Page 1
〔ISO11014:2009〕〔Shachihata Inc.〕 〔CS-20N_blue_d〕 1/5
Safety Data Sheet
(MSDS)
Issued Date : May 16,2008
Revised Date : February 12,2013
SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name
Company Name
Address
Telephone
Fax
Emergency Call
Recommended use
：
Xstamper Refill Ink Color : (Blue)
CS-10N
CS-20N
CS-60N
Xstamper Products
Dyestuff type Xstamper
:
Shachihata Inc.
:
4-69,Amazuka-cho,Nishi-ku,Nagoya City,451-0021,Japan
:
+ 81- 52- 521- 3600
:
+ 81- 52- 521- 3899
:
+ 81- 52- 521- 3600 (Shachihata Inc. [Japan] )
:
Stamp ink
SECTION 2 HAZARDS IDENTIFICATION
GHS Classification
Physical Hazards
Flammable liquids Category 3
Health Hazards
Serious eye damage /eye irritation Category 2B
Environmental Hazards Classification not possible
LABEL ELEMENTS
Symbols
Signal word
Hazard statement
Precautionary statement
【Prevention】
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. (P210)
Take precautionary measures against static discharge. (P243)
Wear protective gloves/protective clothing/eye protection/face protection. (P280)
Wash hands thoroughly after handling. (P264)
【Response】
In case of fire : Use dry chemical powder,form or carbon dioxide for extinction. (P370+P378)
IF INHALED : Remove victim to fresh air and keep at rest in a position comfortable (P304+P340)
IF IN EYES : Rinse cautiously with water for several minutes. (P305+P351+P338)
If eye irritation persists : Get medical advice/attention. (P337+P313)
IF SWALLOWED : Get medical advice/attention if you feel unwell.Rinse mouth. (P301+P314+P330)
【Storage】
Store in a well-ventilated place. Keep container tightly closed. (P403+P233)
【Disposal】
Dispose of contents/container to waste in accordance with (P501)
local/regional/ national/international regulation (to be specified).
:
:
Warning
:
Flammable liquid and vapour (H226)
:
Causes eye irritation (H320)
for breathing.
Remove contact lenses, if present and easy to do. Continue rinsing.
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〔ISO11014:2009〕〔Shachihata Inc.〕 〔CS-20N_blue_d〕 2/5
SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Mixture
Ingredients
Chemical Name /
Generic name
Ethanol
Derivative of vegetable oil
Glycol class solvent
2-(2-butoxyethoxy)ethanol
Vegetable oil 1～10
Synthetic resin
Dyestuff
total
:
:
Mixture
Composition
weight %
1～10 64-17-5 Flam.Liq. 2
40～50
5～15 Confidential none
5～15
5～15
10～20
SECTION 4 FIRST-AID MEASURES
IF INHALED
IF ON SKIN
IF IN EYES
IF SWALLOWED
:
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Consult a doctor if symptoms persist.
:
Remove/Take off immediately all contaminated clothing.Wash with soap and water.
If skin irritation/rash occurs or feel unwell, consult a doctor for medical advice.
:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do.Continue rinsing.If eye irritation persists, get medical advice/attention.
:
After rinse mouth immediately, give about 250 ml of water or milk and thin in the stomach,
and do not vomit forcibly.Moreover, do not give anything from the mouth to the patient
when not conscious.Receive the doctor's treatment (stomach pump) promptly.
100
CAS
Registry No.
Confidential
112-34-5
Confidential
Confidential
Confidential
Hazard statementHazard Class
(category)
none none
Eye Irrit.2A
none
none none
none
H225
none
H319
none
none
SECTION 5 FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA
UNSUITABLE EXTINGUISHING MEDIA
SPECIFIC EXTINCTION METHOD
For initial stage extinction, carbon dioxide or dry chemical powder.
When a fire extends, fire is extinguished by a large amount of water spray.
Do not discharge extinguishing waters into the aquatic environment.
SPECIAL PROTECTIVE FOR FIRE- FIGHTERS
In the extinction work, an appropriate protective equipment (gloves, glasses, and mask) has to be worn.
Because during a fire, hazardous gases may be generated, fire-fighters have to wear self-contained breathing
apparatus and other protective equipment.
:
Dry chemical powder, foam or carbon dioxide
:
Water jet
SECTION 6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Evacuate personnel to safe area. Shut off all sources of ignition.
No Flares, smoking or flame in area. Put on protective equipment. Ensure adequate ventilation.
ENVIRONMENTAL PRECAUTIONS
Do not throw the leakage thing directly into environment.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP
In case of a small spill, absorb with dry sand, soil, sawdust, cloth, etc.,
then place in a chemical waste containers.
In case of large spills, dike and prevent overflow, cover spills with foam,
then place in a chemical container using non-sparking tools.
SECONDARY ACCIDENT PREVENTION MEASURE
All ignition sources should be quickly removed. (No smoking in vicinity,prohibit sparks or fire sources)
SECTION 7 HANDLING AND STORAGE
Handling
:
Use with adequate ventilation.
Avoid contact with skin, eyes and clothing.
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
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〔ISO11014:2009〕〔Shachihata Inc.〕 〔CS-20N_blue_d〕 3/5
Do not eat, drink or smoke when using this product.
Storage
:
Keep containers tightly closed and store in a cool and dry place.
Keep away from heat and flame,ignition source and sunlight.
Keep out of the reach of children.
SECTION 8 EXPOSURE CONTROLS AND PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMIT
ACGIH (2010)
Ethanol STEL 1000ppm
OSHA PEL
Ethanol TWA 1000ppm
DIRECTIVE 2006/15/EC
2-(2-butoxyethoxy)ethanol TWA 10ppm
STEL 15ppm
Japan Society for Occupational Health (2010) none
PERSONAL PROTECTION
:
Respiratory Protection
Not required, but wear mask to prevent organic gas,if necessary.
:
Hand Protection
Not required, but wear safety gloves, if necessary.
:
Eye Protection
Not required, but wear safety glasses, if necessary.
:
Skin Protection
Not required, but wear personal protection apron,boots,if necessary.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odour
pH
Boiling point
Flash point
Relative Density (at 25ºC )
Solubility in Water
:
blue liquid
:
none
:
Not applicable
:
No data available
:
40 ℃ (closed cup)
1.0
:
:
( g/cm
Insoluble
3
)
SECTION 10 STABILITY AND REACTIVITY
Stability
Conditions to Avoid
Incompatible Materials
Hazardous Decomposition Products
:
Stable under normal handling.
:
High temperature, Direct sunlight, Fire
:
Strong oxidising agents
CO, CO
:
2
SECTION 11 TOXICOLOGICAL INFORMATION
Acute toxicity
Serious eye damage /eye irritation
Carcinogenicity
:
LD/LC50 values that are relevant for classification
[Ethanol]
Oral-rat LD50 7,060mg/kg
Inhalation-rat LC50 20,000ppm/10h
[2-(2-butoxyethoxy)ethanol]
Oral-rat LD50 5,660mg/kg
Dermal-rabbit LD50 2,700mg/kg
:
Category 2B Causes eye irritation
:
Not listed by IARC, EPA, EU, NTP.
SECTION 12 ECOLOGICAL INFORMATION
Hazardous to the aquatic environment (acute)
Hazardous to the aquatic environment (chronic)
Hazardous to the ozone layer
:
Classification not possible
:
Classification not possible
:
Classification not possible
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〔ISO11014:2009〕〔Shachihata Inc.〕 〔CS-20N_blue_d〕 4/5
SECTION 13 DISPOSAL CONSIDERATIONS
Disposal must be made according to official regulations.
Comply with all Federal, State, and Local regulations regarding disposal.
Do not allow product to reach ground, any water course or sewage system.
SECTION 14 TRANSPORT INFORMATION
UN number (DOT, ADR, IMDG, IATA)
UN proper shipping name (DOT, ADR, IMDG, IATA)
UN Classification
Packing group (DOT, ADR, IMDG, IATA)
Marine pollutant (Y/N)
EmS number
SECTION 15 REGULATORY INFORMATION
< EU Information >
Regulation (EC) No 1272/2008 (CLP)
Substance name
Hazard Class & Category
Symbols
Signal word
Hazard statements
Substance name
Hazard Class & Category
Symbols
Signal word
Hazard statements
Directive 67/548/EEC or 1999/45/EC
Substance name
Classification
R-Phrase
S-Phrase
Symbolsand indicationsofdanger specific F : Highly flammable
:
[Ethanol]
:
Flammable liquids, Category 2
:
GHS02
:
Danger
:
H225 Highly flammable liquid and vapour
:
[2-(2-butoxyethoxy)ethanol]
:
Eye irritation, Category 2A
:
GHS07
:
Warning
:
H319 Causes serious eye irritation
:
[Ethanol]
:
F; R11
:
R11 Highly flammable.
:
S2 Keep out of the reach of children.
S7 Keep container tightly closed.
S16 Keep away from sources of ignition - No smoking.
:
UN1210
:
PRINTING INK,flammable
:
3
III
:
:
N
:
F-E,S-D
Substance name
Classification
R-Phrase
S-Phrase
Symbolsand indicationsofdanger specific Xi: Irritation
< USA Information >
OSHA STATUS : This product is hazardous under 29 CFR 1910.1200.
TSCA STATUS : All components on TSCA INVENTORY.
TSCA Hazard Communication Program (40 CFR Part 721) (SNUR) : not Listed
CERCLA REPORTABLE QUANTITY (40 CFR 117,302) : not Listed
SARA TITLE III Section 313 (40 CFR 372) : not Listed
California Proposition 65 (Chemicals known to cause cancer) : not Listed
Refer to any other federal , state , EU , national and local regulations.
:
[2-(2-butoxyethoxy)ethanol]
:
Xi; R36
:
R36 Irritating to eyes.
:
S2 Keep out of the reach of children.
S24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
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〔ISO11014:2009〕〔Shachihata Inc.〕 〔CS-20N_blue_d〕 5/5
SECTION 16 OTHER INFORMATION
ＲｏＨＳ
ＥＬＶ
EU RoHS Directive(2002/95/EC) and ELV Directive(2000/53/EC)
This product not contain lead,mercury, cadmium, hexavalent chromium,
polybromiated biphenyls (PBB) or polybrominated diphenylethers (PBDE).
compliant
This data sheet may not be enough when evaluating danger or hazard.The above information, which is created from currently available
documents, information and data, may be revised when new findings announced.This document has been written on the assumption
that when dealing with a large amount of ink on the business case and emergency.When handling as a normal product, please refer to
the notes that is described in the produce or packaging.The information contained herein is not intended to provide any kind of
warranty other than information, there is no guarantee for the accuracy of the content.
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