3M 504 User Manual

3M BRAND 504 RESPIRATOR CLEANING WIPE 09/20/16

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Safety Data Sheet

Copyright,2016,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group:

11-7028-1

Version Number:

17.01

Issue Date:

09/20/16

Supercedes Date:

03/06/15

SECTION 1: Identification

1.1. Product identifier

3M BRAND 504 RESPIRATOR CLEANING WIPE

Product Identification Numbers

70-0703-1713-9, 70-0716-5104-9, XE-1015-0194-0

1.2. Recommended use and restrictions on use

Recommended use

Cleaning respirators.

1.3. Supplier’s details
MANUFACTURER:

3M

DIVISION:

Personal Safety Division

ADDRESS:

3M Center, St. Paul, MN 55144-1000, USA

Telephone:

1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or [phone] (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classification

Serious Eye Damage/Irritation: Category 2B.
Skin Corrosion/Irritation: Category 2.

2.2. Label elements

Signal word

Warning

Symbols

Exclamation mark |

Pictograms

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Hazard Statements

Causes eye irritation.
Causes skin irritation.

Precautionary Statements

Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
If skin irritation occurs: Get medical advice/attention.

2.3. Hazards not otherwise classified

None.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt

WATER 7732-18-5 50 - 70 Trade Secret *
CELLULOSE TOWELETTE None 30 - 50 Trade Secret *
SURFACTANTS 68439-46-3 0.1 - 1 Trade Secret *
BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM
CHLORIDES

68424-85-1 0.1 - 0.95 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If Swallowed:

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

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4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Carbon monoxide During Combustion
Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate
authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Avoid release to the environment.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.

8.2. Exposure controls

8.2.1. Engineering controls

No engineering controls required.

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8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

General Physical Form:

Solid moist

Specific Physical Form:

Non-Woven Material

Odor, Color, Grade:

Towelette impregnated with clear liquid, no odor

Odor threshold

No Data Available

pH

5.75 - 6.75 [Details: CONDITIONS: Excluding towelette]

Melting point

Not Applicable

Boiling Point

Approximately 212 ºF [Details: CONDITIONS: Excluding
towelette]

Flash Point

No flash point

Evaporation rate

0.33 [Ref Std: BUOAC=1] [Details: Excluding Towlette]

Flammability (solid, gas)

Not Classified

Flammable Limits(LEL)

Not Applicable

Flammable Limits(UEL)

Not Applicable

Vapor Pressure

Approximately 17.54 mmHg [@ 20 ºC] [Details: Excluding
Towlette]

Vapor Density

No Data Available

Density

1.0 g/ml [Details: Excluding Towlette]

Specific Gravity

Approximately 1 [Ref Std: WATER=1] [Details:
CONDITIONS: Excluding towelette]

Solubility in Water

Complete

Solubility- non-water

No Data Available

Partition coefficient: n-octanol/ water

No Data Available

Autoignition temperature

No Data Available

Decomposition temperature

No Data Available

Viscosity

No Data Available

Molecular weight

No Data Available

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Volatile Organic Compounds

No Data Available

Percent volatile

Approximately 100 % [Details: CONDITIONS: Excluding
towlette]

VOC Less H2O & Exempt Solvents

No Data Available

SECTION 10: Stability and reactivity

10.1. Reactivity

This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

None known.

10.5. Incompatible materials

None known.

10.6. Hazardous decomposition products

Substance Condition

None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye Contact:

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:

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Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg
SURFACTANTS Dermal Rabbit LD50 > 2,000 mg/kg

SURFACTANTS Ingestion Rat LD50 1,378 mg/kg
BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM
CHLORIDES

Dermal Rabbit LD50 645 mg/kg

BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM
CHLORIDES

Ingestion Rat LD50 366 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

SURFACTANTS Rabbit Irritant

Serious Eye Damage/Irritation

Name Species Value

SURFACTANTS Professio

nal
judgeme
nt

Corrosive

Skin Sensitization

Name Species Value

SURFACTANTS Guinea

pig

Not sensitizing

Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

SURFACTANTS In Vitro Not mutagenic

Carcinogenicity

For the component/components, either no data are currently available or the data are not sufficient for classification.

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

SURFACTANTS Dermal Not toxic to female reproduction Rat NOAEL 250

mg/kg/day

2 generation

SURFACTANTS Dermal Not toxic to development Rat NOAEL 250

mg/kg/day

2 generation

SURFACTANTS Dermal Some positive male reproductive data

exist, but the data are not sufficient for
classification

Rat NOAEL 100

mg/kg/day

2 generation

Target Organ(s)

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Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

SURFACTANTS Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

Not
available

NOAEL Not
available

not available

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

SURFACTANTS Dermal kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 125

mg/kg/day

13 weeks

SURFACTANTS Dermal hematopoietic

system

All data are negative Rat NOAEL 125

mg/kg/day

13 weeks

Aspiration Hazard

For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

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15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification
and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group:

11-7028-1

Version Number:

17.01

Issue Date:

09/20/16

Supercedes Date:

03/06/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com