Identification of the Substance or Preparation and Company
Product
Manufacturer
Nickel Cadmium cells and batteries
BYD
LIMITED
Company Limited
Production sites
Emergency telephone number
2.
Composition & Information on Ingredients
Ingredients
Nickel hydroxide
Cadmium
Sodium hydroxide
Potassium
hydroxide
Cobalt oxide
Content
--I
5
--
=25
--
=I
--
=2
--
1
=I
--
30%
40%
4%
6%
2%
Yan An Road, KuiChong, Longgang,
Shenzhen, 51 811 9,
Tel: 86-755-89888888
Fax: 86-755-89773959
Tel: 86-755-89888888
CAS No.
12054-48-7
7440-43-9
131 0-73-2
1 3 1 0-58-3
1
1307-96-6
P.R.China
Classification
Carc. Cat. 3; R40
Xn;
R20122
R43
N; R50-53
Carc. Cat. 2; R45
Muta. Cat. 3; R68
Repr.Cat. 3; R62-63
T;
R48/23/25T+; R26
N;
R50-53
C; R35
Xn; R22
I
C;
R35
I
Xn; R22
3.
Hazards
Do not short circuit, puncture, incinerate, crush, immerse,force discharge or expose to temperature
above the declared operating temperatur<r\nge of product. Risk of fire or explosion.
Under normal conditions of use, the electrode materials and liquid electrolyte they contain are not
exposed to the outside, provided
Effects of Overexposure
Eye Effects: In the case of a fire or cell rupture the electrolyte solution inside battery is extremely
Skin Effect: Contact with electrolyte solution inside battery may cause serious burns to skin tissues.
Ingestion: Ingestion of electrolyte solution causes tissue damage to throat area and
Inhalation:,No exposure possible except in the case of fire of abuse. Effects of inhalation of nickel
Identification
the
battery integrity is maintained and seals remain intact.
'
corrosive to eye tissue a?d may result in permanent blindness. Contact with nickel
oxide may cause minor
Contact with nickel compounds may cause result in chronic eczema or nickel itch.
gastrotrespiratory tract, Ingestion of nickel compounds causes nausea and intestinal
disorders.
\
-.
irritition.
irritation of nasal mucous membranes to damage of lung
>
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ilEI~lB~BEa~8
BYD
4.
First Aid measures
COMPANY
LIMITED
The information below refers to exposure to the ingredients.
Batterv
Eve Contact: Flush with plenty of water for at least
Electrolvte:
15
minutes if abuse causes safety
vents to activate. Get immpdiate medical attention.
Skin Contact: Remove contaminated clothing and flush effected areas with plenty of
water for at least 15 minutes. Wash with soap and water.
Inaestion: Do not induce vomiting. Dilute by giving water. If available give several
glasses of mild. Get immediate medical attention. Do not give anything by
mouth to an unconscious person. Call a physician or Poison Control
Centre immediately
Inhalation: Remove to fresh air. Give oxygen or artificial respiration if needed. Get
immediate medical attention.
Further treatment: See a doctor if necessary.
5.
Fire-fighting measures
Suitable extinguishing media
Dry powder, carbon dioxide (C02), sand.
Extinguishing media which must not be used for safety reasons
Water, water spray.
Specific hazards
Risk of receptacle bursting.
Special protective equipment for firefighters
In the event of fire, wear self contained breathing apparatus. Wear personal protective
The information below refers to exposure to the ingredients.
Personal precautions
Remove personnel from area undil fumes dissipate. Use personal protective
equipment. Avoid contact with skin
Environmental precautions
an; eyes.
I,
Prevent further leakage or spillage if safe to do so.
Do not allow material to contaminate ground water system.
Methods for cleaning up
Pick up and transfer to properly labelled containers. Dispose of in accordance with
local regulations.
1
47,~
:
,I
Date:
79
b'
6
'
7.
Handling and Storage
Handling
Storage
Other
8.
Exposure Controls & Personal Protection
Exposure Limit
Values
Respiratory
I
protection
Hand protection
Eye protection
Other
The cells and batteries manufactured from them may be highly charged
and are capable of high-energy discharge. Care should be taken to handle
cells properly to avoid shorting or misuse that will result in rapid
uncontrolled electrical, chemical, or heat energy release.
Do not short circuit. Do not dispart cell. Do not allow an exposed flame or
spark to come near the
batteries in non conductive trays.
The cells and batteries shall not be stored in high temperature, the
maximum temperature is 6O0C(less than one month), otherwise the cells
and batteries maybe leakage. Besides, the cells and batteries shall be
protected from short circuit and protected from movement that could result
in short circuit.
Follow manufacturer's recommendations regarding maximum
I
recommended currents and operating temperature range.
Nickel compounds: 0.5mglm3 TWA
Cadmium compounds:
Potassium hydroxide:
NOISHIMSHA approved respirator if cell broken open during a
Use
fire to maintain exposure levels below the
nickel comoounds.
If exposure to electrolyte solution, or dried salts is likely, use any
water-insoluble non-performance glove,
use leather or wool.
I
Use splash goggles or face shield if cell activates due to abuse.
I
Rubber apron or equivalent if exposure to electrolyte solution is likely.
ttJEIRfREiBBEB
BYD
COMPANY
tells. Do not mix new and used batteries. Keep
0.01
mglm3 TWA
2mglm3 MAC
LIMITED
TWA
for cadmium and
i.e., synthetic rubber. Do not
9.
Physical and Chemical Properties
1
Appearance
Odour
Color
PH
Flash Point
Flammability
Rlatetive density
Solutbility(Water)
Keep away from heat and sources of ignition
Aluminum, zinc and other active metals, acid, chlorinated and
aromatic hydrocarbons, nitro-carbons, halocarbons. Water.
Harmful if swallowed. May cause sensitization by inhalation
and skin contact.
Toxic: danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
I
Avoid repeated exposure.
I
May cause cancer. Possible risk of irreversible effects.
~ossible risko~kbfe~ty_P~~I~isk
1
unborn child.
LIMITED
=
273mglkg cadmium oxide
ofhm*
12.Ecological Information
Mobility
Persistence
degradability
Ecotoxicity effects
13.Disposal Considerations
Waste from residues
unused products
Contaminated
~ackaaina
14.Transport lnformation
Not classified as dangerous in the meaning of sea and air transport regulations.
BYR
the purpose of transportation by the
lnternational Civil Aviation Organization (ICAO), the lnternational Air Transport
Association (IATA) or the lnternational Maritime Dangerous Goods regulations (IMDG).
The only DOT requirement
130 which states: "Batteries, dry are not subject to the requirements of this subchapter
only when they are offered for transportation in a manner that prevents the dangerous
evolution of heat (for example, by the effective insulation of exposed terminals)."
requires that batteries being transported'by air must be protected frdm short-circuiting
and protected from movement that could lead to short-circuiting.
BYD batteries are not subject to these regulations and are exempted from
because:
IMDG(internationa1 Maritime Dangerous Goods Regulations), special Provision 304
which states: "batteries, dry, containing corrosive electrolyte which will not follow out of
the battery when case is cracked are not subject to the provisions of this Code
provided, but the batteries shall be securely packed and protected against
carbon, nickel cadmium batteries.
-
I
None known if usedldisposed of correctly
and I Not readily biodegradable
Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. (The information
below refers to exposure to the ingredients.)
I
The battery is a hazardous waste under RCRA.
Dispose of in accordance with appropriate local regulations..
Should not be released into the environment.
Not applicable
sealedM~l_cadm~hW~
U.S.
br shipping Nickel Cadmium batteries is Special Provision
-
s~eno?eu~&d~mtts
Department of Transportation (DOT), the
include alkali-manganese, silver oxide, Zinc
goo&
regutation fur
IATA
UN3028
I
ttilEIHWRBIE8
BYD
COMPANY
International Civil Aviation Organization(lCA0) and International Air Transport
Association (IATA), Special Provision A1 23 which states: "An electrical battery or battery
powered device having the potential of dangerous evolutions of heat that is not
prepared so as to prevent a short
insulation of exposed terminals; or in the case of equipment, by disconnection of the
circuit(e.g. in the case of batteries, by the effective
LIMITED
fl
15.Regulatory Information
The preparation is classified as dangerous in accordance with Directive
Symbol I T+ - Very toxic C - Corrosive
R
-phrases
S
-phrases 28 - After contact with skin, wash immediately with plenty of soap and
1~35 - Causes severe burns.
R26 - Very toxic by inhalation.
-
May cause cancer.
R45
R62
-
Possible risk of impaired fertility.
-
Possible risk of harm to the unborn child.
R63
-
Possible risk of irreversible effects.
R68
R43
-
May cause sensitization by skin contact.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
S
112 - Keep locked up and out of the reach of children.
ater.
36/37/39
protection.
45 - In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
53 -Avoid exposure - obtain special instructions before use.
60
-
aste.
-
61
1
ata sheets.
-
Wear suitable protective clothing, gloves and eyelface
This material and its container must be disposed of as hazardous
Avoid release to the environment. Refer to special instructions/safety
N - Dangerous for the environment
1999/45/EC.
-
16.0ther information
The data in this
Date issued: 2004/06/20 Last Date Revised: 201 2/06/29
Note: This information has been com'piled from sources considdred to be dependable
and is accurate and reliable. It is the user's responsibility to satisfy himself as to the
suitability and completeness of this information for his own particular use. We do not
accept liability for any loss or damage that may occur, whether direct, indirect, incidental
or consequential, from the use of this information ncr do we offer warranty against patent
MSDS
relates only to the specific material designed herein.
0
is also available by contacting BYD.
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