Page 1
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
2013
2015
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Product form
:
Mixture
Product name
:
TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-326BK, TN-329BK, TN-331BK, TN-336BK,
TN
TN
Use of the substance/mixture
:
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers,
multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and
for use in the products stated. Information provided on this SDS is only consistent with the
specified by Brother
Emergency number
:
CHEMTREC
+1
+1
For France only:
Antipoison Center telephone number: ORFILA +33
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
SECTION 1: Identification of the substance/mixture and of the compan y/undertaking
1.1. Product identifier
-339BK, TN-341BK, TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
1.2. Relevant identified uses of the substance or mixture and uses advised against
-361BK, TN-369BK, TN-900BK Toner
1.2.1. Relevant identified uses
Date of issue: 12 September
Revision date: 20 March
SDS No:PT413-01-
Version:
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Manufacturer Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada) Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe) Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address sds.info@brother.co.jp
1.4. Emergency telephone number
-703-527-3887 (International)
-800-424-9300 (North America)
use
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Not classified
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP]
No labeling applicable
-1-45-425-959
Page 2
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
2013
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Name
Product identifier
%
Classification
67/548/EEC
Classification
1272/2008 [CLP]
Styrene-acrylate copolymer
25767-47-9
(EC no) -
70 - 80
Not classified
Not classified
Fatty Acid Ester
(CAS No) **
(EC no) -
10 - 20
Not classified
Not classified
Carbon Black (bound)
1333-86-4
(EC no) 215-609-9
5 - 7
Not classified
Not classified
PMMA
(CAS No) 9011-14-7
(EC no) -
1 - 3
Not classified
Not classified
Silicon Dioxide (amorphous)
(CAS No) 112945-52-5
(EC no) 231-545-4
< 2
Not classified
Not classified
Silicon Dioxide (amorphous)
7631-86-9
(EC no) 231-545-4
< 2
Not classified
Not classified
Silicon Dioxide (amorphous)
(CAS No) 844491-94-7
(EC no) 430-570-1
< 1
Not classified
Not classified
Styrene-acrylate Resin
**
(EC no) -
< 1
Not classified
Not classified
First-aid measures general
:
If symptoms persist, obtain medical attention.
First-aid measures after inhalation
:
Obtain medical attention. In case of accident by inhalation : remove casualty to fresh air and
keep at rest.
First-aid measures after skin contact
:
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap
and water.
First-aid measures after eye contact
:
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.
First-aid measures after ingestion
:
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to
drink.
Symptoms/injuries after inhalation
:
For large quantities: May cause irritation to the respiratory system. Increased difficulty in
breathing. Sn
Symptoms/injuries after eye contact
:
May cause eye irritation.
Symptoms/injuries after ingestion
:
May cause stomach ache. Unlikely route of exposure.
Suitable extinguishing media
:
Extinguish preferably with dry chemical, carbon dioxide, water, foam.
Unsuitable extinguishing media
:
Do not use water jet.
Explosion hazard
:
May form explosible dust clouds in air.
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
SECTION 3: Composition/information on ingredients
3.2. Mixture
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
** CONFIDENTIAL
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
(CAS No)
(CAS No)
(CAS No)
(CAS No)
according to
Directive
according to
Regulation (EC) No.
4.2. Most important symptoms and effects, both acute and delayed
eezing. Coughing.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
Page 3
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
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Firefighting instructions
:
Do not use high-pressure water in order to prevent creating a dust cloud and spreading fire dust.
Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self
contained breathing apparatus (SCBA) during the attack phase of firefighting operations and
during cleanup in enclosed or poorly ventilated areas immediately a
having suitable respiratory protection must leave the area to prevent significant exposure to toxic
combustion gases from any source.
Emergency procedures
:
Ensure adequate ventilation. Avoid contact with skin and eyes.
Emergency procedures
:
Avoid generation of dust. Do not breathe dust. A suitable dust mask or dust respirator with filter
type A/P may be appropriate.
Methods for cleaning up
:
Sweep the spilt toner or remove it with a vacuum cleaner and transfer into a sealed container
carefully. Sweep slowly to minimize generation of dust during cleanup. If a vacuum cleaner is
used, the motor must be rated as dust e
taken into the vacuum only to be passed back into the environment due to pore size in the bag or
filter.
Precautions for safe handling
:
Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high
concentrations of dust. Avoid contact with
Storage conditions
:
Keep away from oxidizing agents.
Carbon Black (bound) (1333-86-4)
Belgium
Local name
Carbone (noir de)
Belgium
Limit value (mg/m³)
3.5 mg/m³
Denmark
Local name
Carbon black
Denmark
Limit (long-term) (mg/m³)
3.5 mg/m³
Denmark
Anmærkninger (DK)
K
Finland
Local name
Nokimusta
Finland
HTP-arvo (8h) (mg/m³)
3.5 mg/m³
Finland
HTP-arvo (15 min)
7 mg/m³
France
Local name
Noir de carbone
France
VME (mg/m³)
3.5 mg/m³
Ireland
Local name
Carbon black
Ireland
OEL (8 hours ref) (mg/m³)
3.5 mg/m³
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
5.3. Advice for firefighters
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
-
fter a fire. Personnel not
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
6.1.2. For emergency responders
6.2. Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water drains.
6.3. Methods and material for containment and cleaning up
xplosion proof. Potential for very fine particles to be
6.4. Reference to other sections
SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
eyes.
7.3. Specific end use(s)
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. This cart ridge shoul d
be used as supplied by Brother and for use in the products stated.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Page 4
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
2013
2015
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Carbon Black (bound) (1333-86-4)
Ireland
OEL (15 min ref) (mg/m3)
7 mg/m³
Portugal
Local name
Carbono, preto (Negro de fumo)
Portugal
OEL TWA (mg/m³)
3.5 mg/m³
Spain
Local name
Negro de humo
Spain
VLA-ED (mg/m³)
3.5 mg/m³
Spain
Notes
véase Apartado 9
United Kingdom
Local name
Carbon black
United Kingdom
WEL TWA (mg/m³ )
3.5 mg/m³
United Kingdom
WEL STEL (mg/m³)
7 mg/m³
Norway
Local name
Carbon Black (lampesot)
Norway
TWA (A N) (mg/ m³)
3.5 mg/m³
USA - ACGIH
Local name
Carbon black
USA - ACGIH
ACGIH TWA (mg/m³)
3 mg/m³
USA - ACGIH
Remark (ACGIH)
Bronchitis
USA - OSHA
Local name
Carbon black
USA - OSHA
OSHA PEL (TWA) (mg/m³)
3.5 mg/m³
Silicon Dioxide (amorphous) (7631-86-9)
Germany
Local name
Kieselsäuren, amorphe
Germany
TRGS 900 Occupational exposure limit value (mg/m³)
4 mg/m³
Latvia
Local name
Silīcija dioksīds
Latvia
OEL TWA (mg/m³)
1 mg/m³
USA - OSHA
OSHA PEL (TWA) (mg/m³)
20 mg/m³ 20mppcf 80%SiO2
Silicon Dioxide (amorphous) (112945-52-5)
USA - OSHA
OSHA PEL (TWA) (mg/m³)
20 mg/m³ 20mppcf 80%SiO2
Silicon Dioxide (amorphous) (844491-94-7)
USA - OSHA
OSHA PEL (TWA) (mg/m³)
20 mg/m³ 20mppcf 80%SiO2
Appropriate engineering controls
:
Good general ventilation should be sufficient under normal use.
Personal protective equipment
:
Not normally required. For use other than in normal operating procedures (such as in the event
of large spill),
Hand protection
:
protective gloves.
Eye protection
:
Safety goggles.
Skin and body protection
:
Long sleeved clothing and long pants.
Respiratory protection
:
Dust mask. (Large spillages: Respirator).
Environmental exposure controls
:
Avoid release to the environment.
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
8.2. Exposure controls
the following should be applied:
Page 5
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
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Physical state
:
Solid
Appearance
:
Powder
Color
:
Black Odor
:
odorless
Odor threshold
:
No information available
pH : Not applicable
Relative evaporation rate (butyl acetate=1)
:
No information available
Relative evaporation rate (ether=1)
:
Not available
Melting point
:
No information available
Freezing point
:
No information available
Boiling point
:
Not applicable
Flash point
:
Not applicable
Auto-ignition temperature
:
No information available
Decomposition temperature
:
Not available
Flammability (solid, gas)
:
Not applicable
Vapor pressure
:
Not applicable
Relative vapor density at 20 °C
:
Not applicable
Relative density
:
No information available
Relative density of saturated gas/air mixture
:
No information available
Solubility
:
Insoluble in water
Log Pow
:
No information available
Log Kow
:
No information available
Viscosity, kinematic
:
Not applicable
Viscosity, dynamic
:
Not applicable
Explosive properties
:
Explosive limits of toner particles suspended in air approximately equal to that of coal dust
Oxidizing properties
:
No information available
Explosion limits
:
No information available
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No information available.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
No information available.
10.4. Conditions to avoid
Keep at temperature not exceeding 200 °C. Avoid friction, sparks, or other means of ignition.
10.5. Incompatible materials
Strong oxidizing agents.
10.6. Hazardous decomposition products
Carbon monoxide. Carbon dioxide. Nitrogen oxides.
Page 6
Safety Data Sheet
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Acute toxicity
:
Not classified
LD50 oral rat
> 2000 mg/kg (OECD 420 method)
LC50 inhalation rat (mg/l)
> 5.2 mg/l/4h (OECD 436 method)
Skin corrosion/irritation
:
Non-irritant. (OECD 404 method)
pH
Serious eye damage/irritation
:
Minimal irritant to the eye. (OECD 405 method)
pH
Respiratory or skin sensitization
:
It is not a skin sensitizer. (OECD 429 method)
Germ cell mutagenicity
:
AMES test : Negative. (OECD 471 method)
Carcinogenicity
:
Carbon Black: In 1996, the IARC re-evaluated carbon black as a Group 2B carcinogen (possible
human carcinogen). This classific
human evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity.
The classification is based upon the development of lung tumors in rats receiving chronic
inhalation e
Studies performed in animal models other than rats did not show any association between
carbon black and lung tumors. Moreover, a two
preparation containing carbon black demonstrated no association between toner exposure and
tumor development in rats.
Other ingredients of this product have not been classified as carcinogens according to IARC
monographs, NTP and OSHA
Reproductive toxicity
:
Not classified
Specific target organ toxicity (single exposure)
:
Not classified
Specific target organ toxicity (repeated
:
Not classified
Aspiration hazard
:
Not classified
Carbon Black (bound) (1333-86-4)
EC50 Daphnia
> 5600 mg/l 24 h (Daphnia magna)
Silicon Dioxide (amorphous) (7631-86-9)
LC50 fish
5000 mg/l 96 h static (Brachydanio rerio)
EC50 Daphnia
7600 mg/l 48 h (Ceriodaphnia dubia)
EC50 other aquatic organisms 1
440 mg/l 72 h (Pseudokirchneriella subcapitata)
Persistence and degradability
No information available.
Log Pow
No information available
Log Kow
No information available
Ecology - soil
No information available.
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
Other adverse effects
:
No information available.
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
SECTION 11: Toxicological information
11.1. Information on toxicological effects
: Not applicable
: Not applicable
xposures to free carbon black at levels that induce particle overload of the lung.
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
ation is given to chemicals, for which there is inadequate
-year cancer bioassay using a typical toner
exposure)
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
Page 7
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Waste disposal recommendations
:
Do not put toner or toner cartridges into a fire, this can cause fire to spread with the risk of
causing burn injuries. Shred toner cartridges in a dust/explosion controlled environment. Finely
dispersed particles may form explosive mixtures in the air. Dispose in accordance with federal,
state and local regulations.
Proper Shipping Name (ADR/RID)
:
None
Proper Shipping Name (IATA)
:
None
Proper Shipping Name (IMDG)
:
None
Other information
:
None
Special transport precautions
:
None
IBC code
:
Not applicable
Regional legislation
:
EU:Not classified as dangerous for supply/use. (1999/45/EC)
USA: All chemical substances contained in this product are and had been listed on the TSCA
Chemical Substances Inventory, and none is subject to any of the f
section 4 test rules; proposed or final section 5(a)(2) significant new use rules; section 5(e)
consent orders; section 8(a) preliminary assessment information rules; and section 8(d) health
and safety data reporting rules.
Ca
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
In accordance with ADR / IMDG / IATA / DOT / UN
14.1. UN number
Not regulated for transport
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
14.6. Special precautions for user
14.6.1. Overland transport
No additional information available
14.6.2. Transport by sea
No additional information available
14.6.3. Air transport
No additional information available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Contains no REACH candidate substance
15.1.2. National regulations
ollowing TSCA requirements:
nada: WHMIS: Not applicable. (Manufactured article).
Page 8
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Indication of changes:
SECTION 3.
Data sources
:
World Health Organization International Agency for Research on Cancer, IARC Monographs on
the Evaluation on the Carcinogenic Risks to Humans, Volume 93
EU Directive 1999/45/EC
U.S. Department of labor, 29CFR Part 1910.
ACGIH, Threshold Limit Values for Chemical Substances and Physic
Exposure Indices
EU Commission Directive 2009/161/EU.
Abbreviations and acronyms
:
IARC (International Agency for Research on Cancer)
IATA (International Air Transport Association)
IMDG (International Maritime Dangerous Goods Cod
IOELV (Indicative Occupational Exposure Limit)
REACH (Registration, Evaluation and Authorisation of CHemicals)
WHMIS (Workplace Hazardous Material Information System (Canada))
ACGIH (American Conference of Governement Industrial Hygienists)
DOT (Departm
ICAO (International Civil Aviation Organization)
NOHSC (National Occupational Health and Safety Commission (Australia))
NTP (National Toxicology Program) (US)
OSHA (Occupational Safety and Health Administration) (US)
PEL (Permis
STEL (Short Term Exposure Limit)
TLV (Threshold Limit Value) (ACGIH)
TSCA (Toxic Substances Control Act) (US)
TWA (Time Weighted Average).
Other information
:
The information only relates to this specific product. It may not be valid, if used in combination
with any other materials or in any other process, and it is based on our best knowledge as of the
date of preparation (revision).
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
al Agents and Biological
e)
ent Of Transportation (US))
sible Exposure Limit)
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