Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015 Revision: 19.09.2014Version number 102
*
SECTION 1: Identification of the substance/mixture and of the company/undertaking
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1.1 Product identifier
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Trade name: KELA Fuel-paste
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Article numb
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1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
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Application of the substance / the mixture
Fuel paste
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1.3 Details of the supplier of the safety data sheet
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Manufacturer/Supplier:
Keck & Lang GmbH
Nordring 1
DE 89558 Boehmenkirch
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Informing department:
Product safety department. Tel.: +49 (0)7332 8286
E-mail: service@kela.de -
1.4 Emergency telephone number:
+49 (0)7332
er:
8286
Page 1/
9
Tel.: +49 (0)7332 8286
*
SECTION 2: Hazards identification
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2.1 Classification of the substance or mixture
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Classification according to Regulation (EC) No 1272/2008
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
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2.2 Label elements
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Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
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Hazard pictograms
GHS02
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Signal word
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Hazard statem ents
Danger
H225 Highly flammable liquid and vapour.
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Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
(Contd. on page 2)
40.0.4
GB
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015
KELA Fuel-paste
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
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Results of PBT and vPvB assessment
Not applicable.
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PBT:
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Not applicable.
vPvB:
SECTION 3: Composition/information on ingredients
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Revision: 19.09.2014Version number 102
(Contd. of page 1)
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3.2 Mixtures
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Description:
Ethanol, denatured
Solvent mixture.
Mixture of the substances listed below with harmless additions.
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Dangerous components:
CAS: 64-17-5
ethanol
Flam. Liq. 2, H225;
> 70%
EINECS: 200-578-6
Reg.nr.: 01-2119457610-43
CAS: 78-93-3
butanone
Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336
< 1%
EINECS: 201-159-0
Reg.nr.: 01-2119457290-43
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Additional information
For the wording of the listed risk phrases refer to section 16.
SECTION 4: First aid measures
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4.1 Description of first aid measures
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General advice:
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After inhalation
Provide fresh-air circulation. If symptoms con tinue, consult a doctor. In case of respiratory failure or brea thing
irregularities, commence resuscitation or oxygen inha lation and immediately consult a doctor. In case of
unconsciousness, place and transport the patient in a recovery position.
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After skin contact
Remove contaminated clothing immediately. Wash affected areas with plenty of water und soap. If irritation
continues, contact a doctor.
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After eye contact
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After swallowing
Rinse out mouth with water.
Do not induce vomiting; instantly call for medical help.
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4.2 Most important symptoms and effects, both acute and delayed
Dizziness, double vision and o ther ty pical symp to ms of a lcoho lic i ntox icati on. V om iting, un con scio usness. Irritation
of skin, eyes and airways.
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Information for doctor
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4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Instantly remove any clothing soiled by the product.
Rinse immediately opened eye for several minutes under running water. Then consult doctor.
Symptomatic treatment (decontamination, vital functions), no specific antidote known.
SECTION 5: Firefighting measures
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5.1 Extinguishing media
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Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
40.0.4
(Contd. on page 3)
GB
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015 Revision: 19.09.2014Version number 102
- Trade name: KELA Fuel-paste
(Contd. of page 2)
-
For safety reasons unsuitable extinguishing agents
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5.2 Special hazards arising from the substance or mixture
Can form explosive gas-air mixtures. In case of incomplete combustion carbon monoxide can arise. Fumes are
heavier than air and distributed over ground. Inflammation is possible from a far distance.
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5.3 Advice for firefighters
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Protective equipment:
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Additional information
Wear full protective suit with self-contained breathing apparatus.
Endangered containers in the surrounding area should be cooled with a water-hose.
Damp down explosive gas-air mixtu res with water spray jet.
SECTION 6: Accidental release measures
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6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment and keep unprotected persons away.
Extinguish naked flames. Remove flammable sources. No smoking. Avoid sparks. Avoid contact with skin, eyes and
clothing. Avoid inhalation of fumes. Air contaminated rooms thoroughly. Protect against electrostatic sparks.
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6.2 Environmental precautions:
Prevent material from reaching sewage system, holes and cellars.
If large amounts are released, the authorities must be informed.
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6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Dispose of contaminated material as waste according to item 13.
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6.4 Reference to other sections
Danger of explosion
See Section 7 for information on safe handling
See Section 13 for information on disposal.
See Section 8 for information on personal protection equipment.
Water with a full water jet.
Page 3/9
SECTION 7: Handling and storage
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7.1 Precautions for safe ha ndling
Keep containers tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
Avoid contact with eyes or skin.
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Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
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7.2 Conditions for safe storage, including any incompatibilities
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Storage
Protect against direct sunlight, other sources of heat and ignition.
Keep containers tightly closed. Store in cool, dry conditions.
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Requirements to be met by storerooms and containers:
Observe official regulations on storage and handling of water harzardous substances
Store in cool location.
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Information about storage in one common storage facility:
Pay attention to regulations / technical guidelines on mixed storage of flammable liquids.
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Further information about storage conditions:
Unsuitable material for containers and conduits: aluminum and their alloys.
Provide earthing of containers, equipment, pumps and ventilation facilities.
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Storage class
3 (VCI - Konzept, 2007)
(Contd. on page 4)
GB
40.0.4
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015
- Trade name: KELA Fuel-paste
-
7.3 Specific end use(s)
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SECTION 8: Exposure controls/personal protection
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Additional information about design of technical systems:
Room ventilation i.e. vacuum suction. Measures to be taken against electro-static sparks.
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8.1 Control parameters
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Components with critical values that require mo nitoring at the workplace:
64-17-5 ethanol (50-100%)
WEL Long-term value: 1920 mg/m³, 1000 ppm
78-93-3 butanone (< 2.5%)
WEL Short-term value: 899 mg/m³, 300 ppm
Long-term value: 600 mg/m³, 200 ppm
Sk, BMGV
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DNELs
64-17-5 ethanol
Oral DNEL (population) 87 mg/kg bw/day (Long-term - systemic effects)
Dermal DNEL (population) 206 mg/kg bw/day (Long-term - systemic effects)
DNEL (worker) 343 mg/kg bw/day (Long-term - systemic effects)
Inhalative DNEL (population) 950 mg/m³ (Acute - local effects)
DNEL (worker) 1900 mg/m³ (Acute - local effects)
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PNECs
64-17-5 ethanol
PNEC 0.63 mg/kg dw (soil)
PNEC aqua 0.96 mg/l (fresh water)
PNEC sediment 3.6 mg/kg dw (fresh water)
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Additional information:
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8.2 Exposure controls
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Personal protective equipment
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General protective and hygienic measures
Keep away from food, beverages and fodder.
Wash hands during breaks and at the end of the work.
Instantly remove any soiled and impregnated garments.
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
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Breathing equipment:
Not necessary if room is well-ventilated.
Use breathing protection in case of insufficient ventilation.
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Recommended filter d evice f or short term use:
Combination filter A-P2
Take care of limitations and rules for the use of breathing protection equipment (BGR 190).
No further relevant information available.
114 mg/m³ (Long-term - systemic effects)
950 mg/m³ (Long-term - systemic effects)
580 mg/l (380)
0.79 mg/l (marine water)
2.9 mg/kg dw (marine water)
The lists that were valid during the compilation were used as basis.
Page 4/9
Revision: 19.09.2014Version number 102
(Contd. of page 3)
(Contd. on page 5)
GB
40.0.4
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015
- Trade name: KELA Fuel-paste
-
Protection of hands:
Protective gloves.
Check protective gloves prior to each use for their proper condition.
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Material of gloves
Butyl rubber, BR
Recommended thickness of the material:
0.5 mm
≥
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
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Penetration time of glove m aterial
Change gloves if notice sign of disenchantment.
Material of gloves is recommended for a short-term single use to protect from splashes. For permanent usage contact
manufacturer of gloves.
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Eye protection:
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Body protection:
Tightly sealed safety glasses.
Protective work clothing.
SECTION 9: Physical and chemical properties
Revision: 19.09.2014Version number 102
(Contd. of page 4)
Page 5/9
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9.1 Information on basic physical and chemical properties
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General Information
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Appearance:
Form:
Colour:
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Smell:
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pH-value (100 g/l) at 20 °C:
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Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
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Flash point:
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Ignition temperature:
gel
blue
Sweetish
ca. 7.0
Not determined
~ 78 °C
12 °C (DIN 51755)
425 °C (DIN 51794)
for ethanol
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Self-inflammability:
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Danger of explosion:
Product is not selfigniting.
Product is not explosive. However, formation of explosive air/steam mixtures is
possible.
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Critical values for explosion:
Lower:
Upper:
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Vapour pressure at 20 °C:
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Density at 20 °C
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Solubility in / Miscibility with
Water:
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Viscosity:
dynamic at 20 °C:
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9.2 Other information
~ 3.5 Vol %
~ 15 Vol %
57 mbar
ca. 0.808 g/cm3
Fully miscible
1.19 mPas
Evaporation number (ethanol): 8,0 (Ether = 1) (DIN 53170)
Evaporation number (ethanol): 1,7 (nBuAc = 1) (ASTM D 3539)
GB
(Contd. on page 6)
40.0.4
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015
- Trade name: KELA Fuel-paste
SECTION 10: Stability and reactivity
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10.1 Reactivity
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10.2 Chemical stability
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Thermal decompositio n / conditions to be avoided:
Can be distilled without decomposing at normal pressure
To avoid: warmth, flames, sparks
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10.3 Possibility of hazardous reactions
Reacts with oxygen
Reactions with strong oxidizing agents.
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10.4 Conditions to avoid
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10.5 Incompatible materials:
strong oxidizing agents
Strong acids
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10.6 Hazardous decomposition products:
No further relevant information available.
Formation of carbon monoxide and carbon dioxide in case of fire.
Page 6/9
Revision: 19.09.2014Version number 102
(Contd. of page 5)
SECTION 11: Toxicological information
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11.1 Information on toxicological effects
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Acute toxicity:
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LD/LC50 values that are relevant for classification:
64-17-5 ethanol
Oral LD50 10470 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rab)
Inhalative LC 50 / 4 h > 20 mg/l (mouse)
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Primary irritant effect:
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on the skin:
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on the eye:
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Sensitisation:
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Subacute to chronic toxicity:
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STOT-repeated exposure:
64-17-5 ethanol
Oral NOAEL 1760 mg/kg (rat) (OECD 408, 90 d, target organ: liver)
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Additional toxicologica l information:
High exposures irritates the mucous membranes of the eyes and the respiratory and digestive system.
High concentrations of vapors in air may cause drowsiness and dizziness.
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CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
The ingredients in this mixture do not meet th e criteria fo r classification as CMR categories according to CLP.
mild irritant
Irritant effect.
No sensitizing effect known.
Can cause liver damage.
*
SECTION 12: Ecological information
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12.1 Toxicity
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Aquatic toxicity:
64-17-5 ethanol
EC 50 / 48 h > 10000 mg/l (Daphnia magna)
EC 50 / 72 h 275 mg/l (Chlorella vulgaris)
LC 50 / 48 h 8140 mg/l (Leuciscus idus)
(Contd. on page 7)
40.0.4
GB
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 06.06.2015
- Trade name: KELA Fuel-paste
-
12.2 Persistence and degradability
The product ist readily biodegradable,
biodegradabitilty: BOD 5 (20 °C): ethanol = 71 % ThOD
2-butanone = 83 % des ThOD
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12.3 Bioaccumulative potential
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12.4 Mobility in soil
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Additional ecological info rmation:
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General notes:
Product is water soluble.
Do not allow to enter drainage system, surface or ground water
Water hazard class 1 (Self-assessment): slightly hazardous for water.
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12.5 Results of PBT and vPvB assessment
Not applicable.
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PBT:
-
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Not applicable.
vPvB:
12.6 Other adverse effects
SECTION 13: Disposal considerations
No bioaccumulation expected. The product is biodegradable and water soluble.
No further relevant information available.
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Revision: 19.09.2014Version number 102
(Contd. of page 6)
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13.1 Waste treatment m e thods
The following advice is related to new material and not to any processed products. In case of a mixture with other
products other disposal methods may b eco me ne ce ssary. If in dou bt seek ad vice from produ ct su pplier o r from loc al
authorities.
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Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
If possible, send to be recycled, otherwise burn or deposit in a certified facility.
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Uncleaned packagings:
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Recommendation:
Disposal must be made according to official regulations.
Rented packaging: After optimal emptying, close immediately and return to the supplier without cleaning. Care
should be taken that no other materials get into the packaging.
Other containers: After complete emptying and cleaning, send to be reconditioned or recycled.
Caution: Leftovers in the containers may cause the risk of explosion.
Uncleaned containers should not be perforated, cut or welded.
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Recommended cleaning agent:
*
SECTION 14: Transport information
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14.1 UN-Number
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ADR, IMDG, IATA
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14.2 UN proper shipping name
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ADR
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IMDG
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IATA
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14.3 Transport hazard class(es)
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ADR
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Class
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Label
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IMDG, IATA
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Class
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Label
Water, if necessary with cleaning agent.
UN1170
1170 ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
ETHANOL SOLUTION
3 (F1) Flammable liquids.
3
3 Flammable liquids.
3
(Contd. on page 8)
GB
40.0.4
according to 1907/2006/EC, Article 31
Printing date 06.06.2015
- Trade name: KELA Fuel-paste
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14.4 Packing group
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ADR, IMDG, IATA
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14.5 Environmental hazards:
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Marine pollutant:
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14.6 Special precautions for user
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Kemler Number:
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EMS Number:
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14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
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Transport/Additional information:
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ADR
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Limited quantities (LQ)
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UN "Model Regulation":
Page 8/9
Safety data sheet
Revision: 19.09.2014Version number 102
(Contd. of page 7)
II
Not applicable.
No
Warning: Flammable liquids.
33
F-E,S-D
Not applicable.
1L
UN1170, ETHANOL SOLUTION (ETHYL ALCOHOL
SOLUTION), 3, II
SECTION 15: Regulatory information
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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National regulations
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Information about limitation of use:
100% volatile organic compounds (Council Directive 2010/75/EC).
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VOC
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15.2 Chemical safety assessment:
*
SECTION 16: Other information
These data are based on our present knowledge. However, they sh all not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
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Relevant phrases
Complete wording of hazard statements and risk phrases (H- and R-phrases) mentioned in section 3. These phrases
refer to the constituents. The labelling for this product is stated in section 2.
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
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Department issuing data specification sheet:
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Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
LEV. Local Exhaust Ventilation
NOAEL: No Observed Adverse Effect Level
RPE: Respiratory Protective Equipment
RCR: Risk Characterisation Ratio (RCR= PEC/PNEC)
ADR: Accord européen sur le transport des march and ises danger euses p ar Rout e (European Agreement conc erning the Internati onal Carriage
of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
CLP: Classification, Labelling and Packaging (Regulation (EC) No. 1272/2008)
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
Employment restrictions concerning young persons must be observed.
A Chemical Safety Assessment has not been carried out.
see item 1: Informing department
(Contd. on page 9)
GB
40.0.4
Printing date 06.06.2015
- Trade name: KELA Fuel-paste
Page 9/9
Safety data sheet
according to 1907/2006/EC, Article 31
Revision: 19.09.2014Version number 102
CAS: Chemical Abstracts Service (division of the American Chemical Society)
TRGS: Technische Regeln für Gefahrstoffe (Technical Rules for Dangerous Substances, BAuA, Germany)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
-
* Data compared to the previous version altered.
(Contd. of page 8)
GB
40.0.4
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