Comet 32987 User Manual

SAFETY DATA SHEET
Issuing Date: 09-Jan-2015
Product Name
Product Code(s) Product ID: Product Type: Recommended Use Restrictions on Use Manufacturer
Revision Date: 07-Apr-2015
Version 2
1. IDENTIFICATION
CometÒ Deodorizing Cleanser with ChlorinolÒ 3-10 15885959_PROF_NG Finished Product - Professional Use Only Hard Surface Cleaner Do not mix with other cleaning products or chemicals as irritating fumes may be formed. Procter & Gamble Professional
2 P&G Plaza Cincinnati, Ohio 45202
Procter & Gamble Inc. P.O. Box 355, Station A Toronto, ON M5W 1C5
1-800-332-7787
E-mail Address Emergency Telephone
pgsds.im@pg.com Transportation (24 HR)
CHEMTREC - 1-800-424-9300 (U.S./ Canada) or 1-703-527-3887 Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:. Hazard Category
Eye Damage / Irritation Signal Word
Hazard Statements Hazard pictograms
Precautionary Statements ­Prevention
Precautionary Statements ­Response
Category 2B WARNING
Causes eye irritation None
Wash hands thoroughly after handling Do not mix with other cleaning products or chemicals as irritating fumes may be formed
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Drink 1 or 2 glasses of water
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15885959_PROF_NG - CometÒ Deodorizing Cleanser with ChlorinolÒ
Revision Date: 07-Apr-2015
Precautionary Statements ­Storage
Precautionary Statements ­Disposal
Hazards not otherwise classified (HNOC)
None
None
None
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
Chemical Name Synonyms Trade Secret CAS-No Weight %
Limestone - No 1317-65-3 40 - 100
Sodium carbonate - No 497-19-8 5 - 10
Calcium hydroxide (Ca(OH)2)
Troclosene sodium, dihydrate - No 51580-86-0 1 - 5
Benzenesulfonic acid,
mono-C10-16-alkyl derivs., sodium
salts
- No 1305-62-0 1 - 5
- No 68081-81-2 1 - 5
4. FIRST AID MEASURES
First aid measures for different exposure routes Eye contact Skin contact Ingestion
Inhalation Most important symptoms/effects,
acute and delayed Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician
Rinse with plenty of water. Get medical attention immediately if irritation persists. Rinse with plenty of water. Get medical attention if irritation develops and persists. Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately if
symptoms occur. Move to fresh air. If symptoms persist, call a physician. None under normal use conditions.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Unsuitable Extinguishing Media Special hazard
Dry chemical, CO 2, alcohol-resistant foam or water spray. None. None known.
Special protective equipment for fire-fighters
Specific hazards arising from the chemical
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
None.
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15885959_PROF_NG - CometÒ Deodorizing Cleanser with ChlorinolÒ
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Revision Date: 07-Apr-2015
Personal precautions Advice for emergency responders
Use personal protective equipment. Do not get in eyes, on skin, or on clothing. Use personal protective equipment as required.
Methods and materials for containment and cleaning up Methods for containment Methods for cleaning up
Prevent dust cloud. Prevent further leakage or spillage if safe to do so. Sweep up and shovel into suitable containers for disposal. Dispose of in accordance with
local regulations.
7. HANDLING AND STORAGE
Precautions for safe handling Advice on safe handling
Use personal protective equipment as required. Keep container closed when not in use. Never return spills in original containers for re-use. Keep out of the reach of children.
Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible products
Keep containers tightly closed in a dry, cool and well-ventilated place. Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines
.
Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PEL
Limestone 1317-65-3 TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirable
fraction
(vacated) TWA: 15 mg/m
total dust
(vacated) TWA: 5 mg/m
Mexico: TWA 10 mg/m
Mexico: STEL 20 mg/m
3
3
respirable fraction
Calcium hydroxide (Ca(OH)2) 1305-62-0 TWA: 5 mg/m
3
TWA: 15 mg/m3 total dust
Mexico: TWA 5 mg/m
TWA: 5 mg/m3 respirable
(vacated) TWA: 5 mg/m
fraction
3
not in effect as a result of
reconsideration
Chemical Name CAS-No Alberta Quebec Ontario TWAEV British Columbia
Limestone 1317-65-3 TWA: 10 mg/m
3
TWA: 10 mg/m
3
TWA: 10 mg/m
STEL: 20 mg/m
Calcium hydroxide (Ca(OH)2) 1305-62-0 TWA: 5 mg/m
3
TWA: 5 mg/m
3
TWA: 5 mg/m
3
No relevant exposure guidelines for other ingredients
Exposure controls Engineering Measures Distribution, Workplace and Household Settings:
Ensure adequate ventilation
TWA: 3 mg/m
TWA: 5 mg/m
3
3
3
3
3
3
3
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15885959_PROF_NG - CometÒ Deodorizing Cleanser with ChlorinolÒ
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction
Personal Protective Equipment Eye Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
Wear suitable protective clothing
Revision Date: 07-Apr-2015
Respiratory Protection Distribution, Workplace and Household Settings:
No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):
In case of insufficient ventilation wear suitable respiratory equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C Appearance Odor Odor threshold
Property
pH value Melting/freezing point Boiling point/boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limits in Air
Upper flammability limit
Lower Flammability Limit Vapor pressure Vapor density Relative density Water solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition temperature Decomposition temperature Viscosity of Product
solid white Pine No information available
Values
12.3 No information available No information available No information available No information available No information available
No information available No information available No information available No information available No information available 15% No information available No information available No information available . No information available . No information available
Note
(as 1% solution)
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15885959_PROF_NG - CometÒ Deodorizing Cleanser with ChlorinolÒ
Revision Date: 07-Apr-2015
VOC Content (%)
Products comply with US state and federal regulations for VOC content in consumer products.
Reactivity Stability Hazardous polymerization Hazardous Reactions Conditions to Avoid Materials to avoid Hazardous Decomposition Products
None under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. None under normal processing. None under normal processing. Do not mix with other cleaning products or chemicals as irritating fumes may be formed. None under normal use.
11. TOXICOLOGICAL INFORMATION
Product Information Information on likely routes of exposure
Inhalation Skin contact Ingestion Eye contact
No known effect. No known effect. No known effect. Irritating to eyes.
10. STABILITY AND REACTIVITY
Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute toxicity
Skin corrosion/irritation Serious eye damage/eye irritation Skin sensitization Respiratory sensitization Germ cell mutagenicity Neurological Effects Reproductive toxicity Developmental toxicity Teratogenicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration hazard Carcinogenicity
No known effect. No known effect. Irritating to eyes. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect. No known effect.
Component Information
Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation
Sodium carbonate 497-19-8 2800 mg/kg bw (Guideline
Calcium hydroxide (Ca(OH)2) 1305-62-0 > 2000 mg/kg bw (OECD
Benzenesulfonic acid,
mono-C10-16-alkyl derivs., sodium
salts
68081-81-2 1090.00 mg/kg (rat) - -
not indicated; rat)
425; rat)
> 2000 mg/kg bw (EPA 16
CFR 1500.40; rabbit)
> 2500 mg/kg bw (EU
Method B.3 and OECD
402; rabbit)
-
-
Ecotoxicity
12. ECOLOGICAL INFORMATION
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15885959_PROF_NG - CometÒ Deodorizing Cleanser with ChlorinolÒ
The product is not expected to be hazardous to the environment.
Revision Date: 07-Apr-2015
Persistence and degradability Bioaccumulative potential Mobility Other adverse effects
Waste treatment Waste from Residues / Unused
Products Contaminated packaging
California Hazardous Waste Codes (non-household setting)
DOT IMDG
No information available. No information available. No information available. No information available.
13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
331
14. TRANSPORT INFORMATION
Not regulated Not regulated
IATA
Not regulated
15. REGULATORY INFORMATION
U.S. Federal Regulations SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990.
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
California Proposition 65
This product is not subject to warning labeling under California Proposition 65.
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15885959_PROF_NG - CometÒ Deodorizing Cleanser with ChlorinolÒ
U.S. State Regulations (RTK)
Chemical Name CAS-No New Jersey
Limestone 1317-65-3 X
Calcium hydroxide (Ca(OH)2) 1305-62-0 X
Troclosene sodium, dihydrate 51580-86-0 X
Chemical Name CAS-No Massachusetts
Limestone 1317-65-3 X
Calcium hydroxide (Ca(OH)2) 1305-62-0 X
Troclosene sodium, dihydrate 51580-86-0 X
Chemical Name CAS-No Pennsylvania
Limestone 1317-65-3 X
Calcium hydroxide (Ca(OH)2) 1305-62-0 X
Troclosene sodium, dihydrate 51580-86-0 X
International Inventories
United States
All intentionally-added components of this product(s) are listed on the US TSCA Inventory.
Revision Date: 07-Apr-2015
Canada
This product is in compliance with CEPA for import by P&G.
Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory CEPA - Canadian Environmental Protection Act
16. OTHER INFORMATION
HMIS Ratings Health hazard Flammability Physical hazard
NFPA Ratings Health hazard Flammability Instability
Issuing Date: Revision Date: Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text
2 0 0
2 0 0
09-Jan-2015 07-Apr-2015
End of SDS
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