Hanna Instruments HI8417, HI8519, HI8520, HI8521 User Manual

Instruction Manual
HI8417 - HI8519 HI8520 - HI8521
Microprocessor
Bench-top
pH Meters
ON
BUFFER VALUES 20°C
d1
NBS
t1
pH
STD
OFF
6,88
d2
pH
NBS
7,02
t2
pH
STD
4,00
d3
pH
NBS
t3
pH
STD
pH
CAL
4,00
9,22
10,05
CON
°C
http://www.hannainst.com
°C
°C
pH
mV
Compliance with the CE Directives
pH
These Instruments are in
Dear Customer, Thank you for choosing a Hanna Instruments Product. Please read this instruction manual carefully before using the instru-
ment. This manual will provide you with all the necessary information for
the correct use of the instrument, as well as a precise idea of its versatility in a wide range of applications.
These instruments are in compliance with CSA, UL and (EN 50081-1 and EN 50082-1) directives.
TABLE OF CONTENTS
PRELIMINARY EXAMINATION 3 GENERAL DESCRIPTION 3 FUNCTIONAL DESCRIPTION AND SPECIFICATIONS: HI8417 5 HI8519 8 HI8520 10 HI8521 12
OPERATIONAL GUIDE 14 PH CALIBRATION 18 PROCEDURE FOR HI8417 18 PROCEDURE FOR HI8519 20 PROCEDURE FOR HI8520/HI8521 21 CAL. W/ MANUAL TEMP. COMPENSATION 22 PH VALUES AT VARIOUS TEMPERATURE 23 TEMPERATURE CALIBRATION 23 TROUBLESHOOTING GUIDE 24 ELECTRODE CONDITIONING & MAINTENANCE 25 TEMPERATURE-RESISTANCE CORRELATION FOR HANNA PH SENSITIVE GLASS 28 ACCESSORIES 30 ELECTRODE APPLICATION REFERENCE GUIDE 37 WARRANTY 38 CE DECLARATION OF CONFORMITY 39
ISO 9000 Certified Company since 1992
2
PRELIMINARY EXAMINATION
Remove the instrument from the packing material and examine it to make sure that no damage has occurred during shipping. If there is any damage, notify your dealer.
Note: Save all packing material until you are sure that the instru-
ment functions correctly. All defective items must be returned in the original packing with the supplied accessories.
GENERAL DESCRIPTION
HI8417, HI8519, HI8520 and HI8521 Hanna Instruments bench­top pH meters are designed for simplicity of use.
They feature: large liquid crystal display (LCD), user friendly key­board, error codes to guide the user in calibration and troubleshooting and storage of calibration data even after the unit is shut off.
HI8417, HI8519 and HI8521 can also measure ion concentration (ISE) and ORP in the mV range (with automatic range switching from ISE to ORP when reading exceeds ±399.9mV, HI8417 and HI8521 only).
All models, except for HI8519, are microprocessor-based and provide automatic or manual temperature compensation for both calibration and measurement.
These models meet the most stringent demands of the laboratory:
HI8417 pH/mV/°C meter automatically recognizes six standard calibration buffer values-three each for NBS (pH 4.01, 6.86, 9.18) technical standard calibration buffers (pH 4.01, 7.01, 10.01).
A recorder output of 0 to 2 Volts is available and the wide mV range and high resolution allow for ORP or ion-selective measurement.
HI8417 comes supplied with HI1131B glass-body combination pH electrode, HI7669/2W temperature probe (with 1 meter / 3.3' cable), 12VDC adapter (HI710005 or HI710006) and a dust cover.
HI 8519 pH/mV meter includes: manual temperature compensation and front panel knobs for offset and slope calibration.
HI8519 comes supplied with HI1332B plastic-body combination pH electrode, 12VDC adapter (HI710005 or HI710006) and a dust cover.
3
HI8520 pH/°C meter automatically recognizes 3 standard calibration buffer values (4.01, 7.01 and 10.01 pH).
HI8520 comes supplied with HI1332B plastic-body combination pH electrode, HI7669/2W temperature probe (with 1 meter/ 3.3' cable), 12VDC adapter (HI710005 or HI710006) and a dust cover.
HI8521 pH/mV/°C meter automatically recognizes 3 standard cali­bration buffer values (4.01, 7.01 and 10.01 pH).
HI8521 comes supplied with HI1332B plastic-body combination pH electrode, HI7669/2W temperature probe (with 1 meter/ 3.3' cable), 12VDC adapter (HI710005 or HI710006) and a dust cover.
4
FUNCTIONAL DESCRIPTION &
SPECIFICATIONS OF HI8417
THE FRONT PANEL OF HI8417
HI 8417
°C
BUFFER VALUES 20°C
ON
OFF
NBS
d1t1pHpH6,88
STD
pH
d2
NBS
pH
t2
STD
pH
NBS
pH
STDd3t3
7,02 4,00
4,00 9,22
10,05
pH
°C
CAL
CON
pH
mV
°C
ON / OFF To turn the instrument ON and OFF. (Warning: Push the OFF key before unplugging instrument. If unplugged before turned off, the meter's memory will be erased).
CAL To enter the calibration mode. CON To confirm the calibration data.
°C / °C To set temperature for manual compensation.
pH/mV To select mV for mV, ORP or ISE measurements
or pH for pH measurements.
Large LCD on the left
This LCD displays the temperature measured by the HI7669/2W probe or the value set manually with the keyboard. If the tempera­ture has been set manually, the "°C" symbol will flash. When the temperature probe is connected the "°C" symbol stops flashing. When the temperature measured by the probe is out of range (-10 / +125°C), the "Err3" signal appears.
Large LCD on the right
This LCD displays the pH or mV reading. The corresponding pH or mV symbol will be displayed along with the measured value. An error signal ("Err1", "Err2", "Err4" or "Err5") will appear on this display to indicate when the range is exceeded or if the buffer during calibration is wrong.
5
THE REAR PANEL OF HI8417
TEMPERATURE
COMBINED pH or ORP
ELECTRODES
REFERENCE ELECTRODE
RESET
RECORDER
0-2 VOLT
PROBE
DC POWER 12V to 20V
+
1
23
4
5
6
1. BNC socket for pH and ORP electrode.
2. Reference Jack socket for reference electrode.
3. RESET button.
4. Recorder output connections.
5. Temp. Probe socket (for HI7669/2W).
6. DC Power Socket (for HI710005 or HI710006).
Electrode and probe connections
For combination pH or ORP electrodes (with internal reference) plug the electrode's BNC to the socket provided (#1).
For an electrode with a separate reference, connect the measuring electrode's BNC to the BNC socket (#1) and the reference electrode's jack to the socket provided (#2).
For temperature measurements and automatic temperature com­pensation connect the temperature probe to the °C socket (#5).
Recorder Output HI8417 is provided with a recorder output from 0 to 2 volts. Connect
the recorder output (#4) and select the pH or mV range by pressing the pH/mV key. The output signal is related to the values as follows:
pH output:
0.01 pH = 1.42857 mV
e.g. 0.00 pH = 0 mV
7.00 pH = 1000 mV
14.00 pH = 2000 mV
mV output:
0.1 mV= 0.05 mV
e.g. -1999 mV = 0 mV
0.0 mV = 1000 mV
+1999 mV = 2000 mV The output impedance is 100 ohms. The maximum output short­circuit current is 20 mA.
RESET button
The RESET button (#3) is used when the instrument displays errone­ous messages due to strong electrical interference or when the
6
instrument's power supply is disconnected before the meter is switched off. Press the RESET button and restart the entire operation.
Power connection
Plug the 12VDC adapter (HI710005 or HI710006) into the DC socket (#6).
Note: Make sure the main line is protected by a fuse. Note: HI8417 uses a rechargeable battery to retain the pH calibra-
tion data. It lasts approximately one month when fully charged. The battery is automatically charged any time the meter is plugged-in (either turned on or off).
SPECIFICATIONS HI8417 Range pH 0.00 to 14.00
ISE 0.0 to ±399.9mV
ORP ±1999mV
°C -10.0 to 125.0
Resolution pH 0.01
ISE 0.1mV
ORP 0.1/1mV
°C 0.1
Accuracy pH ±0.01 (@ 20°C / 68°F)ISE ±0.2 mV
ORP ±1 mV
°C ±0.5
Typical EMC pH ±0.01 Deviation ISE/ORP ±0.2mV
°C ±0.7
Recorder pH 0 to 2 V Output mV 0 to 2 V
Max. Current 20mA
Offset ±1 pH Slope from 85% to 105% Calibration Automatic 2 points with 5 memorized buffers
(pH 4.01, 6.86, 7.01, 9.18, 10.01)
Temperature Manual from 0 to 100°C (32 to 212°F) Compensation Automatic from -10 to 125°C (14 to 257°F) Electrode HI1131B glass body combination refillable
pH electrode (included) Temp. Probe HI7669/2W Temperature Probe (included) Input Impedance 1012 ohm Power Power socket for 12VDC Environment 0 to 50°C (32 to 122°F);
95% RH (not condensing)
Dimensions 230Lx170Wx70H mm (9.1x6.7x2.7") Shipping Weight 1.5 Kg (3.3 lb.)
7
FUNCTIONAL DESCRIPTION &
SPECIFICATIONS OF HI8519
THE FRONT PANEL OF HI8519
pH
HI 8519
OFFSET SLOPE TEMPERATURE °C
OFFSET
Temperature
Buffer Values (pH)
°C°F4.01 7.01
0
4.01
32
10
4.00
50
20
4.00
68
30
4.02
86
40
4.04
104
7.13
7.07
7.03
7.00
6.98
SLOPE
10.01
10.32
10.18
10.06
pH
9.96
9.88
mV
TEMPERATURE °C
°C
ON
OFF
ON/OFF To switch the meter ON and OFF. pH To display pH values. mV To display mV values. °C To display temperature values set by the temperature knob
(for pH compensation).
Knobs OFFSET For adjustment of offset during pH calibration. SLOPE For adjustment of slope during pH calibration. TEMP °CFor setting temperature in °C.
THE REAR PANEL OF HI8519
COMBINED pH
ORP
REFERENCE
ELECTRODES
ELECTRODE
12
1. BNC socket for pH or ORP electrode.
2. Reference Jack socket for reference electrode.
3. DC Power Socket (for HI710005 or HI710006).
DC POWER 12V to 20V
3
+
THIS METER IS NOT
PROTECTED BY FUSE
8
Electrode and probe connections
For combination pH or ORP electrodes (with internal reference) plug the electrode's BNC to the socket provided (#1).
For an electrode with a separate reference, connect the measuring electrode's BNC to the BNC socket (#1) and the reference electrode's jack to the socket provided (#2).
Power connection
Plug the 12VDC adapter (HI710005 or HI710006) into the DC socket (#3).
Note: Make sure the main line is protected by a fuse.
SPECIFICATIONS HI 8519
Range pH 0.00 to 14.00
mV ±1999
Resolution pH 0.01
mV 1
Accuracy pH ±0.01 (@20°C / 68°F) mV ±1 Typical EMC pH ±0.06 Deviation mV ±4 Calibration Manual 2 points through
offset and slope knobs
Temperature Manual from 0 to 100°C Compensation (32 to 212°F) Electrode HI 1332B plastic body, combination,
double junction refillable
pH electrode (included)
Input Impedance 1012 ohm Power 12VDC power Environment 0 to 50°C (32 to 122°F); 95% RH Dimensions 230x170x70 mm (9.1x6.7x2.7") Shipping Weight 1.35 Kg (3 lb.)
9
FUNCTIONAL DESCRIPTION &
SPECIFICATIONS OF HI8520
THE FRONT PANEL OF HI8520
ERROR SYMBOLS
E1: pH out of range E2: °C out of range E4: wrong pH 7 E5: wrong pH 4/10
°C
Temperature Buffer Values (pH)
CAL
CON
°F
°C
0
32
10
50
20
68
30
86
40
104
4.01 7.01 10.01
4.01
7.13
4.00
4.00
4.02
4.04
10.32
7.07
10.18
7.03
10.06
7.00
9.96
6.98
9.88
ON
OFF
RANGE
ON / OFF To switch instrument ON and OFF. RANGE To display pH or temperature measurements. CAL/CON CAL to enter the calibration procedure and CON to
confirm calibration data.
/ For setting temperature for manual compensation.
THE REAR PANEL OF HI8520
TEMPERATURE
DC POWER 12V to 20V
COMBINED pH or ORP
REFERENCE
RESET
ELECTRODE
ELECTRODES
23
1
1. BNC socket for pH electrode.
2. Reference Jack socket for reference electrode.
3. RESET button.
4. Temperature Probe socket (for HI7669/2W).
5. DC Power Socket (for HI710005 or HI710006).
Electrode and probes connections
For combination pH electrodes (with internal reference) plug the electrode's BNC to the socket provided (#1).
For an electrode with a separate reference, connect the measuring electrode's BNC to the BNC socket and the reference electrode's jack to the socket provided (#2).
For temperature measurements and automatic temperature com­pensation connect the temperature probe to the °C socket (#4).
RESET button
The RESET button (#3) is used when the instrument displays errone­ous messages due to strong electrical interference or when the instrument's power supply is disconnected before the meter is switched
PROBE
+
4
5
10
off. Press the RESET button and restart the entire operation.
Power connection
Plug the 12VDC adapter (HI710005 or HI710006) into the socket on the back of the meter (#5).
Note: Make sure the main line is protected by a fuse. Note: HI8520 uses a rechargeable battery to retain the pH calibra-
tion data. It lasts approximately one month when fully charged. The battery is automatically charged any time the meter is plugged-in (either turned on or off).
SPECIFICATIONS HI 8520
Range pH 0.00 to 14.00
°C 0.0 to 100.0
Resolution pH 0.01
°C 0.1
Accuracy pH ±0.01 (@20°C / 68°F) °C ±0.4 Typical EMC pH ±0.02 Deviation °C ±0.4 Calibration Automatic 2 points with auto-buffer
recogntion
Temperature Automatic or Manual Compensation From 0 to 100°C (32 to 212°F) Electrode HI 1332B plastic body, combination,
double junction refillable
pH electrode (included)
Temperature Probe HI 7669/2W temp. probe (included) Input Impedance 1012 ohm Power 12VDC power Environment 0 to 50°C (32 to 122°F); 95% RH Dimensions 230x170x70 mm (9.1x6.7x2.7") Shipping Weight 1.35 Kg (3 lb.)
11
FUNCTIONAL DESCRIPTION &
SPECIFICATIONS OF HI8521
THE FRONT PANEL OF HI8521
ERROR SYMBOLS
E1: pH out of range E2: °C out of range E3: mV out of range E4: wrong pH 7 E5: wrong pH 4/10
°C
Temperature Buffer Values (pH)
CAL
CON
°F
°C
0
32
10
50
20
68
30
86
40
104
4.01 7.01 10.01
4.01
7.13
4.00
4.00
4.02
4.04
10.32
7.07
10.18
7.03
10.06
7.00
9.96
6.98
9.88
ON
OFF
RANGE
ON / OFF To switch instrument ON and OFF. RANGE To display pH / ORP / Temperature measurements. CAL/CON CAL to enter the calibration procedure and CON to
confirm calibration data.
/ For setting temperature for manual compensation.
THE REAR PANEL OF HI8521
TEMPERATURE
DC POWER 12V to 20V
COMBINED pH or ORP
REFERENCE
RESET
ELECTRODE
ELECTRODES
23
1
1. BNC socket for pH or ORP electrode.
2. Reference Jack socket for reference electrode.
3. RESET button.
4. Temperature Probe socket (for HI7669/2W).
5. DC Power Socket (for HI710005 or HI710006).
PROBE
+
4
5
Electrode and probes connections
For combination pH or ORP electrodes (with internal reference) plug the electrode's BNC to the socket provided (#1).
For an electrode with a separate reference, connect the measuring electrode's BNC to the BNC socket and the reference electrode's jack to the socket provided (#2).
For temperature measurements and automatic temperature com­pensation connect the temperature probe to the °C socket (#4).
RESET button
The RESET button (#3) is used when the instrument displays errone­ous messages due to strong electrical interference or when the
12
instrument's power supply is disconnected before the meter is switched off. Press the RESET button and restart the entire operation.
Power connection
Plug the 12VDC adapter (HI710005 or HI710006) into the socket on the back of the meter (#5).
Note: Make sure your main line is protected by a fuse. Note: HI8521 uses a rechargeable battery to retain the pH calibra-
tion data. It lasts approximately one month when fully charged. The battery is automatically charged any time the meter is plugged-in (either turned on or off).
SPECIFICATIONS HI 8521
Range pH 0.00 to 14.00
ISE 0.0 to ±399.9mV
ORP 0 to ±1999mV
°C 0.0 to 100.0
Resolution pH 0.01
ISE 0.1mV
ORP 1mV
°C 0.1
Accuracy pH ±0.01 (@20°C / 68°F) ISE ±0.2mV
ORP ±0.1mV
°C ±0.4
Typical EMC pH ±0.05 Deviation ISE/ORP ±4mV
°C ±0.1
Calibration Automatic 2 points with auto-buffer
recogntion
Temperature Automatic or Manual Compensation From 0 to 100°C (32 to 212°F) Electrode HI 1332B plastic body, combination,
double junction refillable
pH electrode (included)
Temperature Probe HI 7669/2W temp. probe (included) Input Impedance 1012 ohm Power 12VDC power Environment 0 to 50°C (32 to 122°F); 95% RH Dimensions 230x170x70 mm (9.1x6.7x2.7") Shipping Weight 1.4 Kg (3.1 lb.)
13
OPERATIONAL GUIDE
pH
TAKING PH MEASUREMENTS
Connect the instrument to the 12VDC adapter (HI710005 or HI710006). Plug the adapter into the mains.
Make sure that the instrument has been calibrated for pH before taking pH measurements (see page 18).
For HI8519 only:
• Connect the pH electrode to the meter and switch
the instrument on by pressing the ON/OFF key.
• Immerse the electrode tip (4 cm/1½") into the sample and shake
briefly.
• Take the temperature of the solution with a
ChecktempC or a glass thermometer (e.g.25°C).
ON
OFF
°C
C °
• Press the °C key to display temperature settings on
the LCD.
• Adjust the Temperature °C knob to display the
temperature of the sample.
• Press the pH key to display the pH measurement.
• The display shows the pH value of the test solution
compensated for temperature.
For HI8417, HI8520, HI8521 only:
• Connect the electrode and the temperature
probe (if automatic temperature compensa­tion is desired).
• Press the ON/OFF key to turn the meter on. The
meter will automatically default to the pH measure­ment mode.
• Immerse the electrode and the temperature probe
in the sample and shake briefly. Wait for 30 sec­onds before taking readings.
• The display shows the pH reading compensated for
temperature.
°C
pH
ON
OFF
14
• In HI8417 the temperature reading is also displayed on the left
LCD.
°C
pH
Note: the electrode should be submerged approximately 4 cm (1½")
into the solution. If the temperature probe is used, it should be located as close to the pH electrode as possible.
(1½
4 cm
")
If measurements are taken in different samples successively, it is recommended that the electrode is rinsed thoroughly for better condi­tioning and to eliminate cross-contamination of the sample.
For the rinsing process, it is recommended to use a liberal amount of the next solution to be measured.
Using refillable electrodes
Unscrew the small refill cap to open the refill hole during measure­ments. After measurement replace the refill hole cap.
MANUAL TEMPERATURE COMPENSATION FOR HI8417, HI8520 AND HI8521
• When the temperature probe is not connected,
take the temperature of the solution with a ChecktempC or a glass thermometer.
• Press the RANGE key to enter the temperature mode
(not necessary for HI8417).
15
C °
°C
RANGE
• When the temperature is set manually,
ºC
"°C" symbol blinks. With the tempera­ture probe connected, the "°C" symbol is displayed continuously.
• Use the UP or DOWN arrow keys to
°C
°C
manually adjust the display reading to the value of the reference ther­mometer.
TAKING TEMPERATURE MEASUREMENTS (NOT FOR HI
8519)
• Taking a temperature measurement is very easy.
• Turn the instrument ON and press the RANGE key
RANGE
(for HI8520 and HI8521 only) to get into tem­perature mode.
• Make sure the temperature probe is connected and allow the reading to stabilize (1 or 2 min­utes).
• The temperature value will be dis­played on the left LCD for HI8417.
°C pH
TAKING ORP MEASUREMENTS
HI8417, HI8519 and HI8521 have the capability to take ORP measurements, using an ORP electrode. Hanna Instruments offers a variety of ORP electrodes for this purpose (see page 35). Contact your Dealer for more information.
Just as pH measurements allow the acidity or the alkalinity of a substance to be expressed in numbers, oxidation-reduction potential (redox) measurements provide the quantification of the oxidizing or reducing power of any liquid.
For HI8519 only:
• Connect the ORP electrode to the meter and submerge the tip (4 cm / 1½") into the sample to be tested.
Note: ORP measurements are taken without tem-
perature compensation.
• Press the mV key to enter the mV mode. Allow a few minutes for the reading to stabilize.
• The display will indicate the absolute mV value (positive or negative).
mV
mVmV
(1½ ")
4 cm
16
For HI8417 and HI8521
• Connect the ORP electrode to the meter and submerge the tip (4 cm / 1½") into the sample to be tested.
Note: ORP measurements are taken without temperature compensa-
tion.
• Press the pH/mV key (HI8417) or RANGE key (HI8521) once to enter
RANGE
pHpH
mVmV
the mV mode.
• Allow a few minutes for the reading to stabilize.
• The display will indicate the absolute mV value (positive or negative).
mV
• When values are less than ±400 mV, tenths of mV are dis­played; for values greater than ±400 mV, the decimal digit disappears. Note that the change in scale (from 0.1mV to 1mV resolution) is automatic. "Err2" for HI8417 or "E3" for HI8521 appears if the value exceeds ±1999 mV (out of range).
AFTER MEASUREMENTS
• Press the ON/OFF key again to switch the instru­ment OFF.
ON
OFF
17
PH CALIBRATION
IMPORTANT
The instrument's pH range should be re-calibrated:
• When the meter is new.
• Whenever the pH electrode is replaced.
• At least once a month.
• After use in aggressive chemicals.
• After cleaning procedure and changing the reference electrolyte.
• For greatest accuracy.
INITIAL PREPARATION
Pour small quantities (up to 4cm / 1½" level) of pH 7.01 (HI7007 or HI8007) and pH4.01 (HI7004 or HI8004) or pH 10.01 (HI7010 or HI8010) solution into clean beakers. If possible use plastic beakers to minimize any EMC interferences.
If you are measuring in the acid range use pH4.01 as second buffer or pH 10.01 if you are measuring in the alkaline range.
Note: with HI8417 HI7006/HI8006 (pH 6.86) and HI7009/HI8009
(pH 9.18) can be used in place of HI7007/HI8007 (pH 7.01) and HI7010/HI8010 (pH 10.01) respectively.
For accurate calibration, use two bea-
RINSE
kers for each buffer solution; the first for rinsing the electrode, the second
HI 7007
for calibration. In this way, contami­nation of the buffer is minimized.
Note: the electrode should be submerged approxi-
mately 4 cm (1½") into the solution. If the temperature probe is used, it should be posi­tioned as close to the pH electrode as possible.
4
0
0
I 7 H
HI 7004 HI 7007
CALIBRATION
HI 7007
(1½ ")
4 cm
PH CALIBRATION FOR HI8417
HI8417 provides 6 pre-programmed calibration buffers: three NBS buffers (d1, d2, d3 i.e. pH 6.86, 4.01, 9.18 respectively) and three technical buffers (t1, t2, t3 i.e. pH 7.01, 4.01, 10.01 respectively).
When the ATC probe is not used, make sure the temperature is set manually to reflect the temperature of the solution (see page 23).
18
Procedure:
• Switch the instrument on after connecting the pH electrode and the temperature probe.
• Immerse the pH electrode and the ATC probe into a neutral pH buffer solution (pH 7.01 for technical buffers, or pH 6.86 for NBS buffers).
Shake briefly and wait 1-2 minutes for thermal equilibrium.
• Press the CAL key. The symbol "d1" will appear on the display. For calibration with technical buffers (pH 7.01), press CAL key again and "t1" will appear on the display.
(Note: the "pH" symbol will be flashing throughout the calibration procedure).
• Press the CON key. The buffer value will be displayed on the right LCD.
• Allow 1-2 minutes for the pH reading to stabi­lize.
The pH reading will be temperature compensated. E.g. if the buffer temperature is at 25°C, the right display will
show "pH 7.01". If the buffer temperature is at 20°C, the display will show "pH 7.03" (see page 23).
°C
pH
ON
CAL
CON
If "Err4" appears the calibration solution is wrong. Repeat the process using fresh buffers.
Note: If you are not using the ATC probe, refer to page 22 to
manually correct for temperature.
• Press the CON key again to accept the buffer value.
CON
The first point calibration is now complete.
• If the pH/mV key is pressed at this point, the cali­bration process is ended and only the offset of the meter is calibrated. This is known as one point calibration. For greatest accuracy, however, it is recommended that a two-point calibra­tion is performed.
• Rinse the electrode and the temperature probe before immersing them into pH 4.01/ pH10.01 (or 9.18) calibration buffer, shake briefly and wait for thermal equilibrium.
19
• The meter automatically recognizes the buffer value and prompts for the second at "d2" or "t2" (= pH 4.01, acid) or "d3" or "t3" (pH 9.18 and pH10.01 respectively, alkaline).
CON
• Press the CON key to confirm the pH value.
• The display will indicate the temperature compen­sated buffer value e.g. if the temperature is at 25°C, the display will show "pH 4.01" or "10.01" or "pH 9.18", depending on the solution being used. If the temperature is at 20°C, the display will show respectively "pH 4.00" or "pH 10.06" or "pH 9.22" (see page 23).
°C
pH
• Press CON key again to confirm calibration. The
CON
meter is now calibrated.
• The pH symbol will stop flashing and the unit is ready for measurements.
• If the reading is drifting, turn the meter off and repeat the calibration procedure waiting longer for the reading to stabilize. However, usually 1 or 2 minutes is enough time to prevent a drifting reading.
Note: If you need to unplug the instrument, press the OFF key thus
switching the instrument off before disconnecting the power cord. In this way the instrument will retain the calibration data. Otherwise, re-calibration might be necessary. In the case of a power failure while the instrument is operational, re­calibration might be required.
PH CALIBRATION FOR HI8519
Note: If you need to calibrate to NBS standards, use pH 6.86
(HI7006 or HI8006) and pH 9.18 (HI7009 or HI8009) in­stead of pH7.01 and 10.01 respectively.
Use a ChecktempC or a glass thermometer with an resolution of 0.1°
as reference thermometer.
20
Procedure:
• Switch the instrument on after connecting the pH electrode.
• Rinse and immerse the pH electrode in pH 7.01 buffer and shake briefly. Wait 1 or 2 minutes for the reading to stabilize.
• Note the temperature of the buffer solution using a ChecktempC or a glass thermometer (e.g.20°C).
• Press the °C key to select temperature setting. Ad­just the Temperature °C knob until display shows the noted temperature.
°C
ON
OFF
C
°
°C
°C
TEMPERATURE °C
• Press the pH key to select pH measure­ment.
• Wait 1-2 minutes and adjust the OFFSET knob until display shows the pH value at the noted temperature (see the pH versus temperature chart at page 23).
• Rinse and immerse the pH electrode in pH 4.01/pH 10.01 buffer and shake
pH
briefly.
• Wait 1-2 minutes and adjust the SLOPE knob until display shows the pH value at the noted temperature (see the pH versus temperature chart at page 23).
• The pH calibration is now complete.
pH
PH CALIBRATION FOR HI8520 AND HI8521
Procedure:
• Switch instrument on after connecting the pH elec­trode and the temperature probe.
• Immerse the pH electrode and the temperature probe in pH 7.01 buffer solution, shake briefly and wait 1 or 2 minutes for thermal equilibrium.
• Press the RANGE key to display pH measurement.
OFFSET
SLOPE
pH
ON
OFF
RANGE
(1½
4 cm
")
21
• Press the CAL key. The temperature compensated
CAL
buffer value will be displayed e.g. if the buffer temperature is at 25°C, the display will show pH7.01. If the buffer temperature is at 20°C, display will show pH 7.03 (see page 23). If
pH
"E4" appears the calibration solution is wrong.
• Wait until the pH symbol stops flashing: that means the reading is stable.
CON
• Press the CON key. The symbol "E5" will appear to indicate that the electrode is still in pH 7.01 buffer, but expecting a pH 4.01 or 10.01 buffer.
• Rinse the electrode and temperature probe be­fore immersing them into pH 4.01 / pH 10.01 calibration buffer, shake briefly and wait for thermal equilibrium.
• The symbol "E5" should disappear and the temperature compen­sated buffer value is flashing.
• Wait until the pH symbol stops flashing, press the CON key to confirm the calibration.
• The pH calibration is now complete.
CALIBRATION WITH MANUAL TEMPERATURE COMPEN­SATION FOR HI8417, HI8520 AND HI8521 ONLY)
If for some reason the temperature probe is defective, or it is required to calibrate with manual temperature compensation, follow the proce­dure below:
• Unplug the temperature probe from the meter.
• Note the temperature of the buffer with a ChecktempC or a glass thermometer.
• Use the UP and DOWN arrow keys to set the temperature to the noted tem­perature.
• Follow the calibration procedure as for pH calibration with temperature probe connected (see page 18 for HI8417 or page 21 for HI8520/HI8521).
C
°
C °
ºC
22
PH VALUES AT VARIOUS TEMPERATURE
Temperature has an effect on pH. The calibration buffer solutions are effected by temperature changes to a lesser degree than normal solutions.
For manual temperature calibration (standard with HI 8519 or op­tional with HI 8417, HI 8520 and HI 8521) please refer to the following chart.
TEMP pH VALUES
°C °F 4.01 6.86 7.01 9.18 10.01
0
32
4.01
6.98
7.13
9.46
10.32
5
41
4.00
6.95
7.10
9.39
10.24
10
50
4.00
6.92
7.07
9.33
10.18
15
59
4.00
6.90
7.04
9.27
10.12
20
68
4.00
6.88
7.03
9.22
10.06
25
77
4.01
6.86
7.01
9.18
10.01
30
86
4.02
6.85
7.00
9.14
9.96
35
95
4.03
6.84
6.99
9.10
9.92
40
104
4.04
6.84
6.98
9.07
9.88
45
113
4.05
6.83
6.98
9.04
9.85
50
122
4.06
6.83
6.98
9.01
9.82
55
131
4.07
6.84
6.98
8.99
9.79
60
140
4.09
6.84
6.98
8.97
9.77
65
149
4.11
6.85
6.99
8.95
9.76
70
158
4.12
6.85
6.99
8.93
9.75
For instance, if the buffer temperature is 25°C, the display should show pH 4.01, 7.01 or 10.01 at pH 4, 7 or 10 buffers, respectively.
At 20°C, the display should show pH 4.00, 7.03 or 10.06. The meter reading at 50°C will then be 4.06, 6.98 or 9.82.
TEMPERATURE CALIBRATION
(HI8417, HI8520, HI8521 ONLY)
All Hanna bench-top meters have been accurately temperature cali­brated at the factory. We recommend that you have your bench-top meters temperature calibrated once a year.
Your nearest Hanna Service Center is available to quickly service your meter. Contact your Dealer or the nearest Hanna Service Center for more information.
23
TROUBLESHOOTING
Symptoms are:
The instrument does not work with the HI7669/2W probe (not HI8519)
The meter fails to calibrate or gives erroneous results
The meter is slow in responding or gives erroneous readouts
The meter does not accept the 2nd buffer solution
The reading drifts
"Err1" (for HI8417) "E 1" (for HI8520/ HI8521) on the display
"Err3" (for HI8417) "E 2" (for HI8520/ HI8521) on the display
"Err2" (for HI8417) "E 3" (for HI8521) on the display
"Err4" (for HI8417) "E 4" (for HI8520/ HI8521) on the
display
"Err5" (for HI8417) "E 5" (for HI8520/ HI8521) on the display
The Problem is:
A defective ATC Probe
A defective pH electrode
The electrode is not working or the dia­phragm is clogged
A defective pH electrode or bad buffer solution
Temperature not stable
Out of range on the pH scale
Out of range in °C
Out of range in mV
Erroneous buffer solution used for offset calibration
Defective electrode
Erroneous buffer solution used for slope calibra­tion
Defective electrode
Possible Solutions:
Replace the probe.
Replace the electrode and repeat the pH calibration.
Leave the electrode in a storage solution after clean­ing the diaphragm.
If the problem is not solved, replace the electrode and re­calibrate the pH scale.
Try the cleaning procedure. If this does not work, re­place the electrode and re-calibrate the pH. Use fresh buffer solution.
Thermal equilibrium not reached. Wait longer.
a) Verify the pH electrode is con­nected.
b) Make sure the pH sample is included between 0 and 14 pH.
c) Check the level of the electrode's filling electrolyte and the state of the electrode itself.
Verify the temperature probe is connected and make sure the °C is within -10/125°C for HI8417 or -10/100°C for HI8520/HI8521.
Verify the temperature probe is connected and make sure the mV is within ±1999 range.
Make sure that the buffer solution used is of pH 7 and replace if necessary.
Replace the electrode and re-calibrate the pH scale.
Be sure the correct pH buffer solution is being used for slope calibration (4.01,
9.18 or 10.01 pH).
Check the electrode and re­place if necessary.
24
ELECTRODE CONDITIONING
AND MAINTENANCE
Reference Filling Hole
Reference Filling Hole
Sensitive Wire
Reference Wire
Reference Junction
Glass Bulb
Reference Wire
Reference Junction
Platinum or Gold tip
Plastic Body
pH Electrode
Reference
Plastic Body
ORP Electrode
Glass Body
pH Electrode
Wire
Glass Body
ORP Electrode
Reference
Wire
Sensitive
Wire
Reference
Junction
Glass
Bulb
Reference
Junction
Platinum or
Gold tip
PREPARATION
Remove the protective cap. DO NOT BE ALARMED IF ANY SALT DEPOSITS ARE PRESENT. This is normal with electrodes and they will disappear when rinsed with water. During transport tiny bubbles of air may form inside the glass bulb affecting proper functioning of the electrode. These bubbles can be removed by "shaking down" the electrode as you would do with a glass thermometer. If the bulb and/or junction is dry, soak the electrode in HI 70300 or HI 80300 Storage Solution for at least one hour.
25
For refillable electrodes:
If the filling solution (electrolyte) is more than 2½ cm (1") below the fill hole, add HI 7082 or HI 8082 3.5M KCl Electrolyte Solution for double junction or HI 7071 or HI 8071 3.5M KCl+AgCl Electrolyte Solution for single junction electrodes.
For a faster response, unscrew the fill hole screw during measure­ments.
For AmpHel® electrodes:
If the electrode does not respond to pH changes, the battery is run down and the electrode should be replaced.
MEASUREMENT
Rinse the electrode tip with distilled water. Immerse the tip (bottom 4 cm /1½") in the sample and stir gently for a few seconds.
For a faster response and to avoid cross contamination of the samples, rinse the electrode tip with a few drops of the solution to be tested, before taking measurements.
STORAGE
To minimize clogging and assure a quick response time, the glass bulb and the junction should be kept moist and not allowed to dry out.
Replace the solution in the protective cap with a few drops of HI 70300 or HI 80300 Storage Solution or, in its absence, Filling Solution (HI 7071 or HI 8071 for single junction or HI 7082 or HI 8082 for double junction electrodes). Follow the Preparation Procedure above before taking measurements.
Note: NEVER STORE THE ELECTRODE IN DISTILLED OR DEIONIZED WA-
TER.
PERIODIC MAINTENANCE
Inspect the electrode and the cable. The cable used for connection to the meter must be intact and there must be no points of broken insulation on the cable or cracks on the electrode stem or bulb. Connectors must be perfectly clean and dry. If any scratches or cracks are present, replace the electrode. Rinse off any salt deposits with water.
For refillable electrodes:
Refill the reference chamber with fresh electrolyte (HI 7071 or HI 8071 for single junction or HI 7082 or HI 8082 for double junction elec­trodes). Allow the electrode to stand upright for 1 hour.
Follow the Storage Procedure above.
26
CLEANING PROCEDURE
General Soak in Hanna HI 7061 or HI 8061 General Clean-
ing Solution for approximately ½ hour.
Removal of films, dirt or deposits on the membrane/junction:
- Protein Soak in Hanna HI 7073 or HI 8073 Protein Cleaning
Solution for 15 minutes.
- Inorganic Soak in Hanna HI 7074 or HI 8074 Inorganic Clean-
ing Solution for 15 minutes.
- Oil/grease Rinse with Hanna HI 7077 or HI 8077 Oil and Fat
Cleaning Solution.
IMPORTANT: After performing any of the cleaning procedures rinse the electrode thoroughly with distilled water, refill the reference chamber with fresh electrolyte (not necessary for gel-filled electrodes) and soak the electrode in HI 70300 or HI 80300 Storage Solution for at least 1 hour before taking measurements.
TROUBLESHOOTING
Evaluate your electrode performance based on the following.
Noise (Readings fluctuate up and down) could be due to: – Clogged/Dirty Junction: Refer to the Cleaning Procedure
above.
– Loss of shielding due to low electrolyte level (in refillable
electrodes only): refill with fresh HI 7071 or HI 8071 for single junction or HI 7082 or HI 8082 for double junction electrodes.
Dry Membrane/Junction: Soak in HI 70300 or HI 80300 Stor­age Solution for at least 1 hour.
Drifting: Soak the electrode tip in warm (approx. 50-60°C) Hanna HI 7082 or HI 8082 Solutions for one hour and rinse the tip with distilled water. Refill with fresh HI 7071 or HI 8071 for single junction electrodes and HI 7082 or HI 8082 for double junction electrodes (refillable electrodes only).
Low Slope: Refer to the cleaning procedure above.
No Slope: Check the electrode for cracks in glass stem or bulb and replace the electrode.
Slow Response/Excessive Drift: Soak the tip in HI 7061 or HI 8061 Solutions for 30 minutes, rinse thoroughly in distilled water and then follow the Cleaning Procedure above.
27
TEMPERATURE-RESISTANCE
0
0+10+20+30+40+50+60+70+80+90
C
CORRELATION
The resistance of glass electrodes partially depends on the tempera­ture. The lower the temperature, the higher the resistance. It takes longer time for the reading to stabilize if the resistance is higher. In addition, the response time will suffer to a greater degree at tempera­tures below 10°C.
9
2x10
-10
9
1x10
-10
8
2x10
-10
8
1x10
-10
7
2x10
-10
-10
7
1x10
-10
-20-2
-40 -20 0 +10 +20 +30 +40+50 +60 +70 +80 +90 °C
°
Since the resistance of the pH electrode is in the range of 200 Mohm, the current across the membrane is in the pico Ampere range. Large currents can disturb the calibration of the electrode for many hours.
For these reasons high humidity environments, short circuits and static discharges are detrimental for a stable pH reading.
The pH electrode's life also depends on the temperature. If constantly used at high temperatures, the electrode life is drastically reduced.
Typical Electrode Life Ambient Temperature 1- 3 years 90 °C Less than 4 months
120°C Less than 1 month
28
High concentrations of sodium ions interfere with readings in alkaline solutions; the pH at which the interference starts to be significant depends upon the composition of the glass. This interference is the alkaline error and causes the pH to be underestimated. Hanna's glass formulations have the indicated characteristics.
Alkaline Error
Sodium Ion Correction for the Glass at 20-25°C Concentration pH Error
0.1 Mol L-1 Na
1.0 Mol L-1 Na
+
+
13.00
13.50
14.00
12.50
13.00
13.50
14.00
0.10
0.14
0.20
0.10
0.18
0.29
0.40
29
ACCESSORIES
pH CALIBRATION SOLUTIONS
HI 70004P pH 4.01 Buffer Sachets, 20mL, 25 pcs HI 70007P pH 7.01 Buffer Sachets, 20mL, 25 pcs HI 70010P pH 10.01 Buffer Sachets, 20mL, 25 pcs HI 7004L pH 4.01 Buffer Solution, 460 mL HI 7006L pH 6.86 Buffer Solution, 460 mL HI 7007L pH 7.01 Buffer Solution, 460 mL HI 7009L pH 9.18 Buffer Solution, 460 mL HI 7010L pH 10.01 Buffer Sol., 460 mL
pH CALIBRATION SOLUTIONS IN FDA APPROVED BOTTLES
HI 8004L pH 4.01 Buffer Solution, 460 mL HI 8006L pH 6.86 Buffer Solution, 460 mL HI 8007L pH 7.01 Buffer Solution, 460 mL HI 8009L pH 9.18 Buffer Solution, 460 mL HI 8010L pH 10.01 Buffer Solution, 460 mL
ELECTRODE STORAGE SOLUTION
HI 70300L Storage Solution, 460 mL
ELECTRODE STORAGE SOLUTION IN FDA APPROVED BOTTLES
HI 80300L Storage Solution, 460 mL
ELECTRODE CLEANING SOLUTIONS
HI 70000P Electrode Cleaning Sachets, 20 mL, 25 pcs HI 7061L General Cleaning Sol., 460 mL HI 7073L Protein Cleaning Sol., 460mL HI 7074L Inorganic Cleaning Sol., 460mL HI 7077L Oil & Fat Cleaning Sol.,460 mL
ELECTRODE CLEANING SOLUTIONS IN FDA APPROVED BOTTLES
HI 8061L General Cleaning Solution, 460 mL HI 8073L Protein Cleaning Solution, 230 mL HI 8077L Oil & Fat Cleaning Solution, 460mL
REFILL ELECTROLYTE SOLUTIONS
HI 7071 3.5M KCl + AgCl Electrolyte, 4x50mL, for single
junction electrodes
HI 7072 1M KNO3 Electrolyte, 4x50 mL
30
HI 7082 3.5M KCl Electrolyte, 4x50 mL, for double junction
electrodes
REFILL ELECTROLYTE SOLUTIONS IN FDA APPROVED BOTTLES
HI 8071 3.5M KCl + AgCl Electrolyte, 4x50mL, for single
junction electrodes
HI 8072 1M KNO3 Electrolyte, 4x50 mL HI 8082 3.5M KCl Electrolyte, 4x50 mL, for double junction
electrodes
ORP PRETREATMENT SOLUTIONS
HI 7091L Reducing Pretreatment Solution, 460 mL HI 7092L Oxidizing Pretreatment Solution, 460 mL
pH & ORP ELECTRODES
All electrodes part numbers ending in B are supplied with a BNC connector and 1 m (3.3') cable.
HI 1043B
Glass-body, double junction, refillable, combination pH electrode. Use: strong acid/alkali.
12 mm
0.5"
HI 1043
"S" VERSION
9.5mm DIA
120 mm
4.7"
0.37"
HI 1053B
Glass-body, triple ceramic, conic shape, refillable, combination pH electrode. Use: emulsions.
12 mm
0.5"
HI 1053
31
120 mm
4.7"
"S" VERSION
HI 1083B
Glass-body, micro, Viscolene, non-refillable, combination pH elec- trode. Use: biotechnology, micro titration.
HI 1083
12 mm
0.5"
5 mm
0.2"
120 mm
3 mm
0.12"
"
3.0 mm DIA
0.12"
HI 1131B
Glass-body, single junction, refillable, combination pH electrode. Use: general purpose.
12 mm
0.5"
HI 1131
"S" VERSION
9.5mm DIA
120 mm
4.7"
0.37"
HI 1330B
Glass-body, semimicro, single junction, refillable, combination pH electrode. Use: laboratory, vials.
HI 1330
"S" VERSION
120 mm
4.7"
5mm DIA
0.2"
5mm
0.2"
HI 1331B
Glass-body, semimicro, single junction, refillable, combination pH electrode. Use: flasks.
HI 1331
"S" VERSION
8 mm
0.3"
7.5mm DIA
210 mm
8.25"
0.29"
HI 1230B
Plastic-body (Ultem®), double junction, gel-filled, combination pH electrode. Use: general, field.
12 mm
0.5"
HI 1230
120 mm
"
"
4.7"
32
HI 2031B
Glass-body, semimicro, conic, refillable, combination pH electrode. Use: semisolid products.
6 mm
0.25"
HI 2031
75 mm
"
"
2.95"
HI 1332B
Plastic-body (Ultem®), double junction, refillable, combination pH electrode. Use: general purpose.
12 mm
0.5"
HI 1332
"S" VERSION
120 mm
4.7"
FC 100B
Plastic-body (Kynar®), double junction, refillable, combination pH electrode. Use: general purpose for food industry.
12 mm
0.5"
FC 100
120 mm
4.7"
FC 200B
Plastic-body (Kynar®), open junction, conic, Viscolene, non-refillable, combination pH electrode. Use: meat & cheese.
6 mm
0.25"
FC 200
75 mm
2.95"
33
FC 210B
Glass-body, double junction, conic, Viscolene, non-refillable, combi­nation pH electrode. Use: milk, yogurt.
12 mm
0.5"
FC 210
120 mm
4.7"
FC 220B
Glass-body, triple-ceramic, single junction, refillable, combination pH electrode. Use: food processing.
12 mm
0.5"
FC 220
9.5mm DIA
120 mm
4.7"
0.37"
FC 911B
Plastic-body (Kynar®), double junction, refillable with built-in ampli­fier, combination pH electrode. Use: very high humidity.
12 mm
0.5"
FC 911
110 mm
4.3"
HI 1413B
Glass-body, single junction, flat tip, Viscolene, non-refillable, combi­nation pH electrode. Use: surface measurement.
12 mm
0.5"
HI 1413
110 mm
4.3"
Ultem® is registered Trademark of "General Electrics Co." Kynar® is registered Trademark of "Pennwalt Corp."
34
ORP electrodes:
HI 3131B
Glass-body, refillable, combination platinum ORP electrode. Use: titration.
12 mm
0.5"
HI 3131
150 mm
"S" VERSION
5.9"
HI 3230B
Plastic-body (Ultem®), gel-filled, combination platinum ORP elec- trode. Use: general purpose.
12 mm
0.5"
HI 3230
120 mm
"S" VERSION
4.7"
HI 4430B
Plastic-body (Ultem®), gel-filled, combination gold ORP electrode. Use: general purpose.
12 mm
0.5"
HI 4430
120 mm
"S" VERSION
4.7"
Extension cables for screw-type electrodes only (screw to BNC connector): HI7855/1 Extension cable 1m (3.3') long HI7855/3 Extension cable 3m (9.9') long HI7855/5 Extension cable 5m (16.5') long
HI 7855 SERIES CABLE CONNECTORS
CONNECTOR AND 3.0 mm (0.12") CABLE WITH BNC
CONNECT TO SCREW TYPE ELECTRODES
35
CONNECT TO THE
BNC SOCKET
OF THE METER
HI7855/10 Extension cable 10m (33') long HI7855/15 Extension cable 15m (49.5') long
Power Units:
HI710005 Voltage adapter from 115 VAC to 12 VDC HI710006 Voltage adapter from 230 VAC to 12 VDC
OTHER ACCESSORIES
ChecktempC Pocket-size thermometer (range -50.0 to 150.0°C) HI 76405 Electrode holder
HI 7669/2W Temperature probe with 1 m (3.3') screened cable (not
for HI 8519)
HI 8427 pH and ORP electrode simulator with 1 m (3.3') co-
axial cable ending in female BNC connectors
HI 931001 pH and ORP electrode simulator with LCD and 1 m
(3.3') coaxial cable ending in female BNC connectors
MANPHBNR3 Instructions manual
36
ELECTRODE APPLICATION
REFERENCE GUIDE
Application Electrodes
1. Aquarium HI 1332B, HI 1911B
2. Bath-water HI 1910B, HI1130B
3. Beer HI 1131B
4. Bread HI 2031B, FC200B
5. Cheese FC 200B
6. Dairy products FC 911B, FC100B
7. Dirty water HI 1910B, HI 1912B
8. Emulsions HI 1053B
9. Environment HI 1230B
10. Flasks HI 1331B
11. Food industry general use FC 911B, FC 100B
12. Fruit FC 200B, FC 220B
13. Fruit juices, organic FC210B
14. Galvanizing waste solution HI 1130B, HI1912B
15. Heavy-duty applications HI 1135B
16. High purity water HI 1053B
17. Horticulture HI 1053B, FC 200B
18. In-line applications HI 1134B, HI1135B, HI 2114B, HI 2910B
19. Laboratory general use HI 1131B, HI 1230B, HI1332B, HI 1330B
20. Leather HI 1413B
21. Lemon juice FC 100B
22. Meat FC 200B, HI 2031B
23. Micro plate sampling of less than HI1083B 100 mL
24. Milk and Yogurt FC210B
25. Paints HI 1053B
26. Paper HI 1413B
27. Photographic chemicals HI 1230B
28. Quality control HI 1332B
29. Sausages FC 200B, HI2031B
30. Semisolid products HI 2031B
31. Skin HI 1413B
32. Soil samples HI1230B
33. Solvents HI 1043B
34. Strong acid HI 1043B
35. Submersion application HI 1130B
36. Surface measurements HI 1413B
37. Swimming pool H I1130B, HI 2114B, HI 2910B
38. Titrations with constant HI1131B temperature range
39. Titrations with wide temperature HI 1131B range
40. Very high humidity FC 911B, HI 1912B, HI 1911B
41. Vials and test tube HI 1330B
42. Wine processing FC 220B
37
WARRANTY
All Hanna Instruments meters are guaranteed for two years against defects in workmanship and materials when used for their intended purpose and maintained according to instructions. The electrodes and the probes are guaranteed for a period of six months. This warranty is limited to repair or replacement free of charge.
Damage due to accident, misuse, tampering or lack of prescribed maintenance are not covered.
If service is required, contact the dealer from whom you purchased the instrument. If under warranty, report the model number, date of purchase, serial number and the nature of the failure. If the repair is not covered by the warranty, you will be notified of the charges incurred. If the instrument is to be returned to Hanna Instruments, first obtain a Returned Goods Authorization number from the Cus­tomer Service department and then send it with shipping costs prepaid. When shipping any instrument, make sure it is properly packaged for complete protection.
To validate your warranty, fill out and return the enclosed warranty card within 14 days from the date of purchase.
All rights are reserved. Reproduction in whole or in part is prohibited without the written consent of the copyright owner, Hanna Instruments Inc., 584 Park East Drive, Woonsocket, Rhode Island, 02895 , USA.
Hanna Instruments reserves the right to modify the design, con­struction and appearance of its products without advance notice.
38
CE DECLARATION OF CONFORMITY
DECLARATION OF CONFORMITY
We
Hanna Instruments Srl V.le delle industrie 12 35010 Ronchi di Villafranca (PD) ITALY
herewith certify that the bench pH meters
have been tested and found to be in compliance with the following regulations:
HI 8417 HI 8519 HI 8520 HI 8521
IEC 801-2 Electrostatic Discharge IEC 801-3 RF Radiated IEC 801-4 Fast Transient EN 55022 Radiated, Class B
Date of Issue: 20-12-1995
D.Volpato - Engineering Manager
On behalf of
Hanna Instruments S.r.l.
Recommendations for Users
Before using these products, make sure that they are entirely suitable for the environment in which they are used.
Operation of these instruments in residential area could cause unacceptable interferences to radio and TV equipment, requiring the operator to take all necessary steps to correct interferences.
The glass bulb at the end of the electrode is sensitive to electrostatic discharges. Avoid touching this glass bulb at all times.
During calibration of instruments, ESD wrist straps should be worn to avoid possible damage to the electrode by electrostatic discharge.
To maintain the EMC performance of equipment, the recommended cables noted in the user's manual must be used.
In particular cases the instruments could turn off. In such cases, turn them on by pressing the ON/OFF key.
Any variation introduced by the user to the supplied equipment may degrade the instruments' EMC performance.
To avoid electrical shock, do not use these instruments when voltages at the measurement surface exceed 24VAC or 60VDC.
To avoid damage or burns, do not perform any measurement in microwave ovens.
39
http://www.hannainst.com
PRINTED IN PORTUGAL
MANPHBNR3 05/98
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