Page 1
Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
Section: 1. Product and Company Identification
1.1 Product Identifier
Product form Substance
Product Name Carbon dioxide
CAS No 124-38-9
Formula 100% CO
Other means of identification Zip Sparkling Gas, CARBON DIOXIDE, CO
2
2
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substances/mixture Beverage product dispensing. Use as directed.
1.3 Details of supplier of the safety data sheet
Zip Water (AUST) Pty Ltd
67 Allingham Street Condell Park
NSW Australia 2200
Telephone 1800 638 633
Email sales@zipindustries.com
www.zipwater.com
1.4 Emergency telephone number
Emergency telephone number
+61 2 406 384 992
+61 2 428 045 027
Section: 2. Hazard Identification
2.1 Classification of the substance or mixture
Hazard Class and Category Code Regulation EC 1272/2008 (CLP)
Physical hazards
Classification EC 67/548 or EC 1999/45
Gases under pressure – Liquefied gas – Warning – (CLP: Press. Gas) H280/H281
Not classified as dangerous substance/mixture.
2.2 Label elements
Labelling Regulation EC 1272/2008 (CLP)
Hazard Pictogram
Hazard pictogram code
Signal word
Hazard statement
Precautionary statements
Prevention
GHS04
Warning
H281 - Contains refrigerated gas; may cause cryogenic burns of injury
H280 - Contains gas under pressure; may explode if heated
P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing gas
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
P262 - Do not get in eyes, on skin, or on clothing
Response
Storage
P336+P315 - Thaw frosted parts with lukewarm water. Do not rub affected area.
Get immediate medical advice / attention.
P403 - Use and store in a well-ventilated place
Keep container below 50°C
2.3 Other Hazards
Other hazards not contributing to
the classification
Asphyxiant in high concentrations
Contact with liquid may cause cold burns/frostbite
2.4 Unknown acute toxicity
No data available
Section: 3. Composition/Information on ingredients
3.1 Substance
Name Carbon dioxide
Name Content CAS No EC No Annex No Classification
Carbon Dioxide 100% 124-38-9 204-696-9 --------- *1 Not classified (DSD/DPD)
Liq. Gas (H280/H281)
Contains no other components or impurities which will influence the
classification of the product.
* 1: Listed in Annex IV / V REACH, exempted from registration.
* 2: Registration deadline not expired.
* 3: Registration not required: Substance manufactured or imported < 1t/y
Full text of R-phrases see chapter 16. Full text of H-statements see chapter 16
3.2 Mixture
N/A
Section: 4. First aid measures
4.1 Description of first aid measures
Inhalation
Eye contact
Skin contact
EN (English AU) SDS ID: PN-800758
In high concentrations may cause asphyxiation. Symptoms may include loss of
mobility/consciousness. Victim may not be aware of asphyxiation.
Low concentrations of CO
Remove victim to uncontaminated area wearing self-contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial
respiration if breathing stopped.
Immediately flush eyes thoroughly with water for at least 15 minutes.
In case of frostbite spray with water for at least 15 minutes. Apply a sterile
dressing. Obtain medical assistance.
MAY CAUSE FROSTBITE. For exposure to liquid, cold vapour, or solid carbon
dioxide (dry ice), immediately warm frostbite area with warm water not to exceed
41°C. Water temperature should be tolerable to normal skin. Maintain skin
warming for at least 15 minutes or until normal colouring and sensations have
returned to the affected area. In case of massive exposure, remove clothing
while showering with warm water. Seek medical evaluation and treatment as
soon as possible.
cause increased respiration and headache.
2
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Page 3
Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
Ingestion
Ingestion is not considered a potential route of exposure
4.2 Most important symptoms and effects, both acute and delayed
No additional information available
4.3 Indication of any immediate attention and special treatment needed
None
Section: 5. Firefighting measures
5.1 Extinguisher media
Suitable extinguishing media
5.2 Special hazard arising from the substance or mixture
Explosion hazard
Reactivity
5.1 Advice for firefighters
Specific methods
Use extinguishing media appropriate for surrounding fire.
Heat of fire can build pressure in container and cause it to rupture. Containers
are equipped with a pressure relief device. No part of the container should be
subjected to a temperature higher than 50°C.
No reactivity hazard other than the effects described in sub-sections below.
If possible, stop flow of product.
Coordinate fire measure to the surrounding fire. Cool endangered containers
with water spray jet from a protected position. Do not empty contaminated fire
water into drains.
Move away from the container and cool with water from a protected position.
If leaking do not spray water onto container. Water surrounding area (from
protected position) to contain fire.
Special protective equipment for
firefighters
Flammable class
In confined space use self-contained breathing apparatus.
Non-flammable.
Section: 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal precautions
6.2 Environmental precautions
6.3 Methods and material for containment and cleaning up
Clean up methods
WARNING! Liquid and gas under pressure. Rapid release of gaseous carbon
dioxide through a valve can result in the formation of dry ice, which is very cold
and can cause frostbite.
Evacuate area.
Use protective clothing.
Wear self-contained breathing apparatus when entering area unless atmosphere
is proved to be safe.
Ensure adequate air ventilation.
Try to stop release.
Prevent from entering sewers, basements and work pits, or any place where its
accumulation can be dangerous.
Ventilate area.
Prevent waste from contaminating the surrounding environment. Discard any
product, residue, disposable container, or liner in an environmentally acceptable
manner, in full compliance with federal, provincial, and local regulations. If
EN (English AU) SDS ID: PN-800758
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
necessary, call your local supplier for assistance.
6.4 Reference to other sections
See also sections 8 and 13.
Section: 7. Handling and Storage
7.1 Precautions for safe handling
Safe use of product
Use only properly specified equipment which is suitable for this product, its
supply pressure and temperature. Contact your gas supplier if in doubt.
Only experienced and properly instructed persons should handle gases under
pressure.
The product must be handled in accordance with good industrial hygiene and
safety procedures.
Do not smoke while handling product.
Ensure the complete gas system was (or is regularly) checked for leaks before
use.
Safe handling of gas receptacle
Refer to supplier's container handling instructions.
Do not allow back feed into the container.
Protect cylinders from physical damage; do not drag, roll, slide or drop.
When moving bulk cylinders/containers, even for short distances, use a cart
(trolley, hand truck, etc.) designed to transport bulk cylinders/containers.
Leave valve protection caps in place until the container has been secured
against either a wall or bench or placed in a container stand and is ready for
use.
If user experiences any difficulty operating cylinder valve discontinue use and
contact supplier.
Never attempt to repair or modify container valves or safety relief devices.
Damaged valves should be reported immediately to the supplier.
Keep container valve outlets clean and free from contaminates particularly oil
and water.
Replace valve outlet caps or plugs and container caps where supplied as soon
as container is disconnected from equipment.
Close container valve after each use and when empty, even if still connected to
equipment.
Never attempt to transfer gases from one cylinder/container to another.
Never use direct flame or electrical heating devices to raise the pressure of a
container.
Do not remove or deface labels provided by the supplier for the identification of
the cylinder contents.
General
Handling
Containers, which contain or have contained flammable or explosive
substances, must not be inerted with liquid carbon dioxide. Potential production
of solid CO
discharge production, the system must be adequately grounded.
Suck back of water into the container must be prevented.
Do not allow backfeed into the container.
Use only properly specified equipment which is suitable for this product, its
supply pressure and temperature. Contact your gas supplier if in doubt.
particles must be ruled out. In order to rule out potential electrostatic
2
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
Refer to supplier's container handling instructions.
7.2 Conditions for safe storage, including any incompatibilities
Keep away from combustible materials.
Keep container below 50°C in a well ventilated place.
Observe all regulations and local requirements regarding storage of containers.
Containers should not be stored in conditions likely to encourage corrosion.
Containers should be stored in the vertical position and properly secured to
prevent toppling.
Stored containers should be periodically checked for general condition and
leakage.
Container valve guards or caps should be in place.
Store containers in location free from fire risk and away from sources of heat
and ignition.
Storage
Keep container below 50°C in a well ventilated place.
7.3 Specific end use
None
Section: 8. Exposure control/personal protection
8.1 Control parameters
Occupational Exposure Limits
Carbon dioxide
x Value 8h (CZ) [mg/m3] : 9000
x ILV (EU) - 8 H - [mg/m³] : 9000
x ILV (EU) - 8 H - [ppm] : 5000
x TLV© -TWA [ppm] : 5000
x TLV© -STEL [ppm] : 30000
x AGW (8h) - Germany [mg/m³] TRGS 900 : 9100
x AGW (8h) - Germany [ppm] TRGS 900 : 5000
x MAK (AU) Tagesmittelwert (ml/m³) : 5000
x MAK (AU) Tagesmittelwert (mg/m³) : 9000
x MAK (AU) Kurzzeitwerte (ml/m³) : 10000
x MAK (AU) Kurzzeitwerte (mg/m³) : 18000
x VLA-ED - Spain [ppm] : 5000
x VLA-ED - Spain [mg/m3] : 9150
x VLA-EC - Spain [ppm] : 15000
x VLA-EC - Spain [mg/m3] : 27400
x NGV - [ppm] : 5000
x NGV - [mg/m³] : 9000
x KTV - [ppm] : 10
x KTV - [mg/m³] : 10
x HTP-värden (FI) - 8 H - [ppm] : 5000
x HTP-värden (FI) - 8 H - [mg/m³] : 9100
x Grænserværdier (DK) (ppm) : 5000
x Grænserværdier (DK) (ppm) : 9000
x Grænserværdier (DK) : 9000
x GV Value Limit (Norway) [ppm] : 5000
x GV Value Limit (Norway) [mg/m³] : 9000
x 8-Hour TWA (PL) (NDS) (mg/m³) : 9000
x 15-Minute STEL (PL)(NDSCh) (mg/m³) : 27000
x Valori Limite di Soglia (IT) 8 ore [ppm] : 5000
x Valori Limite di Soglia (IT) 8 ore [mg/m3] : 9000
EN (English AU) SDS ID: PN-800758
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
DNEL: Derived no effect level
x TLV-TWA (Belgium) (ppm) : 5000
x TLV-STEL (Belgium) (ppm) : 30000
x Value 15min. (CZ) [mg/m3] : 45000
In Australia, the recognised exposure limits for CO
Weighted Average (TWA) of 5,000 ppm and a 15 minute Short Term Exposure
Limit (STEL) of 30,000 ppm. CO
Dangerous to Life or Health (IDLH).
None available
at 40,000 ppm is considered Immediately
2
reference an 8-hour Time
2
PNEC: Predicted no effect
concentration
None available
8.2 Exposure control
8.2.1 Appropriate engineering
control
8.2.2 Individual protection
measures, e.g. personal protective
equipment
Personal protection
8.2.3 Appropriate engineering
control
Systems under pressure should be regularly checked for leakages.
Provide adequate general and local exhaust ventilation.
Consider work permit system e.g. for maintenance activities.
A risk assessment should be conducted and documented in each work area to
assess the risks related to the use of the product and to select the PPE that
matches the relevant risk.
The following recommendations should be considered.
Wear safety glasses with side shields
Wear leather safety gloves and safety shoes when handling cylinders.
Ensure adequate ventilation.
Protect eyes, face and skin from liquid splashes.
Refer to local regulations for restriction of emissions to the atmosphere. See
section 13 for specific methods for waste gas treatment.
Section: 9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance - Physical state at 20°C
/ 101.3kPa
Liquefied gas
Colour
Odour
Odour threshold
pH value
Molar mass [g/mol]
Melting point [°C]
Boiling point [°C]
Critical temperature [°C]
Flash point [°C]
Evaporation rate (ether=1)
Flammability range [vol% in air]
Vapour pressure [20°C]
EN (English AU) SDS ID: PN-800758
Colourless.
No odour warning properties.
Odour threshold is subjective and inadequate to warn for overexposure.
Not applicable for gas-mixtures
Not applicable for gases and gas-mixtures.
-56.6
-78.5 (s)
30
Not applicable for gas-mixtures.
Not applicable for gas-mixtures.
Non-flammable
57.3 bar
Not applicable
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Relative density, gas (air=1)
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
1.52
Relative density, liquid (water=1)
Solubility in water [mg/l]
Partition coefficient n-octanol/water
Viscosity at 20°C [mPa.s]
Explosive Properties
1.03
2000
Not applicable for gas-mixtures.
Not applicable.
Not applicable.
9.2 Other information
Gas group
Additional information
Molecular weight
Liquefied gas
Gas/vapour heavier than air. May accumulate in confined spaces, particularly at
or below ground level.
44
Section: 10. Stability and reactivity
10.1 Reactivity
No reactivity hazard other than the effects described in sub-sections below.
Stability and reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
10.5 Incompatible materials
10.6 Hazardous decomposition products
Stable under normal conditions.
Liquid spillages can cause embrittlement of structural materials.
Stable under normal conditions
None
None
None
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Section: 11. Toxicological information
11.1 Information on toxicological effects
Toxicity information
Acute toxicity
Rat inhalation LC50 [ppm/4h]
Skin corrosion/irritation
Serious eye damage/irritation
Respiratory or skin sensitisation
STOT-single exposure
STOT-repeated exposure
EN (English AU) SDS ID: PN-800758
In high concentrations cause rapid circulatory insufficiency even at normal levels
of oxygen concentration. Symptoms are headache, nausea and vomiting, which
may lead to
unconsciousness and death
No known toxicological effects from this product.
No data available.
No known effects from this product.
No known effects from this product.
No known effects from this product.
No known effects from this product.
No known effects from this product.
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
Aspiration hazard
Not applicable for gases and gas-mixtures
Section: 12. Ecological information
12.1 Toxicity
No data available
12.2 Persistence – degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
Ecological effects information
Effect on global warming
Global warming potential [CO2=1]
When discharged in large quantities may contribute to the greenhouse effect.
Can cause frost damage to vegetation.
Contains greenhouse gas(es) not covered by 842/2006/EC
1
Section: 13. Disposal consideration
13.1 Waste treatment methods
May be vented to atmosphere in a well ventilated place.
Do not discharge into any place where its accumulation could be dangerous.
Refer to the code of practice of EIGA (Doc. 30/10 “Disposal of Gases,
downloadable at http://www.eiga.org) for more guidance on suitable disposal
methods.
Contact supplier if guidance is required.
General
Do not discharge into any place where its accumulation could be dangerous.
Discharge to atmosphere in large quantities should be avoided.
Contact supplier if guidance is required.
13.2 Additional information
None
Section: 14. Transport information
UN Number
Labelling ADR, IMDG, IATA
Land transport (ADR/RID)
H.I. nr
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1013
2.2: Non-flammable, non-toxic gas
20
Page 9
UN proper shipping name
Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
CARBON DIOXIDE
Transport hazard class(es)
Classification code
Packing Instruction(s)
Tunnel Restriction
HAZCHEM - Emergency Action
Code
Sea transport (IMDG)
Proper shipping name
Class
Emergency Schedule (EmS) - Fire
Emergency Schedule (EmS) Spillage
Packing instruction
Air transport (ICAO-TI/IATADGR)
Proper shipping name (IATA)
2
2 A
P200
C/E Tank carriage: Passage forbidden through tunnels of category C, D and E;
Other carriage: Passage forbidden through tunnels of category E
2T
2 = Fine water spray.
T = Recommended personal protective equipment: Full fire kit and breathing
apparatus.
Appropriate measures: dilute.
CARBON DIOXIDE
2.2
F-C
S-V
P200
CARBON DIOXIDE
Class
Passenger and Cargo Aircraft
Packing instruction - Passenger and
Cargo Aircraft
Packing instruction - Cargo Aircraft
only
Special precaution for user
Labelling ADR
In case of spillage and/or leakage
2.2
Allowed.
200
200
x Avoid transport on vehicles where the load space is not separated from
the driver's compartment.
x Ensure vehicle driver is aware of the potential hazards of the load and
knows what to do in the event of an accident or an emergency.
x Before transporting product containers :
o Ensure there is adequate ventilation.
o Ensure that containers are firmly secured.
o Ensure cylinder valve is closed and not leaking.
o Ensure valve outlet cap nut or plug (where provided) is correctly
fitted.
o Ensure valve protection device (where provided) is correctly
fitted.
2.2: Non-flammable, non-toxic gas.
Clean up even minor leaks or spills if possible without unnecessary risk
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Other transport information
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
x Avoid transport on vehicles where the load space is not separated from
the driver's compartment.
x Ensure vehicle driver is aware of the potential hazards of the load and
knows what to do in the event of an accident or an emergency.
x Before transporting product containers :
o Ensure that containers are firmly secured.
o Ensure there is adequate ventilation.
o Compliance with applicable regulations.
Personal precautions
Emergency action in case of
accident
Additional information
The driver shall not attempt to deal with any fire of the load.
Stop the engine.
No naked lights. No smoking.
Mark roads and warns other road users.
Keep public away from danger area.
NOTIFY POLICE AND FIRE BRIGADE IMMEDIATELY.
None
Section: 15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for substance or mixture
EU legislation
Seveso directive 96/82/EC
Not covered.
National legislation
Ensure all national/local regulations are observed
15.2 Chemical Safety Assessment
A CSA does not need to be carried out for this product
Section: 16. Other information
Indication of changes
Training advice
Revised safety data sheet in accordance with commission regulation (EU) No
453/2010
Asphyxiant in high concentrations.
Receptacle under pressure.
May cause frostbite.
Keep container in a well-ventilated place.
Do not breathe the gas.
Ensure all national/local regulations are observed.
The hazard of asphyxiation is often overlooked and must be stressed during
operator training.
List of full text of H-statements in
section 3
Further information
Note
EN (English AU) SDS ID: PN-800758
H280 - Contains gas under pressure; may explode if heated.
Classification in accordance with calculation methods of regulation (EC)
1272/2008 CLP / (EC) 1999/45 DPD.
This Safety Data Sheet has been established in accordance with the applicable
European Union legislation.
This Safety Data Sheet has been established in accordance with the applicable
European Union legislation.
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
DISCLAIMER OF LIABILITY
The contents and format of this SDS are in accordance with EC Commission D irective 2001/58/EC.
DISCLAIMER OF LIABILITY The information in this SDS was obtained f rom s ources which we believe ar e reliable. However, the information is provided
without any warranty, expr ess or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are
beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for
loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and
is to be used only for this product. If the product is us ed as a component in another pr oduct, this MSDS inf ormation may not be applic able.
Before using this product in any new process or experiment, a thorough material
compatibility and safety study should be carried out.
Details given in this document are believed to be correct at the time of going to
press. Whilst proper care has been taken in the preparation of this document, no
liability for injury or damage resulting from its use can be accepted.
End of document.
EN (English AU) SDS ID: PN-800758
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Carbon Dioxide
Safety Data Sheet PN-800758
This SDS conforms to Code of Practice for the Preparation of Safety Data Sheets for
Hazardous Chemicals
Date of issue: 07/12/2016 Revision edition no.: 3 Supersedes: 30/05/2012
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