EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
1.3 Details of the supplier of the safety data sheet
e-mail address of person
responsible for this SDS
pdl-msds_author@agilent.com
1.2 Relevant identified uses of the substance or mixture and uses advised against
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
1.4 Emergency telephone number
Emergency telephone
number (with hours of
operation)
CHEMTREC®: +(44)-870-8200418
Agilent Technologies Manufacturing GmbH & Co. KG
Hewlett-Packard-Str. 8
76337 Waldbronn
Germany
0800 603 1000
Reagents and Standards for Analytical Chemistry Laboratory Use
EN12916:2006 IP391-07 Sys. Cal. Std. 1
EN12916:2006 IP391-07 Sys. Cal. Std. 2
SECTION 2: Hazards identification
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
2.1 Classification of the substance or mixture
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
EN12916:2006
IP391-07 Sys. Cal.
Std. 1
SKIN CORROSION/IRRITATION
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Narcotic effects)
SHORT-TERM (ACUTE) AQUATIC HAZARD
LONG-TERM (CHRONIC) AQUATIC HAZARD
EN12916:2006
IP391-07 Sys. Cal.
Std. 2
SKIN CORROSION/IRRITATION
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
Category 3
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 2: Hazards identification
See Section 11 for more detailed information on health effects and symptoms.
See Section 16 for the full text of the H statements declared above.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
EN12916:2006 IP391-07
Sys. Cal. Std. 1
H225 - Highly flammable liquid and vapour.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H336 - May cause drowsiness or dizziness.
H410 - Very toxic to aquatic life with long lasting effects.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
H225 - Highly flammable liquid and vapour.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H336 - May cause drowsiness or dizziness.
H410 - Very toxic to aquatic life with long lasting effects.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
P210 - Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P273 - Avoid release to the environment.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
P210 - Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking.
P273 - Avoid release to the environment.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
P301 + P310 - IF SWALLOWED: Immediately call a
POISON CENTER or doctor.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
P301 + P310 - IF SWALLOWED: Immediately call a
POISON CENTER or doctor.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
P403 + P233 - Store in a well-ventilated place. Keep
container tightly closed.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
P403 + P233 - Store in a well-ventilated place. Keep
container tightly closed.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
P501 - Dispose of contents and container in accordance
with all local, regional, national and international regulations.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
P501 - Dispose of contents and container in accordance
with all local, regional, national and international regulations.
SHORT-TERM (ACUTE) AQUATIC HAZARD
LONG-TERM (CHRONIC) AQUATIC HAZARD
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 2: Hazards identification
Other hazards which do
not result in
classification
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Supplemental label
elements
Tactile warning of
danger
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Special packaging requirements
Annex XVII - Restrictions
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Product meets the
criteria for PBT or vPvB
according to
Regulation (EC) No.
1907/2006, Annex XIII
EN12916:2006 IP391-07
Sys. Cal. Std. 1
This mixture does not contain any substances that are
assessed to be a PBT or a vPvB.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
This mixture does not contain any substances that are
assessed to be a PBT or a vPvB.
SECTION 3: Composition/information on ingredients
EN12916:2006 IP391-07 Sys. Cal.
Std. 1
EN12916:2006 IP391-07 Sys. Cal.
Std. 2
EN12916:2006 IP391-07 Sys. Cal.
Std. 1
EC: 205-563-8
CAS: 142-82-5
Index: 601-008-00-2
Flam. Liq. 2, H225
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 1, H410 (M=1)
EC: 203-806-2
CAS: 110-82-7
Index: 601-017-00-1
Flam. Liq. 2, H225
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 1, H410 (M=1)
EC: 202-049-5
CAS: 91-20-3
Index: 601-052-00-2
Acute Tox. 4, H302
Carc. 2, H351
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 1, H410 (M=1)
EN12916:2006 IP391-07 Sys. Cal.
Regulation (EC) No. 1272/2008
[CLP]
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 3: Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
EC: 205-563-8
CAS: 142-82-5
Index: 601-008-00-2
Flam. Liq. 2, H225
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 1, H410 (M=1)
See Section 16 for the full text
of the H statements declared
above.
SECTION 4: First aid measures
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Immediately flush eyes with plenty of water, occasionally
lifting the upper and lower eyelids. Check for and remove
any contact lenses. Continue to rinse for at least 10 minutes.
Get medical attention.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Immediately flush eyes with plenty of water, occasionally
lifting the upper and lower eyelids. Check for and remove
any contact lenses. Continue to rinse for at least 10 minutes.
Get medical attention.
4.1 Description of first aid measures
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If it is suspected that fumes are
still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-tomouth resuscitation. Get medical attention. If necessary,
call a poison center or physician. If unconscious, place in
recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If it is suspected that fumes are
still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-tomouth resuscitation. Get medical attention. If necessary,
call a poison center or physician. If unconscious, place in
recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 4: First aid measures
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Get medical attention immediately. Call a poison center or
physician. Wash out mouth with water. Remove dentures if
any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small
quantities of water to drink. Stop if the exposed person feels
sick as vomiting may be dangerous. Aspiration hazard if
swallowed. Can enter lungs and cause damage. Do not
induce vomiting. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Never give
anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Get medical attention immediately. Call a poison center or
physician. Wash out mouth with water. Remove dentures if
any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small
quantities of water to drink. Stop if the exposed person feels
sick as vomiting may be dangerous. Aspiration hazard if
swallowed. Can enter lungs and cause damage. Do not
induce vomiting. If vomiting occurs, the head should be kept
low so that vomit does not enter the lungs. Never give
anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Continue to rinse for at
least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Continue to rinse for at
least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Protection of first-aiders
EN12916:2006 IP391-07
Sys. Cal. Std. 1
No action shall be taken involving any personal risk or
without suitable training. If it is suspected that fumes are
still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. It may be dangerous
to the person providing aid to give mouth-to-mouth
resuscitation.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
No action shall be taken involving any personal risk or
without suitable training. If it is suspected that fumes are
still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. It may be dangerous
to the person providing aid to give mouth-to-mouth
resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Can cause central nervous system (CNS) depression. May
cause drowsiness or dizziness.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Can cause central nervous system (CNS) depression. May
cause drowsiness or dizziness.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
No known significant effects or critical hazards.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
No known significant effects or critical hazards.
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 4: First aid measures
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Can cause central nervous system (CNS) depression. May
be fatal if swallowed and enters airways.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Can cause central nervous system (CNS) depression. May
be fatal if swallowed and enters airways.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Over-exposure signs/symptoms
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Adverse symptoms may include the following:
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Adverse symptoms may include the following:
4.3 Indication of any immediate medical attention and special treatment needed
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 5: Firefighting measures
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Promptly isolate the scene by removing all persons from the
vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training.
Move containers from fire area if this can be done without
risk. Use water spray to keep fire-exposed containers cool.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Promptly isolate the scene by removing all persons from the
vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training.
Move containers from fire area if this can be done without
risk. Use water spray to keep fire-exposed containers cool.
Hazardous combustion
products
Hazards from the
substance or mixture
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Decomposition products may include the following materials:
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Decomposition products may include the following materials:
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Highly flammable liquid and vapour. Runoff to sewer may
create fire or explosion hazard. In a fire or if heated, a
pressure increase will occur and the container may burst,
with the risk of a subsequent explosion. The vapour/gas is
heavier than air and will spread along the ground. Vapours
may accumulate in low or confined areas or travel a
considerable distance to a source of ignition and flash back.
This material is very toxic to aquatic life with long lasting
effects. Fire water contaminated with this material must be
contained and prevented from being discharged to any
waterway, sewer or drain.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Highly flammable liquid and vapour. Runoff to sewer may
create fire or explosion hazard. In a fire or if heated, a
pressure increase will occur and the container may burst,
with the risk of a subsequent explosion. The vapour/gas is
heavier than air and will spread along the ground. Vapours
may accumulate in low or confined areas or travel a
considerable distance to a source of ignition and flash back.
This material is very toxic to aquatic life with long lasting
effects. Fire water contaminated with this material must be
contained and prevented from being discharged to any
waterway, sewer or drain.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Use dry chemical,
CO₂,
water spray (fog) or foam.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Use dry chemical,
CO₂,
water spray (fog) or foam.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Suitable extinguishing
media
Unsuitable extinguishing
media
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Special precautions for
fire-fighters
Date of issue/Date of revision
EN12916:2006 IP391-07 Sys. Cal. Std. 1,2, Part Number 5190-0485
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830 - United Kingdom (UK)
SECTION 5: Firefighting measures
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Fire-fighters should wear appropriate protective equipment
and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode. Clothing for
fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Fire-fighters should wear appropriate protective equipment
and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode. Clothing for
fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
Special protective
equipment for firefighters
SECTION 6: Accidental release measures
6.2 Environmental
precautions
EN12916:2006 IP391-07
Sys. Cal. Std. 1
Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large
quantities. Collect spillage.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Water polluting material.
May be harmful to the environment if released in large
quantities. Collect spillage.
6.3 Methods and material for containment and cleaning up
6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency
personnel
EN12916:2006 IP391-07
Sys. Cal. Std. 1
No action shall be taken involving any personal risk or
without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering.
Do not touch or walk through spilt material. Shut off all
ignition sources. No flares, smoking or flames in hazard
area. Avoid breathing vapour or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective
equipment.
EN12916:2006 IP391-07
Sys. Cal. Std. 2
No action shall be taken involving any personal risk or
without suitable training. Evacuate surrounding areas.
Keep unnecessary and unprotected personnel from entering.
Do not touch or walk through spilt material. Shut off all
ignition sources. No flares, smoking or flames in hazard
area. Avoid breathing vapour or mist. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective
equipment.
EN12916:2006 IP391-07
Sys. Cal. Std. 1
If specialised clothing is required to deal with the spillage,
take note of any information in Section 8 on suitable and
unsuitable materials. See also the information in "For nonemergency personnel".
EN12916:2006 IP391-07
Sys. Cal. Std. 2
If specialised clothing is required to deal with the spillage,
take note of any information in Section 8 on suitable and
unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision