Herkules SC-06 User Manual

Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
SAFETY DATA SHEET
SC01 & SC06 Sparkle Clean
SECTION 1 – CHEMICAL PRODUCT and COMPANY IDENTIFICATION
Product Family Name: SC01 1qty Sparkle Clean
SC06 6qty Sparkle Clean Application: paint clean up Manufacturer/Supplier: Herkules Equipment Corporation Emergency Phone Number: 734-721-5930
SECTION 2 – HAZARDS IDENTIFICATION
Hazard Classification: Skin corrosion/irritation Category 2 Serious eye damage/eye irritation: Category 2A Reproductive Toxicity: Category 2 Specific target organ toxicity (single exposure): Category 3 Specific target organ toxicity (repeated exposure): Category 2 Aspiration toxicity: Category 1 Flammable aerosols: Category 1 Gases under press: Compressed Gas
Hazard Statements: Causes skin irritation Causes serious eye irritation Suspected of damaging fertility or the unborn child. May cause damage to organs (Blood, Central Nervous System, Eyes, Hematopoietic System, Kidney, Liver, Respiratory System, Skin, and reproductive System) through prolonged or repeated exposure. May be fatal if swallowed and enters the airways Extremely Flammable Aerosol Contains gas under pressure; may explode if heated.
Hazard Symbols:
Precautionary Statements Prevention: Obtain special instructions before use; Do not handle until all safety precautions have been read and understood; Wear protective gloves/protective clothing/eye protection/face protection; Wash face, hand and any exposed skin thoroughly after handling; Do not breathe dust/fume/gas/mist/vapors/spray; Use only outdoors or in well-ventilated area; Keep away from heat/sparks/open flames/hot surfaces- No smoking; Do not spray on an open flame or other ignition source; Pressurized container; do not pierce or burn, even after use.
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 1
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
Response: If exposed or concerned; Get medical advice/attention; Specific treatment (see first aid on the label); IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. If Inhaled: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. If SWALLOWED: Immediately call a poison center/doctor. Do NOT Induce vomiting.
Storage: Store locked up. Sore in a well-ventilated place. Keep container tightly closed. Protect from sunlight, Do not expose to temperatures exceeding 50 C/122 F.
Disposal: Dispose of contents/container to an approved waste disposal plant. Hazards Not Otherwise Classified (HNOC): None.
SECTION 3 – COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number Weight (Percent) * Acetone 67-64-1 40-50 Toluene 108-88-3 20-30 Propane/Isobutane/N-Butane 68476-86-8 10-20 Petroleum Distillates 64742-89-8 1-10 Methyl Acetate 79-20-9 1-10 2-Butoxyethanol 111-76-2 1-10 Isopropyl Alcohol 67-63-0 1-10 Ethylene Glycol 107-21-1 <0.1 Ethyl Benzene 100-41-4 <0.1 Benzene 71-43-2 <0.1 Methanol 67-56-1 <0.1 Acetaldehyde 75-07-0 <0.1
*The specific identity and/or percentage of composition has been withheld as a trade secret.
SECTION 4 – FIRST AID MEASURES
General: Causes skin and eye irritation. May cause respiratory irritation. May cause drowsiness. Harmful if swallowed and
enters airways. Avoid contact with eyes, skin, and clothing. Avoid breathing vapors, mist, or gas.
Eyes: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while
rinsing. If symptoms persist, call a physician.
Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician
or Poison Control Center immediately.
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact
emergency medical services immediately.
Skin: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical attention
immediately if symptoms occur. If symptoms persist, call a physician.
Notes to Physician: Provide general supportive measures and treat symptomatically.
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 2
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
SECTION 5 – FIRE FIGHTING MEASURES
Suitable Extinguishing Media: Water fog. Carbon Dioxide (CO2), Foam, Dry Chemical. Cool Tanks/containers with water spray.
Unsuitable Extinguishing Media: Do not use a cold water stream as it may scatter and spread fire. Special Exposure Hazards: Extremely flammable/Flammable. Keep product and empty container away from hear and
sources of ignition. Explosion Data
Sensitivity to Mechanical Impact: None. Sensitivity to Static Discharge: Yes.
Special Protective Equipment and Precautions for Firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MHSA/NIOSH (approved or equivalent) and full protective gear.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Personal Precautionary Measures: Use with adequate ventilation to keep exposure levels below the OELS. Environmental Precautionary Measures: Vapors can accumulate in low areas. Prevent further leakage or spillage if
safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains.
Procedure for Cleaning/Absorption Methods for containment: Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Use personal protective equipment. Dam up. Cover liquid spill with sand, earth or other noncombustible absorbent material. Take up mechanically or collect in suitable container for disposal. Clean contaminated surface thoroughly.
SECTION 7 – HANDLING AND STORAGE
Handling Precautions: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Avoid skin contact. Use with adequate ventilation. Keep container away from heat, flames, and all other sources of ignition. Keep can away from all sources of electricity such as electric motors and batteries. Do no spray on hot surfaces.
Storage Information: Keep container tightly closed in a dry and well-ventilated place. Keep away from open flames, hot surfaces, and sources of ignition. Keep in properly labeled containers. Keep out of the reach of children. Store locked up.
Incompatible products: Strong acids, alkalis, oxidizing agents. Aerosol Level: 3
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 3
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
SECTION 8 – EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Acetone STEL: 500 ppm TWA: 1000 ppm IDLH: 2500 ppm 67-64-1 TWA: 250 ppm TWA: 2400 mg/m (vacated) TWA: 750 ppm TWA: 590 mg/m3 (vacated) TWA: 1800 mg/m
the cellulose acetone fiber industry It is in effect for all other sectors. (vacated) STEL: 1000 ppm
Toluene TWA: 20 ppm TWA: 200 ppm IDLH: 500 ppm 108-88-3 (vacated) TWA: 100 ppm TWA: 100 ppm (vacated) TWA: 375 mg/m
Propane/Isobutane/ 74-98-6 TWA: 1000 ppm 74-98-6 TWA: 1000 ppm 74-98-6 IDLHL 2100 ppm N-Butane 106-97-8 STEL: 1000 ppm TWA: 1800 mg/m 68476-86-8 75-28-5: STEL: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1800 mg/m (vacated) TWA: 1800 mg/m3 106-97-8 TWA: 800 ppm 106-97-8: (vacated) TWA:800 ppm TWA:1900 mg/m3
Methyl Acetate STEL: 250 ppm TWA: 200 ppm IDLH: 3100 ppm 79-20-9 TWA: 200 ppm TWA: 610 mg/m3 TWA: 200 ppm (vacated) TWA: 200 ppm TWA: 610 mg/m3 (vacated) TWA: 610 mg/m3 STEL: 250 ppm (vacated) STEL: 250 ppm STEL: 760 mg/m3 (vacated) STEL: 760 mg/m3
2-Butoxyethanol TWA: 20 ppm TWA: 50 ppm IDLH: 700 ppm 111-76-2 TWA: 240 mg/m3 TWA: 5 ppm (vacated) TWA: 25 ppm TWA: 24 mg/m3 (vacated) TWA: 120 mg/m3 (vacated) S* S*
Isopropyl Alcohol STEL: 400 ppm TWA: 400 ppm IDLH: 2000 ppm 67-63-0 TWA: 200 ppm TWA: 980 mg/m3 TWA: 400 ppm (vacated) TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 980 mg/m3 STEL: 500 ppm (vacated) STEL: 500 ppm STEL: 1225 mg/m3 (vacated) STEL: 1225 mg/m3
Ethylene Glycol Ceiling: 100 mg/m3 (vacated) Ceiling: 50 ppm 107-21-1 aerosol only (vacated) Ceiling: 125 mg/m3
Ethyl Benzene TWA: 20 ppm TWA: 100 ppm IDLH: 800 ppm 100-41-4 TWA: 435 mg/m3 TWA: 100 ppm (vacated) TWA: 100 ppm TWA:435 mg/m3 (vacated) TWA: 435 mg/m3 STEL: 125 ppm (vacated) STEL: 125 ppm STEL: 545 mg/m3 (vacated) STEL: 545 mg/m3
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 4
3
(vacated) STEL: 2400 mg/m
3
3
TWA: 250 ppm
The acetone STEL does not apply to
3
TWA: 375 mg/m (vacated) STEL: 150 ppm STEL: 150 ppm (vacated) STEL: 560mg/m3 STEL: 560 mg/m3 Ceiling: 300 ppm
3
TWA: 1000 ppm
3
3
(vacated) TWA: 1900 mg/m3 75-28-5: TWA:800 ppm TWA: 1900 mg/m3
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Benzene STEL: 2.5 ppm TWA: 10 ppm applies to industry IDLH: 500 ppm 71-43-2 TWA: 0.5 ppm segments exempt from the TWA: 0.1 ppm Skin- potential benzene standard at 29 CFR STEL: 1 ppm significant contribution 1910.1028 to overall exposure TWA: 1 ppm by the cutaneous route (vacated) TWA: 10 ppm unless specified in 1910.1028 (vacated) STEL: 50 ppm 10 min unless specified in 1910.1028 (vacated) Ceiling: 25 ppm unless specified in 1910.1028 Ceiling 25 ppm STEL: 5 ppm see 29 CFR 1910.1028
Methanol STEL: 250 ppm TWA: 200 ppm IDLH: 6000 ppm 67-56-1 TWA: 200 ppm TWA: 260 mg/m3 TWA: 200 ppm Skin- potential significant (vacated) TWA: 200 ppm TWA: 260 mg/m3 contribution to overall (vacated) TWA: 260 mg/m3 STEL: 250 ppm exposure by the cutaneous (vacated) STEL: 250 ppm STEL: 325 mg/m3 route (vacated) STEL: 325 mg/m3 (vacated) S*
Acetaldehyde Ceiling: 25 ppm TWA: 200 ppm IDLH: 2000 ppm 75-07-0 TWA: 360 mg/m3 (vacated) TWA: 100 ppm (vacated) TWO 180 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 270 mg/m3
ACGIH: (American Conference of Governmental Industrial Hygienists) OSHA: (Occupational Safety & Health Administration) NIOSH IDLH: Immediately Dangerous to Life and Health
Other Exposure Guidelines – Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F. 2d 962 (11th Cir., 1992).
Other Precautions: Handle in accordance with good industrial hygiene and safety practice.
Personal Protective Equipment Eye/Face Protection: Safety glasses with side shields.
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current regulations.
Skin and Body Protection: Chemical resistant apron. Protective gloves.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Aerosol Appearance: Clear Color: Colorless Odor: Solvent Boiling point range Flash Point: -96.4 C / - 141 F (based on propellant)
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 5
Evaporation rate: No information available Flammability (solid, gas): No information available Specific Gravity: 0.783 Water solubility: Practically insoluble Partition coefficient: n-octanol/water VOC Content (%): 48.87
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
SECTION 10 – STABILITY AND REACTIVITY
Reactivity: No data available Chemical Stability: Stable under recommended storage conditions. Possibility of Hazardous Reactions: None under normal processing. Conditions to Avoid: Extremes of temperature and direct sunlight. Incompatibility (Materials to Avoid): Strong acids, alkalis, oxidizing agents. Hazardous Decomposition Products: Carbon oxides, Hydrocarbons, Fumes.
SECTION 11 – TOXICOLOGICAL INFORMATION
Principle Route of Exposure: Eye or skin contact, inhalation Symptoms Related to the Physical, Chemical and Toxicological Characteristics Eye Contact: Irritating to eyes. Ingestion: Harmful and may be fatal if swallowed and enters airways and lungs. Inhalation: Avoid inhaling vapors or mists. May cause irritation to respiratory system. Skin Contact: Irritating to skin.
Chemical Name LD50 Oral LD50 Dermal LD50 Inhalation Acetone (67-64-1) =5800 mg/kg (Rat) - =50100 mg//m3 (Rat) 8 h Toluene (108-88-3) =2600 mg.kg (Rat) =12000 mg/kg (Rabbit) =12.5 mg/L (Rat) 4 h Propane/Isobutane/N-Butane (68476-86-8) - - =31mg/l (Rat) 4 hr Petroleum Distillates (64742-89-8) - =300 mg/kg (Rabbit) ­Methyl Acetate (79-20-9) > 5 g/kg (Rat) > 5 g/kg (Rabbit) = 16000 ppm (Rat) 4 h 2-Butoxyethanol (111-76-2) =470 mg/kg (Rat) = 99 mg/kg (Rabbit) = 450 ppm (Rat) 4 h Isopropyl Alcohol (67-63-0) =1870 mg/kg (Rat) =4059 mg/kg (Rabbit) =72600 mg/m3 (Rat) 4 h Ethylene Glycol (107-21-1) =4700 mg/kg (Rat) =10600 mg/kg (Rat) ­Ethyl Benzene (100-41-4) =3500 mg/kg (Rat) = 15400 mg/kg (rabbit) =17.2 mg/L (Rat) 4 h Benzene (71-43-2) =800 mg/kg (Rat) > 8200 mg/kg (Rabbit) = 44.66 mg/L (Rat) 4 h Methanol (67-56-1) =6200 mg/kg (Rat) - =22500 ppm (Rat) 8 h Acetaldehyde (75-07-0) =660 mg/kg (Rat) - =13000 ppm (Rat) 4 h
Information on toxicological effects Symptoms: Causes skin and eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness.
Harmful and may be fatal if swallowed and enters airways.
Delayed and immediate effects as well as chronic effects from short and long-term exposure. Skin corrosion /irritation Irritating to the skin. Eye damage/irritation Irritating to the eyes. Irritation Causes skin and eye irritation. May cause respiratory irritation. Sensitization No information available. Germ cell mutagenicity. Not a germ cell mutagen. Carcinogenicity The table that follows indicates whether each agency has evaluated a listed ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA Toluene (108-88-3) - Group 3 - ­2-Butoxyethanol (111-76-2) - Group 3 - ­Ethyl Benzene (100-41-4) A3 Group 2B - ­Benzene (71-43-2) A1 Group 1 Known X Acetaldehyde (75-07-0) A2 Group 2B Reasonably Anticipated X
ACGIH: American Conference of Governmental Industrial Hygienists A3 – Animal Carcinogen IARC: International Agency for Research on Cancer Group 3 – Not Classifiable as to Carcinogenicity in Humans Group 1 – Carcinogenic to Humans OSHA: Occupational Safety & Health Administration X- Present
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 6
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
Toxicity Tests Specific target organ systemic toxicity (single exposure): May cause respiratory irritation. May cause drowsiness or dizziness. Specific target organ systemic toxicity (repeated exposure): May cause damage to blood, central nervous system, eyes, Hematopoietic system, kidney, liver, respiratory system, skin and reproductive system through prolonged or repeated use. Chronic toxicity: intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. May cause adverse liver effects. Reproductive/Developmental Toxicity: Product is or contains a chemical which is a known or suspected reproductive hazard. Aspiration Hazard: May be fatal if swallowed and enters airways.
Numerical measures of toxicity – Product information Unknown Acute Toxicity: 0% of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 11142 mg/kg ATEmix (dermal) 7485 mg/kg ATEmix (inhalation-dust/mist) 35.6 mg/l ATEmix (inhalation-vapor) 71 mg/l
SECTION 12 – ECOLOGICAL INFORMATION
Persistence/Degradability: Not determined Bio-accumulation:
Chemical Name log Pow Acetone (67-64-1) -0.24 Toluene (108-88-3) 2.7 Propane/Isobutane/N-Butane (68476-86-8) <=2.8 Methyl Acetate (79-20-9) 0.18 2-Butoxyethanol (111-76-2) 0.81 Isopropyl Alcohol (67-63-0) 0.05 Ethylene Glycol (107-21-1) -1.93 Ethyl Benzene (100-41-4) 3.2 Benzene (71-43-2) 2.1 Methanol (67-56-1) -0.77 Acetaldehyde (75-07-0) 0.5
Ecotoxicological Information Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Acetone - 4.74-6.33 mL/LC50 10294-17704 mg/L EC50 (67-64-1) Oncorhynchus mykiss 96 Daphnia magna 48h Static 6210-8120 mg/L LC50 12600-12700 mg/L EC50 Pimeplales promelas 96h Daphnia magna 48h static 8300 mg/L LC50 Lepomis macrochrius 96h
Toluene 433 mg/L EC50 15.22-19.05 mg/L LC50 5.46-9.83 mg/L EC50 (108-88-3) Pseudokirchneriella Pimephales promelas 96h Daphnia magna 48h Static subcapitata 96h 12.5 mg/L flow-through 12.6 mg/L LC50 11.5 mg/L EC50 Daphnia EC50 Pseudokirchneriella Oncorhynchus mykiss 96h magna 48h subcapitata 72h static static 5.89-7.81 mg/LC50 Oncorhynchus mykiss 96h flow-through 14.1-17.16 mg/L LC50 Oncorhynchrus mykiss 96h static 5.8 mg/L LC50 Oncorhynchus mykiss 96h semi-static 11.0-15.0 (continued)
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 7
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
Ecotoxicological Information (continued) Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other
aquatic invertebrates Toluene (continued) mg/L LC50 Lepomis macrochirus 96h static 54 mg/L LC50 Oryzias latipes 96h static 28.2 mg/L LC50 Poecilia reticulate 96H semi-static 50.87-70.34 mg/L LC50 Poecilia reticuluata
96h static
Propane/Isobutane/ N-Butane (68476-86-8) - - -
Petroleum Distillates 4700 mg/L EC50 - ­(64742-89-8) Pseudokirchneriella subcapitata 72h
Methyl Acetate 120 mg/L EC50 295-348 mg/L LC50 1026-7 mg/L EC50 Daphnia (79-20-9) Desmodesmus subspicatus Pimephales promelas 96h magna 48h 72h flow-through 250-350 mg/L LC50 Brachydanio rerio 96h static
2-Butoxyethanol - 1490 mg/L LC50 Lepomis 1000 mg/L EC50 Daphnia (111-76-2) macrochirus 96h static 2950 magna 48h mg/L LC50 Lepomis macrochirus 96h
Isopropyl Alcohol 1000 mg/L EC50 9640 mg/L LC50 13299 mg/L EC50 Daphnia (67-63-0) Desmodesmus subspicatus Pimephales promelas 96h magna 48h 96h 1000 mg/L EC50 flow-through 11130 mg/L DEsmodesmus subspicatus LC50 Pimephales promelas 72h 96h static 1400000 μg/L LC50 Lepomis macrochirus 96h
Ethylene Glycol 6500-13000 mg/L EC50 41000 mg/L LC50 46300 mg/L EC50 Daphnia (107-21-1) Pseudokirchneriella Oncorhynchus mykiss 96h magna 48h subcapitata 96h 14-18 mL/L LC50
Oncorhynchus mykiss 96h static 27540 mg/L LC50 Lepomis macrochirus 96h static 40761 mg/L LC50 Oncorhynchus mykiss 96h static 40000-60000 mg/L LC50 Pimephales promelas 96h static 16000 mg/L LC50 Poecilia reticulate 96h static
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 8
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
Ecotoxicological Information (continued) Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other
aquatic invertebrates Ethyl Benzene 4.6 mg/L EC50 11.0-18.0 mg/L LC50 1.8-2.4 mg/L EC50 (100-41-4) Pseudokirchneriella Oncorhynchus mykiss 96h Daphnia magna 48h subcapitata 72h 438 mg/L static 4.2 mg/L LC50 EC50 Pseudokirchneriella Oncorhynchus mykiss 96h subcapitata 96h 2.6-11.3 semi-static 7.55-11 mg/L mg/L EC50 LC50 Pimephales promelas Pseudokirchneriella 96 flow-through 32 mg/L subcapitata72 static 1.7- LC Lepomis macrochirus
7.6 mg/L EC50 96 static 9.1-15.6 mg/L Pseudokirchneriella LC50 Pimephales promelas subcapitata 96h static 96h static 9.6 mg/L LC50
Benzene 29 mg/L EC50 10.7-14.7 mg/L LC50 8.76-15.6 mg/L EC50 (71-43-2) Pseudokirchneriella Pimephales promelas 96h Daphnia magna 48h Static subcapitata 72h flow-through 5.3 mg/L LC50 10 mg/L EC50 Daphnia Oncorhynchus mykiss 96h magna 48h flow-through 22.49 mg/L LC 50 Lepomis macrochirus
Poecilia reticulate 96h static Pimephales promelas 96h static
Methanol - 28200 mg/L LC50 ­(67-56-1) Pimephales promelas 96h flow-
Pimephales promelas 96h static
Lepomis macrochirus 96h flow-through Acetaldehyde - 28.0-34.0 mg/L LC50 3.64-6.15 mg/L EC50
(75-07-0) Pimephales promelas 96h Daphnia magna 48h static flow-through 53 mg/L LC50 48.3 mg/L EC50 Daphnia Lepomis macrochirus 96h magna 48h static 1.8-2.4 mg/L LC50 Oncorhynchus mykiss 96h static
39.8-46.8 mg/L LC50 Pimephale promelas 96h static
The chemicals above have no measurable toxicity to microorganisms.
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 9
Poecilia reticulate 96h static
96h static 28.6 mg/L LC50 22330-41160 μg/L 70000-142000 μg/L
LC50 Lepomis macrochirus 96h static
through 100 mg/L LC50 19500-20700 mg/L LC50
Oncorhynchus mykiss 96h flow-through 18-20 mg/L LC50 Oncorhynchus mykiss 96h static 13500-17600 mg/L LC50
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
SECTION 13 – DISPOSAL CONSIDERATIONS
Disposal Method: This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Dispose of in accordance with federal, state and local regulations.
Contaminated Packaging: Do not re-use empty containers. Follow all applicable national or local regulations.
SECTION 14 – TRANSPORT INFORMATION
Ground Transportation
DOT – CONSUMER COMMODITY ORM-D or LIMITED QUANTITY
Air Transportation
IATA – UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY. IMDG – UN1950, AEROSOLS, 2.1, LTD. QTY.
SECTION 15 – REGULATORY INFORMATION Chemical Name | TSCA | DSL/NDSL | EINECS/ELINCS | ENCS | IECSC | KECL | PICCS | AIC
Acetone X X X X X X X X Toluene X X X X X X X X Propane/Isobutane/ X X X X X X X X
N-Butane Petroleum Distillates X X X NOT LISTED X X X X Methyl Acetate X X X X X X X X 2-Butoxyethanol X X X X X X X X Isopropyl Alcohol X X X X X X X X Ethylene Glycol X X X X X X X X Ethyl Benzene X X X X X X X X Benzene X X X X X X X X Methanol X X X X X X X X Acetaldehyde X X X X X X X X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS – European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS – Japan Existing and New Chemical Substances IENCSC – China Inventory of Existing Chemical Substances KECL – Korean Existing Inventory of Chemicals and Chemical Substances PICCS – Philippines Inventory of Chemicals and Chemical Substances AICS – Australian Inventory of Chemical Substances
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 10
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
U.S. Federal Regulations SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does contain a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulation, Part 372: Chemical Name CAS-No. Weight% SARA 313 – Threshold Values % Toluene - 108-88-3 108-88-3 23.8137 1.0 2-Butoxyethanol - 111-76-2 111-76-2 4.21836 1.0 Isopropyl Alcohol - 67-63-0 67-63-0 1.70439 1.0 Ethylene Glycol - 107-21-1 107-21-1 <0.1 1.0 Ethyl Benzene - 100-41-4 100-41-4 <0.1 0.1 Benzene - 71-43-2 71-43-2 <0.1 0.1 Methanol - 67-56-1 67-56-1 <0.1 1.0 Acetaldehyde - 75-07-0 75-7-0 <0.1 0.1
SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Star Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard Yes Reactive Hazard No
Clean Water Act This product does contain the following substances which are regulated pollutants pursuant to the Clean Air Act (40 CFR 122.21 and 40 CFR 122.42):
Chemical Name CWA-Reportable Quantities CWA – Toxic Pollutants CWA- Priority Pollutants CWA-Hazardous Substances Toluene 1000 lbs. X X X 108-88-3 Ethyl Benzene 1000 lbs. X X X 100-41-4 Benzene 10 lbs. X X X 71-43-2 Acetaldehyde 1000 lbs. X 75-7-0
CERCLA This material, as supplied does contain substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Chemical Name Hazardous Substances RQs RQ Acetone 5000 lb RQ 5000 lb final RQ 67-64-1 RQ 2270 kg final RQ Toluene 1000 lb 1 lb RQ 1000 lb final RQ 108-88-3 RQ 454 final RQ RQ 1 lb final RQ RQ 0.454 kg final RQ Ethylene Glycol 5000 lb RQ 5000 lb final RQ 107-21-1 RQ 2270 kg final RQ Ethyl Benzene 1000 lb RQ 1000 lb final RQ 100-41-4 RQ 454 kg final RQ Benzene 10 lb RQ 10 lb final RQ 71-43-2 RQ 4.54 kg final RQ Methanol 5000 lb RQ 5000 lb final RQ 67-56-1 RQ 2270 kg final RQ Acetaldehyde 1000 lb RQ 1000 lb final RQ 75-7-0 RQ 454 kg final RQ
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 11
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
U.S. State Regulations California Proposition 65
This product contains the following Proposition 65 chemicals:
This product can exposure users to chemicals including those listed below, which are known to the State of California to cause cancer. birth defects or other reproductive harm. For more information, visit www.p65warnings.ca.gov.
Chemical Name California Prop. 65 Toluene 108-88-3 Developmental 20-30% Ethylene Glycol 107-21-1 Developmental <0.1% Ethyl Benzene 100-41-4 Cancer 1-10% Benzene 71-43-2 Cancer/Developmental <0.1% Methanol 67-56-1 Developmental <0.1% Acetaldehyde 75-7-0 Cancer <0.1%
U.S. State Right to Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania
Acetone X X 67-64-1 Toluene X X X 108-88-3 Petroleum Distillates X 64742-89-8 Methyl Acetate X X X 79-20-9 2-Butoxyethanol X X X 111-76-2 Isopropyl Alcohol X X X 67-63-0 Ethylene Glycol X X X 107-21-1 Ethyl Benzene X X X 100-41-4 Benzene X X X 71-43-2 Methanol X X X 67-56-1 Acetaldehyde X X X 75-7-0
EPA Pesticide Registration Number: Not applicable Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by the CPR.
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 12
Herkules Equipment Corporation
2760 Ridgeway Court
Walled Lake, MI 48390-1662
Fax: 248-960-7109
www.herkules.us
SECTION 16 - OTHER INFORMATION
NFPA Health Hazard 2 Flammability 4 Instability 0 Physical and chemical hazards – HMIS Health Hazard 2 Flammability 4 Physical Hazard 1 Personal protection B
DISCLAIMER: All information presented herein is believed to be accurate; however, it is the user’s responsibility to determine in advance of need that the information is current and suitable for their circumstances. No warranty or guarantee, express or implied, is made by Herkules as to this information, or as to the safety, toxicity or effect of the use of this product.
Updated October 12, 2020
l155_01_herkules_sparkle_clean_safety_data_sheet pg. 13
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