Generated using Total SDS™ (patent-pending), www.GSMSDS.com
Initial preparation date:
2020.02.24
Tough 2000 Resin
Page 1 of 15
Safety Data Sheet
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product Name:
Product code:
Tough 2000 Resin
FLTO2001
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Uses advised against:
Reasons why uses advised against:
For use in Formlabs SLA Printers
Not determined or not applicable.
Not determined or not applicable.
1.3 Details of the manufacturer/supplier of the safety data sheet
Manufacturer:
United States
Formlabs, Inc
35 Medford St
Suite 201 Somerville, MA 02143
+1 617 855 0762
sds@formlabs.com
1.4 Emergency telephone number:
1-800-424-9300 (24/7)
Supplier:
Germany
Formlabs GmbH
Nalepastr. 18
12459 Berlin
+49 30 555 795 880
SECTION 2: Hazard(s) identification
2.1 Classification of the substance or mixture:
Classification according to Regulation (EC) No. 1272/2008 (CLP):
Skin irritation, category 2
Eye Irritation, category 2
Skin sensitization, category 1
Specific target organ toxicity - single exposure, category 3, respiratory tract irritation
Chronic aquatic hazard, category 2
Hazard-determining components of labeling:
Urethane Dimethacrylate
Methacrylate Monomer
Isobornyl methacrylate
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Additional Information:
2.2 Label elements
None
Labelling according to Regulation (EC) No 1272/2008 (CLP)
Hazard pictograms:
Signal word:
Warning
Safety Data Sheet
Page 2 of 15
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Secret
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Hazard statements:
H315 Causes skin irritation
H319 Causes serious eye irritation
2020.02.24
H317 May cause an allergic skin reaction
H335 May cause respiratory irritation
H411 Toxic to aquatic life with long lasting effects
Precautionary statements:
P264 Wash skin thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P272 Contaminated work clothing should not be allowed out of the workplace
P273 Avoid release to the environment
P271 Use only outdoors or in a well-ventilated area
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P332+P313 If skin irritation occurs: Get medical advice/attention
P362 Take off contaminated clothing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
P337+P313 If eye irritation persists: Get medical advice/attention
P333+P313 If skin irritation or rash occurs: Get medical advice/attention
P363 Wash contaminated clothing before reuse
P391 Collect spillage
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P312 Call a POISON CENTER/doctor if you feel unwell
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container in accordance with local/regional/national regulations
2.3 Other hazards:
None known
SECTION 3: Composition/information on ingredients
3.1 Substance:
3.2 Mixture:
Identification
CAS number:
72869-86-4
EC number:
276-957-5
CAS number:
Trade Secret
EC number:
Not applicable.
REACH Registration
No.
Name
–
–
Urethane Dimethacrylate
Methacrylate Monomer
Skin Sens. 1; H317
Classification according
to Regulation (EC) No.
1272/2008 (CLP)
Skin Sens. 1; H317
Aquatic Chronic 2;
H411
Eye Irrit. 2; H319
Weight %
45-65
15-25
Trade
CAS number:
7534-94-3
EC number:
231-403-1
–
Isobornyl methacrylate
Skin Irrit. 2; H315
STOT SE 3 (RI); H335
Aquatic Chronic 3;
H412
10-20
Eye Irrit. 2; H319
Safety Data Sheet
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CAS number:
Phenyl bis(2,4,6-
Skin Sens. 1; H317
<0.6
162881-26-7
EC number:
trimethylbenzoyl)-phosphine
oxide
Aquatic Chronic 4;
H413
423-340-5
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
2020.02.24
–
Additional information:
Full Text of H and EUH statements:
SECTION 4: First aid measures
None
See section 16
4.1 Description of first aid measures
General notes:
Show this Safety Data Sheet to the doctor in attendance.
Following inhalation:
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If
experiencing respiratory symptoms: Call a POISON CENTER or doctor.
Following skin contact:
Wash off immediately with soap and plenty of water while removing contaminated clothing and shoes.
Continue rinsing for at least 15 minutes. See a physician if irritation persists.
Following eye contact:
Immediately flush eyes, under eyelids with water for 15 minutes. Remove contact lenses, if easy to do
so. Protect unexposed eye. Continue rinsing on the way to hospital.
Following ingestion:
If swallowed, DO NOT induce vomiting unless told to do so by physician or poison control center. Rinse
mouth with water. Never give anything to drink to an unconscious person. Seek medical advice.
Self-Protection of the first aider:
Not determined or not available.
4.2 Most important symptoms and effects, both acute and delayed
Acute symptoms and effects:
Symptoms may include blistering, irritation, burns and pain. Effects are dependent on exposure (dose,
concentration, contact time).
Delayed symptoms and effects:
Effects are dependent on exposure (dose, concentration, contact time).
4.3 Indication of any immediate medical attention and special treatment needed
Specific treatment:
None known.
Notes for the doctor:
Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media:
Alcohol- resistant foam, Dry chemical or Carbon dioxide
Unsuitable extinguishing media:
None known
5.2 Special hazards arising from the substance or mixture:
Evacuate all personnel to a predetermined safe location, no less than 2,500 feet in all directions. Can
explode or detonate under fire conditions. Burning material may produce toxic vapors.
5.3 Advice for firefighters
Safety Data Sheet
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According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
2020.02.24
Personal protection equipment:
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA)
Special precautions:
Avoid inhaling gases, fumes, mist, dust, vapor or aerosols. Avoid contact with eyes, skin, hair or clothing.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Clean and neutralize spill area, tools and equipment by washing with water and soap. Absorb rinsate and
add to the collected waste. Waste must be classified and labeled prior to recycling or disposal. Dispose of
waste as indicated in Section 13.
6.2 Environmental precautions:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and material for containment and cleaning up:
Clean and neutralize spill area, tools and equipment by washing with water and soap. Absorb reinstate
and add to the collected waste. Waste must be classified and labeled prior to recycling or disposal.
Dispose of waste as indicated in Section 13.
6.4 Reference to other sections:
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Avoid contact with skin, eyes, and clothing. Follow good hygiene procedures when handling chemical
materials. Refer to Section 8. Follow proper disposal methods. Refer to Section 13. Do not eat, drink,
smoke, or use personal products when handling chemical substances.
7.2 Conditions for safe storage, including any incompatibilities:
Store in a cool, dry, well ventilated place. Store away from sources of heat or ignition. Store away from
incompatible materials described in Section 10. Keep containers closed when not in use
7.3 Specific end use(s):
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Only those substances with limit values have been included below.
Occupational Exposure limit values:
No occupational exposure limits noted for the ingredient(s).
Biological limit values:
No biological exposure limits noted for the ingredient(s).
Derived No Effect Level (DNEL):
Ingredient Name:
Methacrylate Monomer
Safety Data Sheet
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Acute - Oral
Not determined or not applicable.
Acute - Inhalation
No hazard identified
Acute - Dermal
No hazard identified
Chronic - Oral
Not determined or not applicable.
Chronic - Inhalation
14.7 mg/m³
Chronic - Dermal
4.2 mg/kg bw/day
Acute - Oral
Not determined or not applicable.
Acute - Inhalation
No hazard identified
Acute - Dermal
No hazard identified
Chronic - Oral
Not determined or not applicable.
Chronic - Inhalation
No hazard identified
Chronic - Dermal
Hazard identified but no DNEL available
Acute - Oral
No hazard identified
Acute - Inhalation
No hazard identified
Acute - Dermal
No hazard identified
Chronic - Oral
2.5 mg/kg bw/day
Chronic - Inhalation
8.8 mg/m³
Chronic - Dermal
2.5 mg/kg bw/day
Acute - Oral
Not determined or not applicable.
Acute - Inhalation
No hazard identified
Acute - Dermal
No hazard identified
Chronic - Oral
Not determined or not applicable.
Chronic - Inhalation
No hazard identified
Chronic - Dermal
Hazard identified but no DNEL available
Acute - Oral
Not determined or not applicable.
Acute - Inhalation
No hazard identified; 7.84 mg/m³; 16.46 mg/m³
Acute - Dermal
No hazard identified; 3.33 mg/kg bw/day; 4.67 mg/kg bw/day
Chronic - Oral
Not determined or not applicable.
Chronic - Inhalation
7.84 mg/m³; 11.75 mg/m³; 16.46 mg/m³; 21 mg/m³
Chronic - Dermal
3 mg/kg bw/day; 3.33 mg/kg bw/day; 4.67 mg/kg bw/day
Acute - Oral
Not determined or not applicable.
Acute - Inhalation
No hazard identified; Hazard identified but no DNEL available
Acute - Dermal
Hazard identified but no DNEL available; No hazard identified
Chronic - Oral
Not determined or not applicable.
Chronic - Inhalation
No hazard identified; Hazard identified but no DNEL available
Chronic - Dermal
Hazard identified but no DNEL available; No hazard identified
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
CAS #:
Workers - Systemic
Workers - Local
Trade Secret
Effects
Effects
2020.02.24
General Population -
Systemic Effects
General Population -
Local Effect
Ingredient Name:
CAS #:
Workers - Systemic
162881-26-7
Effects
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Workers - Local
Effects
Safety Data Sheet
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no DNEL available
Acute - Inhalation
3.92 mg/m³; Hazard identified but no DNEL available; 1.93
mg/m³; 2.92 mg/m³; 3.92 mg/m³
Acute - Dermal
No hazard identified; 1.67 mg/kg bw/day
Chronic - Oral
No hazard identified; 1.5 mg/kg bw/day; 1.67 mg/kg bw/day
1.67 mg/kg bw/day
Chronic - Dermal
1.5 mg/kg bw/day
Acute - Oral
Not determined or not applicable.
Acute - Inhalation
Hazard identified but no DNEL available; No hazard identified
Acute - Dermal
Hazard identified but no DNEL available; No hazard identified
Chronic - Oral
Not determined or not applicable.
Chronic - Inhalation
No hazard identified; Hazard identified but no DNEL available
Chronic - Dermal
Hazard identified but no DNEL available; No hazard identified
Fresh water
0.904 mg/L
Freshwater sediments
6.28 mg/kg
Marine water
0.904 mg/L
Marine sediments
6.28 mg/kg
Food chain
Not determined or not available.
Microorganisms in sewage treatment
10 mg/L
Soil (agricultural)
0.727 mg/kg
Air No hazard identified
Fresh water
0.8 µg/L
Freshwater sediments
0.712 mg/kg
Marine water
0.8 µg/L; 1 µg/L; 1 µg/L
Marine sediments
0.712 mg/kg
Food chain
Not determined or not available.
Microorganisms in sewage treatment
1 mg/L
Soil (agricultural)
Not determined or not available.
Air No hazard identified
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
General Population -
Systemic Effects
General Population -
Local Effect
2020.02.24
Acute - Oral
Chronic - Inhalation 1.93 mg/m³; 2.9 mg/m³; 2.92 mg/m³; 3.92 mg/m³; 5.2 mg/m³;
No hazard identified; 1.67 mg/kg bw/day; Hazard identified but
Predicted No Effect Concentration (PNEC):
Ingredient Name:
CAS #:
Environmental Protection Target PNEC
Ingredient Name:
CAS #:
Environmental Protection Target PNEC
Trade Secret
162881-26-7
Methacrylate Monomer
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Information on monitoring procedures:
Not determined or not applicable.
8.2 Exposure controls
Appropriate engineering controls:
Effective ventilation in all processing areas.
Personal protection equipment
Safety Data Sheet
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exposure:
Grey Liquid
Characteristic acrylate
Not determined or not available.
Not determined or not available.
Not determined or not available.
> 100°C
> 93.5°C
Not determined or not available.
Not Flammable
Not determined or not available.
Not determined or not available.
Not determined or not available.
Not determined or not available.
1.11 g/cm3
Not determined or not available.
Not determined or not available.
Not determined or not available.
Not determined or not available.
Not determined or not available.
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Eye and face protection:
Safety goggles or safety glasses with side shields
Skin and body protection:
Impervious clothing and chemical resistant gloves
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory protection
General hygienic measures:
Handle in accordance with good industrial hygiene and safety measures. Wash hands and face after
handling chemical products. Wash hands before eating, drinking and smoking. Wash hands at the end of
the workday.
Environmental exposure controls:
Emissions from ventilation or work process equipment should be checked to ensure they comply with the
requirements of environmental protection legislation.
Product (substance / mixture) related measures to prevent
2020.02.24
Not determined or not applicable.
Instruction measures to prevent exposure:
Organisational measures to prevent exposure:
Technical measures to prevent exposure:
Not determined or not applicable.
Not determined or not applicable.
Not determined or not applicable.
Risk management measures to control exposure:
SECTION 9: Physical and chemical properties
Not determined or not applicable.
9.1 Information on basic physical and chemical properties
Appearance
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point/range
Flash point (closed cup)
Evaporation rate
Flammability (solid, gas)
Upper flammability/explosive limit
Lower flammability/explosive limit
Vapor pressure
Vapor density
Density
Relative density
Solubilities
Partition coefficient (n-octanol/water)
Auto/Self-ignition temperature
Decomposition temperature
Safety Data Sheet
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1600 cps @ 25°C
Not determined or not available.
Not determined or not available.
Not determined or not available.
Methacrylate Monomer
oral LD50 Rat: >2000 mg/kg
dermal
LD50 Rabbit : >5000 mg/kg
oral LD50 Rat: >2000 mg/kg
dermal
LD50 Rabbit: >3000 mg/kg
Isobornyl methacrylate
Causes skin irritation
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
2020.02.24
Dynamic viscosity
Kinematic viscosity
Explosive properties
Oxidizing properties
9.2 Other information
SECTION 10: Stability and reactivity
10.1 Reactivity:
Does not react under normal conditions of use and storage.
10.2 Chemical stability:
Stable under normal storage and handling conditions.
10.3 Possibility of hazardous reactions:
Under normal conditions of storage and use, hazardous reactions will not occur.
10.4 Conditions to avoid:
Incompatible materials.
Avoid storage >38°C (100°F) and exposure to light/direct sunlight and heat.
10.5 Incompatible materials:
Strong oxidizing agents.
Polymerization initiators, including peroxides, strong oxidizing agents, alcohols, copper, copper alloys,
carbon steel, iron, rust, and strong bases.
10.6 Hazardous decomposition products:
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1 Information on toxicological effects Acute toxicity
Assessment:
Product data:
Substance data:
Name
Based on available data, the classification criteria are not met.
No data available.
Route
Result
Isobornyl methacrylate
Skin corrosion/irritation
Assessment:
Causes skin irritation.
Product data:
No data available.
Substance data:
Name
Serious eye damage/irritation
Result
Safety Data Sheet
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Isobornyl methacrylate
Causes serious eye irritation
Urethane Dimethacrylate
May cause an allergic skin reaction.
oxide
Isobornyl methacrylate
May cause respiratory irritation
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Assessment:
Causes serious eye irritation.
Product data:
No data available.
Substance data:
Name
Methacrylate Monomer
Respiratory or skin sensitization
Assessment:
May cause an allergic skin reaction.
Product data:
No data available.
Substance data:
Name
2020.02.24
Result
Causes serious eye irritation.
Result
Methacrylate Monomer
Phenyl bis(2,4,6-
May cause an allergic skin reaction.
May cause an allergic skin reaction.
trimethylbenzoyl)-phosphine
Carcinogenicity
Assessment:
Product data:
Substance data:
International Agency for Research on Cancer (IARC):
National Toxicology Program (NTP):
Germ cell mutagenicity
Assessment:
Product data:
Substance data:
Reproductive Toxicity
Assessment:
Product data:
No data available.
Substance data:
Based on available data, the classification criteria are not met.
No data available.
No data available.
None of the ingredients are listed.
None of the ingredients are listed.
Based on available data, the classification criteria are not met.
No data available.
No data available.
Based on available data, the classification criteria are not met.
No data available.
Specific target organ toxicity (single exposure)
Assessment:
May cause respiratory irritation.
Product data:
No data available.
Substance data:
Name
Result
Safety Data Sheet
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LC50 Danio rerio: 1.79 mg/L (96 hours)
EC50 Daphnia magna: 2.57 mg/L (48 hours)
Isobornyl methacrylate
NOEC Daphnia magna: 0.233 mg/L (21 days)
oxide
Urethane Dimethacrylate
This substance is not readily biodegradable.
Isobornyl methacrylate
Readily biodegradable
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
2020.02.24
Specific target organ toxicity (repeated exposure)
Assessment:
Product data:
No data available.
Substance data:
Aspiration toxicity
Assessment:
Product data:
No data available.
Substance data:
Based on available data, the classification criteria are not met.
No data available.
Based on available data, the classification criteria are not met.
No data available.
Information on likely routes of exposure:
No data available.
Symptoms related to the physical, chemical and toxicological characteristics:
No data available.
Other information:
No data available.
SECTION 12: Ecological information
12.1 Toxicity
Acute (short-term) toxicity
Assessment:
Based on available data, the classification criteria are not met.
Product data:
Substance data:
Name
Isobornyl methacrylate
Chronic (long-term) toxicity
Assessment:
Product data:
Substance data:
Name
No data available.
Toxic to aquatic life with long lasting effects.
No data available.
Phenyl bis(2,4,6trimethylbenzoyl)-phosphine
12.2 Persistence and degradability
Product data:
Substance data:
Name
No data available.
Result
Result
EC50 Activated sludge : 100 mg/L
Result
Methacrylate Monomer
Phenyl bis(2,4,6-
This substance is readily biodegradable.
This substance is not readily biodegradable.
trimethylbenzoyl)-phosphine
oxide
Safety Data Sheet
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organic soil and sediment particles.
oxide
Urethane Dimethacrylate
This substance is not vPvB.
Isobornyl methacrylate
This substance is not vPvB
oxide
value (0.97 at 20 deg C).
oxide
Urethane Dimethacrylate
This substance is not PBT.
Isobornyl methacrylate
This substance in not PBT
oxide
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
12.3 Bioaccumulative potential
Product data:
Substance data:
Name
Methacrylate Monomer
2020.02.24
No data available.
Phenyl bis(2,4,6trimethylbenzoyl)-phosphine
Result
The substance has low potential to bioaccumulate because of log Kow
Bioaccumulation in organisms is not to be expected.
12.4 Mobility in soil
Product data:
Substance data:
Name
Urethane Dimethacrylate
Methacrylate Monomer
Phenyl bis(2,4,6trimethylbenzoyl)-phosphine
12.5 Results of PBT and vPvB assessment
PBT assessment:
No data available.
Result
This substance is expected to disturb between the water column and
The substance has a low potential for adsorption to soil.
Based upon the log Koc of 3.85 an adsorption to the soil is expected.
Methacrylate Monomer
This substance is not PBT.
Phenyl bis(2,4,6trimethylbenzoyl)-phosphine
This substance is not PBT.
vPvB assessment:
Methacrylate Monomer
Phenyl bis(2,4,6trimethylbenzoyl)-phosphine
12.6 Other adverse effects:
12.7 Hazard to the ozone layer
Assessment:
Product data:
Substance data:
SECTION 13: Disposal considerations
13.1 Waste treatment methods
13.1.1 Product / Packaging disposal:
Based on available data, the classification criteria are not met.
No data available.
No data available.
No data available.
This substance is not vPvB.
This substance is not vPvB.
Not determined or not available.
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UN 3082
Environmentally hazardous liquid, N.O.S. Methacrylate Polymer
III
Marine Pollutant
None
4.1.1.8
UN 3082
Environmentally hazardous liquid, N.O.S. Methacrylate Polymer
III
Marine Pollutant
None
4.1.1.8
UN 3082
Environmentally hazardous liquid, N.O.S. Methacrylate Polymer
III
Marine Pollutant
None
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Waste codes / waste designations according to LoW:
2020.02.24
Not determined or not available.
13.1.2 Waste treatment-relevant information:
13.1.3 Sewage disposal-relevant information:
13.1.4 Other disposal recommendations:
characterize all waste materials according to applicable regulatory entities
SECTION 14: Transport information
International Carriage of Dangerous Goods by Road/Rail (ADR/RID)
UN number
UN proper shipping name
UN transport hazard class(es)
Packing group
Environmental hazards
Special precautions for user
Additional Information
International Carriage of Dangerous Goods by Inland Waterways (ADN)
UN number
UN proper shipping name
UN transport hazard class(es)
Not determined or not available.
Not determined or not available.
It is the responsibility of the waste generator to properly
9
This product is not regulated as a dangerous good when
transported in sizes of <5L or <5 kg provided the packaging
meets the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to
9
Packing group
Environmental hazards
Special precautions for user
Additional Information
This product is not regulated as a dangerous good when
transported in sizes of <5L or <5 kg provided the packaging
meets the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to
International Maritime Dangerous Goods (IMDG)
UN number
UN proper shipping name
UN transport hazard class(es)
Packing group
Environmental hazards
Special precautions for user
9
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4.1.1.8
UN 3082
Environmentally hazardous liquid, N.O.S. Methacrylate Polymer
III
Marine Pollutant
None
This product is not regulated as a dangerous good when
meet the general provisions of 5.0.2.4.1, 5.0.2.6.1 and 5.0.2.8
None
None
None
72869-86-4
Urethane Dimethacrylate
Listed
Trade Secret
Methacrylate Monomer
Listed
7534-94-3
Isobornyl methacrylate
Listed
Listed
Not
Listed
Listed
Listed
Listed
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Additional Information
International Air Transport Association Dangerous Goods Regulations (IATA-DGR)
UN number
UN proper shipping name
UN transport hazard class(es)
2020.02.24
This product is not regulated as a dangerous good when
transported in sizes of <5L or <5 kg provided the packaging
meets the general provisions of 4.1.1.1, 4.1.1.2 and 4.1.1.4 to
9
Packing group
Environmental hazards
Special precautions for user
Additional Information
transported in sizes of ≤5L or 5≤ kg provided the packaging
Transport in bulk according to Annex II of MARPOL and the IBC Code
Bulk Name
Ship type
Pollution category
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture.
European regulations
Inventory listing (EINECS):
162881-26-7
REACH SVHC candidate list:
72869-86-4
Trade Secret
7534-94-3
162881-26-7
REACH SVHC Authorizations:
72869-86-4
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Urethane Dimethacrylate
Methacrylate Monomer
Isobornyl methacrylate
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Urethane Dimethacrylate
Not
Listed
Not
Not
Not
Not
Safety Data Sheet
Page 14 of 15
Generated using Total SDS™ (patent-pending), www.GSMSDS.com
Listed
7534-94-3
Isobornyl methacrylate
Not
Listed
162881-26-7
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Not
Listed
Listed
Listed
Listed
Listed
Urethane Dimethacrylate
72869-86-4
Water hazard class 1: slightly hazardous to water
Isobornyl methacrylate
7534-94-3
Water hazard class 1: slightly hazardous to water
phosphine oxide
Ingredient Name
CAS Class
Base Emission Rate
Max Concentration
Urethane Dimethacrylate
72869-86-4
Not Applicable
Methacrylate Monomer
Trade Secret
Not Applicable
Isobornyl methacrylate
7534-94-3
Not Applicable
mg/m³
Phenyl bis(2,4,6-trimethylbenzoyl)-
162881-26-7
Not Applicable
Skin irritation, category 2
Calculation method
Eye Irritation, category 2
Calculation method
Skin sensitization, category 1
Calculation method
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Trade Secret
2020.02.24
Methacrylate Monomer
Not
REACH Restriction:
72869-86-4
Trade Secret
7534-94-3
162881-26-7
Urethane Dimethacrylate
Methacrylate Monomer
Isobornyl methacrylate
Phenyl bis(2,4,6-trimethylbenzoyl)-phosphine oxide
Water hazard class (WGK) (Product):
Water hazard class (WGK) (Substance):
Ingredient Name
Methacrylate Monomer
Phenyl bis(2,4,6-
CAS
Trade Secret Water hazard class 1: slightly hazardous to water
162881-26-7 Water hazard class 1: slightly hazardous to water
trimethylbenzoyl)-
Other regulations
Germany TA Luft:
Not determined.
Class
Not
Not
Not
Not
phosphine oxide
15.2 Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
SECTION 16: Other information
Abbreviations and Acronyms:
Classification procedure:
Classification according to Regulation (EC) No. 1272/2008 (CLP)
None
Method Used
Safety Data Sheet
Page 15 of 15
Generated using Total SDS™ (patent-pending), www.GSMSDS.com
respiratory tract irritation
Chronic aquatic hazard, category 2
Calculation method
Eye Irrit. 2
Eye Irritation, category 2
STOT SE 3 (RI)
Specific target organ toxicity - single exposure, category 3, respiratory tract irritation
Aquatic Chronic 4
Chronic aquatic hazard, category 4
H319 Causes serious eye irritation
H335 May cause respiratory irritation
H413 May cause long lasting harmful effects to aquatic life
According to Regulation (EC) No. 1272/2008 (CLP) and (EC) No. 1907/2006 (REACH)
Initial preparation date:
Tough 2000 Resin
Classification according to Regulation (EC) No. 1272/2008 (CLP)
Specific target organ toxicity - single exposure, category 3,
2020.02.24
Method Used
Calculation method
Summary of classification(s) in section 3:
Skin Sens. 1
Skin Irrit. 2
Aquatic Chronic 2
Aquatic Chronic 3
Skin sensitization, category 1
Skin irritation, category 2
Chronic aquatic hazard, category 2
Chronic aquatic hazard, category 3
Summary of hazard statements in section 3:
H317
H315
H411 Toxic to aquatic life with long lasting effects
H412
Disclaimer:
May cause an allergic skin reaction
Causes skin irritation
Harmful to aquatic life with long lasting effects
This product has been classified in accordance with EC No. 1272/2008 (CLP) and EC No. 1907/2006
(REACH). The information provided in this SDS is correct, to the best of our knowledge, based on
information available. The information given is designed only as a guidance for safe handling, use,
storage, transportation and disposal and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials, unless specified in the text. The responsibility to provide a safe
workplace remains with the user.
Initial preparation date:
2020.02.24
End of Safety Data Sheet
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