May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products.
POTENTIAL HEALTH EFFECTS
Liquid contact can cause irritation, which may be severe.
EYES:
Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis
SKIN:
(rash).
INHALATION:
death with longer exposure. Keep people away from such vapors without self-contained breathing apparatus.
SIGNS AND SYMPTOMS OF OVEREXPOSURE
Can cause severe eye irritation.
EYES:
Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold" burn).
SKIN:
INHALATION:
loss of consciousness).
ACUTE TOXICITY:
arrhythmia may result.
High concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness, and possibly
High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis and
4. FIRST AID MEASURES
Immediately flush eyes with plenty of water. Get medical attention, if irritation persists.
EYES:
In case of cold burns (frostbite) caused by rapidly expanding gas or vaporizing liquids, get medical attention promptly.
SKIN:
Clear, Colorless, Volatile Liquid
Warning! High concentrations of vapor can reduce oxygen available for breathing. Harmful if inhaled.
Overexposure may cause dizziness and loss of concentration. At higher levels, CNS depression and cardiac
INGESTION:
instructed to do so by a physician.
INHALATION:
medical attention.
Ingestion is unlikely because of the physical properties and is not expected to be hazardous. Do not induce vomiting unless
Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate
NOTES TO PHYSICIAN:
p
O
used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at the control of
symptoms and the clinical conditions.
Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD:
FLAMMABLE LIMITS:
AUTOIGNITION TEMPERATURE:
FLAMMABLE CLASS:
FLAME PROPAGATION OR BURNING RATE OF SOLIDS:
EXTINGUISHING MEDIA:
EXPLOSION HAZARDS:
become combustible when mixed with air under pressure and exposed to strong ignition sources.
FIRE FIGHTING PROCEDURES:
FIRE FIGHTING EQUIPMENT:
equivalent) and full protective gear.
COMMENTS:
*Based on ASHRAE Standard 34 with match ignition.
None*
Not Applicable
This product is not flammable at ambient temperatures and atmospheric pressure. However, this material may
6. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDURES:
RELEASE NOTES:
Spills and releases may have to be reported to Federal and/or local authorities.
Not Applicable
> 750°C (1382°F)
Not Applicable
As appropriate for combustibles in area.
Use water spray to cool containers.
As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or
Isolate hazard area. Keep unnecessary and unprotected personnel from entering.
7. HANDLING AND STORAGE
HANDLING:
STORAGE:
Follow standard safety precautions for handling and use of compressed gas cylinders.
Store in a cool place in original container and protect from sunlight.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
Chemical NameOSHA PELACGIH TLVSupplier
1,1,1,2-Tetrafluoroethane (HFC-134a)
OSHA TABLE COMMENTS:
* (AEL)=Acceptable Exposure Limit as established by the manufacture
1.
ENGINEERING CONTROLS:
use of this product.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE:
Skin contact with liquid may cause frostbite. General work clothing and gloves (leather) should provide adequate protection. If
SKIN:
prolonged contact with the liquid or gas is anticipated, insulated gloves constructed of PVA, neoprene or butyl rubber should be used.
Any contaminated clothing should be promptly removed and washed before reuse.
RESPIRATORY:
whenever work
A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed
lace conditions warrant a respirator's use.
Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the
Wear safety glasses with side shields (or goggles) and a face shield.
EXPOSURE LIMITS
ppm
NE NE
TWA
mg/m3ppmmg/m3ppm
1,000
ppm
[1]
9. PHYSICAL AND CHEMICAL PROPERTIES
py
PHYSICAL STATE:
Faint ethereal odor
ODOR:
Neutral
pH:
PERCENT VOLATILE:
VAPOR PRESSURE:
VAPOR DENSITY:
BOILING POINT:
FREEZING POINT:
SOLUBILITY IN WATER:
EVAPORATION RATE:
SPECIFIC GRAVITY:
MOLECULAR WEIGHT:
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES:
PRESSURE GENERATING:
313 REPORTABLE INGREDIENTS:
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY:
[(800)424-8802] and to your Local Emergency Planning Committee.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY:
CANADA
WHMIS CLASS:
DOMESTIC SUBSTANCE LIST (INVENTORY):
AEROSOLS IN LIMITED QUANTITIES OF CLASS 2
UN1950
UN1950
Releases to air, land, or water which exceed the RQ must be reported to the National Response Center
This product is listed on the TSCA Inventory.
Class A, Class D2B.
2.2
2.2
IMMEDIATE / PRESSURE
YES
ACUTE:
Not considered a SARA 313 "Toxic Chemical".
YES
All components of this product are listed on the Canadian DSL.
EUROPEAN COMMUNITY
EEC LABEL SYMBOL AND CLASSIFICATION
Currently not classified according to EEC Directives.
GENERAL COMMENTS:
COMMENTS:
WARNING: Contains 1,1,1,2-tetrafluoroethane (HFC-134a), a greenhouse gas which may contribute to global warming.
16. OTHER INFORMATION
APPROVED BY:
REVISION SUMMARY
Section 14 ADR/RID Hazard Class ADR/RID Item Number
HEALTH:
FLAMMABILITY:
PHYSICAL HAZARD:
PERSONAL PROTECTION:
DATA SOURCES:
Communication Standard (29CFR1910.1200) Various Federal, State and Local Regulations
Pierce A. Pillon
HMIS RATING
Code of Federal Regulations (CFR) The Sigma-Aldrich Library of Regulatory and Safety Data OSHA Hazard
1,1,1,2-tetrafluoroethane is subject to U.S. Environmental Agency Clean Air Act Regulations, (40CFR Part 82).
1
1
0
Chemist
TITLE:
Revision #: 3 This MSDS replaces the August 23, 2004 MSDS. Any changes in information are as follows: In
NFPA CODES
2
1
0
MANUFACTURER DISCLAIMER:
or any of its subsdiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials my present unknown hazards and should by
used wth caution. Althou
h certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
To the best of our knowledge, the information contained herein is accurate. However, neither Stratus,
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