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7438A023AA
User Manual
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Canon 7438A023AA User Manual

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Page 1
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
2 Hazard(s) identification
Skin Corr.
1A
H314
Causes severe skin burns and eye damage.
Eye Dam.
1
H318
Causes serious eye damage.
Acute Tox.
4
H302
Harmful if swallowed.
Acute Tox.
4
H332
Harmful if inhaled.
(Contd. on page 2)
GHS05 Corrosion
GHS07
Product identifier Trade name : Alkaline Manganese Button Cell (Mercury Free)-Cell Item No.:
L2366F、L1560F、L1154F、L1142F、L1131F、L1121F、L936F、L926F、L921F、L754F、 L736F、L726F、L721F、L626F、L621F、L526F、L521F
Recommended use of the chemical and restrictions on use : Application of the substance / the preparation : Electronic products Details of the supplier of the safety data sheet Manufacturer/Supplier :
CHUNG PAK BATTERY WORKS LIMITED
CHUNG PAK (GUANG DONG) BATTERY INDUSTRIAL CO., LTD
Full address :
7/F., CHUNG PAK COMMERCIAL BUILDING, 2 CHO YUEN STREET, YAU TONG BAY, KOWLOON, HONGKONG GANCUN SECTION FOCHEN ROAD CHEN CUN COUNTY SHUNDE DISTRICT FOSHAN CITY GUANGDONG PROVINCE CHINA
Phone number :
852-27171338 Fax : 852 2772 7727
Email : dylan.cai@chungpak.com Other US contact point : No available Further information obtainable from :
CHUNG PAK BATTERY WORKS LIMITED CHUNG PAK (GUANG DONG) BATTERY INDUSTRIAL CO., LTD
Emergency telephone number :
USA Poison Center Tel: +1 800 222 1222 +86-757-23312338 Dylan
Remark :
Safety Data Sheet
29 CFR 1910.1200
Effective Date ：27/04-2015
Classification of the substance or mixture
Classification according to OSHA Hazard Communication Standard (29 CFR 1910.1200)
Information concerning particular hazards for human and environment :
The product has to be labeled due to the calculation procedure of OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification system :
The classification is according to the latest edition of OSHA Hazard Communication Standard (29 CFR
1910.1200), and extended by company and literature data.
Page 2
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
(Contd. on page 1)
H302+H332
Harmful if swallowed or if inhaled.
H314
Causes severe skin burns and eye damage.
P101
If medical advice is needed, have product container or label at hand.
P102
Keep out of reach of children.
P103
Read label before use.
P260
Do not breathe dusts or mists.
P303+P361+P353
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338
If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a poison center/doctor.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local / regional / national / international regulations.
Hazards not otherwise classified (HNOC) No further relevant information available.
3 Composition / information on ingredients
Composition:
1313-13-9
manganese dioxide
25.1-29.7%
Acute Tox.4, H302; Acute Tox. 4, H332
7439-89-6
iron
40.2-48%
7440-66-6
zinc
9-10.7%
7732-18-5
water
4.57-5.96%
1310-58-3
potassium hydroxide
3.72-4.88%
Skin Corr. 1A, h314; Acute Tox. 4, H302
7440-50-8
copper
0.03-0.04%
7782-42-5
Graphite
3.43-4.12%
25038-54-8
Polyamide 6
1.61-2.2%
9004-34-6
Cellulose
0.35-0.88%
7440-02-0
nickel
1.48-1.57%
1314-13-2
zinc oxide
0.37-0.62%
9003-04-7
Sodium Polyacrylic Acid
0.1-0.2%
9003-01-4
Polyacrylic Acid
0.02-0.08%
(Contd. on page 3)
29 CFR 1910.1200
Effective Date ：27/04-2015
Label elements Labeling according to OSHA Hazard Communication Standard (29 CFR 1910.1200) Hazard pictograms
GHS05 GHS07
Signal word : Danger Hazard-determining components of labeling :
manganese dioxide
potassium hydroxide
Hazard statements
Precautionary statements
Chemical characterization: Mixtures Description
Mixture of the substances listed below with nonhazardous additions.
：
For the wording of listed risk phrases refer to section 16.
Page 3
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
(Contd. on page 2)
21645-51-2
aluminium hydroxide
0.05-0.08%
7789-23-3
potassium fluoride
0.05-0.1%
20661-21-6
indium hydroxide
0.05-0.1%
Note: In(OH)3
Remark：
zinc (CAS: 7440-66-6) Note: Zn
manganese dioxide (CAS: 1313-13-9)
Note: MnO
potassium hydroxide (CAS: 1310-58-3)
Note: KOH
Graphite (CAS: 7782-42-5) Note: Carbon(C)
copper(CAS: 7440-50-8) Note: Cu
iron (CAS: 7439-89-6) Note: Fe
water (CAS: 7732-18-5) Note: H2O
Cellulose (CAS: 9004-34-6)
Note: Paper
nickel (CAS: 7440-02-0) Note: Ni
zinc oxide (CAS: 1314-13-2)
Note: ZnO
aluminium hydroxide(CAS: 21645-51-2)
Note: Al(OH)
potassium fluoride (CAS: 7789-23-3)
Note: KF
indium hydroxide CAS: 20661-21-6)
2
3
29 CFR 1910.1200
Effective Date ：27/04-2015
Description of first aid measures General description:
Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact: After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing:
Do not induce vomiting; immediately call for medical help. Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Most important symptoms and effects, both acute and delayed No further relevant information
available.
Indication of any immediate medical attention and special treatment needed
Page 4
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
5 Fire-fighting measures
extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Protective equipment: Mouth respiratory protective device.
6 Accidental release measures
Ensure adequate ventilation.
7 Handling and storage
Specific end use(s): No further relevant information available.
8 Exposure controls / personal protection
Components with limit values that require monitoring at the workplace:
1313-13-9 manganese dioxide (25.1-29.7%)
PEL (USA)
Ceiling limit value: 5mg/m3
as Mn
REL (USA)
Short-term value: 3mg/m3
Long-term value: 1mg/m3
as Mn
TLV (USA)
Long-term value: 0.02*0.1* mg/m3
as Mn；* respirable **inhalable fraction
1310-58-3 potassium hydroxiede (3.72-4.88%)
REL (USA)
Ceiling limit value: 2mg/m3
TLV(USA)
Ceiling limit value: 2mg/m3
7440-50-8 copper (0.03-0.04%)
PEL (USA)
Long-term value: 1*0.1**mg/m3
as Cu *dusts and mists **fume
REL (USA)
Long-term value: 1*0.1**mg/m3
as Cu *dusts and mists **fume
TLV(USA)
Long-term value: 1*0.2**mg/m3
*dusts and mists **fume; as Cu
(Contd. on page 5)
(Contd. on page 3)
29 CFR 1910.1200
Effective Date ：27/04-2015
Suitable extinguishing agents:
CO2、
Special hazards arising from the substance or mixture: No further relevant information available. Special protective equipment and precautions for firefighters
Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Keep unprotected persons away.
Environmental precautions: Do not allow to enter sewers/surface or ground water. Methods and material for containment and cleaning up:
Use neutralizing agent. Dispose contaminated material as waste according to item 13.
Precautions for safe handling:
Thorough dedusting. Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires: No special measures required. Storage： Conditions for safe storage, including any incompatibilities Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed.
Page 5
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
(Contd. on page 4)
7782-42-5 Graphite (3.43-4.12%)
PEL (USA)
Long-term value: 15mppcf*mg/m3
*impinge samples counted by light field techn.
REL (USA)
Long-term value: 2.5mg/m3
*respirable dust
TLV(USA)
Long-term value: 1*0.2**mg/m3
all forms except graphite fibers; *resp. fraction
9004-34-6 Cellulose (0.35-0.88%)
PEL (USA)
Long-term value: 15* 5** mg/m3
*total dust **respirable fraction
REL (USA)
Long-term value: 10* 5** mg/m3
*total dust **respirable fraction
TLV(USA)
Long-term value: 10mg/m3
Protective gloves
Tightly sealed goggles
29 CFR 1910.1200
Effective Date ：27/04-2015
Additional information: The lists that were valid during the creation were used as basis. Based on the composition shown in Section 3, the following measures are suggested for
occupational safety measure.
Appropriate engineering controls:
Wash clothing and shoes before reuse.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. See Section 7 for information about design of technical facilities.
Personal protective equipment: Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
Protection of hands
：
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has
to be observed.
Eye protection:
Page 6
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
(Contd. on page 5)
General Information
Appearance:
Form:
Solid
Color:
Silvery
Odor:
Odorless
Odour threshold:
Not available
pH-value:
Not available
Change in condition
Melting point/ Melting range:
Not available
Freezing point：
Not available
Boiling point/ Boiling range:
Not available
Flash point:
Not available
Flammability (solid, gaseous):
Not available
Auto-Ignition temperature:
Not available
Decomposition temperature:
Not available
Explosion limits：
Lower:
Not available
Upper:
Not available
Vapor pressure:
Not available
Density:
Not available
Relative density:
Not available
Vapour density:
Not available
Evaporation rate:
Not available
Solubility in/ Miscibility with
Water:
Not available
Partition coefficient (n-octanol/water)
Not available
Viscosity:
Dynamic:
Not available
Kinematic:
Not available
Other information
Voltage 1.5V
(Contd. on page 7)
10 Stability and reacivity
Hazardous decomposition products: No dangerous decomposition products known.
11 Toxicological information
LD/LC50 values that are relevant for classification:
1310-58-3 potassium hydroxide
Oral
LD50
273 mg/kg (rat)
29 CFR 1910.1200
Effective Date ：27/04-2015
9 Physical and chemical properties
Reactivity: Data not available Chemical stability: Stable under normal operating and storage conditions. Possibility of hazardous reactions: No dangerous reactions known. Conditions to avoid: No further relevant information available. Incompatible materials: No further relevant information available.
Acute toxicity:
Page 7
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
(Contd. on page 6)
7439-89-6 iron
Oral
LD50
30000 mg/kg (rat)
9004-34-6 Cellulose
Oral
LD50
＞5000 mg/kg (rat)
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
14 Transport information
UN-Number
DOT，IMDG，IATA
UN3028
UN proper shipping name
DOT
Batteries, dry, containing potassium hydroxide solid
IMDG, IATA
BATTERIES, DRY, CONTAINING POTASSIUM
HYDROXINDE, SOLID
(Contd. on page 8)
29 CFR 1910.1200
Effective Date ：27/04-2015
Primary irritant effect: on the skin: Strong caustic effect on skin and mucous membranes. on the eye: Strong caustic effect. Sensitization: No sensitizing effects known. Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations: Harmful
Corrosive Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
Carcinogenic categories
Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability: No further relevant information available. Bioaccumulative potential: No further relevant information available. Mobility in soil: No further relevant information available.
Waste treatment methods Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Page 8
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
(Contd. on page 7)
Transport hazard class (es)
DOT
Class
8 Corrosive substances
Label
8
IMDG，IATA
Class
8 Corrosive substances
Label
8
Packing group
DOT，IMDG，IATA
Not applicable
Environmental hazards:
Marine pollutant:
No
Special precautions for user
Warning: Corrosive substances
EMS Number:
F-A，S-B
Segregation groups
Alkalis
Transport in bulk according to Annex Ⅱ of
MARPOL 73/78 and the IBC Code
Not applicable
UN ”Model Regulation”
UN3028, Batteries, dry, containing potassium
hydroxide solid, 8
15 Regulatory information
Section 335 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (specific toxic chemical listings):
1313-13-9
manganese dioxide
7440-50-8
copper
TSCA (Toxic Substances Control Act):
1313-13-9
manganese dioxide
7439-89-6
iron
7732-18-5
water
1310-58-3
potassium hydroxide
7440-50-8
copper
7782-42-5
Graphite
9004-34-6
Cellulose
(Contd. on page 9)
29 CFR 1910.1200
Effective Date ：27/04-2015
Safety, health and environmental regulations/legislation specific for the substance or mixture Sara
Page 9
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
Chemical known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
EPA (Environmental Protection Agency)
1313-13-9
manganese dioxide
D
7440-66-6
zinc Ⅱ 7440-50-8
copper
D
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institution for Occupational Safety & Health)
None of the ingredients is listed.
Health = 3
Reactivity = 0
Health = 4
Reactivity = 0
Proposition 65
Cancerogenity categories
Safety Data Sheet
29 CFR 1910.1200
Effective Date ：27/04-2015
(Contd. on page 8)
NFPA ratings (scale 0-4)
HMIS ratings (scale 0-4)
Relevant phrases
H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled.
Fire = 0
Fire = 0
The contents and format of this SDS are in accordance with 29 CFR 1910.1200 (g)
DISCLAIMER OF LIABILITY
applicable.
(Contd. on page 10)
Page 10
Safety Data Sheet
Trade Name ：Alkaline Manganese Button Cell (Mercury Free)-Cell
*This sample is likely to be classified as article and is out of scope of a SDS as set out in 29 CFR Part
*************************************************************************************
29 CFR 1910.1200
Effective Date ：27/04-2015
Remark:
1910.1200. This SDS is generated for client’s reference only.
Date of preparation/last revision 2015.04.27/-
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent Acute Tox. 4: Acute toxicity，Hazard Category 4 Skin Corr. 1A: Skin corrosion/irritation，Hazard Category 1A Eye Dam . 1: Serious eye damage/eye irritation，Hazard Category 1
(Contd. on page 9)
End of document
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