Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-326BK, TN-329BK, TN-331BK, TN-336BK,
TN
TN
Use of the substance/mixture
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers,
multifunction devices and fax receivers. The cartridge should be used as supplied by Brother and
for use in the products stated. Information provided on this SDS is only consistent with the
specified by Brother
For France only:
Antipoison Center telephone number: ORFILA +33
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
SECTION 1: Identification of the substance/mixture and of the compan y/undertaking
1.1. Product identifier
-339BK, TN-341BK, TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
1.2. Relevant identified uses of the substance or mixture and uses advised against
-361BK, TN-369BK, TN-900BK Toner
1.2.1. Relevant identified uses
Date of issue: 12 September
Revision date: 20 March
SDS No:PT413-01-
Version:
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Manufacturer Brother Industries, Ltd.
15-1 Naeshiro-cho, Mizuho-ku, Nagoya 467-8561, Japan
Telephone (for information): +81-52-824-2735
Importer (USA) Brother International Corporation
200 Crossing Boulevard, Bridgewater, NJ 08807, USA
Telephone (for information): +1-877-276-8437
Importer (Canada) Brother International Corporation (Canada) Ltd.
1 Hotel de Ville, Dollard des Ormeaux, Quebec, H9B 3H6, Canada
Telephone (for information): +1-514-685-0600
Importer (Europe) Brother International Europe Ltd.
Brother House, 1 Tame Street, Guide Bridge, Audenshaw, Manchester M34 5JE, UK
Telephone (for information): +44-161-330-6531
Importer (Australia) Brother International (Aust.) Pty. Ltd. ACN 001 393 835
Level 3, Building A, 11 Talavera Road, Macquarie Park, NSW 2113, Australia
Telephone (for information): +61-2-9887-4344
E-mail Address sds.info@brother.co.jp
1.4. Emergency telephone number
-703-527-3887 (International)
-800-424-9300 (North America)
use
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Not classified
Australia Classification
Not classified as hazardous according to the criteria of NOHSC
2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]
No labeling applicable
-1-45-425-959
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
Styrene-acrylate copolymer
1333-86-4
(EC no) 215-609-9
(CAS No) 9011-14-7
(EC no) -
Silicon Dioxide (amorphous)
(CAS No) 112945-52-5
(EC no) 231-545-4
Silicon Dioxide (amorphous)
7631-86-9
(EC no) 231-545-4
Silicon Dioxide (amorphous)
(CAS No) 844491-94-7
(EC no) 430-570-1
First-aid measures general
If symptoms persist, obtain medical attention.
First-aid measures after inhalation
Obtain medical attention. In case of accident by inhalation : remove casualty to fresh air and
keep at rest.
First-aid measures after skin contact
Remove contaminated clothing immediately and wash affected skin with plenty of water or soap
and water.
First-aid measures after eye contact
Obtain medical attention. If substance has got into the eyes, immediately wash out with plenty of
water for at least 15 minutes.
First-aid measures after ingestion
Obtain immediate medical attention. Wash out mouth with water and give 100-200 ml of water to
drink.
Symptoms/injuries after inhalation
For large quantities: May cause irritation to the respiratory system. Increased difficulty in
breathing. Sn
Symptoms/injuries after eye contact
May cause eye irritation.
Symptoms/injuries after ingestion
May cause stomach ache. Unlikely route of exposure.
Suitable extinguishing media
Extinguish preferably with dry chemical, carbon dioxide, water, foam.
Unsuitable extinguishing media
May form explosible dust clouds in air.
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
2.3. Other hazards
This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
SECTION 3: Composition/information on ingredients
3.2. Mixture
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
** CONFIDENTIAL
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
(CAS No)
(CAS No)
(CAS No)
(CAS No)
according to
Directive
according to
Regulation (EC) No.
4.2. Most important symptoms and effects, both acute and delayed
eezing. Coughing.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
Safety Data Sheet
Product name: TN-311BK TN-316BK, TN-319BK, TN-321BK, TN-
Firefighting instructions
Do not use high-pressure water in order to prevent creating a dust cloud and spreading fire dust.
Use appropriate respirator for carbon monoxide and carbon dioxide. Wear positive pressure self
contained breathing apparatus (SCBA) during the attack phase of firefighting operations and
during cleanup in enclosed or poorly ventilated areas immediately a
having suitable respiratory protection must leave the area to prevent significant exposure to toxic
combustion gases from any source.
Ensure adequate ventilation. Avoid contact with skin and eyes.
Avoid generation of dust. Do not breathe dust. A suitable dust mask or dust respirator with filter
type A/P may be appropriate.
Sweep the spilt toner or remove it with a vacuum cleaner and transfer into a sealed container
carefully. Sweep slowly to minimize generation of dust during cleanup. If a vacuum cleaner is
used, the motor must be rated as dust e
taken into the vacuum only to be passed back into the environment due to pore size in the bag or
filter.
Precautions for safe handling
Keep out of the reach of children. Avoid generation of dust. Avoid inhalation of high
concentrations of dust. Avoid contact with
Keep away from oxidizing agents.
Carbon Black (bound) (1333-86-4)
Limit (long-term) (mg/m³)
OEL (8 hours ref) (mg/m³)
326BK, TN-329BK, TN-331BK, TN-336BK, TN-339BK, TN-341BK,
TN-346BK, TN-349BK, TN-351BK, TN-359BK, TN-376BK, TN-379BK,
TN-361BK, TN-369BK, TN-900BK Toner
5.3. Advice for firefighters
Date of issue: 12 September
Revision date: 20 March
Version:
SDS No:PT413-01-
-
fter a fire. Personnel not
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
6.1.2. For emergency responders
6.2. Environmental precautions
Prevent substance entering sewers. Washings must be prevented from entering surface water drains.
6.3. Methods and material for containment and cleaning up
xplosion proof. Potential for very fine particles to be
6.4. Reference to other sections
SECTION 8: Exposure controls/personal protection. SECTION 13: Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
eyes.
7.3. Specific end use(s)
These products are black toner in a cartridge for Brother Industries, Ltd. laser printers, multifunction devices and fax receivers. This cart ridge shoul d
be used as supplied by Brother and for use in the products stated.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters