3M™ Concrete Repair Horizontal, Gray 12/30/15
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Page 1 of 2
Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
19-0351-7
Version Number:
2.01
Issue Date:
12/30/15
Supercedes Date:
04/16/15
Product identifier
3M™ Concrete Repair Horizontal, Gray
ID Number(s):
62-2649-1222-1, 62-2649-1233-8
Recommended use
Industrial use
Supplier's details
MANUFACTURER:
3M
DIVISION:
Industrial Adhesives and Tapes Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:
19-0350-9, 19-0349-1
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M
3M USA SDSs are available at www.3M.com
3M™ Concrete Repair Horizontal, Gray 12/30/15
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Page 2 of 2
3M™ Concrete Repair Horizontal Gray, Part B 04/16/15
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Page 1 of 10
Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
19-0349-1
Version Number:
5.00
Issue Date:
04/16/15
Supercedes Date:
07/01/11
SECTION 1: Identification
1.1. Product identifier
3M™ Concrete Repair Horizontal Gray, Part B
1.2. Recommended use and restrictions on use
Recommended use
Structural adhesive
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Industrial Adhesives and Tapes Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2B.
Skin Sensitizer: Category 1A.
2.2. Label elements
Signal word
Warning
Symbols
Exclamation mark |
Pictograms
Hazard Statements
3M™ Concrete Repair Horizontal Gray, Part B 04/16/15
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Causes eye irritation.
May cause an allergic skin reaction.
Precautionary Statements
Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Polyether Polyol 9082-00-2 40 - 70 Trade Secret *
Tetrakis(2-hydroxypropyl)ethylenediamine 102-60-3 10 - 30 Trade Secret *
Propoxylated Trimethylolpropane 25723-16-4 10 - 30 Trade Secret *
Amorphous Silica 68611-44-9 1 - 5 Trade Secret *
m-Xylene-.alpha.alpha'.-diamine 1477-55-0 <= 0.5 Trade Secret *
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate 41556-26-7 <= 0.5 Trade Secret *
Polymeric Benzotriazole 104810-48-2 <= 0.5 Trade Secret *
Polymeric Benzotriazole 104810-47-1 <= 0.5 Trade Secret *
Substituted Piperydinyl Sebacate 82919-37-7 <= 0.2 Trade Secret *
*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
3M™ Concrete Repair Horizontal Gray, Part B 04/16/15
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medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Chloride During Combustion
Oxides of Nitrogen During Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
3M™ Concrete Repair Horizontal Gray, Part B 04/16/15
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when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing
agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidizing agents.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
m-Xylene-.alpha.alpha'.-diamine 1477-55-0 ACGIH CEIL:0.1 mg/m3 Skin Notation
Bis(1,2,2,6,6-pentamethyl-4piperidinyl) sebacate
41556-26-7 CMRG TWA:1 mg/m3
SILICA, AMORPHOUS 68611-44-9 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Substituted Piperydinyl Sebacate 82919-37-7 CMRG TWA:1 mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Fluoroelastomer
Neoprene
Respiratory protection
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An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Liquid
Specific Physical Form:
Viscous
Odor, Color, Grade:
Slight ammonia like odor, gray.
Odor threshold
No Data Available
pH
Not Applicable
Melting point
No Data Available
Boiling Point
>=400 ºF
Flash Point
>=290 ºF [Test Method: Tagliabue Closed Cup]
Evaporation rate
<=1 [Ref Std: WATER=1]
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
Not Applicable
Vapor Density
>=1 [Ref Std: AIR=1]
Density
1.04 g/ml
Specific Gravity
1.04 [Ref Std: WATER=1]
Solubility in Water
Negligible
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
Not Applicable
Decomposition temperature
No Data Available
Viscosity
3,200 - 5,600 centipoise
Hazardous Air Pollutants
0 % weight [Test Method: Calculated]
VOC Less H2O & Exempt Solvents
0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part A]
VOC Less H2O & Exempt Solvents
0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as
supplied]
VOC Less H2O & Exempt Solvents
0 % [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part A]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
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10.5. Incompatible materials
Strong acids
Strong oxidizing agents
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo
induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
Polyether Polyol Dermal Rabbit LD50 > 5,000 mg/kg
Polyether Polyol Ingestion Rat LD50 > 10,000 mg/kg
Propoxylated Trimethylolpropane Dermal Rat LD50 > 2,000 mg/kg
Propoxylated Trimethylolpropane Ingestion Rat LD50 > 2,500 mg/kg
Tetrakis(2-hydroxypropyl)ethylenediamine Dermal Rabbit LD50 > 2,000 mg/kg
Tetrakis(2-hydroxypropyl)ethylenediamine Ingestion Rat LD50 3,280 mg/kg
Amorphous Silica Dermal Rabbit LD50 > 5,000 mg/kg
Amorphous Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Amorphous Silica Ingestion Rat LD50 > 5,110 mg/kg
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m-Xylene-.alpha.alpha'.-diamine Dermal Rabbit LD50 > 2,000 mg/kg
m-Xylene-.alpha.alpha'.-diamine Inhalation-
Dust/Mist
(4 hours)
Rat LC50 1.2 mg/l
m-Xylene-.alpha.alpha'.-diamine Ingestion Rat LD50 980 mg/kg
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Ingestion Rat LD50 3,125 mg/kg
Polymeric Benzotriazole Dermal Rat LD50 > 2,000 mg/kg
Polymeric Benzotriazole Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 5.8 mg/l
Polymeric Benzotriazole Ingestion Rat LD50 > 5,000 mg/kg
Substituted Piperydinyl Sebacate Ingestion Rat LD50 3,125 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propoxylated Trimethylolpropane Rabbit No significant irritation
Amorphous Silica Rabbit No significant irritation
m-Xylene-.alpha.alpha'.-diamine Rat Corrosive
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Rabbit No significant irritation
Polymeric Benzotriazole Rabbit No significant irritation
Substituted Piperydinyl Sebacate Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Propoxylated Trimethylolpropane Rabbit Mild irritant
Amorphous Silica Rabbit No significant irritation
m-Xylene-.alpha.alpha'.-diamine Rabbit Corrosive
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Rabbit No significant irritation
Polymeric Benzotriazole Rabbit No significant irritation
Substituted Piperydinyl Sebacate Rabbit No significant irritation
Skin Sensitization
Name Species Value
Amorphous Silica Human
and
animal
Not sensitizing
m-Xylene-.alpha.alpha'.-diamine Guinea
pig
Sensitizing
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate Guinea
pig
Sensitizing
Polymeric Benzotriazole Guinea
pig
Sensitizing
Substituted Piperydinyl Sebacate Guinea
pig
Sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
Amorphous Silica In Vitro Not mutagenic
m-Xylene-.alpha.alpha'.-diamine In Vitro Not mutagenic
m-Xylene-.alpha.alpha'.-diamine In vivo Not mutagenic
Bis(1,2,2,6,6-pentamethyl-4-piperidinyl) sebacate In Vitro Not mutagenic
Substituted Piperydinyl Sebacate In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
Amorphous Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
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Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
Amorphous Silica Ingestion Not toxic to female reproduction Rat NOAEL 509
mg/kg/day
1 generation
Amorphous Silica Ingestion Not toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Amorphous Silica Ingestion Not toxic to development Rat NOAEL
1,350
mg/kg/day
during
organogenesi
s
m-Xylene-.alpha.alpha'.-diamine Ingestion Not toxic to female reproduction Rat NOAEL 450
mg/kg/day
1 generation
m-Xylene-.alpha.alpha'.-diamine Ingestion Not toxic to male reproduction Rat NOAEL 450
mg/kg
1 generation
m-Xylene-.alpha.alpha'.-diamine Ingestion Not toxic to development Rat NOAEL 450
mg/kg/day
1 generation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
m-Xylene-.alpha.alpha'.diamine
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
Not
available
NOAEL Not
avaliable
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Amorphous Silica Inhalation respiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
m-Xylene-.alpha.alpha'.diamine
Ingestion endocrine system |
blood | bone
marrow
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 600
mg/kg/day
28 days
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
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Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of
handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored,
treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: *2 Flammability: 1 Physical Hazard: 1 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
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and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:
19-0349-1
Version Number:
5.00
Issue Date:
04/16/15
Supercedes Date:
07/01/11
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
3M™ Concrete Repair Horizontal Gray, Part A 08/16/16
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Page 1 of 11
Safety Data Sheet
Copyright,2016,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
Document Group:
19-0350-9
Version Number:
7.00
Issue Date:
08/16/16
Supercedes Date:
10/27/15
SECTION 1: Identification
1.1. Product identifier
3M™ Concrete Repair Horizontal Gray, Part A
1.2. Recommended use and restrictions on use
Recommended use
Structural adhesive
1.3. Supplier’s details
MANUFACTURER:
3M
DIVISION:
Industrial Adhesives and Tapes Division
ADDRESS:
3M Center, St. Paul, MN 55144-1000, USA
Telephone:
1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.
Respiratory Sensitizer: Category 1.
Skin Sensitizer: Category 1.
Specific Target Organ Toxicity (single exposure): Category 3.
Specific Target Organ Toxicity (repeated exposure): Category 1.
2.2. Label elements
Signal word
Danger
Symbols
Exclamation mark | Health Hazard |
Pictograms
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Hazard Statements
Causes serious eye irritation.
Causes skin irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure:
respiratory system |
Precautionary Statements
Prevention:
Do not breathe dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
In case of inadequate ventilation wear respiratory protection.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.
Get medical advice/attention if you feel unwell.
Storage:
Keep container tightly closed.
Store locked up in a well-ventilated place.
Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.
2.3. Hazards not otherwise classified
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
4,4'-diphenylmethane diisocyanate 101-68-8 30 - 60 Trade Secret *
poly(diphenylmethane-4,4'-diisocyanate) 25686-28-6 15 - 40 Trade Secret *
diphenylmethanediisocyanate prepolymer 68424-09-9 15 - 40 Trade Secret *
amorphous silica 67762-90-7 1 - 5 Trade Secret *
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*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Oxides of Nitrogen During Combustion
Toxic Vapor, Gas, Particulate During Combustion
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
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6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and
allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent
material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available
inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does
not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a
container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure
build-up. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with
fresh air. Read and follow safety precautions on the solvent label and SDS. Dispose of collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed to prevent contamination with water or air. If contamination is
suspected, do not reseal container. Store away from acids. Store awayfrom strong bases.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
FREE ISOCYANATES 101-68-8 Manufacturer
determined
TWA:0.005 ppm;STEL:0.02
ppm
4,4'-diphenylmethane
diisocyanate
101-68-8 ACGIH TWA:0.005 ppm
4,4'-diphenylmethane
diisocyanate
101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm)
SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
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8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Neoprene
Nitrile Rubber
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron - Neoprene
Apron – Nitrile
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form:
Liquid
Specific Physical Form:
Viscous
Odor, Color, Grade:
Low or no detectable odor, opaque.
Odor threshold
No Data Available
pH
Not Applicable
Melting point
No Data Available
Boiling Point
>=400 ºF
Flash Point
>=290 ºF [Test Method: Tagliabue Closed Cup]
Evaporation rate
<=1 [Details: Gels with exposure to humidity.]
Flammability (solid, gas)
Not Applicable
Flammable Limits(LEL)
Not Applicable
Flammable Limits(UEL)
Not Applicable
Vapor Pressure
<=0.000004 mmHg [@ 68 ºF]
Vapor Density
>=1 [Ref Std: AIR=1]
Density
1.11 g/ml
Specific Gravity
1.11 [Ref Std: WATER=1]
Solubility in Water
Negligible
Solubility- non-water
No Data Available
Partition coefficient: n-octanol/ water
No Data Available
Autoignition temperature
Not Applicable
Decomposition temperature
No Data Available
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Viscosity
1,250 - 2,750 centipoise
Hazardous Air Pollutants
< 60 % weight [Test Method: Calculated]
Molecular weight
No Data Available
VOC Less H2O & Exempt Solvents
0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part B]
VOC Less H2O & Exempt Solvents
0 % [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part B]
VOC Less H2O & Exempt Solvents
0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as
supplied]
SECTION 10: Stability and reactivity
10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.
10.5. Incompatible materials
Water
Strong acids
Strong bases
10.6. Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
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Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
May cause additional health effects (see below).
Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Additional Health Effects:
Prolonged or repeated exposure may cause target organ effects:
Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate,
bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure.
Additional Information:
Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE > 50 mg/l
Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
4,4'-diphenylmethane diisocyanate Dermal Rabbit LD50 > 5,000 mg/kg
4,4'-diphenylmethane diisocyanate Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.368 mg/l
4,4'-diphenylmethane diisocyanate Ingestion Rat LD50 31,600 mg/kg
poly(diphenylmethane-4,4'-diisocyanate) Dermal Rabbit LD50 > 5,000 mg/kg
poly(diphenylmethane-4,4'-diisocyanate) Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.368 mg/l
poly(diphenylmethane-4,4'-diisocyanate) Ingestion Rat LD50 31,600 mg/kg
amorphous silica Dermal Rabbit LD50 > 5,000 mg/kg
amorphous silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
amorphous silica Ingestion Rat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
4,4'-diphenylmethane diisocyanate official
classifica
tion
Irritant
poly(diphenylmethane-4,4'-diisocyanate) official
classifica
tion
Irritant
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amorphous silica Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
4,4'-diphenylmethane diisocyanate official
classifica
tion
Severe irritant
poly(diphenylmethane-4,4'-diisocyanate) official
classifica
tion
Severe irritant
amorphous silica Rabbit No significant irritation
Skin Sensitization
Name Species Value
4,4'-diphenylmethane diisocyanate official
classifica
tion
Sensitizing
poly(diphenylmethane-4,4'-diisocyanate) official
classifica
tion
Sensitizing
amorphous silica Human
and
animal
Not sensitizing
Respiratory Sensitization
Name Species Value
4,4'-diphenylmethane diisocyanate Human Sensitizing
poly(diphenylmethane-4,4'-diisocyanate) Human Sensitizing
Germ Cell Mutagenicity
Name Route Value
4,4'-diphenylmethane diisocyanate In Vitro Some positive data exist, but the data are not
sufficient for classification
poly(diphenylmethane-4,4'-diisocyanate) In Vitro Some positive data exist, but the data are not
sufficient for classification
amorphous silica In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
4,4'-diphenylmethane diisocyanate Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
poly(diphenylmethane-4,4'-diisocyanate) Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
amorphous silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test Result Exposure
Duration
4,4'-diphenylmethane diisocyanate Inhalation Some positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 0.004
mg/l
during
organogenesi
s
poly(diphenylmethane-4,4'-diisocyanate) Inhalation Some positive developmental data exist,
but the data are not sufficient for
classification
Rat NOAEL 0.004
mg/l
during
organogenesi
s
amorphous silica Ingestion Not toxic to female reproduction Rat NOAEL 509
mg/kg/day
1 generation
amorphous silica Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
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mg/kg/day
amorphous silica Ingestion Not toxic to development Rat NOAEL 1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
4,4'-diphenylmethane
diisocyanate
Inhalation respiratory irritation May cause respiratory irritation official
classifica
tion
NOAEL Not
available
poly(diphenylmethane-4,4'diisocyanate)
Inhalation respiratory irritation May cause respiratory irritation official
classifica
tion
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
4,4'-diphenylmethane
diisocyanate
Inhalation respiratory system Causes damage to organs through
prolonged or repeated exposure
Rat LOAEL
0.004 mg/l
13 weeks
poly(diphenylmethane4,4'-diisocyanate)
Inhalation respiratory system Causes damage to organs through
prolonged or repeated exposure
Rat LOAEL
0.004 mg/l
13 weeks
amorphous silica Inhalation respiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored,
treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.
EPA Hazardous Waste Number (RCRA): Not regulated
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SECTION 14: Transport Information
For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
4,4'-diphenylmethane diisocyanate
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
101-68-8 30 - 60
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health: *2 Flammability: 1 Physical Hazard: 1 Personal Protection: X - See PPE section.
Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).
Document Group:
19-0350-9
Version Number:
7.00
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Issue Date:
08/16/16
Supercedes Date:
10/27/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3M USA SDSs are available at www.3M.com
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