Page 1
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 1 / 10
SECTION 1: Identification of the substance/mixture and of the compan y/undertaking
1.1 Product identifier
Product name (code)
LC11C (LK3637001, LC4690001), LC16C (LK3526001, LK4710001),
LC38C (LK3661001, LK4196001), LC39C (LK5405001), LC60C (LK5729001),
LC61C (LK3366001, LK4297001), LC67C (LK3669001, LK4222001), LC975C (LK5670001),
LC980C (LK3374001, LK4048001), LC985C (LK46210
01, LK5401001), LC990C (LK4461001),
LC1100C (LK3572001, LK3985001), LC65HYC (LK3291001, LK4330001),
LC67HYC (LK3524001, LK4277001), LC990HYC (LK3525001, LK4481001),
LC1100HYC (LK3523001, LK4021001)
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant Identified Use(s)
These products are dark blue ink in a cartridge for Brother Industries, Ltd. inkjet multifunction
devices and fax receivers. The cartridge
products stated. Information provided on this SDS is only consistent with the use specified by
Brother.
1.3 Details of the supplier of the safety data sheet
Manufacturer
Brother Industries, Ltd.
15
Telephone (for information): +81-52-824-2735
Importer (USA)
Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada)
Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe)
Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia)
Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address
sds.info@brother.co.jp
1.4 Emergency telephone number
Emergency Telephone
(24 hours)
CHEMTREC
+1
+1
For France only:
Antipoison Center telephone number: ORFILA +33-1-45-425-959
should be used as supplied by Brother and for use in the
-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
-703-527-3887 (International)
-800-424-9300 (North America)
Page 2
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 2 / 10
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Not classified as hazardous
Classification according to Directive 1999/45/EC
Not classified as hazardous
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008
Hazard pictograms
None
Signal Word
None
Hazard Statements
EUH208 - Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction.
Precautionary statements
None
2.3 Other hazards
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This product contains no substance
considered to be very persistent nor very bioaccumulating (vPvB).
Page 3
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 3 / 10
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description of the mixture: Water based inkjet ink (Mixture).
Chemical Name
CAS-No
EC-No
w/w%
Classification
(67/548/EEC)
Classification
(EU Reg. 1272/2008)
Glycerol
56-81-5
200-289-5
15-25
Not classified
Not classified
Triethylene glycol monobutyl ether
143-22-6
205-592-6
1-5
Xi; R41
Eye Dam. 1 (H318)
Diethylene glycol
111-46-6
203-872-2
1-5
Xn; R22
Acute Tox. 4 (H302)
Cyan Dye (Copper Phthalocyanine
derivative dye)
*
445-470-1
<5
Xi; R41
R52/53
Eye Dam. 1 (H318)
Aquatic Chronic 3 (H412)
Water
7732-18-5
231-791-2
65-75
Not classified
Not classified
1,2-benzisothiazol-3(2H)-one
2634-33-5
220-120-9
< 0.05
Xn; R22
Xi; R41
N; R50
Acute Tox. 4 (Oral), H302
Aquatic Acute 1, H400
For the full text of R-phrases and H-Statements see Section 16
* Registered
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
If symptoms persist, obtain medical attention.
Inhalation
Obtain medical attention. In case of accident by inhalation remove casualty to fresh air and keep at
rest.
Skin contact
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap and
water.
Eye contact
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.
Ingestion
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to
drink.
4.2 Most important symptoms and
effects, both acute and delayed
Skin contact: Repeated and/or prolonged skin contact may cause irritation.
Eye contact: May cause eye irritation.
Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Unlikely route of exposure.
Inhalation: Unlikely route of exposure.
4.3 Indication of any immediate
medical attention and special
treatment needed
Treat symptomatically.
Xi; R38
R43
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
Page 4
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 4 / 10
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable Extinguishing Media
Extinguish preferably with dry chemical, carbon dioxide, water spray, foam.
Unsuitable Extinguishing Media
None.
5.2 Special hazards arising from the
substance or mixture
Thermal decomposition of organic components may result in occurrence of oxides of carbon. Toxic
gases may be formed upon combustion and represents a hazard to firefighters. Combustion
products: See Section: 10.
5.3 Advice for firefighters
Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure
self
during cleanup in enc
suitable respiratory protection must leave the area to prevent significant exposure to toxic
combustion gases from any source.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective
equipment and emergency
procedures
Ensure adequate ventilation. Avoid contact with eyes.
6.2 Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water
drains.
6.3 Methods and materials for
containment and cleaning up
Wipe up with absorbent towel Wash with water to remove remaining traces of ink
6.4 Reference to other sections
For personal protection: See section 8.
For disposal considerations: See section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Keep out of the reach of children. Avoid contact with skin and eyes.
7.2 Conditions for safe storage,
including any incompatibilities
Keep away from oxidizing agents.
7.3 Specific end use(s)
These products are dark blue ink in a cartridge for Brother Industries, Ltd. inkjet multifunction
devices and fax receivers. This cartridge should be used as supplied by Brother and for use in the
products stated.
SECTION 8: Exposure controls/personal protection
8.1 Control Parameters
Occupational Exposure Limits
Chemical Name
Glycerol
56-81-5
ACGIH T LV
TWA: 10 mg/m3 mist
OSHA PEL
TWA: 15 mg/m3 mist, total particulate
TWA: 5 mg/m3 mist, respirable fraction
European Union
-
The United Kingdom
STEL: 30 mg/m3
TWA: 10 mg/m3
-contained breathing apparatus (SCBA) during the attack phase of firefighting operations and
losed or poorly ventilated areas immediately after a fire. Personnel not having
Page 5
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 5 / 10
France
TWA: 10 mg/m3
Spain
TWA: 10 mg/m3
Germany
TWA: 50 mg/m3
Ceiling / Peak: 100 mg/m3
Portugal
TWA: 10 mg/m3
Finland
TWA: 20 mg/m3
Switzerland
STEL: 100 mg/m3
TWA: 50 mg/m3
Poland
TWA: 10 mg/m3
Ireland
TWA: 10 mg/m3
Chemical Name
Diethylene glycol
111-46-6
ACGIH T LV
-
OSHA PEL
-
European Union
-
The United Kingdom
STEL: 69 ppm
STEL: 303 mg/m3
TWA: 101 mg/m3
Germany
TWA: 10 ppm
Denmark
TWA: 2 .5 ppm
TWA: 11 mg/m3
Austria
STEL 40 ppm
TWA: 44 mg/m3
Switzerland
STEL: 40 ppm
TWA: 44 mg/m3
Poland
TWA: 10 mg/m3
Ireland
TWA: 23 ppm
TWA: 100 mg/m3
8.2 Exposure controls
Appropriate engineering controls
Good general ventilation should be sufficient under normal use.
Personal protective equipment
Not normally required. For use other than in normal operating procedures (such as in the event of
large spill), the following should be applied:
Eye Protection
Safety goggles.
Hand Protection
Protective gloves.
Skin and body protection
Long sleeved clothing and long pants.
Respiratory protection
Large spillages: Wear suitable respiratory protective equipment.
Environmental Exposure Controls
Avoid release to the environment.
TWA: 23 ppm
TWA: 44 mg/m3
Ceiling / Peak: 40 ppm
Ceiling / Peak: 176 mg/m
STEL 176 mg/m3
TWA: 10 ppm
STEL: 176 mg/m3
TWA: 10 ppm
3
Page 6
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 6 / 10
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Physical state
Liquid
Color
Dark blue
Odor
Slight
Odor Threshold
No information available
pH
7 - 9
Melting point/freezing point
-/< -5 °C
Initial boiling point and boiling range
> 100 °C
Flash Point
Not less than 93.3°C
( Tag closed cup; Cleveland open cup )
Evaporation rate
No information available
Flammability (solid, gas)
Not applicable
Upper/lower flammability or explosive
limits
No information available
Vapor pressure
No information available
Vapor density
No information available
Relative density
1.0 - 1.1 (H2O=1)
Solubility(ies)
Soluble (water)
Partition coefficient: n-octanol/water
No information available
Auto-ignition temperature
>400 °C
Decomposition temperature
No information available
Viscosity
1 - 5 mPa·s
Explosive properties
Not explosive
Oxidizing properties
No information available
9.2 Other information
No information available.
SECTION 10: Stability and reactivity
10.1 Reactivity
No information available.
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous
reactions
No information available.
10.4 Conditions to avoid
No information available.
10.5 Incompatible materials
Strong oxidizing agents.
10.6 Hazardous decomposition
products
Contains: Carbon monoxide (CO). Carbon dioxide (CO2).
Page 7
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 7 / 10
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Inhalation
No information available.
Eye contact
No information available.
Skin contact
No information available.
Ingestion
LD50 > 2000 mg/kg (Method OECD#420)
Skin corrosion/irritation
Non-irritant. (Method: OECD#404)
Serious eye damage/irritation
Minimal irritant to the eye. (Method: OECD#405)
Respiratory or skin sensitisation
It is not a skin sensitizer. (Method: OECD#429)
Mutagenicity
Negative. (Method: OECD#471)
Carcinogenicity
Ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA
Page 8
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 8 / 10
SECTION 12: Ecological information
12.1 Toxicity
Chemical Name
Toxicity to algae
Toxicity to fish
Toxicity to daphnia and other
aquatic invertebrates
Glycerol
56-81-5
LC50: 51 - 57 mL/L 96 h
static (Onco r hynchus my kiss)
EC50: >500 mg/L 24 h
(Daphnia magna)
Triethylene glycol monobutyl ether
143-22-6
EC50: >500 mg/L 72 h
LC50: 2200 - 4600 mg/L 96 h
(Pimephales promelas)
EC50: >500 mg/L 48 h
Diethylene glycol
LC50: 75200 mg/L 96 h
promelas)
EC50: 84000 mg/L 48 h
12.2 Persistance and degradability
No information available.
12.3 Bioaccumulative potential
Chemical Name
log Pow
Glycerol
-1.76
Triethylene glycol monobutyl ether
0.51
Diethylene glycol
-1.98
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB
assessment
This product contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This product contains no substance considered to be very persistent nor very bioaccumulating
(vPvB).
12.6 Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of in accordance with Federal, State, and local regulations.
(Desmodesmus subspicatus)
static (Leuciscus idus)
LC
: 2400 mg/L 96 h
50
static (Pimephales promelas)
LC
: 2400 mg/L 96 h
50
(Daphnia magna)
111-46-6
flow-through (Pimephales
(Daphnia magna)
Page 9
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 9 / 10
SECTION 14: Transport information
Not classified according to the United Nations "Recommendations on the Transport of Dangerous Goods"
14.1 UN Number
None
14.2 UN proper shipping name
None
14.3 Transport hazard class(es)
None
14.4 Packing Group
None
14.5 Environmental hazards
None
14.6 Special precautions for user
None
14.7 Transport in bulk according to
Annex II of Marpol 73/78 and the IBC
Code
Not applicable
Not regulated under DOT, IMDG, IATA.
SECTION 15: Regulatory information
15.1 Safety, health and environmental
regulations/legislation specific for the
substance or mixture
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA:
Chemical Substances Inventory, and none is subject to any of the following TSCA requirements:
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent
orders; section 8(a)
data reporting rules.
Canada: WHMIS: Not applicable. (Manufactured article)
15.2 Chemical Safety Assessment
No.
All chemical substances contained in this product are and had been listed on the TSCA
preliminary assessment information rules; and section 8(d) health and safety
Page 10
SAFETY DATA SHEET
Issuing Date: 26-December-2007
Revision Date: 1-April -2015
Product name: LC11C, LC16C, LC38C, LC39C, LC60C, LC61C,
LC67C, LC975C, LC980C, LC985C, LC990C, LC1100C, LC65HYC,
LC67HYC, LC990HYC, LC1100HYC Ink
Version: 11
SDS No: BHC018-01-EUUSOTHER
_________________________________________________________________________________________________________________
_________________________________________________________________________________________________________________
EN
Page 10 / 10
SECTION 16: Other information
Full text of R-phrases referred to
under sections 2 and 3
R22 - Harmful if swallowed
R41
R38
R43
R50
R52/53
environment.
Full text of H-Statements referred to
under sections 2 and 3
H302 - Harmful if swallowed
H315
H318
H317
H400
H412 - Harmful to aquatic life with long lasting effects
Additional information
The information relates only to this product. It may not be valid, if used in combination with any other
materials or in any other process, and it is based on our best knowledge as of the date of preparation
(revision).
Revision Note
SECTION 2, 3.
References:
U.S. 29CFR Part 1910
ACGIH Threshold Limit Values for Chemical Substances and Physical
Exposure Indices
IARC Monographs on the Evaluation Carcinogenic Risks to Humans World Health Organization
EU Directive 91/322/EEC and 2000/39/EC
NTP 11th Report on Carcinogens
Abbreviations:
ACGIH: American Conference of Governmental Industrial Hygienists
DOT: Department Of Transportation (US)
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods
NOHSC: National Occupational Health and S
NTP: National Toxicology Program (US)
OSHA: Occupational Safety and Health Administration (US)
PEL: Permissible Exposure Limit
STEL: Short Term Exposure Limit
TLV: Threshold Limit Value (ACGIH)
TSCA: Toxic Substances Control Ac
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Material Information System (Canada)
- Risk of serious damage to eyes
- Irritating to skin
- May cause sensitization by skin contact
- Very toxic to aquatic organisms
- Harmful to aquatic organisms, may cause long-term adverse eff ects in the aquatic
- Causes skin irritation
- Causes serious eye damage
- May cause an allergic skin reaction
- Very toxic to aquatic life
Agents and Biological
afety Commission (Australia)
t (US)
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