Ajax 14278 User Manual

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

Product name

:

AJAX CLEANER POWDER-OXYGEN BLEACH

Product code

:

200000017621

Company

:

Colgate-Palmolive Co

Telephone

Emergency telephone

:

For emergencies involving spill, leak, fire, exposure or acci-

Medical Emergency
(24HR):

For MEDICAL EMERGENCIES involving this product call:
[phone]

Recommended use

:

A formulated multi-purpose cleaner

Appearance

powder

Colour

off-white

Acute toxicity (Inhalation)

:

Category 4

Hazard pictograms

:

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

: B01809190000

Manufacturer or supplier's detai ls

Commerical Consumer Group
191 East Hanover Avenue
Morristown, NJ 07960-3151

: US: Consumer Affairs - 1-800-468-6502

number

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS Label element

dent call CHEMTREC (24hr) at [phone] or
[phone].

Signal word
Hazard statements

: Warning
: H332 Harmful if inhaled.

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

Prevention:

Inhalation

:

May be harmful if inhaled.

Skin :

May cause skin irritation upon prolonged contact.

Eyes

:

Causes eye irritation on direct contact.

Ingestion

:

May be harmful if swallowed in large quantities.

Aggravated Medical Condi-

:

None known.

IARC

No component of this product present at levels greater than or

ACGIH

No component of this product present at levels greater than or

OSHA

No component of this product present at levels greater than or

NTP

No component of this product present at levels greater than or

Chemical Name

CAS-No.

Concentration (%)

LIMESTONE

1317-65-3

>= 90

- <= 100

SODIUM CARBONATE

497-19-8

>= 5

- < 10

If inhaled

:

Remove victim to fresh air. Get medical attention, if symp-

Precautionary statements

Potential Health Effects

tion

:

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P271 Use only outdoors or in a well-ventilated area.

Response:

P304 + P340 + P312 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing. Call a
POISON CENTER or doctor/ physician if you feel unwell.

Carcinogenicity:

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

equal to 0.1% is identified as a carcinogen or potential carcino­gen by ACGIH.

equal to 0.1% is identified as a carcinogen or potential carcino­gen by OSHA.

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

SECTION 4. FIRST AID MEASURES

toms persist.

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

:

In case of eye contact

:

Flush eyes with water at least 15 minutes. Get medical atten-

:

:

Suitable extinguishing media

:

Use water spray, alcohol-resistant foam, dry chemical or car-

Hazardous combustion prod-

:

No hazardous combustion products are known

Special protective equipment

:

Self-contained breathing apparatus and full protective clothing

:

Methods and materials for

:

Cover with inert, absorbent material and remove to disposal
Conditions for safe storage

:

Store at controlled room temperature at 20-25°C (68-77°F).

Components

CAS-No.

Value type
exposure)

Control parame­concentration

Basis
pirable)

TWA (total)

10 mg/m3

NIOSH REL

pirable)

In case of skin contact

Flush skin with large amounts of water. If irritation develops
and persists, get medical attention.

If swallowed
Most important symptoms

and effects, both acute and
delayed

SECTION 5. FIREFIGHTING MEASURES

ucts

for firefighters

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec­tive equipment and emer­gency procedures

tion if eye irritation develops or persists.
Drink 8 ounces of clear water. Get medical attention.
Harmful if inhaled.

bon dioxide.

should be worn when fighting chemical fires.

Use personal protection recommended in Section 8 of the
SDS.

containment and cleaning up

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONT RO L S/PERSONAL PROT ECTION

Components with workplace control parameters

LIMESTONE 1317-65-3 TWA (Res-

TWA (Res-

container. Spill area ma y be slipper y. Flush with ple nt y of wa­ter.

(Form of

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ters / Permissible
5 mg/m3 NIOSH REL

5 mg/m3 NIOSH REL

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

TWA (total)

10 mg/m3

NIOSH REL

TWA (total
dust)

15 mg/m3

OSHA Z-1
able fraction)

TWA (Total
dust)

15 mg/m3

OSHA P0

TWA (respir-

5 mg/m3

OSHA P0

Engineering measures

:

In an industrial work environment, no special precautions or

Respiratory protection

:

General and local exhaust ventilation is recommended to

Protective measures

:

In an industrial work environment, if a splash is likely, chemi­Hygiene measures

:

In an industrial work environment, avoid eye and prolonged

:

:

pH

:

10.4

:

:

TWA (respir-

able dust
fraction)

control measures are required.

Personal protective equipment

maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are un­known, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any hazard­ous chemical is limited. Use a positive pressure air supplied
respirator if there is any potential for uncontrolled release,
exposure levels are unknown, or any other circumstance
where air purifying respirators may not provide adequate
protection.

5 mg/m3 OSHA Z-1

SECTION 9. PHYSI CAL AND CHEMIC AL PRO PER TIES

Appearance
Colour

Flash point
Density

SECTION 10. STABILITY AND REACTIVITY

cal goggles may be needed. Prolonged skin contact may
require protective gloves. For consumer use, no unusual
precautions are necessary.

skin contact.

powder
off-white

No data available

1.04 g/cm3

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

:

Incompatible materials

:

Strong oxidizing agents

Hazardous decomposition

:

None known.

Acute oral toxicity

:

Acute toxicity estimate : > 5,000 mg/kg

Acute inhalation toxicity

:

Acute toxicity estimate : 1.63 mg/l
Acute oral toxicity

:

LD50 (Rat): > 2,000 mg/kg

Acute inhalation toxicity

:

LC50 (Rabbit): > 3 mg/l
Acute dermal toxicity

:

LD50 (Rat): > 2,000 mg/kg
Acute oral toxicity

:

LD50 (Rat): 2,800 mg/kg

Acute inhalation toxicity

:

LC50 (Rabbit): 2.3 mg/l
Acute dermal toxicity

:

LD50 (Rabbit): > 2,000 mg/kg

Possibility of hazardous reac­tions

Hazardous polymerisation does not occur.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Harmful if inhaled.

Product:

Components:
LIMESTONE:

Method: Calculation method

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Method: OECD Test Guideline 420

Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403

SODIUM CARBONATE:

Skin corrosion/irritation

Not classified based on available information.

Components:
LIMESTONE:

Method: OECD Test Guideline 402

Exposure time: 2 h
Test atmosphere: No information available.
Method: No information available.

Method: No information available.

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

Remarks: No data available

Result: No eye irritation

Exposure routes: Inhalation

Exposure routes: Dermal

Exposure routes: Dermal

Result: No skin irritation

SODIUM CARBONATE:

Serious eye damage/eye irritation

Not classified based on available information.

Components:
LIMESTONE:

SODIUM CARBONATE:

Result: Irritation to eyes, reversing within 21 days

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.

Components:
LIMESTONE:

Result: Does not cause respiratory sensitisation.

Result: Does not cause skin sensitisation.

SODIUM CARBONATE:

Exposure routes: Inhalation
Remarks: No data available

Remarks: No data available

Germ cell mutagenicity

Not classified based on available information.

Carcinogenicity

Not classified based on available information.

Reproductive toxicity

Not classified based on available information.

STOT - single exposure

Not classified based on available information.

STOT - repeated exposure

Not classified based on available information.

Aspiration toxicity

Not classified based on available information.

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NA

AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

Waste from residues

:

Any disposal practice must be in compliance with local, state

DOT

:

Not regulated.

TDG

:

Not regulated.

IATA

:

Not regulated.

IMDG

:

Not regulated.

Further information
Product:

Remarks: This product has not been tested as a whole. However, this formula was reviewed by
expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is
determined to be safe for its intended use. This review has taken into consideration available
safety-related information including information on individual ingredients, similar formulas and
potential ingredient interactions. This review is a component of the hazard determination used to
prepare the statements in Section 3 of the SDS.

SECTION 12. ECOLOGICAL INFORMATION

The product has not been tested as a whole for environmental toxicity. However, environmental
information on the ingredients in this product have been reviewed by the Environmental, Health and
Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This
evaluation is based on available information on individual ingredients, interactions of ingredients,
and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants
are biodegradable) or testing conducted on the final product (i.e., This product is biodegradable).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

and federal laws and regulations (contact local or state envi­ronment agency for specific rules). Do not dump in sewers,
any body of water or on the ground.

SECTION 14. TRANSPORT INFORMATION

International Regulation
Transport in bulk according to An n ex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

National Regulations

SECTION 15. REGULATORY INFORMATION

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

OSHA Hazards

(lbs)

(lbs)

SODIUM DODECYL BENZENE
SULFONATE

25155-30-0

1000

*

(lbs)

(lbs)

SULFUR DIOXIDE

7446-09-5

500

*

SARA 311/312 Hazards

:

Acute Health Hazard

SARA 302

:

No chemicals in this material are subject to the reporting re-

SARA 313

SODIUM DODECYL
SULFONATE

25155-30-0

Sulfuric Acid

SULFURIC ACID

SODIUM DODECYL
SULFONATE

25155-30-0

Sulfuric Acid

SULFURIC ACID

: Combustible dust, Moderate skin irritant, Severe eye irritant

EPCRA - Emergency Planning and Community Right-to-Kn ow Act
CERCLA Reportable Quantity

Components CAS-No. Component RQ

*: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Su bst ance s Reportable Quantity

Components CAS-No. Component RQ

*: Calculated RQ exceeds reasonably attainable upper limit.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean
Air Act Section 12 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111
SOCMI Intermediate or Final VOC's (40 CFR 60.489).

quirements of SARA Title III, Section 302.

: This material does not contain any chemical components with

known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

Calculated product RQ

Calculated product RQ

Clean Water Act

The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta­ble 116.4A:

BENZENE

The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table

117.3:
BENZENE

This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section
307

Massachusetts Right To Know

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AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

SODIUM DODECYL BENZENE
SULFONATE

25155-30-0

Sulfuric Acid

SULFURIC
ACID

SULFUR DIOXIDE

7446-09-5

SODIUM CARBONATE

497-19-8

SODIUM DODECYL BENZENE
SULFONATE

25155-30-0

Sulfuric Acid

SULFURIC
ACID

SULFUR DIOXIDE

7446-09-5

SODIUM SULFATE

7757-82-6

LIMESTONE

1317-65-3

SODIUM CARBONATE

497-19-8

SODIUM DODECYL BENZENE
SULFONATE

25155-30-0

California Prop 65

:

This product does not contain any chemicals known to State
productive harm.

TSCA

:

All ingredients in this product are listed on the TSCA Inventory

Pennsylvania Right To Know

New Jersey Right To Know

LIMESTONE 1317-65-3

LIMESTONE 1317-65-3

of California to cause cancer, birth defects, or any other re-

The components of this product are reported in the following inventories:

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

or are not required to be listed on the TSCA Inventory.

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NA

AJAX CLEANER POWDER-OXYGEN BLEACH

This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the
product. For information regarding consum er app lic ations of this product, refer to the product label.

Version 1.1

SDS Number: 660000000222

Revision Date: 05/14/2015

NFPA:

HMIS III:

Flammability

Health

2

0

0

PHYSICAL HAZARD

HEALTH

0

0

2

0 = not significant, 1 =Slight,

SECTION 16. OTHER INFORMATION

Further information

Disclaimer: The information on this sheet is limited to the material identified and is believed by
the Colgate-Palmolive Company to be correct based on its knowledge and information as of
the date noted. Colgate makes no representation, guarantee or warranty, expressed or im­plied, as to the accuracy, reliability or completeness of the information and assumes no re­sponsibility for injury, damage or loss resulting from the use of the material.

Special hazard.

Instability

FLAMMABILITY

2 = Moderate, 3 = High
4 = Extreme, * = Chronic

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