MATERIAL SAFETY DATA SHEET
Product number
050-004
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1. Product and Company Identification
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Product name Gleme Glass Cleaner
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Effective date
29-Mar-2012
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Company information
Claire Manufacturing Co.
1005 S. Westgate Drive
Addison, IL 60101 United States
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Company phone
General Assistance 1-630-543-7600
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Emergency telephone US
1-866-836-8855
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Emergency telephone outside US
1-952-852-4646
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Version #
26
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Supersedes date
03-Jan-2012
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Product use
Glass cleaner
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Emergency overview
Aerosol. CONTENTS UNDER PRESSURE.
May be ignited by heat, sparks or flames.
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2. Hazards Identification
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Routes of exposure
Skin contact. Ingestion.
Potential health effects
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Eyes
Health injuries are not known or expected under normal use.
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Skin
May be harmful if absorbed through skin. Frequent or prolonged contact may defat and
dry the skin, leading to discomfort and dermatitis.
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Inhalation
Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
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Ingestion
Exposure by ingestion of an aerosol is unlikely. Components of the product may be
absorbed into the body by ingestion.
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Target organs
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is
repeated and prolonged and may cause blood damage. These effects have not been
observed in humans.
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Chronic effects
Unconsciousness. Cyanosis (blue tissue condition, nails, lips, and/or skin). May be
harmful if absorbed through skin. Frequent or prolonged contact may defat and dry the
skin, leading to discomfort and dermatitis.
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Signs and symptoms
Cyanosis (blue tissue condition, nails, lips, and/or skin). Defatting of the skin. Skin
irritation.
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CAS # Percent
1 - 364-17-5
Components
Ethyl Alcohol
1 - 3111-76-22-Butoxyethanol
1 - 374-98-6Propane
1 - 3106-97-8n-Butane
> 90Non-hazardous and other components below reportable levels
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3. Composition / Information on Ingredients
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Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation
develops or persists.
First aid procedures
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4. First Aid Measures
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Skin contact
Immediately take off all contaminated clothing. Wash off with warm water and soap. Get
medical attention if irritation develops and persists.
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Inhalation
If symptoms develop move victim to fresh air. Get medical attention if symptoms occur.
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Product name: Glem e Gl ass Cleaner
Product #: 050-004 Revision date: 29-MAR-2012 P ri nt date: 29-MAR-2012
MSDS US
1 / 5
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Pro Link Glass Cleaner
Pro Link Inc
Canton, MA United States
1-866-836-8855
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Pro Link Glass Cleaner
Ingestion
If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. If
ingestion of a large amount does occur, call a poison control center immediately.
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Notes to physician
In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under
observation.
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Flammable properties
Heat may cause the containers to explode. Vapor or gas may spread to distant ignition
sources and flash back. Runoff to sewer may cause fire or explosion hazard.
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5. Fire Fighting Measures
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Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Extinguishing media
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Protective equipment and
precautions for firefighters
In case of fire and/or explosion do not breathe fumes. Containers should be cooled with
water to prevent vapor pressure build up. Move containers from fire area if you can do so
without risk. For massive fire in cargo area, use unmanned hose holder or monitor
nozzles, if possible. If not, withdraw and let fire burn out.
Protection of firefighters
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Methods for containment
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer,
basements or confined areas.
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6. Accidental Release Measures
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Methods for cleaning up
Should not be released into the environment.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface
thoroughly to remove residual contamination.
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Handling
Pressurized container: Do not pierce or burn, even after use. DO NOT handle, store or
open near an open flame, sources of heat or sources of ignition. Protect material from
direct sunlight. Do not smoke while using or until sprayed surface is thoroughly dry. Use
only in area provided with appropriate exhaust ventilation. Do not use if spray button is
missing or defective. Do not re-use empty containers. Avoid breathing
dust/fume/gas/mist/vapors/spray. Avoid contact with skin. Avoid contact with eyes. Wear
personal protective equipment. Avoid prolonged exposure.
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7. Handling and Storage
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Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Keep away from heat and flame. Do
not expose to heat or store at temperatures above 120°F/49°C as can may burst. Avoid
exposure to long periods of sunlight. Store in a well-ventilated place. Keep away from
food, drink and animal feedingstuffs. Level 1 Aerosol (NFPA 30B)
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Exposure limits
ACGIH
Components
CAS #
Ethyl Alcohol 64-17-5
TWA
1000 ppm
STEL
1000 ppm
Ceiling
Not established
2-Butoxyethanol 111-76-2 20 ppm Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
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n-Butane 106-97-8 1000 ppm Not established Not established
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8. Exposure Controls / Personal Protection
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OSHA
Components
CAS #
Ethyl Alcohol 64-17-5
TWA
1000 ppm
STEL
Not established
Ceiling
Not established
2-Butoxyethanol 111-76-2 50 ppm Not established Not established
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Propane 74-98-6 1000 ppm Not established Not established
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Eye / face protection
Not normally needed.
Personal protective equipment
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Skin protection
Chemical resistant gloves. Wear appropriate chemical resistant clothing.
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Product name: Glem e Gl ass Cleaner
Product #: 050-004 Revision date: 29-MAR-2012 P ri nt date: 29-MAR-2012
MSDS US
2 / 5
Pro Link Glass Cleaner
Respiratory protection
When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. If permissible levels are exceeded use NIOSH
mechanical filter / organic vapor cartridge or an air-supplied respirator.
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Appearance
Compressed liquefied gas.
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9. Physical & Chemical Properties
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Boiling point
206.6 °F (97.2 °C) estimated
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Color
Colorless.
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Density
0.9604 g/cm3 estimated
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Flammability (HOC)
3.2733 kJ/g estimated
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Flash back
No
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Flash point
-156 °F (-104.4 °C) Propellant
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Form
Aerosol.
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Freezing point
Not available
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Odor
Butyl
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pH
9.5 - 10.5
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Physical state
Liquid.
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Pressure
70 - 90 psig @ 70F
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Solubility
Completely
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Specific gravity
0.9605 estimated
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Conditions to avoid
Heat, flames and sparks.
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10. Chemical Stability & Reactivity Information
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Incompatible materials
None known.
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Hazardous decomposition products
Irritants.
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Acute effects
Acute LD50: 7571 mg/kg estimated, Rat, Dermal
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11. Toxicological Information
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
111-76-2 Inhalation LC50 Rat 2.21 mg/L 4 h; Inhalation LC50 Rat 450 ppm 4 h; Oral LD50 Rat
470 mg/kg; Dermal LD50 Rat 2270 mg/kg; Dermal LD50 Rabbit 220 mg/kg
2-Butoxyethanol
64-17-5 Oral LD50 Rat 7060 mg/kg; Inhalation LC50 Rat 124.7 mg/L 4 hEthyl Alcohol
106-97-8 Inhalation LC50 Rat 658 mg/L 4 hn-Butane
74-98-6 Inhalation LC50 Rat 658 mg/L 4 hPropane
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Sensitization
Not expected to be hazardous by OSHA criteria.
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Carcinogenicity
IARC - Group 1 (Carcinogenic to Humans)
64-17-5 Monograph 100E [in preparation] (in alcoholic beverages); Monograph 96 [2010] (in
alcoholic beverages)
Ethyl Alcohol
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Teratogenicity
Not expected to be hazardous by OSHA criteria.
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Ecotoxicity
Components of this product have been identified as having potential environmental
concerns.
LC50 36327 mg/L estimated, Fish, 96.00 Hours,
EC50 26428 mg/L estimated, Daphnia, 48.00 Hours,
IC50 11902 mg/L estimated, Algae, 72.00 Hours,
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12. Ecological Information
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Disposal instructions
Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material
to drain into sewers/water supplies. This product, in its present state, when discarded or
disposed of, is not a hazardous waste according to Federal regulations (40 CFR 261.4
(b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at
the time of disposal, whether the product meets RCRA criteria for hazardous waste.
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13. Disposal Considerations
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Product name: Glem e Gl ass Cleaner
Product #: 050-004 Revision date: 29-MAR-2012 P ri nt date: 29-MAR-2012
MSDS US
3 / 5
Pro Link Glass Cleaner
Department of Transportation (DOT) Requirements
Aerosols
2.1
UN1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
153, N82
LTD QTY
None
None
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
Additional information:
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14. Transport Information
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Further information
Until 12/31/2013, the "Consumer Commodity - ORM-D" marking may still be used in
place of the new limited quantity diamond mark for packages of UN 1950 Aerosols.
Limited quantities require the limited quantity diamond mark on cartons after 12/31/13
and may be used now in place of the "Consumer Commodity ORM-D" marking but not
concurrently.
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IMDG
AEROSOLS
2.1
1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
LTD QTY
5F
None
2
Packaging exceptions
Item
Labels required
Transport Category
Additional information:
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IATA
Aerosols, flammable
2.1
1950
Hazard class
UN number
Proper shipping name
Basic shipping requirements:
LTD QTY
2.1
Packaging exceptions
Labels required
Additional information:
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US federal regulations
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
111-76-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
2-Butoxyethanol
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
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15. Regulatory Information
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29 CFR 1910.1200 hazardous
chemical
Yes
Occupational Safety and Health Administration (OSHA)
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None
CERCLA (Superfund) reportable quantity
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Section 302 extremely
hazardous substance
No
Superfund Amendments and Reauthorization Act of 1986 (SARA)
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Section 311 hazardous chemical
Yes
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Product name: Glem e Gl ass Cleaner
Product #: 050-004 Revision date: 29-MAR-2012 P ri nt date: 29-MAR-2012
MSDS US
4 / 5
Pro Link Glass Cleaner
Hazard categories (311/312)
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
No
Yes
No
No
No
China
Europe
Europe
Japan
Korea
Inventory of Existing Chemical Substances in China (IECSC)
European Inventory of New and Existing Chemicals (EINECS)
European List of Notified Chemical Substances (ELINCS)
Inventory of Existing and New Chemical Substances (ENCS)
Existing Chemicals List (ECL)
Yes
A
"Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
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State regulations
U.S. - Pennsylvania - RTK (Right to Know) List
111-76-2 Present2-Butoxyethanol
64-17-5 PresentEthyl Alcohol
106-97-8 Presentn-Butane
74-98-6 PresentPropane
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Further information
HMIS® is a registered trade and service mark of the NPCA.
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16. Other Information
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HMIS® ratings
Health: 1
Flammability: 2
Physical hazard: 0
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Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text. The information in the sheet was written based on the best knowledge and
experience currently available. The information provided in this Safety Data Sheet is
correct to the best of our knowledge, information and belief at the date of its publication,
The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or
quality specification, The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any
process, unless specified in the text and The information in the sheet was written based
on the best knowledge and experience currently available.
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MSDS sections updated
Product and Company Identification: Product and Company Identification
Hazards Identification: Emergency overview
Hazards Identification: Chronic effects
Hazards Identification: Main symptoms
Toxicological Information: Carcinogenicity
Toxicological Information: Reproductivity
Transport Information: Further information
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Prepared by
Regulatory Compliance
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Product name: Glem e Gl ass Cleaner
Product #: 050-004 Revision date: 29-MAR-2012 P ri nt date: 29-MAR-2012
MSDS US
5 / 5
Pro Link Glass Cleaner
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