Safety Data Sheet
DEFROSTING SPRAY 250 ml ELECTROLUX
Safety Data Sheet dated 7/2/2013, version 1
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product Identifier
Mixture identification:
Trade name: DEFROSTING SPRAY 250 ml ELECTROLUX
Trade code: 9029792968
1.2. Relevant identified uses of the substance/mixture and uses advised against
Recommended use:
Defrosting spray for refrigeretors
1.3. Details of the supplier of the safety data sheet
Company:
AXOR SRL
Via dell'Artigianato 8
35020 Pernumia (PD)
Phone n. 0039 429763476
Competent person responsible for the safety data sheet:
axor@axor.net
1.4. Emergency telephone number
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
None.
R Phrases:
R10 Flammable.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
R Phrases:
R10 Flammable.
S Phrases:
S16 Keep away from sources of ignition - No smoking.
S2 Keep out of reach of children.
S25 Avoid contact with eyes.
S46 If swallowed, seek medical advice immediately and show this container or label.
List of all ingredients by decreasing weight, divided into percentage weight categories (Reg
648/2004EC Ann. VII, C).
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
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DEFROSTING SPRAY 250 ml ELECTROLUX
N.A.
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and
related classification:
12.5% - 15% PROPAN-2-OL; ISOPROPYL ALCOHOL; ISOPROPANOLO
Index number: 603-117-00-0, CAS: 67-63-0, EC: 200-661-7
F,Xi; R11-36-67
2.6/2 Flam. Liq. 2 H225
3.3/2 Eye Irrit. 2 H319
3.8/3 STOT SE 3 H336
1% - 3% DIPROPYLENE GLYCOL METHYL ETHER
REACH No.: 01-2119450011-60-000, CAS: 34590-94-8, EC: 252-104-2
substance with a Community workplace exposure limit
4. FIRST AID MEASURES
4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
None
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media:
CO2 or Dry chemical fire extinguishe.
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. ACCIDENTAL RELEASE MEASURES
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DEFROSTING SPRAY 250 ml ELECTROLUX
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove all sources of ignition.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13
7. HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material
residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recomened protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to
sunlight.
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
7.3. Specific end use(s)
None in particular
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
PROPAN-2-OL; ISOPROPYL ALCOHOL; ISOPROPANOL - CAS: 67-63-0
TLV TWA - 200 ppm, A4 - 491,53 mg/m3, A4
TLV STEL - 400 ppm, A4 - 983,07 mg/m3, A4
DIPROPYLENE GLYCOL METHYL ETHER - CAS: 34590-94-8
TLV TWA - 308 mg/m3 pelle
TLV STEL - 150 ppm pelle
DNEL Exposure Limit Values
DIPROPYLENE GLYCOL METHYL ETHER - CAS: 34590-94-8
Worker Industry: 65 mg/kg - Exposure: Human Dermal Long Term, systemic effects
Worker Industry: 310 mg/kg - Exposure: Human Inhalation Long Term, systemic effects
Consumer: 15 mg/kg - Exposure: Human Dermal Long Term, systemic effects
Consumer: 37.2 mg/l - Exposure: Human Inhalation Long Term, systemic effects
Consumer: 1.67 mg/kg - Exposure: Human Oral Long Term, systemic effects
PNEC Exposure Limit Values
DIPROPYLENE GLYCOL METHYL ETHER - CAS: 34590-94-8
Target: Fresh Water - Value: 19 mg/l
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DEFROSTING SPRAY 250 ml ELECTROLUX
Target: Marine water - Value: 1.9 mg/l
Target: Freshwater sediments - Value: 70.2 mg/kg
Target: Marine water sediments - Value: 7.02 mg/kg
Target: Soil (agricultural) - Value: 2.74 mg/kg
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Not needed for normal use.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance and colour: COLOURLESS LIQUID
Odour: NOTE ALCOHOLIC
Odour threshold: N.A.
pH: 7.5 - 8.5
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.
Solid/gas flammability: N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.A.
Flash point: 35 +/- 2 ° C
Evaporation rate: N.A.
Vapour pressure: N.A.
Relative density: 0.95 - 0.99
Solubility in water: SOLUBLE
Lipid solubility: INSOLUBLE
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: N.A.
Oxidizing properties: N.A.
9.2. Other information
Miscibility: N.A.
Fat Solubility: N.A.
Conductivity: N.A.
Substance Groups relevant properties N.A.
10. STABILITY AND REACTIVITY
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None
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10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
Avoid contact with combustible materials. The product could catch fire.
10.6. Hazardous decomposition products
None.
11. TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
N.A.
If not differently specified, the information required in Regulation 453/2010/EC listed below must be
considered as N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.
12. ECOLOGICAL INFORMATION
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
N.A.
12.2. Persistence and degradability
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in
force.
14. TRANSPORT INFORMATION
14.1. UN number
ADR-UN number: 1993
14.2. UN proper shipping name
ADR-Shipping Name: LIQUID FLAMMABLE
14.3. Transport hazard class(es)
ADR-Class: 3
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DEFROSTING SPRAY 250 ml ELECTROLUX
14.4. Packing Group
ADR-Packing Group: gr III
14.5. Environmental hazards
14.6. Special Precautions for User
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
N.A.
The product has been classified, labeled and packaged in accordance with the requirements
of ADR.
Dangerous goods packed in limited quantities, which complies with the provisions of Chapter
3.4, are entitled to special diposizioni (exemptions) from the ADR.
15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Restrictions related to the product or the substances contained according to Annex XVII Regulation
(EC) 1907/2006 (REACH) and subsequent modifications:
None
Where applicable, refer to the following regulatory provisions :
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent
amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)
15.2. Chemical Safety Assessment
No
16. OTHER INFORMATION
Full text of phrases referred to in Section 3:
R11 Highly flammable.
R36 Irritating to eyes.
R67 Vapours may cause drowsiness and dizziness.
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
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ADR:
European Agreement concerning the International Carriage of
Dangerous Goods by Road.
CAS:
Chemical Abstracts Service (division of the American Chemical
Society).
CLP:
Classification, Labeling, Packaging.
DNEL:
Derived No Effect Level.
EINECS:
European Inventory of Existing Commercial Chemical Substances.
GefStoffVO:
Ordinance on Hazardous Substances, Germany.
GHS:
Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA:
International Air Transport Association.
IATA-DGR:
Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO:
International Civil Aviation Organization.
ICAO-TI:
Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG:
International Maritime Code for Dangerous Goods.
INCI:
International Nomenclature of Cosmetic Ingredients.
KSt:
Explosion coefficient.
LC50:
Lethal concentration, for 50 percent of test population.
LD50:
Lethal dose, for 50 percent of test population.
LTE:
Long-term exposure.
PNEC:
Predicted No Effect Concentration.
RID:
Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STE:
Short-term exposure.
STEL:
Short Term Exposure limit.
STOT:
Specific Target Organ Toxicity.
TLV:
Threshold Limiting Value.
TWATLV:
Threshold Limit Value for the Time Weighted Average 8 hour day.
(ACGIH Standard).
WGK:
German Water Hazard Class.
N.A.:
N.A.
N.D.:
DEFROSTING SPRAY 250 ml ELECTROLUX
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This MSDS cancels and replaces any preceding release.
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