Pro-Link RA008 User Manual

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SAFETY DATA SHEET
1. Identification
Product number
0881
Product identifier
Disinfectant Spray for Hospital Use
Revision date
Company information
Sprayway, Inc. 1005 S. Westgate Drive Addison, IL 60101 United States
Company phone
General Assistance 1-630-628-3000
Emergency telephone US
1-866-836-8855
Emergency telephone outside US
1-952-852-4646
Version #
02
Supersedes date
Recommended use
Disinfectant
Recommended restrictions
None known.
2. Hazard(s) identification
Category 1Flammable aerosols
Physical hazards
Category 2ASerious eye damage/eye irritation
Health hazards
Not classified.
OSHA defined hazards
Label elements
Signal word
Danger
Hazard statement
Extremely flammable aerosol. Causes serious eye irritation.
Prevention
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection.
Response
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Storage
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Not classified.
Hazard(s) not otherwise classified (HNOC)
Category 3Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 3Hazardous to the aquatic environment,
long-term hazard
Supplemental information
Hazard statement
Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Prevention
Avoid release to the environment.
Response
Collect spillage.
% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. % of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
3. Composition/information on ingredients
Mixtures
Hazardous components
CAS number
%Chemical name Common name and synonyms
64-17-5
Ethyl Alcohol
40 - 60
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
REORDER #RA008
PRO-LINK DISINFECTANT SPRAY
PRO-LINK 500 CHAPMAN STREET
CANTON, MA 02021 United States 1-800-74-LINKS
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Hazardous components
CAS number
%Chemical name Common name and synonyms
106-97-8
Butane
10 - 20
74-98-6
Propane
2.5 - 10
90-43-7
o-Phenylphenol
0.1 - 1
7632-00-0
Sodium Nitrite
Other components below reportable levels 20 - 40
0.1 - 1
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation
If symptoms develop move victim to fresh air. Get medical attention if symptoms persist.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion
In the unlikely event of swallowing contact a physician or poison control center.
Most important symptoms/effects, acute and delayed
Irritation of eyes and mucous membranes.
Indication of immediate medical attention and special treatment needed
Provide general supportive measures and treat symptomatically.
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
5. Fire-fighting measures
Suitable extinguishing media
Powder. Alcohol resistant foam. Water. Carbon dioxide (CO2).
Unsuitable extinguishing media
None known.
Specific hazards arising from the chemical
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
Special protective equipment and precautions for firefighters
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire-fighting equipment/instructions
Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not,
withdraw and let fire burn out.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the MSDS.
Methods and materials for containment and cleaning up
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Collect spillage. Prevent product from entering drains. Following product recovery, flush area with water. For waste disposal, see section 13 of the MSDS.
Environmental precautions
Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid contact with eyes. Use only in well-ventilated areas. Observe good industrial hygiene practices. Wash hands thoroughly after handling. Do not empty into drains.
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
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Conditions for safe storage, including any incompatibilities
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store away from incompatible materials (see Section 10 of the MSDS). Level 2 Aerosol.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
PEL 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
STEL 1000 ppmEthyl Alcohol (CAS 64-17-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 1900 mg/m3Butane (CAS 106-97-8)
800 ppm
TWA 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
TWA 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering controls
Provide eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear eye/face protection. Wear safety glasses with side shields (or goggles).
Hand protection
Wear protective gloves.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations
When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Color
Not available.
Form
Aerosol.
Physical state
Gas.
Flash point
-156.00 °F (-104.44 °C) Propellant estimated
Melting point/freezing point
Not available.
Odor
Not available.
pH
Not available.
Solubility(ies)
Not available.
Vapor density
Not available.
Vapor pressure
75 - 85 psig @70F estimated
Viscosity
Not available.
Other information
Specific gravity
0.79 estimated
10. Stability and reactivity
Reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
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Chemical stability
Material is stable under normal conditions.
Possibility of hazardous reactions
Hazardous polymerization does not occur.
Conditions to avoid
Avoid temperatures exceeding the flash point.
Hazardous decomposition products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Ingestion
Expected to be a low ingestion hazard.
Inhalation
No adverse effects due to inhalation are expected.
Skin contact
Not available.
Eye contact
Causes serious eye irritation.
Symptoms related to the physical, chemical and toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity
Test ResultsComponents Species
Butane (CAS 106-97-8)
LC50 Mouse
Inhalation
Acute
680 mg/l, 2 Hours
Rat 658 mg/l, 4 Hours
Ethyl Alcohol (CAS 64-17-5)
LC50 Mouse
Inhalation
Acute
39 mg/l, 4 Hours
Rat 20000 mg/l, 10 Hours
LD50 Dog
Oral
5.5 g/kg
Guinea pig 5.6 g/kg
Mouse 3450 mg/kg
Rat 6.2 g/kg
LD50 Mouse
Other
933 mg/kg
Rat 1440 mg/kg
o-Phenylphenol (CAS 90-43-7)
LD50 Cat
Dermal
Acute
500 mg/kg
LD50 Cat
Oral
500 mg/kg
Guinea pig 3500 mg/kg
Mouse 2000 mg/kg
Rat > 1000 mg/kg
LD50 Mouse
Other
50 mg/kg
Propane (CAS 74-98-6)
LC50 Rat
Inhalation
Acute
> 1442.847 mg/l, 15 Minutes
658 mg/l/4h
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
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Test ResultsComponents Species
Sodium Nitrite (CAS 7632-00-0)
LC50 Rat
Inhalation
Acute
5.5 mg/l, 4 Hours
LD50 Mouse
Oral
175 mg/kg
Rabbit 186 mg/kg
Rat 85 mg/kg
LD50 Mouse
Other
158 mg/kg
Rat 65 mg/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation
Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye irritation
Causes serious eye irritation.
Respiratory sensitization
Not available.
Skin sensitization
This product is not expected to cause skin sensitization.
Germ cell mutagenicity
No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.
Carcinogenicity
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
o-Phenylphenol (CAS 90-43-7) 3 Not classifiable as to carcinogenicity to humans.
Reproductive toxicity
Not available.
Specific target organ toxicity ­single exposure
Not classified.
Specific target organ toxicity ­repeated exposure
Not classified.
Aspiration hazard
Not likely, due to the form of the product.
12. Ecological information
Ecotoxicity
Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
Product Test ResultsSpecies
Disinfectant Spray for Hospital Use (CAS Mixture)
IC50Algae 472.2222 mg/L, 72 Hours, estimatedAlgae
EC50Crustacea 890.5942 mg/L, 48 Hours, estimatedDaphnia
LC50Fish 1684.6193 mg/L, 96 Hours, estimatedFish
Components Test ResultsSpecies
Ethyl Alcohol (CAS 64-17-5)
Aquatic
EC50Crustacea 7700 - 11200 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish > 100.1 mg/l, 96 hoursFathead minnow (Pimephales promelas)
o-Phenylphenol (CAS 90-43-7)
IC50Algae 0.85 mg/L, 72 HoursAlgae
EC50Crustacea 1.75 mg/L, 48 HoursDaphnia
Aquatic
EC50Crustacea 1 - 2.4 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 3.4 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Sodium Nitrite (CAS 7632-00-0)
Aquatic
EC50Crustacea 16.14 - 26.61 mg/l, 48 hoursGreasyback shrimp (Metapenaeus
ensis)
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
Page 6
Components Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
LC50Fish 0.15 - 0.25 mg/l, 96 hoursRainbow trout,donaldson trout
(Oncorhynchus mykiss)
Persistence and degradability
No data is available on the degradability of this product.
Bioaccumulative potential
No data available.
Partition coefficient n-octanol / water (log Kow)
Ethyl Alcohol -0.31 Propane 2.36 Butane 2.89 o-Phenylphenol 3.09
Mobility in soil
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Waste from residues / unused products
Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN1950
UN number
Aerosols, flammable
UN proper shipping name
2.1
Transport hazard class(es)
Not available.
Subsidiary class(es)
Not available.
Packing group
Read safety instructions, SDS and emergency procedures before handling.
Special precautions for user
None
Labels required
N82
Special provisions
306
Packaging exceptions
None
Packaging non bulk
None
Packaging bulk
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
IATA
UN1950
UN number
Aerosols, flammable
UN proper shipping name
2.1
Transport hazard class(es)
-
Subsidiary class(es)
Not available.
Packaging group
No
Environmental hazards
2.1
Labels required
10L
ERG Code
Read safety instructions, SDS and emergency procedures before handling.
Special precautions for user
LTD QTY
Packaging Exceptions
IMDG
UN1950
UN number
AEROSOLS
UN proper shipping name
2.1
Transport hazard class(es)
-
Subsidiary class(es)
Not available.
Packaging group
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
Page 7
No
Marine pollutant
Environmental hazards
None
Labels required
F-D, S-U
EmS
Read safety instructions, SDS and emergency procedures before handling.
Special precautions for user
LTD QTY
Packaging Exceptions
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable.
DOT
IATA; IMDG
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Sodium Nitrite (CAS 7632-00-0) LISTED
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No
SARA 302 Extremely hazardous substance
No
SARA 311/312 Hazardous chemical
No
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8) Propane (CAS 74-98-6)
Safe Drinking Water Act (SDWA)
Not regulated.
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
Page 8
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number
Not listed.
Food and Drug Administration (FDA)
Not regulated.
US state regulations
US. New Jersey Worker and Community Right-to-Know Act
Butane (CAS 106-97-8) 500 lbs o-Phenylphenol (CAS 90-43-7) 500 lbs Propane (CAS 74-98-6) 500 lbs Sodium Nitrite (CAS 7632-00-0) 500 lbs
US. Pennsylvania RTK - Hazardous Substances
Butane (CAS 106-97-8) Ethyl Alcohol (CAS 64-17-5) o-Phenylphenol (CAS 90-43-7) Propane (CAS 74-98-6) Sodium Nitrite (CAS 7632-00-0)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
02
Further information
Not available.
Disclaimer
The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
Revision Information
This document has undergone significant changes and should be reviewed in its entirety.
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Product name: Disinfectant Spray for Hospital Use
Product #: 0881, 1000006974, 1000006973, 1000007011, 1000006976, 1000007214, 1000007838 Version #: 02 Revision date: 06-13-2014 Issue date: 05-01-2014
SDS US
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