SURFACE CONDITIONING
DCR
ATD-3150, ATD-3151, ATD-3152, ATD-3153 & ATD-3154
MATERIAL SAFETY DATA SHEET
According to Reg. 1907/2006/EC, Reg. 543/2010/EC and Dir. 67/548/EC
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
1
State of revision: 3
Date: 07/09/2011
Pag. 1 of 5
Product name DCR – QUICK-CHANGE SURFACE CONDITIONING DISCS
Use of the product Abrasive material for mechanical industry
.A.p.S ELLEIBIB :eman ynapmoC
)NC( atiragraM 04021 - 53 ,oenuC aiV :sserddA
Telephone number: +39 0171 793800
100397 1710 93+ :rebmun xaF
E-mail
bibielle@bibielle.com
Emergency phone number: +39 0171 793800
HAZARDS IDENTIFICATION
2
Classi cation
Hazards for Human
Hazards for the environment
Physical or chemical hazards
COMPOSITION / INFORMATION ON INGREDIENTS
3
Material is composed of abrasive powders supported on a structure of Nylon, cotton/polyester tissue binded by a
polymerized synthetic resin
Abrasive material
Matrix Substance
Abrasive
powders
Structural support
Matrix Structural component
Corundum* (Al2O3) --- --- 1344-28-1 215-691-6
Silicon carbide (CSi) --- ---
The product is classi
1272/2008/CE and to Dir 67/548/EC
No r levant hazards for human
e
r levant e
No hazards for the environment
r levant e
No physical or chemical hazards
Hazard
symbol
Hazard
symbol
ed not hazardous according to Reg.
Classi
cation CAS N. EC N.
409-21-2 206-991-8
cation CAS N. EC N.
Classi
% by
weight**
20 - 60
% by
weight**
Support
Binder Polimerized Synthetic Resin none --- n.a. n.a. 10 - 50
Locking
system
*: Corundum is a natural form of aluminium oxide; it contains small impurities of iron, magnesium and silica
**: any uncertain range concerning % amount of any component does not in
Reference Regulation
Nylon Fiber
Cotton/polyester tissue
Reinforced nylon or plastic
material
BIBIELLE S.p.A. - Via Cuneo , 35 - 12040 Margarita (CN), Italy - Phone: +39 0171 793800
none --- n.a. n.a.
none --- n.a. n.a.
none --- n.a. n.a.
uence the hazard classi cat ion of the material, according to
20 - 60
10 - 40
1 - 20
ATD-3150, ATD-3151, ATD-3152, ATD-3153 & ATD-3154
MATERIAL SAFETY DATA SHEET
According to Reg. 1907/2006/EC, Reg. 543/2010/EC and Dir. 67/548/EC
FIRST AID MEASURES
4
Following statements must be taken as base-rules concerning abrasive materials
Preamble
General informations
Eye contact
Skin contact
Inhalation
Swallowing
FIRE FIGHTING MEASURES
5
Suitable extinguishing agents
Protective equipment
Speci cal risks
ACCIDENTAL RELEASE MEASURES
6
Person-related safety precautions
Measures for environmental
protection
Measures for cleaning/collecting
HANDLING AND STORAGE
7
Handling
Storage
EXPOSURE CONTROLS / PERSONAL PROTECTION
8
Any risk concerning the use in mechanical industry
Risk scenario
Information about design of
technical facilities
Exposure limit values
Experimental toxicological data are not available c oncerning speci
scenarios. Hazard classi
and other available informations
Ensure good ventilation/exhaustion at the workplace.
Safety washing water must be available
Silicon carbide 15 5 10 3
Corundum [Al2O3] 15 5 --- ---
Particles not otherwise
classi
and has to be completed according to safety data sheets of processed materials
and process cooling liquid used
In case of eyes and skin contact, give priority to eyes rst aid measures
Rinse opened eye for several minutes under running water and seek immediate
medical advice, showing this MSDS
Remove contaminated clothes. Immediately wash with water and soap and rinse
thoroughly.
Supply fresh air; consult doctor in case of complaints
No negative e ects in case of swallowing. Drink water and seek immediate
medical advice, showing this MSDS
CO2, extinguishing powder or water spray. Fight larger res with water spray or
alcohol resistant foam
Ordinary protective equipment in case of re- ghting
None
n.a.
Avoid direct contact using recommended handling safety equipment (see § 8).
According to normal use conditions, product does not contain volatile components
Keep in cool, dry, ventilated storage in closed original containers. Do not drink
or eat near the storage place
ed
SURFACE CONDITIONING
DCR
State of revision: 3
Date: 07/09/2011
Pag. 2 of 5
cal exposure
cation of this product was done according to Reg. 1272/2008/EC
for skin and eyes
OSHA 2010
TWA [mg/m
latoT ecnatsbuS
3
10 mg/m
3 mg/m
inhalable fraction (TW A 8 h, ACGIH 2010)
3
respirable fraction (TW A 8 h, ACGIH 2010)
3
]
Respirable
fraction
Inhalable fraction
ACGIH 2010
TWA [mg/m3]
Respirable
fraction
BIBIELLE S.p.A. - Via Cuneo , 35 - 12040 Margarita (CN), Italy - Phone: +39 0171 793800
Respiratory protection
Eyes protection
Hands protection
Skin protection
ATD-3150, ATD-3151, ATD-3152, ATD-3153 & ATD-3154
MATERIAL SAFETY DATA SHEET
According to Reg. 1907/2006/EC, Reg. 543/2010/EC and Dir. 67/548/EC
In case of brief exposure use respiratory lter device
Protection factor: P3
Protective gloves for chemical products, according to standard EN374; materials for long
contact time
Safety goggles or face shield
Use protective clothes and protective shoes
SURFACE CONDITIONING
DCR
State of revision: 3
Date: 07/09/2011
Pag. 3 of 5
Abrasive materials used are inert and cannot cause risks when correctly stored and
managed. During use on machineries, they request sa fety precautions for workers. The
Other informations
PHYSICAL AND CHEMICAL PROPERTIES
9
most part of powder particles comes from the processed material and eventually from the
cooling liquid. Consequently attention and safety precautionary measures on vapours and
dusts environmental removing must be applied
Follow the local Safety Management stan
Appearance
Solid abrasive material
.
dards and instructions
sselruodO ruodO
.a.n HP
.a.n egrahC
.a.n tniop gnilioB
.a.n tniop gnitleM
.a.n tniop hsalF
Vapour pressure n.a.
Water solubility at 20°C Not soluble
Volatile organic chemicals (VOC) No volatile chemicals (VOC) are present at detectable level
Ripartition coe cient n-octanol/water n.a.
STABILITY AND REACTIVITY
10
Stability
Conditions/materials to avoid
Dangerous decomposition products
Stable in normal handling and storage conditions
Keep away from strong oxidizers and electrostatic charges
After overheating and drying, thermical decomposition at °T > 250°C can produce
dangerous vapours as carbon dioxide, carbon oxide and nitrogen oxides
BIBIELLE S.p.A. - Via Cuneo , 35 - 12040 Margarita (CN), Italy - Phone: +39 0171 793800
ATD-3150, ATD-3151, ATD-3152, ATD-3153 & ATD-3154
MATERIAL SAFETY DATA SHEET
According to Reg. 1907/2006/EC, Reg. 543/2010/EC and Dir. 67/548/EC
TOXICOLOGICAL INFORMATIONS
11
Material is inert on structural matrix. Data are referring to used abrasive components
Carcinogenic e ects:
n.a.
Mutagenic e ects: n.a.
Al
(Corundum): > 5000 mg/Kg - DL50, oral rat (IUCLID Data Sheet, European
2O3
Acute toxicity
Chemical Bureau)
CSi (Silicon Carbide): not available data
Chronic toxicity n.a.
SURFACE CONDITIONING
DCR
State of revision: 3
Date: 07/09/2011
Pag. 4 of 5
Skin
Inhalation
Eyes
Other negative e ects
ECOLOGICAL INFORMATIONS
12
Ecological toxicity
Mobility
Biopersistency
Biodegradability
Potential of bioaccumulation
DISPOSAL CONSIDERATIONS
13
Disposal recommendation
TRANSPORT INFORMATION
14
Transport classi cation and
regulation
Mechanical irritating e ects
Irritating (superior respiratory system). Powders produced during use can cause
respiratory irritating e
Mechanical irritating e ects: symptoms can be irri tating, reddening, damages of
corneal surface, tearing. Powders produced during use can cause eyes irritating
ects
e
Other risks can be caused depending on the abrasion process material used
Al2O3 (Corundum):
> 100 mg/l – 96 h, salmo trutta (long time acute toxicity)
> 100 mg/l – 48 h, daphnia magna (long time acute toxicity)
CSi (Silicon carbide): not available data
n.a.
n.a.
n.a.
n.a.
Recovery if possible.
Waste and uncleaned packages must be disposed of in accordance with state
and local environmental regulations.
ONU number: n.a.
ADR/RID: not regulated (road and railway)
ICAO/IATA: not regulated (air transport)
IMDG/IMO: nor regulated (maritime transport)
ects
BIBIELLE S.p.A. - Via Cuneo , 35 - 12040 Margarita (CN), Italy - Phone: +39 0171 793800
ATD-3150, ATD-3151, ATD-3152, ATD-3153 & ATD-3154
REGULATORY INFORMATION
15
Hazard labelling symbols
Risk statements
Precautionary statements
(Dir. 67/548/CE)
Precautionary statements
(Reg. 1272/2008/CE)
Other regulation references
OTHER INFORMATIONS
16
H/R – statements
(full text) (§ 3)
Further informations and
references
LD50
TLV - TWA
STEL
OES
REACH
n.a.
MATERIAL SAFETY DATA SHEET
According to Reg. 1907/2006/EC, Reg. 543/2010/EC and Dir. 67/548/EC
S 22
S 39
P 260
P 280
Reg. 1272/2008/EC on classi cation, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/ EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006
Product does not contains substances classi
---
Informations are updated to:
Dir. 2009/2/EC - 31° update of Dir. 67/548/EC and according to Reg. 1907/2006/EC, Dir.
2001/58/EC and 1999/45/EC and Reg. 1972/2008/EC
Reg. 1272/2008/EC (classi
preparations) modifying directives 67/548/EC, 1999/ 45/EC and Reg. 1907/2006/EC
NIOSH: Registry of toxic e
ACGIH: American Conference of Governmental Ind
When applicable, according to Reg. 1907/2006/EC - chapter II, all substances used in
this preparation where preregistered
Product is according to Reg. 1907/2006/EC – title II requirements (registration of
substances)
Dir. 42/2006/CE (machineries directive): n.a.
ABBREVIATIONS AND ACRONYMS
Average letal dose
Threshold Limit Value - Time Weighted Average
Short Term Exposure Limit
Occupational Exposure Standard
Registration, Evaluation, Autorisation of Chemicals. Regulation 1907/2008/EC
Not applicable/Not available
None
None
Do not breathe dust
Wear eye/face protection
Do not breathe dust
Wear protective gloves/eye/face protection
ed carcinogenic cat. I or cat. 2
cation, labelling and packaging of substances and
ects of chemical substances
ustrial Hygienists
DISCLAIMER
SURFACE CONDITIONING
DCR
State of revision: 3
Date: 07/09/2011
Pag. 5 of 5
THIS PREPARATION MUST BE USED ONLY IN THE PROPER WA Y FOR PROPER USE.
THE INFORMATIONS CONTAINED IN THIS MSDS, AS OF THE ISSUE DATA, IS BELIEVED TO BE TRUE AND CORRECT.
HOWEVER, THE ACCURACY OR COMPLETENESS OF THIS INFORMATION AND ANY RECOMMENDATIONS OR SUGGESTIONS
ARE MADE WI THOUT WARRANTY OR G UARANTEE. SINCE THE CONDITIONS OF USE ARE BEYOND THE CONTROL OF OUR
R TO DETERMINE THE CONDITIO NS OF SAFE USE OF THIS PRODUCT
COMPANY, IT IS THE RESPONSABILITY OF
THE USE
BIBIELLE S.p.A. - Via Cuneo , 35 - 12040 Margarita (CN), Italy - Phone: +39 0171 793800
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