Danfoss R401A, R401B, R409A, R409B, R134a Installation guide

Service on Household
Compressors
Refrigerators and Freezers Using New Refrigerants
April 1996 CN.73.C3.02 1
Replaces CN.73.C2.02
1.0 Introduction
1.1 Blends (mixtures of HFC)
1.2 R134a (HFC)
1.3 R600a (Hydrocarbon)
2.0 General
Since the introduction of R134a, several “transitional substances” have appeared. They have a low ODP number and are intended for service only. These refrigerants are interesting because they do not presuppose the use of polyolester oil.
To ensure a satisfactory miscibility between refrigerant and oil, the application of R134a refrigerant presupposes the use of an R134a compressor charged with polyolester (POE). This will complicate the future servicing when R12 refrigeration systems are to be changed over to R134a refrigerant, as it is difficult to prevent contamination b y residues of the original refrigeration oil, typically mineral oil or alkyl benzene. The presence of residual mineral oil or alkyl benzene is unfortunate because it does not become part of the R134a/POE mixture but circulates independently through the system. The eff ect can be negative if the system contains “oil pockets”. After some time, the oil circulating in the system can collect in quantities which pass through the capillary tube relatively slowly. This will effect the refrigerant injection into the evaporator momentarily.
This refrigerant is flammable and only allowed for use in appliances which fulfil the safety require­ments laid down in amendment TS 95006 to IEC 335 - 2 - 24 (To cover potential risk originated from the use of flamable refrigerants).
In principle there is no need to replace the refrigerant in operational hermetic refrigeration sys­tems. Neither is there any point in replacing refrigerant when servicing, provided that the original refrigerant is available either as new or reclaimed. A precondition here is of course that the legis­lation of the country concerned is not restrictive in this respect. Changing over to an alternative refrigerant is not without problems. Close consideration should be given to the economic justification of proceeding with the task. It is also appropriate to find out just what the user expects in terms of the operation and lifetime of the repaired system. The choice of refrigerant for servicing R12 systems is between the transitional substances (blends) or R134a. Among the refrigerant mixtures offered are R401A and R401B which are marketed by DuPont. These blends are ternary mixtures (non-azeotropes) made of three single components, R22, R152a, and R124. Corresponding mixtures are also marketed by Atochem, R409A (Forane FX 56) and R409B (Forane FX57). They are based on the components R22, R142B, and R124 (table 1). The mixtures are interesting because they do not presuppose the use of polyolester compressor oil. They have a low ODP number and can be used for service when R12 refrigerant is prohibited.
ASHRAE No.
R401A R22 - R152a - R124 53 - 13 - 34 Suwa MP39 0.03 0.22 6.4 Alkyl benzene R401B R22 - R152a - R124 61 - 11 - 28 Suwa MP66 0.035 0.24 6.0 Alkyl benzene R409A R22 - R142B - R124 60 - 15 - 25 Forane FX56 0.05 0.31 8.1 Alkyl benzene R409B R22 - R142B - R124 65 - 10 - 25 Forane FX57 0.05 0.31 7.2 Alkyl benzene R134a 0.0 0.28 0.0 Ester oil
Table 1. Refrigerants for servicing R12 systems
Components Composition%Trade name ODP GWP Temp.
glide
Oil type
2 CN.73.C3.02 April 1996
2.1 Servicing with blends The blends mentioned can be used for servicing, provided the following rules are observed, The original compressor can be used, provided that it is intact. But the compressor oil must
be of the type alkyl benzene. If the original compressor contains mineral oil it has to be changed to alkyl benzene. The
alkyl benzene must have more or less the same viscosity as the original oil. A viscosity of about 30 cSt is a suitable choice for household refrigeration compressors.
Table 2 shows the oil types used in Danfoss compressors.
Compressor type Compressor
V
TL-A 115 2 - 4 Synthetic Unchanged TL-A 220 2 - 4 Mineral Alkyl benzene TL-A 220 5 Synthetic Unchanged TLS-A 220 4 Mineral Alkyl benzene TLS-A 220 5 Synthetic Unchanged TLES-A 220 4 Mineral Alkyl benzene TLES-A 220 5 Synthetic Unchanged TFS-A 115 4 - 5 Synthetic Unchanged TFS-AT 220 4 - 5 Synthetic Unchanged TF-B 115 4 Synthetic Unchanged TL-B 220 2.5 - 3 Mineral Alkyl benzene TL-B 220 4 Synthetic Alkyl benzene NLE-A 115 6 - 7 Synthetic Unchanged NF-A 115 6 Synthetic Unchanged NL-A 220 6 - 7 Mineral Alkyl benzene NLE-A 230 6 - 7 Mineral Alkyl benzene FR-A 115 7.5 - 8.5 Mineral Alkyl benzene FR-A 220 7.5 - 10 Mineral Alkyl benzene FR-A 220 11 V-Oil 7041 Unchanged FF-AT 220 6 - 10 Mineral Alkyl benzene FFS-A 115 7 - 9 Mineral Alkyl benzene FF-BK 115 6.5 - 8.5 Mineral Alkyl benzene FF-BX 115 6.5 - 8.5 Mineral Alkyl benzene FR-B 220 6 - 11 Mineral Alkyl benzene FR-H 220 7 V-Oil 7041 Unchanged SC-A 115 12 - 15 Mineral Alkyl benzene SC-A 220 12 - 15 Mineral Alkyl benzene SC-A 220 18 - 21 V-Oil 7041 Unchanged SC-AA 240 15 V-Oil 7041 Unchanged SC-B 115/220 10 - 2 1 V-Oil 7041 Unchanged SC-H 220 10 - 15 V-Oil 7041 Unchanged SC-HH 220 10 - 15 V-Oil 7041 Unchanged
displacement
3
cm
Present oil type Oil type for blendVoltage
Table 2. Oil types
If the original compressor is defective, the choice is between an R12 compressor and an R134a compressor. The refrigeration capacity should be about the same as that of the original compres­sor. The R12 compressor oil must be changed over to alkyl benzene oil, provided that the original oil charge was mineral oil. The R134a compressor can be used directly charged with polyolester oil. The filter drier must always be replaced. The new filter drier must contain a desiccant of the type XH9 (UOP) or Siliporite H3R (CECA) The system components, especially the evaporator, will always contain some oil transferred from the original compressor. This is not critical if the new compressor contains alkyl benzene. But if a compressor containing polyolester is to be used, residues in the original oil must be kept to the lowest possible.
April 1996 CN.73.C3.02 3
Normally, the limit is 10% of the original oil charge. To ensure that the system is charged with a refrigerant mixture of the correct composition, the charge should be led to the charging device or charging valve as liquid.
The blends in table 1 are non-azeotropes. There­fore the composition changes during evaporation and condensation. This leads to temperature changes at constant pressure. This condition is called “temperature glide”. The ex­tent of the temperature glide for the actual blends is given in table 1. Fig. 1 shows a pressure - enthalpy diagram for non­azeotropic refrigerants. A temperature rise occurs from point “D” (inlet evaporator) to point “A” (outlet evaporator). This phenomenon can result in a different tempera­ture distribution in the appliance compared to the distribution with R12. The temperature at the outlet of the evaporator will always be higher than the tem-
Fig. 1 Pressure - enthalpy diagram
perature at the inlet of the evapor ator . The diff erence corresponds with the temperature glide shown in ta-
ble 1. The influence of the storage temperature depends on the design of the refrigerating circuit and the location of the thermostat bulb.
2.2 Servicing with R134a
Even though the use of the “service blends” gives the least complicated procedure, the possibility of R134a is worth considering. The main problem when changing from R12 to R134a is the oil problem. Any mixing with oil residues will give a negative influence on the function of the system, as described in the introduction. The preconditions for changing over to R134a are:
The compressor must be replaced with an original R134a compressor filled with an ap­proved polyolester oil.
The filter drier must be replaced with a new drier containing desiccant of the type XH7 (XH9) or Siliporite H3R (CECA).
Oil residues in the system components must be kept on the lowest possible level. Up to 5% residues in the total oil charge can be accepted.
Small hermetic systems are sensitive because of the use of capillary tube as the throttling
device. Therefore the aim is to achieve a still smaller content of residual oil. The oil residues in household refrigeration systems are normally lower than 5% of the total oil
charge. A bigger quantity may occur if the system contains oil pockets. If so it will be necessary to clean the system by carefully blowing out each component with dry N2.
4 CN.73.C3.02 April 1996
2.3 Servicing with R600a
R600a is a hydrocarbon. This refrigerant is flammable and is only allowed for use in appliances which fulfil the requirements laid down in amendment TS 95006 to IEC 335 - 2 - 24 (To cover potential risk originated from the use of flammable refrigerants). Consequently, R600a is only allowed to be used in household appliances which are designed for this refrigerant and fulfil the above-mentioned standard. R600a is heavier than air. The concentration will always be highest at floor level. The explosion limits are as follows,
Lower limit: 1.5% by vol. (38 g/m3) Upper limit: 8.5% by vol. (203 g/m3) Ignition temperature: 460°C
2.3.1 General
2.3.2 Transportation of refrigerant and replaced compressors
2.3.3 Tools
In order to carry out service and repair on R600a systems the service personnel must be properly trained to be able to handle a flammable refrigerant. This includes knowledge on tools, tr ansporta­tion of compressors and refrigerant, and the relevant regulations and safety precautions when carrying out service and repair.
Warning: Do not use open fire.
The refrigerant must be stored and transported in approved containers. Max 2 x 500 g refrigerant is allowed to be transported in a service car. Replaced compressors containing refrigerant residues must be sealed before being transported.
In general: No open fire when troubleshooting and repairing. The refrigeration circuit must be opened with a tube cutter or a special tool. For tube connections, traction-stable compression fittings (e.g. socalled lockrings) must be used. Vacuum pumps must be explosion-safe. It must be possible to lead the discharge air from the vacuum pump into open air. Leak detection cannot take place with normal halogen leak detectors, as they do not react on hydrocarbons. A special detector reacting on hydrocarbon must be used instead. Another possibil­ity is to use a leak spray.
Both solutions presuppose that the vapour pressure in the system is higher than 1 bar. Fig. 2 shows the saturated vapour pressure as a func­tion of the temperature. The pressure is lower than the normal atmospheric pressure below
-11°C. Accordingly it is necessary to increase the pressure in the system in order to carry out a leak detection. This can be done by adding dry nitrogen until a pressure of max 10
Fig. 2 Saturated vapour pressure, R600a
bar has been reached. Then the leak detection can be carried out either using a leak detector for R600a or a leak spray.
April 1996 CN.73.C3.02 5
Repair and refrigerant replacement of R12 systems Guide
Trouble­shooting
System defective
compressor intact
System leakage
1
If the system has lost charge, the leakage must be localised and repaired.
Recover refrigerant
2
Fit a service valve, preferably on the proc­ess tube, and recover the system refriger­ant charge. Equalise to atmospheric pres­sure using dry N
Replace filter drier
3
.
2
Remove the filter drier. Blow the system components through with dry N the system. Fit a new filter drier contain­ing desiccant XH9 or H3R.
Oil change (if necessary)
4
If the original compressor is charged with alkyl benzene it can be used unchanged. If it has been charged with mineral oil, this should be drained out in the best way pos­sible. If necessar y, detach the compres­sor from the system before pouring out the oil. Measure the collected oil in a gauge glass. Note: In connection with small compres­sors, some of the oil charge remains in the motor windings and on the surfaces. Col­lected oil (and recovered refrigerant) must be treated as special waste. Refill the compressor with alkyl benzene in the same quantity as the collected min­eral oil. Refit the compressor into the sys­tem.
Evacuation and charging
5
Evacuate and charge the refrigeration sys­tem with service blends. Fill the refriger­ant mixtures as liquid. Because the opti­mum service blend charge is less than the original R12 charge, it is recommended that filling be started using about 75% of the original charge. The system can then be gradually filled until it is in balance.
End of system repair
6
Close the process tube. Check for leak­age. Run the system. Mark the system with repair date, refrigerant type and amount, and oil type in the compressor.
Blends selected
as refrigerant
. Repair
2
System defective
compressor defective
Recover refrigerant
1
Fit a service valve on the process tube and recover the refrigerant. Equalilise to atmos­pheric pressure using N
Remove the compressor and the filter drier
2
.
2
Blow the system through with dry N2. Compressor selection
3
Select a replacement compressor - either an Rl2 compressor charged with alkyl ben­zene oil or an R134a compressor charged with polyolester oil. The refrigeration ca­pacity of the new compressor must corre­spond to that of the orginal compressor.
Fit new compressor and filter drier
4
Fit the new compressor . Fit a ne w filter drier containing UOP XH9 or Siliporite H3H.
Evacuation and charging
5
Evacuate and charge the refrigeration sys­tem with the service blend. Fill the refriger­ant mixtures as liquid. Because the opti­mum service blend charge is less than the original R12 charge, it is recommended that filling be started using about 75% of the original charge. The system can then be gradually filled until it is in balance.
End of system repair
6
Close the process tube. Check for leakage. Run the system. Mark the system with re­pair date, refrigerant type and amount, and oil type in the compressor.
R134a selected
as refrigerant
System defective
compressor defective
1
Compressor damage If the defect is due to a “burnt out” compressor motor, the system must be scrapped
2
System leakage If the system has lost charge, the leakage must be localised.
3
Recover refrigerant Fit a service valve, preferably on the proc­ess tube, and recover the system refriger­ant charge. Equalise to atmospheric pres­sure using dry nitrogen (N
4
Remove the compressor and the filter drier
).
2
Flush all system components through with dry nitrogen (N Note: It is important that residues of min-
).
2
eral oil or alkyl benzene be kept to the low­est possible level.
5
Compressor selection Select the R134a replacement compres­sor (the original compressor cannot be used with R134a). The refrigeration capac­ity of the new compressor must correspond to that of the original compressor.
6
Fit new compressor and filter drier Fit the new compressor. Fit a new filter drier containing dessicant XH7, XH9 or H3R.
7
Evacuation and charging Evacuate and charge the system with R134a. For LBP systems the optimum R134a charge will be less than the origi­nal R12 charge. Therefore begin by filling about 75% of the original R12 charge and then adjust up gradually until the system is in balance.
8
End of system repair Close the process tube. Check for leak­age. Run the system. Mark the system with repair date, refrigerant type and amount.
6 CN.73.C3.02 April 1996
Repair of refrigeration systems with R600a Guide
Trouble­shooting
Compressor
intact
Preparation
1
Stop the compressor. Check for leakage
2
Fit a service valve on the process tube. Increase the pressure in the system to max 10 bar by means of dry nitrogen (N for leakage by means of a leak spray or suitable leak detector.
Repair the system
3
Release pressure into open air by means of a plastic tube. Repair the system. Fit a new filter drier.
Warning: Do not use open fire .
Evacuation
4
Evacuate the system. The discharge from the vacuum pump must be lead into the open air.
Charging
5
Charge the system with R600a. As some of the original charge is dissolved in the oil, it is recommended that the charging is started with about 90% of the original charg­ing amount.
System check
6
Run the system and check the tempera­tures.
End of system repair
7
Close the process tube with a traction-sta­ble compression fitting. Warning: Do not use open fire.
Labelling
8
Mark the system with repair date. Place a warning label on the compressor. The la­bel must be in accordance with TS (IEC 335 - 2 - 24).
). Check
2
Compressor
defective
Release refrigerant
1
Fit a service valve on the process tube and release the refrigerant into open air by means of a plastic tube.
Safety evacuation
2
In order to ensure that the defective com­pressor does not contain R600a residues, which may be a fire hazard when the com­pressor is scrapped, the system must be evacuated. The discharge from the vacuum pump must be lead into the open air. Equalise to atmospheric pressure using dry nitrogen
).
(N
2
Remove the compressor and the filter drier
3
Close the compressor connectors with rub­ber plugs. Thoroughly blow through the system with dry nitrogen (N Warning: Do not use open fire.
Compressor selection
4
).
2
Select a new R600a compressor. The re­frigeration capacity must correspond to that of the original compressor.
Fit new compressor and filter drier
5
Evacuation and charging
6
Evacuate and charge the system with R600a. The charge must correspond to the original charge. Start the compressor.
System check
7
Run the system and check the tempera­tures.
End of system repair
8
Close the process tube with a traction-sta­ble compression fitting.
Warning: Do not use open fire.
Labelling
9
Mark the system with repair date. Place a warning label on the compressor. The la­bel must be in accordance with TS (IEC 335 - 2 - 24).
April 1996 CN.73.C3.02 7
Danfoss can accept no responsibility for possible errors in catalogues, brochures and other printed material. Danfoss reserves the right to alter its products without notice. This also applies to products already on order provided that such alterations can be made without subsequential changes being necessary in specifications already agreed.
8 CN.73.C3.02 April 1996
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