Agilent ESI-L DATA SHEET

SAFETY DATA SHEET

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 1: Identification of the substance/mixture and of the company/ undertaking

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Product name

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

e-mail address of person responsible for this SDS

pdl-msds_author@agilent.com

1.2 Relevant identified uses of the substance or mixture and uses advised against

Part no.

G1969-85000

1.4 Emergency telephone number

Emergency telephone number (with hours of operation)

CHEMTREC®: +(44)-870-8200418

Agilent Technologies Manufacturing GmbH & Co. KG Hewlett-Packard-Str. 8 76337 Waldbronn Germany 0800 603 1000

Reagents and Standards for Analytical Chemistry Laboratory Use 1 x 100 mL

Material uses

SECTION 2: Hazards identification

See Section 11 for more detailed information on health effects and symptoms.

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

2.1 Classification of the substance or mixture

Product definition

Mixture

See Section 16 for the full text of the H statements declared above.

2.2 Label elements

Hazard pictograms

Signal word

Hazard statements

Precautionary statements

Danger

H225 - Highly flammable liquid and vapour. H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation.

H225

FLAMMABLE LIQUIDS

Category 2

H302

ACUTE TOXICITY (oral)

Category 4

H312

ACUTE TOXICITY (dermal)

Category 4

H332

ACUTE TOXICITY (inhalation)

Category 4

H319

SERIOUS EYE DAMAGE/EYE IRRITATION

Category 2

Date of issue/Date of revision

1/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 2: Hazards identification

Other hazards which do not result in classification

None known.

Prevention

Response

Storage

Disposal

P280 - Wear protective gloves and protective clothing. Wear eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product.

P304 + P312 - IF INHALED: Call a POISON CENTER or doctor if you feel unwell.

Not applicable.

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Tactile warning of danger

Not applicable.

Special packaging requirements

Hazardous ingredients

2.3 Other hazards

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

Not applicable.

- acetonitrile

Product meets the criteria for PBT or vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Mixture

[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern [6] Additional disclosure due to company policy

Type

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

Product/ingredient name

Acetonitrile

EC: 200-835-2 CAS: 75-05-8 Index: 608-001-00-3

≥90

Flam. Liq. 2, H225 Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Eye Irrit. 2, H319

[1] [2]

Identifiers

Type

Regulation (EC) No. 1272/2008

[CLP]

See Section 16 for the full text of the H statements declared above.

Date of issue/Date of revision

2/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 4: First aid measures

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.

4.1 Description of first aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Notes to physician

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Ingestion

Inhalation

Eye contact

: :

Specific treatments

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Inhalation

Harmful if inhaled.

Harmful if swallowed.

Ingestion

Skin contact

Harmful in contact with skin.

Causes serious eye irritation.

Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

No specific data.

:::

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.

Date of issue/Date of revision

3/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 5: Firefighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous combustion products

Hazards from the substance or mixture

Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides cyanides

Highly flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapour/gas is heavier than air and will spread along the ground. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Special protective equipment for firefighters

Use dry chemical,

CO₂,

water spray (fog) or foam.

5.1 Extinguishing media

:::

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special precautions for fire-fighters

SECTION 6: Accidental release measures

6.2 Environmental precautions

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Methods for cleaning up

6.3 Methods and material for containment and cleaning up

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

For emergency responders

6.4 Reference to other sections

See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Date of issue/Date of revision

4/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 7: Handling and storage

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

7.1 Precautions for safe handling

Protective measures

Advice on general occupational hygiene

7.2 Conditions for safe storage, including any incompatibilities

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

7.3 Specific end use(s)

Recommendations

Industrial sector specific solutions

Not available. Industrial applications, Professional applications.

Seveso Directive - Reporting thresholds

Danger criteria

Category

P5c

5000 tonne

50000 tonne

Notification and MAPP threshold

Safety report threshold

Storage

SECTION 8: Exposure controls/personal protection

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace

8.1 Control parameters

Occupational exposure limits

Product/ingredient name

Exposure limit values

Acetonitrile

EH40/2005 WELs (United Kingdom (UK), 1/2020).

STEL: 102 mg/m³ 15 minutes. STEL: 60 ppm 15 minutes. TWA: 40 ppm 8 hours. TWA: 68 mg/m³ 8 hours.

Date of issue/Date of revision

5/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 8: Exposure controls/personal protection

atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Hand protection

When used as intended, use of the product is not expected to result in direct contact with the chemical. However, in case of accidental contact with splash wear good quality:

Glove material: Butyl rubber Glove thickness: ≥ 0.2 mm Breakthrough time: >30 minutes

While not recommended, if typical disposable laboratory nitrile gloves are used, they need to be removed immediately if contacted with the mixture. When contacted with acetonitrile, typical laboratory nitrile gloves have very short breakthrough times, considerably less than 10 minutes.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Skin protection

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

8.2 Exposure controls

Hygiene measures

Acetonitrile

DNEL

Short term Oral

0.6 mg/kg bw/day

General population

Systemic

DNEL

Long term Inhalation

4.8 mg/m³

General population

Local

DNEL

Long term Inhalation

4.8 mg/m³

General population

Systemic

DNEL

Short term Inhalation

22 mg/m³

General population

Local

DNEL

Long term Dermal

32.2 mg/kg bw/day

Workers

Systemic

DNEL

Short term Inhalation

68 mg/m³

Workers

Local

DNEL

Long term Inhalation

68 mg/m³

Workers

Local

DNEL

Short term Inhalation

68 mg/m³

Workers

Systemic

DNEL

Long term Inhalation

68 mg/m³

Workers

Systemic

DNEL

Short term Inhalation

220 mg/m³

General population

Systemic

Product/ingredient name

Exposure

Value

Population

Effects

PNECs

No PNECs available

DNELs/DMELs

Type

Individual protection measures

Date of issue/Date of revision

6/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 8: Exposure controls/personal protection

When used as intended with Agilent instruments, the use of the product under normal laboratory conditions and with standard practices does not result in significant airborne exposures, and, therefore, respiratory protection isn’t needed. In emergency situations, when a respirator is needed, use a full-face supplied air respirator and components tested and approved under appropriate government standards such as CEN (EU) or NIOSH (US).

Respiratory protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Refer to European Standard EN 1149 for further information on material and design requirements and test methods.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Body protection

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

SECTION 9: Physical and chemical properties

81.6°C

Physical state

Melting point/freezing point

Initial boiling point and boiling range

Vapour pressure

Relative density

Vapour density

Solubility(ies)

Liquid.

-45°C

Not available.

1.42 [Air = 1]

11.6 kPa [room temperature]

Soluble in the following materials: cold water and hot water.

Ether-like.

Odour

Clear. / Colourless.

Colour

Evaporation rate

5.79 (butyl acetate = 1)

Auto-ignition temperature

Flash point

524°C

Closed cup: 12.8°C

Lower: 4.4% Upper: 16%

Not available.

Not available. Not available.

Viscosity

Not available.

Odour threshold

Partition coefficient: noctanol/water

Upper/lower flammability or explosive limits

Explosive properties

:::::

: :

:::::

: :

Not available.

Oxidising properties

9.1 Information on basic physical and chemical properties

Appearance

9.2 Other information

Decomposition temperature

Not available.

Flammability (solid, gas)

Not applicable.

No additional information.

Date of issue/Date of revision

7/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 10: Stability and reactivity

10.6 Hazardous decomposition products

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapour to accumulate in low or confined areas.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.

10.2 Chemical stability

Reactive or incompatible with the following materials: metals, acids and alkalis.

: :

10.5 Incompatible materials

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.1 Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Reactive or incompatible with the following materials: oxidising materials

SECTION 11: Toxicological information

Acute toxicity

Acetonitrile

LC50 Inhalation Vapour

Rat

17100 ppm

4 hours

LD50 Oral

Rat

2460 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Carcinogenicity

Mutagenicity

Conclusion/Summary

Not available.

Irritation/Corrosion

Acetonitrile

Eyes - Moderate irritant

Rabbit

24 hours 100 uL

Skin - Mild irritant

Rabbit

500 mg

Product/ingredient name

Result

Score

Exposure

Observation

Sensitiser

Conclusion/Summary

Not available.

Species

11.1 Information on toxicological effects

Acute toxicity estimates

Conclusion/Summary

Not available.

Teratogenicity

Conclusion/Summary

Not available.

Reproductive toxicity

Conclusion/Summary

Not available.

Specific target organ toxicity (single exposure)

Not available.

Product/ingredient name

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

535.4

1177.8

N/A

11.8

N/A

Acetonitrile

500

1100

N/A11N/A

Oral (mg/

kg)

Dermal

(mg/kg)

Inhalation

(gases)

(ppm)

Inhalation

(vapours)

(mg/l)

Inhalation

(dusts

and mists)

(mg/l)

Date of issue/Date of revision

8/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 11: Toxicological information

Potential acute health effects

Routes of entry anticipated: Oral, Dermal, Inhalation.

Specific target organ toxicity (repeated exposure)

Aspiration hazard

Information on likely routes of exposure

Not available.

Potential chronic health effects

Inhalation

Harmful if inhaled.

Harmful if swallowed.

Ingestion

Skin contact

Harmful in contact with skin.

Causes serious eye irritation.

Eye contact

No known significant effects or critical hazards.

General

No known significant effects or critical hazards.

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

No specific data.

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Short term exposure

Long term exposure

Potential immediate effects

Potential delayed effects

Potential immediate effects

Potential delayed effects

Not available.

Other information

Adverse symptoms may include the following: May cause headache, weakness, dizziness, shortness of breath, cyanosis, rapid heart beat, unconsciousness and possible death.

No known significant effects or critical hazards.

Reproductive toxicity

SECTION 12: Ecological information

12.1 Toxicity

Acetonitrile

Acute IC50 3685000 μg/l Fresh water

Aquatic plants - Lemna minor

96 hours

Acute LC50 3600000 μg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 1000000 μg/l Fresh water

Fish - Pimephales promelas

96 hours

Chronic NOEC 1000000 μg/l Fresh water

Aquatic plants - Lemna minor

96 hours

Chronic NOEC 160000 μg/l Fresh water

Daphnia - Daphnia magna

21 days

Product/ingredient name

Species

Result

Exposure

12.2 Persistence and degradability

Date of issue/Date of revision

9/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 12: Ecological information

Mobility

Not available.

LogP

BCF

Potential

12.3 Bioaccumulative potential

12.6 Other adverse effects

No known significant effects or critical hazards.

Product/ingredient name

Acetonitrile

-0.34

low

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetonitrile

--Readily

Acetonitrile

OECD 310 Ready Biodegradability CO2 in Sealed Vessels (Headspace Test)

70 % - Readily - 21 days

Activated sludge

Product/ingredient name

Test

Dose

Result

Inoculum

12.4 Mobility in soil

Soil/water partition coefficient (KOC)

Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 13: Disposal considerations

The classification of the product may meet the criteria for a hazardous waste.

Hazardous waste

The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Methods of disposal

13.1 Waste treatment methods

Product

Packaging

Methods of disposal

Special precautions

The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible.

This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapour from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Date of issue/Date of revision

10/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 14: Transport information

14.6 Special precautions for user

Transport within user’s premises:

always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Hazard identification number

Limited quantity

1 L

Tunnel code

(D/E)

Emergency schedules

F-E, S-D

Additional information

Quantity limitation

Passenger and Cargo Aircraft: 5 L. Packaging instructions: 353. Cargo Aircraft Only: 60 L. Packaging instructions: 364. Limited Quantities - Passenger Aircraft: 1 L. Packaging instructions: Y341.

ADR/RID

IMDG

IATA

:::

ACETONITRILE solution 3

UN1648

ADR/RID

IMDG

IATA

14.1 UN number

14.2 UN proper shipping name

14.3 Transport hazard class(es)

14.4 Packing group

14.5 Environmental hazards

No.

No. UN1648

Acetonitrile solution 3

14.7 Transport in bulk according to IMO instruments

Not available.

SECTION 15: Regulatory information

Other EU regulations

Not applicable.

Label

Industrial emissions (integrated pollution prevention and control) Air

Listed

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)

Annex XIV - List of substances subject to authorisation

Substances of very high concern

None of the components are listed.

Annex XIV

None of the components are listed.

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

Date of issue/Date of revision

11/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 15: Regulatory information

Industrial emissions (integrated pollution prevention and control) Water

Listed

Seveso Directive

This product is controlled under the Seveso Directive.

Danger criteria

Agilent ESI-L DATA SHEET

Specifications and Main Features

Frequently Asked Questions

User Manual