Page 1
Page: 1/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
·
1.1 Product identifier
·
Trade name: Electrocarb Black Silicon Carbide Grain
·
CAS number:
409-21-2
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture:
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Electro Abrasives LLC
701 Willet Road
Buffalo, NY 14218
Phone: (716) 822-2500
·
1.4 Emergency telephone number:
ChemTel Inc.
+1 (800)255-3924, +1 (813)248-0585
Industrial uses.
SECTION 2: Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
The product is not classified as hazardous according to OSHA GHS regulations within the United States.
The substance is not classified as hazardous according to the CLP regulation.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is not classified as hazardous according to OSHA GHS regulations within the United States.
This product does not have a classification according to the CLP regulation.
·
Hazard pictograms
·
Signal word
·
Hazard-determining components of labelling:
·
Hazard statements
·
Precautionary statements
·
Additional information:
Safety data sheet available on request.
·
NFPA ratings (scale 0 - 4)
000
Not Regulated
Health = 0
Fire = 0
Reactivity = 0
Not Regulated
Not applicable.
Not Regulated
Not Regulated.
(Cont'd. on page 2)
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Page 2
Page: 2/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
Electrocarb Black Silicon Carbide Grain
*0
Health = *0
0
Fire = 0
0
Reactivity = 0
* - Indicates a long term health hazard from repeated or prolonged exposures.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
There are no other hazards not otherwise classified that have been identified.
SECTION 3: Composition/information on ingredients
·
3.1 Substances
·
CAS No. Description
409-21-2 silicon carbide
SECTION 4: First aid measures
·
4.1 Description of first aid measures
·
General information:
·
After inhalation:
·
After skin contact:
Brush off loose particles from skin.
Clean with water and soap.
If skin irritation continues, consult a doctor.
·
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Gastric or intestinal disorders.
·
Hazards:
·
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
No further relevant information available.
No special measures required.
Supply fresh air; consult doctor in case of complaints.
(Cont'd. from page 1)
SECTION 5: Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
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Use fire extinguishing methods suitable to surrounding conditions.
(Cont'd. on page 3)
Page 3
Page: 3/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
No further relevant information available.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information:
Electrocarb Black Silicon Carbide Grain
None.
No further relevant information available.
SECTION 6: Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
·
6.2 Environmental precautions
·
6.3 Methods and material for containment and cleaning up
Pick up mechanically.
Send for recovery or disposal in suitable receptacles.
Dispose contaminated material as waste according to section 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
No special measures required.
(Cont'd. from page 2)
SECTION 7: Handling and storage
·
7.1 Precautions for safe handling
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
·
Information about storage in one common storage facility:
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
No special measures required.
No special measures required.
No special requirements.
No special requirements.
No further relevant information available.
(Cont'd. on page 4)
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Page 4
Page: 4/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
Electrocarb Black Silicon Carbide Grain
(Cont'd. from page 3)
SECTION 8: Exposure controls/personal protection
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
409-21-2 silicon carbide
PEL (USA) Long-term value: 15* 5** mg/m³
fibrous dust: *total dust **respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV (USA) Long-term value: 10* 3** mg/m³
fibrous dust:0,1 f/cc; nonfibrous:*inh.,**resp.
EL (Canada) Long-term value: 10* 3** mg/m³
*inhalable;**respirable
EV (Canada) Long-term value: 10* 3** mg/m³, 0,1f/cc*** ppm
nonfibrous: *inh.,**resp.; ***fibrous, resp.
·
DNELs:
·
PNECs:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Avoid contact with the eyes.
Avoid close or long term contact with the skin.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device in case of insufficient ventilation.
·
Protection of hands:
Wear gloves for the protection against mechanical hazards according to NIOSH or EN 388.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
·
Eye protection:
No further relevant information available.
No further relevant information available.
Safety glasses
·
Body protection:
Not required under normal conditions of use.
Protection may be required for spills.
·
Limitation and supervision of exposure into the environment:
·
Risk management measures:
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No special requirements.
No special requirements.
(Cont'd. on page 5)
Page 5
Page: 5/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
Electrocarb Black Silicon Carbide Grain
SECTION 9: Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
Appearance
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Melting point/Melting range:
·
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits
Lower:
Upper:
·
Vapour pressure:
·
Density at 20 °C (68 °F):
·
Relative density:
·
Vapour density:
·
Evaporation rate:
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity
Dynamic:
Kinematic:
·
9.2 Other information
Granulate
Black
Odourless
Not determined.
Neutral
Not determined.
Not determined.
Not applicable.
Product is not flammable.
Not determined.
4712 °F / 2600 °C (8514 °F / 4712 °F) (Sublimation)
Not determined.
Product does not present an explosion hazard.
Not determined.
Not determined.
Not applicable.
3,20 g/cm³ (26,704 lbs/gal)
Not determined.
Not applicable.
Not applicable.
Insoluble.
Not determined.
Not applicable.
Not applicable.
No further relevant information available.
(Cont'd. from page 4)
SECTION 10: Stability and reactivity
·
10.1 Reactivity
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No further relevant information available.
(Cont'd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
Avoid extreme heat.
To avoid thermal decomposition do not overheat.
·
10.3 Possibility of hazardous reactions
·
10.4 Conditions to avoid
·
10.5 Incompatible materials
·
10.6 Hazardous decomposition products
Electrocarb Black Silicon Carbide Grain
No dangerous reactions known.
Excessive heat and contact with oxidizers.
No further relevant information available.
Carbon monoxide and carbon dioxide
SECTION 11: Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
·
Primary irritant effect
·
Skin corrosion/irritation:
·
Serious eye damage/irritation:
·
Respiratory or skin sensitisation:
·
Carcinogenic categories
·
IARC (International Agency for Research on Cancer):
Substance is not listed.
·
NTP (National Toxicology Program):
Substance is not listed.
·
OSHA-Ca (Occupational Safety & Health Administration):
Substance is not listed.
·
Germ cell mutagenicity:
·
Carcinogenicity:
·
Reproductive toxicity:
·
STOT-single exposure:
·
STOT-repeated exposure:
·
Aspiration hazard:
Based on available data, the classification criteria are not met.
None.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
(Cont'd. from page 5)
SECTION 12: Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
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Generally not hazardous for water
No further relevant information available.
Does not accumulate in organisms.
No further relevant information available.
(Cont'd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
·
Additional ecological information:
·
General notes:
Negative ecological effects are, according to the current state of knowledge, not expected.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
·
vPvB:
·
12.6 Other adverse effects
Electrocarb Black Silicon Carbide Grain
(Cont'd. from page 6)
Not applicable.
Not applicable.
No further relevant information available.
SECTION 13: Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Smaller quantities can be disposed of with household waste.
Can be reused after reprocessing.
Contact waste processors for recycling information.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous.
·
Uncleaned packaging:
·
Recommendation:
Disposal must be made according to official regulations.
SECTION 14: Transport information
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
Not Regulated
Not Regulated
Not Regulated
Not Regulated
No
Not applicable.
(Cont'd. on page 8)
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Page 8
Page: 8/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
·
14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code
Electrocarb Black Silicon Carbide Grain
(Cont'd. from page 7)
Not applicable.
SECTION 15: Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
Substance is not listed.
·
Section 313 (Specific toxic chemical listings):
Substance is not listed.
·
TSCA (Toxic Substances Control Act):
Substance is listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
·
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
·
Chemicals known to cause developmental toxicity:
Substance is not listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
Substance is not listed.
·
IARC (International Agency for Research on Cancer)
Substance is not listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
Substance is listed.
(Cont'd. on page 9)
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Page: 9/9
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and OSHA
GHS
Printing date: 11.04.2016 Revision: 11.04.2016
Trade name:
·
Other regulations, limitations and prohibitive regulations
·
Substances of very high concern (SVHC) according to REACH, Article 57
Electrocarb Black Silicon Carbide Grain
(Cont'd. from page 8)
Substance is not listed.
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Abbreviations and acronyms:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
·
Sources
Website, European Chemicals Agency (echa.europa.eu)
Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/
overview/home.do)
Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org)
Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: ISBN: 978-0-470-07488-6
Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN:
978-0-07-176923-5.
Safety Data Sheets, Individual Manufacturers
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
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