Datasheet UNIVERSAL DEGREASER Specification

Page 1
Report Date : 05/11/2012
Revision Date 05/11/2012
Revision 4
Supersedes date 17/01/2012
SDS No. 10700
COO-VARSupplier Lockwood Street Hull HU2 0HN +44 (0) 1482 328053(T) +44 (0) 1482 219266(F) info@coo-var.co.uk
Hydrocarbons, C9, aromatics
Harmful
Dangerous for the environment
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SAFETY DATA SHEET
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name UNIVERSAL DEGREASER CLEANER
Product No. 100/V607/15/D
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses As a cleaner/degreaser solvent
1.3. Details of the supplier of the safety data sheet
Contact Person Technical Department - 08.30 - 16.30 hrs Mon - Thurs, 08.30 - 15.00 hrs Fri as above
1.4. Emergency telephone number
+44 (0) 1482 328053 (08.30 - 16.30 hrs Mon - Thurs, 08.30 - 15.00 hrs Fri)
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Xn;R65. Xi;R37. N;R51/53. R10, R66, R67.
2.2. Label elements
Contains
Labelling
Risk Phrases
Safety Phrases
R10 Flammable.
R37 Irritating to respiratory system.
R51/53
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S29/56
S37 Wear suitable gloves.
S46
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
If swallowed, seek medical advice immediately and show this container or label.
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SDS No. 10700
Hydrocarbons, C9, aromatics
60-100%
CAS-No.:
EC No.: 918-668-5
Classification (67/548/EEC) Xn;R65. Xi;R37. N;R51/53. R10,R66,R67.
Classification (EC 1272/2008) Flam. Liq. 3 - H226 EUH066 STOT SE 3 - H335, H336 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411
Registration Number: 01-2119455851-35-xxxx
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
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S51 Use only in well-ventilated areas.
S61
S64 If swallowed, rinse mouth with water (only if the person is conscious).
2.3. Other hazards
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
Avoid release to the environment. Refer to special instructions/safety data sheets.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
General information
Get medical attention if any discomfort continues.
Inhalation
Move into fresh air and keep at rest. Perform artificial respiration if breathing has stopped. Place unconscious person on the side in the recovery position and ensure breathing can take place. Ingestion
Get medical attention immediately! DO NOT INDUCE VOMITING!
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. DO NOT use solvents or thinners
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Immediately flush with plenty of water or eyewash solution for up to 10 minutes. Consult a physician for specific advice.
4.2. Most important symptoms and effects, both acute and delayed
General information
If adverse symptoms develop as described the casualty should be transferred to hospital as soon as possible.
4.3. Indication of any immediate medical attention and special treatment needed
No specific first aid measures noted.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Specific hazards
In case of fire, toxic gases may be formed (COx, NOx). Fire creates: Acrid smoke/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
5.3. Advice for firefighters
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SDS No. 10700
STD STEL - 15 MinTWA - 8 Hrs
Name
Notes
19 ppm 100 mg/m3WEL
Hydrocarbons, C9, aromatics
WEL = Workplace Exposure Limit.
Hydrocarbons, C9, aromatics DNEL Consumer Oral Long Term Systemic Effects 11 mg/kg/day Consumer Dermal Long Term Systemic Effects 11 mg/kg/day Consumer Inhalation. Long Term Systemic Effects 32 mg/m3 Industry Dermal Long Term Systemic Effects 25 mg/kg/day Industry Inhalation. Long Term Systemic Effects 100 mg/m3
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Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation of vapours and contact with skin and eyes. Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses. Contain spillages with sand, earth or any suitable adsorbent material. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.
6.3. Methods and material for containment and cleaning up
Collect with absorbent, non-combustible material into suitable containers. Collect spillage in containers, seal securely and deliver for disposal according to local regulations.
6.4. Reference to other sections
For personal protection, see section 8.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Read and follow manufacturer's recommendations. Eliminate all sources of ignition. Risk of vapour concentration on the floor and in low-lying areas. Use explosion proof electric equipment. Do not eat, drink or smoke when using the product. Avoid inhalation of vapours/spray and contact with skin and eyes. The Manual Handling Operations Regulations may apply to the handling of containers of this product. To assist employers, the following method of calculating the weight for any pack size is given. Take the pack size volume in litres and multiply this figure by the specific gravity value given in section 9. This will give the net weight of the coating in kilograms. Allowance will then have to be made for the immediate packaging to give an approximate gross weight.
7.2. Conditions for safe storage, including any incompatibilities
Keep containers tightly closed. Keep upright. Protect from light, including direct sunrays. Store in closed original container at temperatures between 5°C and 25°C. Store separated from: Oxidising material. Acids. Alkalis. Storage Class
Flammable liquid storage. The storage and use of this product is subject to the Dangerous Substances and Explosive Atmospheres Regulations (DSEAR). The requirements are given in the HSE Approved Code of Practice and Guidance, Storage od Danderous Substances: DSEAR. Up to 250 litres of liquids with a flashpoint above 32C but below 55C may be kept in a workroom provided they are kept in closed containers in a marked, fire-resisting cupboard or bin. Larger quantities must be kept in a separate , marked storeroom conforming to the structural requirements contained in the HSE guidance note Storage of Flammable Liquids in Containers.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
8.2. Exposure controls
Protective equipment
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Process conditions
Use engineering controls to reduce air contamination to permissible exposure level.
Engineering measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.
Respiratory equipment
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. In case of inadequate ventilation, use air-supplied full-mask. Hand protection
Wear protective gloves. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin. Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Hygiene measures
Wash promptly with soap & water if skin becomes contaminated. Remove contaminated clothing and wash the skin thoroughly with soap and water after work.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Colourless liquid.
Odour of solvents
Solubility Immiscible with water
Relative density 0.88 @25 C
Vapour density (air=1) heavier than air
Viscosity <30 seconds 3mm ISO cup s @ 25C
Flash point 43 CC (Closed cup).
Flammability Limit - Lower(%) 0.8
9.2. Other information
Volatility Description Slightly volatile.
Volatile By Vol. (%) 100
Volatile Organic Compound (VOC) 880 g/litre
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
No specific reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not determined.
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition. Avoid contact with acids and oxidising substances.
10.5. Incompatible materials
Materials To Avoid
Strong alkalis. Strong acids. Strong oxidising substances.
10.6. Hazardous decomposition products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
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Toxicological information on ingredients.
Hydrocarbons, C9, aromatics
Acute toxicity:
Acute Toxicity (Oral LD50)
~ 3592 mg/kg Rat
Acute Toxicity (Dermal LD50)
> 3160 mg/kg Rabbit
Acute Toxicity (Inhalation LC50)
> 6193 mg/l (vapours) Rat 4 hours
Serious eye damage/irritation:
Slightly Irritating.
Respiratory or skin sensitisation:
Not sensitising.
Not Sensitising.
Carcinogenicity:
This substance has no evidence of carcinogenic properties.
Specific target organ toxicity - single exposure:
Target Organs
Central nervous system Respiratory system, lungs
Aspiration hazard:
Kinematic viscosity <= 20.5 mm2/s.
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SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxicological information
No data recorded.
General information
Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
Inhalation
Vapour may irritate respiratory system or lungs. In high concentrations, vapours are narcotic and may cause headache, fatigue, dizziness and nausea. Contains organic solvents which in case of overexposure may depress the central nervous system causing dizziness and intoxication. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. May cause damage to mucous membranes in nose, throat, lungs and bronchial system.
Ingestion
Liquid irritates mucous membranes and may cause abdominal pain if swallowed. May irritate and cause stomach pain, vomiting and diarrhoea. May cause nausea, headache, dizziness and intoxication.
Skin contact
May be absorbed through the skin. Acts as a defatting agent on skin. May cause cracking of skin, and eczema.
Eye contact
Irritation of eyes and mucous membranes.
Route of entry
Inhalation. Skin absorption. Ingestion. Skin and/or eye contact.
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Ecological information on ingredients.
Hydrocarbons, C9, aromatics
Toxic to aquatic organisms LC 50, 96 Hrs, Fish mg/l
9.2 EC 50, 48 Hrs, Daphnia, mg/l
3.2
Ecological information on ingredients.
Hydrocarbons, C9, aromatics
Degradability
The product is easily biodegradable. Biodegradation
Degradation (78%) 28 days
Ecological information on ingredients.
Hydrocarbons, C9, aromatics
Bioaccumulative potential
No data available on bioaccumulation.
Ecological information on ingredients.
Hydrocarbons, C9, aromatics
Mobility:
The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.
Ecological information on ingredients.
Hydrocarbons, C9, aromatics
Not Classified as PBT/vPvB by current EU criteria.
Ecological information on ingredients.
Hydrocarbons, C9, aromatics
Not determined.
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SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
There are no data on the ecotoxicity of this product. The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.
12.1. Toxicity
12.2. Persistence and degradability
Degradability
No data available.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
The product contains volatile, organic compounds which have a photochemical ozone creation potential.
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SDS No. 10700
FLAMMABLE
LIQUID
3
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SECTION 13: DISPOSAL CONSIDERATIONS
General information
Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority.
13.1. Waste treatment methods
Do not allow runoff to sewer, waterway or ground.
Waste Class
When this coating, in its liquid state, as supplied, becomes a waste, it is categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). Part-used containers, not drained and/or rigorously scraped out and containing dried residues of the supplied coating, are categorised as hazardous waste, with code 08 01 11* (SOLVENT BASED LIQUID WASTE). If mixed with other wastes, the above waste code may not be applicable. Used containers, drained and/or rigorously scraped out and containing dry residues of the supplied coating, are categorised as non-hazardous waste, with code 15 01 02 (plastic packaging) or 15 01 04 (metal packaging).
SECTION 14: TRANSPORT INFORMATION
General This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR and IMDG.
14.1. UN number
UN No. (ADR/RID/ADN) 1263
UN No. (IMDG) 1263
UN No. (ICAO) 1263
14.2. UN proper shipping name
Proper Shipping Name Contains 1, 2, 4-Trimethylbenzene, Class 3, PG III, (41 °C c.c.) MARINE POLLUTANT
Proper Shipping Name PAINT
14.3. Transport hazard class(es)
ADR/RID/ADN Class 1263
ADR/RID/ADN Class Class 3: Flammable liquids.
IMDG Class 3
ICAO Class/Division 3
Transport Labels
14.4. Packing group
ADR/RID/ADN Packing group III
IMDG Packing group III
ICAO Packing group III
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
14.6. Special precautions for user
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EMS F-E, S-E
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments.
Statutory Instruments
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health. Approved Code Of Practice
Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Dangerous Substances and Explosive Atmospheres Regulations 2002 [L138] Guidance Notes
Workplace Exposure Limits EH40. CHIP for everyone HSG(108).
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. National Regulations
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. No. 1689.
15.2. Chemical Safety Assessment
No chemical safety assessment has been carried out.
SECTION 16: OTHER INFORMATION
Revision Comments
Issued in new format for Reach compliance in accordance with EC 1272/2008 Issued in accordance with Annex II to REACH, as amended by Commission Regulation (EU) No. 453/2010 Revision to sections 2, 8, 11 & 12 for reclassification of solvents. Issued By Technical Dept. (P.E.)
Revision Date 05/11/2012
Revision 4
Supersedes date 17/01/2012
SDS No. 10700
Safety Data Sheet Status Approved.
Date Date Printed .......................................
Signature Initials ............................................
Risk Phrases In Full
Hazard Statements In Full
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SDS No. 10700
Disclaimer
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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