Zing Z495-QPS6 User Manual

SAFETY DATA SHEET
Issue Date 15-Feb-2017 Revision Date 15-Feb-2017 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier Product Name
Other means of identification Product Code Synonyms
Details of the supplier of the safety data sheet Company Name
Emergency telephone number Emergency Telephone
Zing Black Streak Remover
Nyco Products Company 5332 Dansher Road Countryside, IL 60525 (708) 579-8100 nycoproducts.com
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Not classified Acute toxicity - Dermal Not classified Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2
Label elements
Emergency Overview
Warning
Hazard statements
Causes skin irritation Causes serious eye irritation
Appearance Clear Physical state Liquid Odor Orange
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Z495 Zing Black Streak Remover Revision Date 15-Feb-2017
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Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
Immediately call a POISON CENTER or doctor/physician Specific Treatment (See Section 4 on the SDS) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse
Precautionary Statements - Disposal
Disposal should be in accordance with applicable regional, national and local laws and regulations
Hazards not otherwise classified (HNOC) Other Information
• Harmful to aquatic life with long lasting effects
• Harmful to aquatic life
Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
Surfactant Blend Proprietary 3-7 *
Hydrogen Peroxide 7722-84-1 1-5 *
1-methoxy-2-propanol 107-98-2 1-5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures Skin Contact Eye contact
Inhalation Ingestion Most important symptoms and effects, both acute and delayed Symptoms
Indication of any immediate medical attention and special treatment needed Note to physicians
Wash off immediately with plenty of water. Wash skin with soap and water. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician. Remove to fresh air. Clean mouth with water and drink afterwards plenty of water.
Any additional important symptoms and effects are described in Section 11: Toxicology Information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
Specific hazards arising from the chemical
Caution: Use of water spray when fighting fire may be inefficient.
Z495 Zing Black Streak Remover Revision Date 15-Feb-2017 _____________________________________________________________________________________________
No Information available.
Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge
None. None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal precautions
Ensure adequate ventilation, especially in confined areas.
Environmental precautions Environmental precautions
See Section 12 for additional ecological information.
Methods and material for containment and cleaning up Methods for containment Methods for cleaning up
Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE
Precautions for safe handling Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials
Keep containers tightly closed in a dry, cool and well-ventilated place. None known based on information supplied.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Hydrogen Peroxide
7722-84-1
1-methoxy-2-propanol
107-98-2
.
TWA: 1 ppm TWA: 1 ppm
(vacated) TWA: 1 ppm
STEL: 100 ppm
TWA: 50 ppm
(vacated) TWA: 1.4 mg/m
(vacated) TWA: 100 ppm
(vacated) TWA: 360 mg/m
(vacated) STEL: 150 ppm
(vacated) STEL: 540 mg/m
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Appropriate engineering controls Engineering Controls
Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
TWA: 1.4 mg/m
3
3
3
3
IDLH: 75 ppm
TWA: 1 ppm
TWA: 1.4 mg/m
TWA: 100 ppm
TWA: 360 mg/m
STEL: 150 ppm
STEL: 540 mg/m
3
3
3
Z495 Zing Black Streak Remover Revision Date 15-Feb-2017 _____________________________________________________________________________________________
Skin and body protection Respiratory protection
General Hygiene
Wear chemical resistant gloves. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state
Appearance Color Odor Odor threshold
Property Values Remarks • Method
pH Specific Gravity Viscosity
Melting point/freezing point
Flash point Boiling point / boiling range Evaporation rate Flammability (solid, gas)
Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Water solubility Partition coefficient Autoignition temperature Decomposition temperature
Liquid Clear Colorless Orange No Information available
3.0 - 3.5
1.00 < 25 cP @ 25°C No Information available
> 160 °F 99 °C / 210 ° F Degrees No Information available
No data available
No Information available No Information available No Information available No Information available Complete No Information available No Information available No Information available
Other Information
Density Lbs/Gal VOC Content (%)
8.34
2.86
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
Z495 Zing Black Streak Remover Revision Date 15-Feb-2017 _____________________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Product Information
Inhalation
Avoid breathing vapors or mists. Inhalation of vapors in high concentration may cause irritation of respiratory system.
Eye contact Skin Contact
Avoid contact with eyes. Severely irritating to eyes. Causes severe eye damage. Avoid contact with skin. Irritating to skin. Prolonged contact may cause redness and
irritation.
Ingestion
Do not taste or swallow. May cause gastro intestinal irritation. May cause stomach distress, nausea, or vomiting.
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Surfactant Blend > 2000 mg/kg ( Rat ) > 2000 mg/kg ( Rat ) ­Hydrogen Peroxide
7722-84-1 1-methoxy-2-propanol 107-98-2
= 1518 mg/kg ( Rat ) = 4060 mg/kg ( Rat ) = 2000 mg/kg
( Rabbit )
= 7200 mg/kg (Rat) = 13000 mg/kg (Rabbit) = 7500 mg/L (Rat) 6 h
= 2 g/m3 ( Rat ) 4 h
Information on toxicological effects Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization
Germ cell mutagenicity Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Hydrogen Peroxide 7722-84-1
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 3 -Not classifiable as a human carcinogen
Reproductive toxicity STOT - single exposure STOT - repeated exposure
Target organ effects
Aspiration hazard
No Information available. No Information available. The table below indicates whether each agency has listed any ingredient as a carcinogen.
A3 Group 3 - -
No Information available. No Information available. No Information available. Central nervous system, EYES, Respiratory system, Skin. No Information available.
Numerical measures of toxicity - Product Information Unknown Acute Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) ATEmix (dermal) ATEmix (inhalation-dust/mist)
20,687.00 32,496.00
67.00
12. ECOLOGICAL INFORMATION
Ecotoxicity
0.04% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
Surfactant Blend - 1.2: 96 h Oncorhynchus mykiss
mg/L LC50
5.3: 48 h Daphnia mg/L LC50
Z495 Zing Black Streak Remover Revision Date 15-Feb-2017 _____________________________________________________________________________________________
Hydrogen Peroxide
7722-84-1
1-methoxy-2-propanol
107-98-2
Persistence and degradability
No Information available.
Bioaccumulation
Bioaccumulative potential.
Chemical Name Partition coefficient
1-methoxy-2-propanol
107-98-2
Other adverse effects
Waste treatment methods Disposal of wastes
Contaminated packaging
2.5: 72 h Chlorella vulgaris mg/L EC50
- 20.8: 96 h Pimephales promelas g/L
10.0 - 32.0: 96 h Oncorhynchus
mykiss mg/L LC50 static 16.4: 96 h
Pimephales promelas mg/L LC50
18 - 56: 96 h Lepomis macrochirus
mg/L LC50 static
LC50 static 4600 - 10000: 96 h
Leuciscus idus mg/L LC50 static
-0.437
18 - 32: 48 h Daphnia magna mg/L
EC50 Static 7.7: 24 h Daphnia
magna mg/L EC50
23300: 48 h Daphnia magna mg/L
EC50
No Information available
13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Do not reuse container.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Hydrogen Peroxide
7722-84-1
Toxic
Corrosive
Ignitable Reactive
14. TRANSPORT INFORMATION
The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS.
DOT TDG
Not regulated Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA DSL/NDSL
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
Complies Complies
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Z495 Zing Black Streak Remover Revision Date 15-Feb-2017 _____________________________________________________________________________________________
SARA 311/312 Hazard Categories
Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard
No No No No No
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
Hydrogen Peroxide
7722-84-1
- 1000 lb -
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Hydrogen Peroxide
7722-84-1
1-methoxy-2-propanol
107-98-2
X X X X X X
U.S. EPA Label Information EPA Pesticide Registration Number
Not Applicable
16. OTHER INFORMATION
NFPA Health hazards 2 Flammability 0 Instability 0 Physical and Chemical
Properties Yes
HMIS Health hazards 2 Flammability 0 Physical hazards 0 Personal protection B Issue Date
Revision Date Revision Note
No Information available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
15-Feb-2017 15-Feb-2017
End of Safety Data Sheet
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