 Extremely Hazardous Substances (EHS) : not Listed
EPCRA Section 313 Toxic Chemicals : not Listed
CERCLA Hazardous Substances : not Listed
CAA Section 112(r) List of Substances for Accidental Release Prevention : not Listed
California Proposition 65 : not Listed
: Not applicable.
< Canada Information >
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)
and the SDS contains all the information required by the CPR.
Canada inventory : All components of this product are listed in the DSL/NDSL Inventory.
WHMIS Ingredient Disclosure List (SOR/88-64) : Ethanol , 1,2-Propylene glycol ,
(WHMIS : Canadian Workplace Hazardous Material Information System)
2-(2-butoxyethoxy)ethanol
SECTION 16: Other information, including date of preparation or last revision
Last Revision Date :
Preparation Date : 02.10.2013
ＲｏＨＳ
ＥＬＶ
compliant
This data sheet may not be enough when evaluating danger or hazard.The above information, which is created from
currently available documents, information and data, may be revised when new findings announced.This document has
been written on the assumption that when dealing with a large amount of ink on the business case and emergency.When
handling as a normal product, please refer to the notes that is described in the produce or packaging.The information
contained herein is not intended to provide any kind of warranty other than information, there is no guarantee for the
accuracy of the content.
EU RoHS Directive(2002/95/EC) and ELV Directive(2000/53/EC)
This product does not contain lead, mercury, cadmium, hexavalent chromium,
polybromiated biphenyls (PBB) or polybrominated diphenylethers (PBDE).
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