Born from the fusion of our technical expertise and state-of-the-art manufacturing
As a leading pH electrode manufacturer, HORIBA uses the
latest technology for all your measurement needs.
Since the development of Japan’s first glass electrode for pH meter, HORIBA
has focused on continually improving our electrode technology, especially
in materials and manufacturing. HORIBA is committed to continually explore
and employ groundbreaking solutions in manufacturing next-generation
electrodes so that we always provide you with the newest and best electrodes.
pH Electrode
Selection Guide
Applicable tempe rature
Specification
pH - Sample Conditions
Aqueous
Solution
Solid/
Semisolid
Sample
Containers
range (ºC)
Diameter (mm)16161616161283121212121612312381216
Length (mm)150150150155150198283185203150150150150198185203291283150190
Norm al (over 100
mS/ m)
Low (ap prox.10
Conductivity
Stro ng alkalin e (pH 10-12)
Stro ng acidit y (pH 0-2) * E xcept
HF sam ple
Quick h eat chan ge (within 5 0°C)
High vi scosit y (approx. 5 P a·S)
Containing non-aqueous
solvent
Suspension
Inside
Surface
Micro tube/pl ate (> 50 µL)
Ampule> ø4 mm
Micro c ontaine r (> 2 mL)
Tub e
Beaker10 mL ~ 1 L
Larg e contai ner (> 1 L)
Petri dish
Droplet
~100 mS/m
Very l ow (approx.
5 ~100 mS/ m
High (ap prox.
5 S/m)
ID:13 mm, L :100 ~
150 mm
3-in-1 ELECTRODESCOMBINATION ELECTRODES
PLASTIC
9651-10 D 96 25-10 D 9630-10D 9631-10D 9632-10 D 96 15S-10 D 9680S-10D 96 18S-1 0D 9 681S -10D 63 67-10D 63 77-10D 62 52-10D 9 425 -10C 9 415-10 C 9 418-10 C 9 481-10 C6069-10C9480-10C6261-10C0040-10D
HF sample)
Hydrofluoric acid
Surfactant
Water-based paint
Dye/coloring agent
Protein-c ontaining sample
Medicinal prep aration
Enz yme solut ion
Tris buf fer
Suspension
Agar medium
Jam
Meat/fish/Fruit/vegetable/
HORIBA’s in-house expertise in the manufacture of electrodes is the accumulation of more
than 60 years of experience. Our sophisticated electrode processing technology provides
flexibility in designing various shapes of the electrode bulb and different structural designs
of the electrodes.
ISFET
ELECTRODES
LONG
LONG
0-600-10 00-500-60
ToupH
FL ATGENERAL
Thick membrane
technology
HORIBA’s glass moulding
technology allows the
manufacture of tougher pH
glass bulbs.
Double-junction
electrodes
All HORIBA pH combination
electrodes are double-junction
electrodes. Flexible to use in a
wide-range of applications.
Miniaturization
Unique flat electrode design as well
as 3mm diameter micro-electrode
with integrated temperature sensor
(US Patent No. 7314541/China
Patent No. ZL0315796)
Convenient slider
Refillable electrodes are equipped
with a slider to open or close the
refilling port easily.
Invention
Award
(Japa n)
Fast response &
highly accurate
ToupH glass bulb does not
compromise responsiveness and
sensitivity (US Patent No. 8262877).
Specially designed electrodes are
available for hydrofluoric acid &
strong alkaline application.
Built-in clip for hooking
onto electrode stand arm
Top housing of electrodes is
designed with a built-in clip to hook
onto HORIBA’s electrode stands.
ORP Electrode
ModelElectrode MaterialTemp. Ran ge (°C)Applicatio nPar t No.
Combination ISE*ModelMeasuremen t RangeInterfering Ion InfluencePar t No.
Chloride6560-10C0.4~ 35,000 m g/L CI
Fluoride 656 1-10C0. 2~19,00 0 mg/ L F
Nitrate65 81-10C0.62~62,0 00 mg/L NO
Potassium6582-10C0.04 ~39,00 0 mg/L K
Calcium6583-10C0.4 ~40,0 80 mg/L C a
Ammonia5 002 A-10C0.1~1,000 m g/L NH
• All ion elec trodes (except combinat ion electrodes) require a sensor holde r for attaching to th e electrode stan d. • Please be aware of the h indering ion and p H
range interfe rence of ion elect rodes. • D-73 con nects combinat ion type ion el ectrodes only.
*The sele ction coef ficient is a ratio of the limit concentrat ion of coexisting i ons (mol/L) to the io n concentratio n to be measured (mol/ L); A value of 1000 means th at
the coexisti ng ions can be permitted up to 100 0 times the ion m easured and ‘’N /A’’ means that chemical change occu rs in the solid respo nse membrane.
-
-
-
3
+
2+
3
-
-
2-
3
Br-=0.0 3 NO
, F-, HCO
(ex. Al3+, Fe3+) coex isted and fo amed the c omplex.3014093431
2-
CH3COO-=30 0 SO
Li+, Na+, Mg2+, Sr2+, Ba2+=Over 10003014093433
Mn2+=50 0 Mg2+=1,000 Na+, K+, Ba2+, NH
4
=Over 10003014093432
2-
3
4
4
, SO
, PO
=1,0003014093430
+
4
=Over 1,000 3014093434
—3014093560
Replacement Tip
ModelPart No.
76603014093436
76613014093438
76813014068364
76823014069795
76833014068795
3
membrane (NH
)3 014067 083
(surf ace)
(surf ace)
(surf ace)
(surf ace)
(surf ace)
Conductivity Cells
Cell constant
cm-1 (m-1)
Submersible
Type
Flo w Type
• Conducti ve material: Titanium coated with plati num black • Body housing: Glass except 9 382-10D - Plastic
ModelMeasurement Range
0.1 ( 10) 3551-10 D 0.1 µS/c m~10 mS/cm (10 µS /m~1 S/m)50For l ow conduc tivit y water (de ionized w ater or oth er)0~603014 081712
1 (100) 9382-10D 1 µS/cm ~100 mS/cm (0.1 mS /m~10 S/m)20~30W aterpro of; For ge neral pur pose use0~803014046709
1 (100) 3 552-10 D 1 µS /cm~100 mS /cm (0.1 mS/m~10 S /m)15For gene ral purp ose use0~10 03014 08154 5
10 (1000 ) 3 553 -10D 10 µ S/cm~1 S/c m (1 mS/m~10 0 S/m)50For hig h conduct ivity w ater0~603014 081714
0.1 ( 10) 35 61-10D 0.1 µS /cm~10 mS/c m (10 µS/m~1 S/ m)10For low c onduct ivity wa ter (pur e water or o ther)0~603014082350
1 (100) 3 562-10 D 1 µS /cm~100 mS /cm (0.1 mS/m~10 S /m)16For gene ral purp ose use0~603014 082513
10 (1000 ) 3 573-10C 10 µS/c m~1 S/cm (1 mS /m~100 S/m)4F or high cond uctivi ty wate r0~603014082590
For col umn chrom atogra phy using a ve ry small
amou nt of samp le
Temp. Ran ge
(°C)
0~603014082592
Dissolved Oxygen Probes
TypeModelMeasurement RangeTemp. Ra nge (°C)Response TimePart No.
Field
9551- 20DDO : 0-19. 99mg /L0~40
9551-10 0DD O: 0-19 .99m g/L0~40
Lab952 0-10DDO: 0-19.9 9mg/ L0~45
30 seconds (90% response
time a t constan t tempera ture)
30 seconds (90% response
time a t constan t tempera ture)
20 seconds (90% response
time a t constan t tempera ture)
Par t No.
3014 04709 0
3014 047091
3014046711
02 |
pH Combination Electrodes
HORIBA pH Combination electrodes manufactured with 1 meter cable terminating in BNC connector allow these electrodes to be used with any
pH meter1. Enjoy the full spectrum of features and benefits of these electrodes on your existing pH meter1. (For applications where temperature
measurement and compensation is required, please refer to the 3-in-1 pH electrodes).
Type
pH
Range
Operating
Temperature
Range (°C)
9415 -10C General laboratory application
Standard ToupH electrode
0-140 -10 0Ceramic
Liquid
Junction
The electrode offers quick stability and
drift reduction.
• Constructed with responsive glass that is
10X stronger than JIS standards
• The one-touch refilling port slider allows
one-hand operation
• Waterproof, Pb-free glass
1
pH meters must h ave BNC connecto r
Application
32 00 6116 23
9425 -10 C General field application
Field plastic electrode
3200611625
9481-10C High viscosity application
Sleeve ToupH electrode
320 0611631
9418-10C Precious trace amount sample
Micro ToupH electrode
Overall lengt h: 198 mm
Diameter of pro be: 12 mm
Connecto r: BNC
Overall lengt h: 150 mm
Diameter of pro be: 16 mm
Connecto r: BNC
Overall lengt h: 203 mm
Diameter of pro be: 12 mm
Connecto r: BNC
0-140 -10 0Ceramic
0-140-60
0-140-60Ceramic
Movable
sleeve
Perfect for preparing pH buffers and other
aqueous test solutions.
The electrode has plastic body, which is ideal for
field measurement.
• Can be submerged up to 1m depth and
30mins (with refilling port closed)
• Waterproof, Pb-free glass
Recommended for field use. For measurement of
tap water and drinking water.
The electrode gives stable readings in highly
viscous samples.
• The liquid junction is designed with a
movable sleeve that can be cleaned easily
and prevents clogging
• Waterproof, Pb-free glass
For measurement of highly viscous samples and
samples containing non-aqueous solvents (e.g.,
cosmetics, paints).
The electrode can measure samples as small
as 50μL.
• Compatible with extremely small containers
(e.g., micro tubes)
• Temperature sensor is placed next to the
bulb for quick response
• Waterproof
32 00 6116 27
9480-10C For large containers and long test tubes
Long ToupH electrode
32 00 6116 28
60 69-10C For very slender test tubes
3014081107
| 03
Overall lengt h: 185 mm
Diameter of pro be: 3 mm
Connecto r: BNC
Overall lengt h: 283 mm
Diameter of pro be: 8 mm
Connecto r: BNC
Overall lengt h: 291 mm
Diameter of pro be: 3.15 mm
Connecto r: BNC
0-140 -10 0Ceramic
0-140-60 Ceramic
Suitable for low-volume samples and wide range
of aqueous solutions.
The long, thin body of the electrode is perfect for
large containers and test tubes.
• 283mm length, 8mm diameter
• Constructed with responsive glass that is
10X stronger than JIS standards
• Waterproof, Pb-free glass
For measuring samples (e.g., microbial culture
fluids) in test tubes and tall beakers.
The long, thin body of the electrode is perfect for
very slender test tubes.
• 291mm length, 3mm diameter
• Waterproof
For measuring samples in slender tubes (e.g.,
NMR test tube).
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