Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
Section 1: IDENTIFICATION
1.1 PRODUCT IDENTIFIER
Product Name:
Product Code:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE
07620, 07887
Interior use for kitchen and bath projects.
Tower Sealants
2095 Memorial Park Road
Gainesville, Georgia
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone Number:
30504 USA
1-770-535-8780
CHEMTREC: 1-800-424-9300
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012
Skin Irritation 2
Serious Eye Damage 1
Skin Sensitization 1
Specific Target Organ Toxicity - Repeated Exposure 2
2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012
Hazard Pictogram:
Hazard class
Signal Word:
Hazard Statement:
Danger
Causes skin irritation. Causes serious eye damage. May cause an
allergic skin reaction. May cause damage to organs through
Prevention:
prolonged or repeated exposure.
Wash hands thoroughly after handling. Wear protective gloves/eye
protection/face protection. Contaminated work clothing must not be
allowed out of the workplace. Do not breathe dust/fume/gas/mist/
Response:
vapors/spray.
Get medical advice/attention if you feel unwell. If on skin: Wash with
plenty of water. Take off contaminated clothing and wash it before
reuse. If skin irritation or rash occurs: Get medical advice/attention.
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Immediately call a poison center/doctor.
Page 1 of 10
Storage:
Conforms to OSHA HazCom 2012 & CPR Standards
Disposal:
2.3 ADDITIONAL INFORMATION
Hazards not otherwise classified:
WHMIS Classification(s):
Class D2B - Skin Sensitization
Class D2B - Skin/Eye Irritant
WHMIS Hazard Symbols:
SAFETY DATA SHEET
Not applicable.
Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Not applicable.
WHMIS Signal Word:
3.1 MIXTURES
WARNING
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS No Wt. %
Siloxanes and Silicones, di-Me, hydroxy-terminated 70131-67-8 60 - 100
Silica, amorphous, fumed 7631-86-9 7 - 13
Distillates (petroleum), hydrotreated middle 64742-46-7 3 - 7
Triacetoxyethylsilane 17689-77-9 1 - 5
Butan-2-one O,O',O''-(methylsilylidyne)trioxime 22984-54-9 1 - 5
Titanium dioxide 13463-67-7 0.5 - 1.5
Diphenoxarsin-10-yl oxide 58-36-6 0.1 - 1
The exact percentage (concentration) of composition has been withheld as a trade secret in
accordance with paragraph (i) of §1910.1200.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at least
15 minutes. If easy to do, remove contact lenses, if worn. Immediately call
Skin:
a poison center/doctor.
In case of contact, immediately flush skin with plenty of water. Remove
contaminated clothing and shoes. Wash clothing before reuse. Call a
Inhalation:
Ingestion:
physician if irritation develops and persists.
If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing. Get m edical ad vice/attenti on if you f eel unwell.
If swallowed, do NOT induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get
medical advice/attention if you feel unwell.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 2 of 10
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SAFETY DATA SHEET
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
Causes serious eye damage. Symptoms may include discomfort or pain,
excess blinking and tear production, with marked redness and swelling of
Skin:
Inhalation:
Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians:
Specific Treatments:
the conjunctiva. May cause burns.
Causes skin irritation. Symptoms may include redness, edema, drying,
defatting and cracking of the skin. May cause an allergic skin reaction.
May cause respiratory tract irritation. May cause headache and dizziness.
May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
Symptoms may not appear immediately.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 FLAMMABILITY
Flammability:
5.2 EXTINGUISHING MEDIA
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
Explosion Data:
Sensitivity to Mechanical Impact: Not available.
Sensitivity to Static Discharge: Not available.
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Not flammable by WHMIS/OSHA criteria.
Dry chemical, water spray, foam, carbon dioxide.
None known.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection
(SCBA). Use water spray to keep fire-exposed containers cool.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel. Avoid contact with skin and eyes.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to
sewer or allow to enter waterways. Use appropriate Personal
Methods for Cleaning-Up:
Protective Equipment (PPE).
Preferred method would be to scrape up spilled material and place in
secondary container for disposal. Smaller spills can also be wiped
up. Residual material can be removed with the assistance of hot
water and soap. Provide ventilation.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 3 of 10
Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Do not breathe
dust/fume/gas/mist/vapors/spray. Handle and open container with
care. Use only in well-ventilated areas. When using do not eat, drink
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
or smoke. (See section 8)
Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Keep out of the reach of children. Keep container tightly closed. Store in a
dry, cool and well-ventilated area. Keep from freezing. (See section 10)
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
Siloxanes and Silicones, di-Me, hydroxy-terminated Not available. Not available.
Silica, amorphous, fumed 80 mg/m3/%SiO2 Not available.
Distillates (petroleum), hydrotreated middle Not available. Not available.
Triacetoxyethylsilane Not available. Not available.
Butan-2-one O,O',O''-(methylsilylidyne)trioxime Not available. Not available.
Titanium dioxide 15 mg/m3 (total dust) 10 mg/m³
Diphenoxarsin-10-yl oxide Not available. Not available.
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection:
Body Protection:
Respiratory Protection:
Use ventilation adequate to keep exposures (airborne levels of dust,
fume, vapor, etc.) below recommended exposure limits.
Wear approved eye protection (properly fitted dust- or splash-proof
chemical safety goggles) and face protection (face shield).
Wear chemical resistant gloves.
Wear suitable protective clothing.
In case of insufficient ventilation, wear suitable respiratory equipment.
Respirator selection must be based on known or anticipated exposure levels,
General Health and Safety
Measures:
the hazards of the product and the safe working limits of the selected respirator.
Do not eat, smoke or drink where material is handled, processed or
stored. Wash hands carefully before eating or smoking.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 4 of 10
Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Color:
Odor:
Odor Threshold:
Physical State:
pH:
Melting Point/Freezing Point:
Initial Boiling Point and Boiling Range:
Flash Point:
Evaporation Rate:
Flammability:
Lower Flammability/Explosive Limit:
Upper Flammability/Explosive Limit:
Vapor Pressure:
Vapor Density:
Relative Density/Specific Gravity:
Solubility:
Partition coefficient: n-octanol/water:
Auto-ignition Temperature:
Decomposition Temperature:
Viscosity:
Explosive Properties:
Oxidizing Properties:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Heat. Incompatible materials.
Paste.
White.
Low odor.
Not available.
Liquid.
Not available.
Not available.
Not available.
Not available.
Not available.
Not flammable.
Not available.
Not available.
Not available.
Not available.
1.04 @ 25° C (77° F)
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 5 of 10
Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
10.5 INCOMPATIBLE MATERIALS
Oxidizers. Water, moisture or humid air can caus e hazardous vapor s to form (methyl ethyl ket oxime).
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon, silicon dioxide, formaldehyde, nitrogen oxides.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure:
Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
Causes serious eye damage. Symptoms may include discomfort or pain,
excess blinking and tear production, with marked redness and swelling of
Acute Toxicity:
Skin:
Ingestion:
Inhalation:
the conjunctiva. May cause burns.
Causes skin irritation. Symptoms may include redness, edema, drying,
defatting and cracking of the skin. May cause an allergic skin reaction.
May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
May cause respiratory tract irritation. May cause headache and dizziness.
Ingredient LC50 LD50
Siloxanes and Silicones, di-Me, hydroxy-terminated Not available.
Silica, amorphous, fumed
Distillates (petroleum), hydrotreated middle
Triacetoxyethylsilane Not available. Oral 1462 mg/kg, rat
Butan-2-one O,O',O''-(methylsilylidyne)trioxime Not available.
Titanium dioxide Not available.
Diphenoxarsin-10-yl oxide Not available. Oral 40mg/kg, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
Not available. > 2000 mg/kg, rat > 2000 mg/kg, rabbit
Ingredient
Siloxanes and Silicones, di-Me, hydroxy-terminated Not listed.
Silica, amorphous, fumed I-3
Distillates (petroleum), hydrotreated middle Not listed.
Triacetoxyethylsilane Not listed.
Butan-2-one O,O',O''-(methylsilylidyne)trioxime Not listed.
Titanium dioxide
Diphenoxarsin-10-yl oxide I-1, N-1, CP65
Inhalation
>2.2 mg/L 1h, rat
Inhalation
4.6 mg/L 4 h, rat
Chemical Listed as Carcinogen or
(NTP, IARC, OSHA, ACGIH, CP65)*
G-A4, I-2B, CP65 (airborne, unbound
Oral >64 mL/kg, rat
Dermal >16 mL/kg, rabbit
Oral >5000 mg/kg, rat
Dermal >2000 mg/kg, rabbit
Oral >5000 mg/kg, rat
Dermal >2000 mg/kg, rabbit
Oral 2453 mg/kg, rat
Dermal > 2000 mg/kg, rabbit
Oral >10000 mg/kg, rat
Dermal >10000mg/kg, rabbit
Potential Carcinogen
particles of respirable size)
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
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Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
* See Section 15 for more information.
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory Sensitization:
Skin Sensitization:
STOT-Single Exposure:
Chronic Health Effects:
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Teratogenicity:
STOT-Repeated Exposure:
Aspiration Hazard:
Toxicologically Synergistic Materials:
Other Information:
Embryotoxicity:
Fertility:
Causes skin irritation.
Causes serious eye damage.
Based on available data, the classification criteria are not met.
May cause an allergic skin reaction.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Causes damage to organs through prolonged or repeated exposure.
Based on available data, the classification criteria are not met.
Not available.
Section 12: ECOLOGICAL INFORMATION
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
May cause long-term adverse effects in the aquatic environment.
Not available.
Section 13: DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal recommendations:
Not available.
This material must be disposed of in accordance with all
local, state, provincial, and federal regulations.
Not available.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 7 of 10
Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
14.2 UN PROPER SHIPPING NAME
14.3 TRANSPORT HAZARD CLASS (ES)
14.4 PACKING GROUP
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
DOT TDG
Not regulated. Not regulated.
DOT TDG
Not applicable. Not applicable.
DOT TDG
Not applicable. Not applicable.
DOT TDG
Not applicable. Not applicable.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICAL
Canada: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the SDS contains all the information required by the Controlled Products
Regulations.
US: SDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200)
HazCom 2012
SARA Title III
Ingredient Section 302
(EHS) TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA
RQ (lbs.)
Section
313
Siloxanes and Silicones, di-Me, hydroxyterminated Not listed. Not listed. Not listed . Not listed .
Silica, amorphous, fumed Not listed. Not listed. Not l i s t e d . Not l i s t e d.
Distillates (petroleum), hydrotreated middle Not listed. Not listed. Not listed. Not listed.
Triacetoxyethylsilane Not listed. Not listed. Not listed. Not l isted.
Butan-2-one O,O',O''-(methylsilylidyne)
trioxime Not listed. Not listed. Not listed. Not listed.
Titanium dioxide Not listed. Not listed. Not listed . Not listed .
Diphenoxarsin-10-yl oxide 500/10,000 500 Not li s t e d . Not l i s t e d .
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 8 of 10
Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
California Proposition 65:
This product contains a chemical known to the State of California to cause cancer.
Global Inventories:
State Regulations
Ingredient
Siloxanes and Silicones, di-Me, hydroxy-terminated DSL Yes.
Silica, amorphous, fumed DSL Yes.
Distillates (petroleum), hydrotreated middle DSL Yes.
Triacetoxyethylsilane DSL Yes.
Butan-2-one O,O',O''-(methylsilylidyne)trioxime DSL Yes.
Titanium dioxide DSL Yes.
Diphenoxarsin-10-yl oxide DSL No.
NFPA National Fire Protection Association:
Health:
Fire:
Reactivity:
HMIS-Hazardous Materials Identification System
Health:
Fire:
Physical Hazard:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
CP65 California Proposition 65
OSHA (O) Occupational Safety and Health Administration.
ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen.
A2 - Suspected human carcinogen.
A3 - Animal carcinogen.
A4 - Not classifiable as a human carcinogen.
A5 - Not suspected as a human carcinogen.
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans.
2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals.
2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in
humans in the absence of sufficient evidence of carcinogenicity in experimental animals.
3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens.
2 - Reasonably anticipated to be carcinogens.
Canada
DSL/NDSL
USA
TSCA
3
1
0
3*
1
0
.
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
Page 9 of 10
Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
Section 16: OTHER INFORMATION
Date of Preparation:
Expiry Date:
Version:
Revision Date:
October 8, 2014
October 8, 2017
1.0
October 8, 2014
Disclaimer: We believe the statements, technical information and recommendations contained herein
are reliable, but they are given without warranty or guarantee of any kind. The information contained in
this document applies to this specific material as supplied. It may not be valid for this material if it is used
in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability
and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc.
Phone: (519) 488-5126
Prepared for:
www.nexreg.com
Tower Sealants
End of Safety Data Sheet
Trade Name: DUPONT™ 9.8OZ KITCHEN & BATH PREMIER SILICONE WHITE Print date: 2014-10-08
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