Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
Section 1: IDENTIFICATION
1.1 PRODUCT IDENTIFIER
Product Name:
Product Code:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR
07873, 07874, 07876, 07877
Caulking (Exterior).
Tower Sealants
2095 Memorial Park Road
Gainesville, Georgia
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone Number:
30504 USA
1-770-535-8780
CHEMTREC: 1-800-424-9300
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012
Skin irritation 2
Eye irritation 2A
Skin sensitization 1
Specific target organ toxicity - Repeated exposure 1
2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012
Hazard Pictogram:
Hazard class
Signal Word:
Hazard Statement:
Danger
Causes skin irritation. Causes serious eye irritation. May cause an
allergic skin reaction. Causes damage to organs through prolonged
Prevention:
or repeated exposure.
Wash hands thoroughly after handling. Wear protective gloves/eye
protection/face protection. Contaminated work clothing must not be
allowed out of the workplace. Do not breathe dust/fume/gas/mist/
Response:
vapors/spray. Do not eat, drink or smoke when using this product.
Get medical advice/attention if you feel unwell. If on skin: Wash with
plenty of water. Take off contaminated clothing and wash it before
reuse. If skin irritation or rash occurs: Get medical advice/attention.
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/attention.
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
Storage:
Disposal:
2.3 ADDITIONAL INFORMATION
Hazards not otherwise classified:
2 % of the mixture consists of ingredient(s) of unknown acute toxicity.
Not applicable.
Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Not applicable.
WHMIS Classification(s):
Class D2A - Teratogenicity and Embryotoxicity
Class D2B - Skin/Eye Irritant
WHMIS Hazard Symbols:
WHMIS Signal Word:
3.1 MIXTURES
WARNING
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS No Wt. %
Polymer, Acrylic (non-hazardous) Trade Secret 30.0 - 70.0
Sodium lauryl sulfate 151-21-3 0.1 - 5
Ethylene glycol 107-21-1 0.1 - 5
Ammonium hydroxide 1336-21-6 0.1 - 1
Stoddard solvent 8052-41-3 0.1 - 1
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane 2530-83-8 0.1 - 1
1,2-Benzisothiazolone 2634-33-5 0.1 - 1
3-Iodo-2-propynyl butylcarbamate 55406-53-6 0.1 - 1
Ethyl acrylate 140-88-5 < 0.1
The exact percentage (concentration) of composition has been withheld as a trade secret in
accordance with paragraph (i) of §1910.1200.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. If easy to do, remove contact lenses, if worn. If
Skin:
irritation persists, get medical attention.
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clothing before
Inhalation:
reuse. Call a physician if irritation develops and persists.
If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if
you feel unwell.
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Pri nt date: 2014-11-21
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SAFETY DATA SHEET
Ingestion:
If swallowed, do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
person. Get medical advice/attention if you feel unwell.
Causes serious eye irritation. Symptoms may include discomfort or
pain, excess blinking and tear production, with marked redness and
Skin:
Inhalation:
Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians:
Specific Treatments:
swelling of the conjunctiva.
Causes skin irritation. Symptoms may include redness, edema, drying,
defatting and cracking of the skin. May cause an allergic skin reaction.
May cause respiratory tract irritation. May cause headache and dizziness.
May be harmful if swallowed. May cause stomach distress, nausea
or vomiting.
Symptoms may not appear immediately.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 FLAMMABILITY
Flammability:
5.2 EXTINGUISHING MEDIA
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
Explosion Data:
Sensitivity to Mechanical Impact: Not available.
Sensitivity to Static Discharge: Not available.
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Not flammable by WHMIS/OSHA criteria.
Powder, water spray, foam, carbon dioxide.
None known.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection
(SCBA). Use water spray to keep fire-exposed containers cool. Material may splatter if heated
above 93°C / 200°F.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel. Avoid contact with skin and eyes.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to
sewer or allow to enter waterways. Use appropriate Personal
Protective Equipment (PPE).
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
Methods for Cleaning-Up:
Preferred method would be to scrape up spilled material and place in
secondary container for disposal. Smaller spills can also be wiped
up. Residual material can be removed with the assistance of hot
water and soap. Provide ventilation.
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Do not breathe
dust/fume/gas/mist/vapors/spray. Handle and open container with
care. Use only in well-ventilated areas. When using do not eat, drink
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
or smoke. (See section 8)
Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Keep out of the reach of children. Keep container tightly closed.
Store in a dry, cool and well-ventilated area. Keep from freezing.
(See section 10)
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
-
Sodium lauryl sulfate Not available. Not available.
Ethylene glycol Not available.
Ammonium hydroxide Not available. Not available.
Stoddard solvent 2900 mg/m³; 500 ppm 100 ppm
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane Not available. Not available.
1,2-Benzisothiazolone Not available. Not available.
3-Iodo-2-propynyl butylcarbamate Not available. Not available.
Ethyl acrylate 5 ppm 5 ppm
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection:
Body Protection:
Use ventilation adequate to keep exposures (airborne levels of dust,
fume, vapor, etc.) below recommended exposure limits.
Wear eye protection.
Wear chemical resistant gloves.
Wear suitable protective clothing.
100 mg/m
3
Ceiling
(aerosol only)
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
Respiratory Protection:
In case of insufficient ventilation, wear suitable respiratory equipment.
Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the
General Health and Safety Measures:
selected respirator.
Do not eat, smoke or drink where material is handled, processed
or stored. Wash hands carefully before eating or smoking.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Color:
Odor:
Odor Threshold:
Physical State:
pH:
Melting Point/Freezing Point:
Initial Boiling Point and Boiling Range:
Flash Point:
Evaporation Rate:
Flammability:
Lower Flammability/Explosive Limit:
Upper Flammability/Explosive Limit:
Vapor Pressure:
Vapor Density:
Relative Density/Specific Gravity:
Solubility:
Partition coefficient: n-octanol/water:
Auto-ignition Temperature:
Decomposition Temperature:
Viscosity:
Explosive Properties:
Oxidizing Properties:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions.
Paste.
White when wet, clear when dries.
Sweet acrylic, with a mild ammonia odor.
Not available.
Liquid.
7.5 – 9.0
< 0 °C (< 32 °F)
> 93 °C (> 200 °F)
Not applicable.
Slower than ether.
Not flammable.
Not available.
Not available.
25 mm Hg @ 20 °C (68 °F)
> 1 (Air = 1)
Not available.
Dispersible.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Heat. Incompatible materials.
10.5 INCOMPATIBLE MATERIALS
Oxidizers.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure:
Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
Causes serious eye irritation. Symptoms may include discomfort or pain,
excess blinking and tear production, with marked redness and swelling of
Acute Toxicity:
Skin:
Ingestion:
Inhalation:
Ingredient LC50 LD50
the conjunctiva.
Causes skin irritation. Symptoms may include redness, edema, drying,
defatting and cracking of the skin. May cause an allergic skin reaction.
May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
May cause respiratory tract irritation. May cause headache and dizziness.
-
Sodium lauryl sulfate
Ethylene glycol Not available.
Ammonium hydroxide Not available. Oral 350 mg/kg, rat
Stoddard solvent Not available. Not available.
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane
1,2-Benzisothiazolone Not available. Oral 1020 mg/kg, rat
3-Iodo-2-propynyl butylcarbamate
Ethyl acrylate
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
>20 mg/L 4h, rat > 2000 mg/kg, rat > 2000 mg/kg, rabbit
Inhalation
>3900 mg/m3 1h, rat
Inhalation
> 5.3 mg/L 4h, rat
Inhalation
0.78 mg/L 4h, rat
Inhalation
1414 ppm 4 h, rat
Oral 1288 mg/kg, rat
Dermal 580 mg/kg, rabbit
Oral 4000 mg/kg, rat
Dermal 9530 µL/kg, rabbit
Oral 22600 µL/kg, rat
Dermal 3970 µL/kg, rabbit
Oral 300-500 mg/kg, rat
Dermal >2000 mg/kg, rat
Oral 800 mg/kg, rat
Dermal 500 µL/kg, rabbit
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
Ingredient
-
Sodium lauryl sulfate Not listed.
Ethylene glycol G-A4
Ammonium hydroxide Not listed.
Stoddard solvent Not listed.
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane Not listed.
1,2-Benzisothiazolone Not listed.
3-Iodo-2-propynyl butylcarbamate Not listed.
Ethyl acrylate G-A4, I-2B, O, CP65
* See Section 15 for more information.
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory Sensitization:
Skin Sensitization:
STOT-Single Exposure:
Chronic Health Effects:
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Teratogenicity:
STOT-Repeated Exposure:
Aspiration Hazard:
Toxicologically Synergistic Materials:
Other Information:
Embryotoxicity:
Fertility:
Causes skin irritation.
Causes serious eye irritation.
Based on available data, the classification criteria are not met.
May cause an allergic skin reaction.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Hazardous by WHMIS criteria.
Hazardous by WHMIS criteria.
Based on available data, the classification criteria are not met.
Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met.
Not available.
Section 12: ECOLOGICAL INFORMATION
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
May cause long-term adverse effects in the aquatic environment.
Not available.
Not available.
Chemical Listed as Carcinogen or
Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
Section 13: DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal recommendations:
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
14.2 UN PROPER SHIPPING NAME
14.3 TRANSPORT HAZARD CLASS (ES)
14.4 PACKING GROUP
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
DOT TDG
Not regulated. Not regulated.
DOT TDG
Not applicable. Not applicable.
DOT TDG
Not applicable. Not applicable.
DOT TDG
Not applicable. Not applicable.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICAL
Canada: This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the SDS contains all the information required by the
Controlled Products Regulations.
US: SDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200)
HazCom 2012
This material must be disposed of in accordance with all
local, state, provincial, and federal regulations.
Not available.
Trade Name: DUPONT™ DOOR, WINDOW & SIDING SEALANT W/KEVLAR CLEAR Pri nt date: 2014-11-21
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SAFETY DATA SHEET
SARA Title III
Ingredient Section 302
(EHS) TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA
RQ (lbs.)
Section
313
Sodium lauryl sulfate Not listed. Not listed. Not listed. Not listed.
Ethylene glycol Not listed. Not listed. 5,000 313
Ammonium hydroxide Not listed. Not listed. 1,000 313
Stoddard solvent Not listed. Not listed. Not listed. Not listed.
[3-(2,3-Epoxypropoxy)propyl]
trimethoxysilane Not listed. Not listed. Not listed. Not listed.
1,2-Benzisothiazolone Not listed. Not listed. Not listed. Not listed.
3-Iodo-2-propynyl butylcarbamate Not listed. Not listed. Not listed. 313
Ethyl acrylate Not listed. Not listed. 1,000 313
California Proposition 65:
This product contains a chemical known to the State of California to cause cancer.
Global Inventories:
Ingredient
State Regulations
Canada
DSL/NDSL
USA
TSCA
Sodium lauryl sulfate DSL Yes.
Ethylene glycol DSL Yes.
Ammonium hydroxide DSL Yes.
Stoddard solvent DSL Yes.
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane DSL Yes.
1,2-Benzisothiazolone DSL Yes.
3-Iodo-2-propynyl butylcarbamate DSL Yes.
Ethyl acrylate DSL Yes.
Health:
Fire:
Reactivity:
Health: 1
Fire: 0
Physical Hazard:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
CP65 California Proposition 65
OSHA (O) Occupational Safety and Health Administration.
NFPA National Fire Protection Association:
1
0
0
HMIS-Hazardous Materials Identification System
*
0
ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen.
A2 - Suspected human carcinogen.
A3 - Animal carcinogen.
A4 - Not classifiable as a human carcinogen.
A5 - Not suspected as a human carcinogen.
Trade Name: DUPONT™ AIRTITE SILICONIZED ACRYLIC CAULK CLEAR Print date: 2014-11-21
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SAFETY DATA SHEET
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans.
2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals.
2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in
humans in the absence of sufficient evidence of carcinogenicity in experimental animals.
3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens.
2 - Reasonably anticipated to be carcinogens.
Section 16: OTHER INFORMATION
Date of Preparation: Nov
Expiry Date:
Version:
Revision Date: November 21, 2014
ember 21, 2014
November 21, 2017
1.0
Disclaimer: We believe the statements, technical information and recommendations contained herein
are reliable, but they are given without warranty or guarantee of any kind. The information contained in
this document applies to this specific material as supplied. It may not be valid for this material if it is used
in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability
and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc.
Phone: (51 9) 488-5126
Prepared for:
www.nexreg.com
Tower Sealants
.
End of Safety Data Sheet
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