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BRTTN331Y
User Manual
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Brother BRTTN331Y User Manual

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Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
1/7
Product name
:
TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y, TN-329Y, TN-331Y, TN-336Y, TN-339Y, TN­341Y, TN 900Y Toner
Use of the substance/mixture
:
These products are yellow toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and for use in the products stated. Information provided on this SDS is only consistent with the use specified by Brother
Emergency number
:
CHEMTREC +1 +1
For France only: Antipoison Center telephone number: ORFILA +33

SECTION 1: Identification of the substance/mixture and of the compan y/undertaking

1.1. Product identifier

-346Y, TN-349Y, TN-351Y, TN-359Y, TN-376Y, TN-379Y, TN-361Y, TN-369Y, TN-

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Date of issue: 12 September
Revision date: 20 March
SDS No:YT413-01-
Version:

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

Manufacturer Brother Industries, Ltd. 15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation 200 Crossing Boulevard, Bridgewater, NJ 08807, USA Telephone (for information): +1-877-276-8437
Importer (Canada) Brother International Corporation (Canada) Ltd. 1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada Telephone (for information): +1-514-685-0600
Importer (Europe) Brother International Europe Ltd. Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK Telephone (for information): +44-161-330-6531
Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835 Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia Telephone (for information): +61-2-9887-4344
E-mail Address sds.info@brother.co.jp

1.4. Emergency telephone number

-703-527-3887 (International)
-800-424-9300 (North America)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]

Not classified

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Not classified
Australia Classification
Not classified as hazardous according to the criteria of NOHSC

2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP]

No labeling applicable
-1-45-425-959
Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
2/7
Name
Product identifier
%
Classification
67/548/EEC
Classification
1272/2008 [CLP]
Styrene-acrylate copolymer
25767-47-9
(EC no) -
75 - 90
Not classified
Not classified
Fatty Acid Ester
(CAS No) ** (EC no) -
3 - 10
Not classified
Not classified
Pigment
(CAS No) ** (EC no) **
4 - 10
Not classified
Not classified
PMMA
9011-14-7
(EC no) -
1 - 3
Not classified
Not classified
Silicon Dioxide (amorphous)
(CAS No) 844491-94-7 (EC no) 430-570-1
< 2
Not classified
Not classified
Silicon Dioxide (amorphous)
112945-52-5
(EC no) 231-545-4
1 - 3
Not classified
Not classified
Styrene-acrylate Resin
(CAS No) ** (EC no) -
0.1 - 1
Not classified
Not classified
First-aid measures general
:
If symptoms persist, obtain medical attention.
First-aid measures after inhalation
:
Obtain medical attention. In case of accident by inhalation : remove casualty to fresh air and keep at rest.
First-aid measures after skin contact
:
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap and water.
First-aid measures after eye contact
:
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of water for at least 15 minutes.
First-aid measures after ingestion
:
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to drink.
Symptoms/injuries after inhalation
:
For large quantities: May cause irritation to the respiratory system. Increased difficulty in breathing. Sneezing. Coughing.
Symptoms/injuries after eye contact
:
May cause eye irritation.
Symptoms/injuries after ingestion
:
May cause stomach ache. Unlikely route of exposure.
Suitable extinguishing media
:
Extinguish preferably with dry chemical, carbon dioxide, water, foam.
Unsuitable extinguishing media
:
Do not use water jet.
Explosion hazard
:
May form explosible dust clouds in air.

2.3. Other hazards

This substance/mixture does not meet the PBT criteria of REACH, annex XIII This substance/mixture does not meet the vPvB criteria of REACH, annex XIII

SECTION 3: Composition/information on ingredients

3.2. Mixture

Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:YT413-01-
** CONFIDENTIAL Full text of R- and H- phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures

(CAS No)
(CAS No)
(CAS No)
according to Directive
according to Regulation (EC) No.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
3/7
Firefighting instructions
:
Do not use high-pressure water in order to prevent creating a dust cloud and spreading fire dust. Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self contained breathing apparatus (SCBA) during the attack phase of fi during cleanup in enclosed or poorly ventilated areas immediately after a fire. Personnel not having suitable respiratory protection must leave the area to prevent significant exposure to toxic combustion gases from any source.
Emergency procedures
:
Ensure adequate ventilation. Avoid contact with skin and eyes.
Emergency procedures
:
Avoid generation of dust. Do not breathe dust. A suitable dust mask or dust respirator with filter type A/P may be appropriate.
Methods for cleaning up
:
Sweep the spilt toner or remove it with a vacuum cleaner and transfer into a sealed container carefully. Sweep slowly to minimize gene used, the motor must be rated as dust explosion proof. Potential for very fine particles to be taken into the vacuum only to be passed back into the environment due to pore size in the bag or filter.
Precautions for safe handling
:
Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high concentrations of dust. Avoid contact with eyes.
Storage conditions
:
Keep away from oxidizing agents.
Silicon Dioxide (amorphous) (844491-94-7)
USA - OSHA
OSHA PEL (TWA) (mg/m³)
20 mg/m³ 20mppcf 80%SiO2
Silicon Dioxide (amorphous) (112945-52-5)
USA - OSHA
OSHA PEL (TWA) (mg/m³)
20 mg/m³ 20mppcf 80%SiO2

5.3. Advice for firefighters

Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:YT413-01-

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

6.1.2. For emergency responders

6.2. Environmental precautions

Prevent substance entering sewers. Washings must be prevented from entering surface water drains.

6.3. Methods and material for containment and cleaning up

ration of dust during cleanup. If a vacuum cleaner is

6.4. Reference to other sections

SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

refighting operations and
-

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

These products are yellow toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. This cartridge should be used as supplied by Brother and for use in the products stated.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
4/7
Appropriate engineering controls
:
Good general ventilation should be sufficient under normal use.
Personal protective equipment
:
Not normally required. For use other than in normal operating procedures (such as in the event of large spill)
Hand protection
:
protective gloves.
Eye protection
:
Safety goggles.
Skin and body protection
:
Long sleeved clothing and long pants.
Respiratory protection
:
Dust mask. (Large spillages: Respirator).
Environmental exposure controls
:
Avoid release to the environment.
Physical state
:
Solid
Appearance
:
Powder
Color
:
Yellow
Odor
:
odorless
Odor threshold
:
No information available
pH : Not applicable
Relative evaporation rate (butyl acetate=1)
:
No information available
Relative evaporation rate (ether=1)
:
Not available
Melting point
:
No information available
Freezing point
:
No information available
Boiling point
:
Not applicable
Flash point
:
Not applicable
Auto-ignition temperature
:
No information available
Decomposition temperature
:
Not available
Flammability (solid, gas)
:
Not applicable
Vapor pressure
:
Not applicable
Relative vapor density at 20 °C
:
Not applicable
Relative density
:
No information available
Relative density of saturated gas/air mixture
:
No information available
Solubility
:
Insoluble in water
Log Pow
:
No information available
Log Kow
:
No information available
Viscosity, kinematic
:
Not applicable
Viscosity, dynamic
:
Not applicable
Explosive properties
:
Explosive limits of toner particles suspended in air approximately equal to that of coal dust
Oxidizing properties
:
No information available
Explosion limits
:
No information available

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

, the following should be applied:
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:YT413-01-

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

No information available.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

No information available.

10.4. Conditions to avoid

Keep at temperature not exceeding 200 °C. Avoid friction, sparks, or other means of ignition.
Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
5/7
Acute toxicity
:
Not classified
LD50 oral rat
> 2000 mg/kg (OECD 420 method)
LC50 inhalation rat (mg/l)
> 5.25 mg/l/4h (OECD 436 method)
Skin corrosion/irritation
:
Non-irritant. (OECD 404 method) pH
Serious eye damage/irritation
:
Minimal irritant to the eye. (OECD 405 method) pH
Respiratory or skin sensitization
:
It is not a skin sensitizer. (OECD 429 method)
Germ cell mutagenicity
:
AMES test : Negative. (OECD 471 method)
Carcinogenicity
:
Ingredients of this product have not been classified as carcinogens according to IARC monographs, NTP and OSHA
Reproductive toxicity
:
Not classified
Specific target organ toxicity (single exposure)
:
Not classified
Specific target organ toxicity (repeated
:
Not classified
Aspiration hazard
:
Not classified
Ecology - general
:
No information available.
Persistence and degradability
No information available.
Log Pow
No information available
Log Kow
No information available
Ecology - soil
No information available.
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
Other adverse effects
:
No information available.

10.5. Incompatible materials

Strong oxidizing agents.

10.6. Hazardous decomposition products

Carbon monoxide. Carbon dioxide. Nitrogen oxides.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

: Not applicable
: Not applicable
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:YT413-01-
exposure)

SECTION 12: Ecological information

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
6/7
Waste disposal recommendations
:
Do not put toner or toner cartridges into a fire, this can cause fire to spread with the risk of causing burn injuries. Shred toner cartridges in a dust/explosion controlled environment. Finely dispersed particles may form explosive mixtures in the air. Dispose in accordance with federal, state and local regulations.
Proper Shipping Name (ADR/RID)
:
None
Proper Shipping Name (IATA)
:
None
Proper Shipping Name (IMDG)
:
None
Other information
:
None
Special transport precautions
:
None
IBC code
:
Not applicable
Regional legislation
:
EU:Not classified as dangerous for supply/use. (1999/45/EC) USA: All chemical substances contained in this product are and had been listed on the TSCA
Chemical Substances Inventory, and none is subject to any of the fol section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e) consent orders; section 8(a) preliminary assessment information rules; and section 8(d) health and safety data reporting rules.
Cana

SECTION 13: Disposal considerations

13.1. Waste treatment methods

SECTION 14: Transport information

In accordance with ADR / IMDG / IATA / DOT / UN

14.1. UN number

Not regulated for transport

14.2. UN proper shipping name

14.3. Transport hazard class(es)

Not applicable

14.4. Packing group

Not applicable

14.5. Environmental hazards

Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:YT413-01-

14.6. Special precautions for user

14.6.1. Overland transport

No additional information available

14.6.2. Transport by sea

No additional information available

14.6.3. Air transport

No additional information available

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations

No REACH Annex XVII restrictions Contains no REACH candidate substance

15.1.2. National regulations

lowing TSCA requirements:
da: WHMIS: Not applicable. (Manufactured article).
Safety Data Sheet
Product name: TN-311Y, TN-316Y, TN-319Y, TN-321Y, TN-326Y,
2013 2015
4.0
EUUSOTHER
EN
7/7
Indication of changes:
SECTION 3.
Data sources
:
World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risks to Humans, Volume 93
EU Directive 1999/45/EC U.S. Department of labor, 29CFR Part 1910. ACGIH, Threshold Limit Values for Chemical Substances and Physical
Exposure Indices EU Commission Directive 2009/161/EU.
Abbreviations and acronyms
:
IARC (International Agency for Research on Cancer) IATA (International Air Transport Association) IMDG (International Maritime Dangerous Goods Code) IOELV (Indicative Occupational Exposure Limit) REACH (Registration, Evaluation and Authorisation of CHemicals) WHMIS (Workplace Hazardous Material Information System (Canada)) ACGIH (American Conference of Governement Industrial Hygienists) DOT (Departmen ICAO (International Civil Aviation Organization) NOHSC (National Occupational Health and Safety Commission (Australia)) NTP (National Toxicology Program) (US) OSHA (Occupational Safety and Health Administration) (US) PEL (Permissi STEL (Short Term Exposure Limit) TLV (Threshold Limit Value) (ACGIH) TSCA (Toxic Substances Control Act) (US) TWA (Time Weighted Average).
Other information
:
The information only relates to this specific product. It may not be valid, if used in combination with any other materials or in any other process, and it is based on our best knowledge as of the date of preparation (revision).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:YT413-01-
Agents and Biological
t Of Transportation (US))
ble Exposure Limit)
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