Durable
SAFETY DATA SHEET
Prepared: 15/01/2017
Version: 1
GHS/CLP Labelling
Hazard pictograms:
Signal word: Warning
SECTION 1: Identification of the substance/mixture
and of the company/undertaking
1.1 Product identifier
Product name : Durable
Product code : Not available
Product description : Mixture of methacrylic acid esters, photoinitiators, proprietary pigment and additive package.
Product type : Liquid.
Other means of identification : Not available
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : For use in Formlabs 3D printers.
1.3 Details of the supplier of the safety data sheet
Supplier’s details : Formlabs, Inc.
35 Medford Street, Suite #201
Somerville, MA
USA
E-mail address of person : sds@formlabs.com
responsible for this SDS
1.4 Emergency telephone number
National advisory body/Poison Centre
Telephone number : North America call +1 800 255 3924
Worldwide Intl. call +01 813 248 0585
Hours of operation : 24/7
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture.
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Skin Irrit. 2, H315
Skin Sens. 1, H317
STOT SE 3, H335
Aquatic Chronic 3, H412
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health eects and symptoms.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
2.2 Lebel elements
Hazard pictograms :
Signal word : Warning
Hazard statements : H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H335 - May cause respiratory irritation.
H412 - Harmful to aquatic life with long lasting eects.
Precautory statements
Prevention : P280 - Wear protective gloves. Wear eye or face protection.
P273 - Avoid release to the environment.
P261 - Avoid breathing vapour.
Response : P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER or physician if you feel unwell.
Storage : P405 - Store locked up
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,national
and international regulations.
Hazardous ingredients : Acrylated oligomers
Methacrylated monomers
Methacrylated oligomers
Photoinitiators
Supplemental label elements : Not applicable.
Annex XVII - Restrictions : Not applicable.
on the manufacture,placing
on the market and use of
certain dangerous substances,
mixtures and articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant fastenings
Tactile warning of danger : Not applicable.
2.3 Other hazards
Other hazards which do : None known.
not result in classification
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
SECTION 3: Composition/information on ingredients
3.2 Mixtures : Mixture.
Classification
Product/ingredient name Identifiers %
Regulation (EC) No. 1272/2008 [CLP] Type
Acrylate oligomers Proprietary or
not assigned
Acrylated monomers Proprietary or
not assigned
Methacrylated monomers Proprietary or
not assigned-
Methacrylated oligomers Proprietary or
not assigned
Photoinitiators Proprietary or
not assigned
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable,
are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been
assigned a workplace exposure limit and hence require reporting in this section.
Proprietary Skin Irrit. 2, H315
Eye Irrit. 2, H319
Skin Sens. 1, H317
Proprietary Skin Irrit. 2, H315
Eye Irrit. 2, H319
Proprietary Skin Irrit. 2, H315
Eye Irrit. 2, H319
Skin Sens. 1, H317
Aquatic Chronic 3, H412
Proprietary Eye Irrit. 2, H319
STOT SE 3, H335
Proprietary Skin Sens. 1, H317
Aquatic Chronic 2, H411
See Section 16 for the full text of
the H statements declared above
[1]
[1]
[1]
[1]
[1]
Type:
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.
SECTION 4: First aid measures
4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 20 minutes.
Get medical attention.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical
attention. If necessary, call a poison centre or physician. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Skin contact : Wash with plenty of soap and water. Wash contaminated clothing thoroughly withwater
before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Get medical
attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Stop if the expose person feels sick as
vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical
personnel. Get medical attention if adverse health eects persist or are severe. Never
give anything by mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute delayed
Potential acute health eects
Eye contact : No known significant eects or critical hazards.
Inhalation : May cause respiratory irritation.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant eects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No known significant eects or critical hazards.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities
have been ingested or inhaled.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing media : None known.
5.2 Special hazards arising from the substance or mixture
Hazards from the : This material is harmful to aquatic life with long lasting eects. Fire water contaminated
with this material must be contained and prevented from being discharged to any
waterway, sewer or drainsubstance or mixture
Hazardous thermal : No specific data.
decomposition products
5.3 Advice for firefighters
Special protective actions : No special measures are required.
for fire-fighters
Special protective equipment : Fire-fighters should wear appropriate protective equipment and self-contained
for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to
European standard EN 469 will provide a basic level of protection for chemical incidents.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
For non emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Keep unnecessary and unprotected personnel from entering. Do not touch or walk
through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency : If specialised clothing is required to deal with the spillage, take note of any
responders information in Section 8 on suitable and unsuitable materials. See also the information
in “For non-emergency personnel”.
6.2 Environmental precautions : Avoid dispersal of spilt material and runo and contact with soil, waterways, drains and
sewers. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Water polluting material. May be harmful to the
environment if released in large quantities.
6.3 Methods and material for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material
and place in an appropriate waste disposal container. Dispose of via a licensed
waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an euent treatment plant or proceed as follows. Contain and collect
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations.
Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilt product.
6.4 Reference to : See Section 1 for emergency contact information.
other sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any
available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history
of skin sensitization problems should not be employed in any process in which this
product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing
vapour or mist. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Empty containers retain product
residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is handled,
occupational hygiene stored and processed. Workers should wash hands and face before eating, drinking and
smoking. See also Section 8 for additional information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store
in unlabelled containers. Use appropriate containment to avoid environmental contamination.
7.3 Specific end use(s)
Recommendations : Not available.
Industrial sector : Not available.
specific sections
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
SECTION 8: Exposure controls/personal protection
The information in this section contains generic advice and guidance. Information is provided based on typical anticipated uses
of the product. Additional measures might be required for bulk handling or other uses that could significantly increase worker
exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the eectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as the
following: European Standard EN 689 (Workplace atmospheres - Guidance for the
assessment of exposure by inhalation to chemical agents for comparison with limit values
and measurement strategy) European Standard EN 14042 (Workplace atmospheres Guide for the application and use of procedures for the assessment of exposure to chemical
and biological agents) European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the measurement of chemical
agents). Reference to national guidance documents for methods for the determination
of hazardous substances will also be required.
DNELs/DMELs
No DNELs/DMELs available.
PNECs
No PNECs available.
8.2 Exposure controls
Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour
controls or mist use process enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure to airborne contaminants below any recommended or statutory limits.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check during
use that the gloves are still retaining their protective properties. It should be noted that
the time to breakthrough for any glove material may be dierent for dierent glove
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
manufacturers. In the case of mixtures, consisting of several substances, the protection
time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by
a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a respiratory
protection program to ensure proper fitting, training, and other important aspects of use.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Colour : Transparent light yellow.
Odour : Strong acrylic.
Odour threshold : Not available.
pH : Not available.
Melting point/freezing point : Not available.
Initial boiling point : >100 °C.
and boiling range
Flash point : Closed cup: 130°C [Pensky-Martens.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Upper/lower flammability : Not available.
or explosive limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : 1.04
Solubility(ies) : Not available.
Partition coecient : Not available.
n-octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): 24.8 cm2/s
Explosive properties : Not available.
Oxidising properties : Not available.
9.2 Other information
No additional information.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
SECTION 10: Stability and reactivity
10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : No specific data.
10.5 Incompatible materials : Not available.
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
There is no data available.
Irritation/Corrosion
There is no data available.
Sensitisation
There is no data available.
Mutagenicity
There is no data available.
Carcinogenicity
There is no data available.
Reproductive toxicity
There is no data available.
Teratogenicity
There is no data available.
Specific target organ toxicity (single exposure)
Product/Ingredient name Category Route of exposure Target organs
Acrylated oligomers
Methacrylated oligomers
Category 3
Category 3
Not applicable.
Not applicable.
Respiratory tract irritation.
Respiratory tract irritation.
Specific target organ toxicity (repeated exposure)
There is no data available.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
Aspiration hazard
There is no data available.
Information on likely : Dermal contact. Eye contact. Inhalation. Ingestion.
routes of exposure.
Potential acute health effects
Eye contact : No known significant eects or critical hazards.
Inhalation : May cause respiratory irritation.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant eects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No known significant eects or critical hazards.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate eects : No known significant eects or critical hazards.
Potential delayed eects : No known significant eects or critical hazards.
Long term exposure
Potential immediate eects : No known significant eects or critical hazards.
Potential delayed eects : No known significant eects or critical hazards.
Potential chronic health eects
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : No known significant eects or critical hazards.
Mutagenicity : No known significant eects or critical hazards.
Teratogenicity : No known significant eects or critical hazards.
Developmental eects : No known significant eects or critical hazards.
Fertility eects : No known significant eects or critical hazards.
Other information : Not available.
SECTION 12: Ecological information
12.1 Toxicity
There is no data available.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
12.2 Persistence and degradability
There is no data available.
12.3 Bioaccumulative potential
There is no data available.
12.4 Mobility in soil
Soil/water partition : Not available.
coecient (K
Mobility : Not available.
12.5 Results of PBT and vPvB assessment
PBT : Not applicable.
vPvB : Not applicable.
12.6 Other adverse effects : No known significant eects or critical hazards.
)
OC
SECTION 13: Disposal considerations
The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any
available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Disposal
of this product, solutions and any by-products should comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be taken
when handling empty containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of spilt
material and runo and contact with soil, waterways, drains and sewers.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
SECTION 14: Transport information
ADR/RID
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.
14.2 UN proper
shipping name
14.3 Transport
hazard class(es)
14.4 Packing
group
14.5 Environmental
hazards
Additional
information
14.6 Special precautions : Transport within user’s premises: always transport in closed containers that are upright
for user and secure. Ensure that persons transporting the product know what to do in the event
- - - -
-
-
No. No. No. No.
-
of an accident or spillage.
ADN
-
- -
- -
IMDG IATA
- -
-
-
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
Europe inventory : Not determined.
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Seveso Directive
This product is not controlled under the Seveso Directive.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
15.2 Chemical safety : This product contains substances for which Chemical Safety Assessments are still required.
assessment
SECTION 16: Other information
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DMEL = Derived Minimal Eect Level
DNEL = Derived No Eect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Eect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Skin Irrit. 2, H315
Skin Sens. 1, H317
STOT SE 3, H335
Aquatic Chronic 3, H412
Calculation method
Calculation method
Calculation method
Calculation method
Full text of abbreviated :
H statements
Full text of :
classifications [CLP/GHS]
History
Date of issue (dd/mm/yyyy) : 15/01/2017
Version : 1
Prepared by : KMK Regulatory Services Inc
H315
H317
H319
H335
H411
H412
Acute Tox. 4, H411
Aquatic Chronic
3, H412
Eye Irrit. 2, H319
Skin Irrit. 2, H315
Skin Sens. 1, H317
STOT SE 2, H371
STOT SE 3, H335
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
May cause respiratory irritation.
Toxic to aquatic life with long lasting eects
Harmful to aquatic life with long lasting eects.
LONG-TERM AQUATIC HAZARD - Category 2
LONG-TERM AQUATIC HAZARD - Category 3
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
SKIN CORROSION/IRRITATION - Category 2
SKIN SENSITISATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE Category 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Respiratory tract irritation) - Category 3
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries,
assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is
the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II,
as amended by Commission Regulation (EU)2015/830
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