Agilent ESI-L DATA SHEET

SAFETY DATA SHEET

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 1: Identification of the substance/mixture and of the company/ undertaking

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Product name

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

e-mail address of person responsible for this SDS

pdl-msds_author@agilent.com

1.2 Relevant identified uses of the substance or mixture and uses advised against

Part no.

G1969-85000

1.4 Emergency telephone number

Emergency telephone number (with hours of operation)

CHEMTREC®: +(44)-870-8200418

Agilent Technologies Manufacturing GmbH & Co. KG Hewlett-Packard-Str. 8 76337 Waldbronn Germany 0800 603 1000

Reagents and Standards for Analytical Chemistry Laboratory Use 1 x 100 mL

Material uses

SECTION 2: Hazards identification

See Section 11 for more detailed information on health effects and symptoms.

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

2.1 Classification of the substance or mixture

Product definition

Mixture

See Section 16 for the full text of the H statements declared above.

2.2 Label elements

Hazard pictograms

Signal word

Hazard statements

Precautionary statements

Danger

H225 - Highly flammable liquid and vapour. H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation.

H225

FLAMMABLE LIQUIDS

Category 2

H302

ACUTE TOXICITY (oral)

Category 4

H312

ACUTE TOXICITY (dermal)

Category 4

H332

ACUTE TOXICITY (inhalation)

Category 4

H319

SERIOUS EYE DAMAGE/EYE IRRITATION

Category 2

Date of issue/Date of revision

1/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 2: Hazards identification

Other hazards which do not result in classification

None known.

Prevention

Response

Storage

Disposal

P280 - Wear protective gloves and protective clothing. Wear eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product.

P304 + P312 - IF INHALED: Call a POISON CENTER or doctor if you feel unwell.

Not applicable.

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

Tactile warning of danger

Not applicable.

Special packaging requirements

Hazardous ingredients

2.3 Other hazards

Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles

Not applicable.

- acetonitrile

Product meets the criteria for PBT or vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Mixture

[1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern [6] Additional disclosure due to company policy

Type

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.

Product/ingredient name

Acetonitrile

EC: 200-835-2 CAS: 75-05-8 Index: 608-001-00-3

≥90

Flam. Liq. 2, H225 Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Eye Irrit. 2, H319

[1] [2]

Identifiers

Type

Regulation (EC) No. 1272/2008

[CLP]

See Section 16 for the full text of the H statements declared above.

Date of issue/Date of revision

2/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 4: First aid measures

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.

4.1 Description of first aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Notes to physician

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Ingestion

Inhalation

Eye contact

: :

Specific treatments

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

Potential acute health effects

Inhalation

Harmful if inhaled.

Harmful if swallowed.

Ingestion

Skin contact

Harmful in contact with skin.

Causes serious eye irritation.

Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

No specific data.

:::

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.

Date of issue/Date of revision

3/13

05/02/2021

Date of previous issue

02/01/2020

Version

ESI-L Low Concentration Tuning Mix, Part Number G1969-85000

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 - United Kingdom (UK)

SECTION 5: Firefighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous combustion products

Hazards from the substance or mixture

Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides cyanides

Highly flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapour/gas is heavier than air and will spread along the ground. Vapours may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Special protective equipment for firefighters

Use dry chemical,

CO₂,

water spray (fog) or foam.

5.1 Extinguishing media

:::

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special precautions for fire-fighters

SECTION 6: Accidental release measures

6.2 Environmental precautions

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Methods for cleaning up

6.3 Methods and material for containment and cleaning up

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

For emergency responders

6.4 Reference to other sections

See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Date of issue/Date of revision

4/13

05/02/2021

Date of previous issue

02/01/2020

Version

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