Zing N879-Q12 User Manual

SAFETY DATA SHEET
Issue Date 10-May-2017 Revision Date 10-May-2017 Version 1
1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier Product Name
Other means of identification Product Code Synonyms
Details of the supplier of the safety data sheet Company Name
Emergency telephone number Emergency Telephone
Zing® Formula IV Aluminum Pontoon/Boat Cleaner
Nyco Products Company 5332 Dansher Road Countryside, IL 60525 (708) 579-8100 nycoproducts.com
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Classification OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 4 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Gases) Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Carcinogenicity Category 1A
Label elements
Emergency Overview
Danger
Hazard statements
Harmful if swallowed Toxic in contact with skin Harmful if inhaled Causes severe skin burns and eye damage May cause cancer
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N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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Appearance Colorless Physical state Liquid Odor Acidic Precautionary Statements - Prevention
Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray
Precautionary Statements - Response
Specific Treatment (See Section 4 on the SDS) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Immediately call a POISON CENTER or doctor/physician IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Drink plenty of water Immediately call a POISON CENTER or doctor/physician
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Disposal should be in accordance with applicable regional, national and local laws and regulations
Hazards not otherwise classified (HNOC) Other Information
Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-% Trade Secret
Hydrochloric Acid 7647-01-0 5-10 *
Ammonium Fluoride 12125-01-8 1-5 *
Nonylphenol Ethoxylate 9016-45-9 1-5 *
Hydrofluoric Acid 7664-39-3 .1-1 *
Sulfuric Acid 7664-93-9 .1-1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures General advice Immediate medical attention is required. NOTE: The effect of Hydrofluoric Acid (HF), i.e.
the onset of pain, particularly in dilute solutions, may not be felt for up to 24 hours. It is important that workers have immediate access to the antidote (calcium gluconate) both on
N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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and off the worksite in order to apply it as soon as possible.
Skin Contact
Eye contact
Inhalation
Immediate medical attention is required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. For minor skin contact, avoid spreading material on unaffected skin. For severe burns, immediate medical attention is required. Immediately apply calcium gluconate gel 2.5 % and massage into the affected area using rubber gloves; continue to massage while repeatedly applying gel until 15 minutes after pain is relieved. Alternately, immerse the burned area in a solution of 0.2% iced aqueous Hyamine 1622 or 0.13% iced aqueous Zephiran Chloride. If finger/fingernails are touched, even if there is no pain, dip them in a bath of 5% calcium gluconate for 15 to 20 minutes. Consult a physician immediately in all cases of skin contact no matter how minor.
Keep eye wide open while rinsing. Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Do not rub affected area. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Rinse the eyes with a calcium gluconate 1% solution for 10 minutes. In the case of difficulty opening the lids, administer an analgesic eyewash. Do not use oily drops, ointment, or HF skin burn treatments. Consult an ophthalmologist or eye specialist and physician immediately in all cases. Take to a hospital immediately.
Remove to fresh air. Call a physician or poison control center immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Remove the subject from the contaminated area as soon as possible. Transport subject lying down, with the head higher than the body, to a quiet, uncontaminated and well ventilated location. Administer oxygen (2.5% calcium gluconate if available, can be oxygen nebulized with trained personnel) or cardiopulmonary resuscitation if necessary and as soon as possible. If patient is unconscious, give artificial respiration. Note: Mouth to mouth resuscitation is not recommended. Keep warm (blanket). Consult physician in all cases. Take to a hospital.
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed Symptoms
Indication of any immediate medical attention and special treatment needed Note to physicians
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Immediate medical attention is required. Remove from exposure, lie down. Clean mouth with water and drink afterwards plenty of water. Call a physician or poison control center immediately. When directed by physician, give orally either 1% aqueous calcium gluconate solution, milk or calcium/magnesium containing anti-acid. Such solutions can be beneficial but also may be problematic if they induce vomiting.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Note: Mouth to mouth resuscitation is not recommended..
Any additional important symptoms and effects are described in Section 11: Toxicology Information.
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
Caution: Use of water spray when fighting fire may be inefficient.
N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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Specific hazards arising from the chemical
The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating and toxic gases and vapors. In the event of fire and/or explosion do not breathe fumes.
Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge
None. None.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal precautions
Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid contact with skin, eyes or clothing. Keep people away from and upwind of spill/leak.
Environmental precautions Environmental precautions
Do not allow into any sewer, on the ground or into any body of water. Should not be released into the environment. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
Methods and material for containment and cleaning up Methods for containment
Prevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading. Dike far ahead of liquid spill for later disposal.
Methods for cleaning up
Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Take up mechanically, placing in appropriate containers for disposal. Clean contaminated surface thoroughly. Prevent product from entering drains. Dam up. After cleaning, flush away traces with water.
7. HANDLING AND STORAGE
Precautions for safe handling Advice on safe handling
Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Ensure adequate ventilation, especially in confined areas. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Avoid breathing vapors or mists. Always add acid to water.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers. Keep/store only in original container. Do not reuse container.
Incompatible materials
Incompatible with strong acids and bases. Incompatible with oxidizing agents. Strong bases. Ammonia. Chlorinated compounds. Contact with metals may evolve flammable hydrogen gas. Metals.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Hydrochloric Acid
7647-01-0
.
Ceiling: 2 ppm (vacated) Ceiling: 5 ppm
(vacated) Ceiling: 7 mg/m
Ceiling: 5 ppm
3
IDLH: 50 ppm
Ceiling: 5 ppm
Ceiling: 7 mg/m
3
N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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Ammonium Fluoride
12125-01-8
Hydrofluoric Acid
7664-39-3
Sulfuric Acid
7664-93-9
Propargyl Alcohol
107-19-7
TWA: 0.5 ppm F TWA: 2.5 mg/m3 F
TWA: 2.5 mg/m3 F TWA: 2.5 mg/m3 F
S*
Ceiling: 2 ppm F
TWA: 0.2 mg/m3 thoracic
particulate matter
TWA: 1 ppm
S*
(vacated) TWA: 2.5 mg/m
TWA: 3 ppm F TWA: 2.5 mg/m3 F
(vacated) TWA: 3 ppm F (vacated)
(vacated) STEL: 6 ppm F
(vacated) TWA: 1 mg/m
(vacated) TWA: 1 ppm
(vacated) TWA: 2 mg/m
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
Appropriate engineering controls Engineering Controls
Showers, Eyewash stations & Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Skin and body protection
Tight sealing safety goggles. Face protection shield. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact. Wear protective gloves and protective clothing.
Ceiling: 7 mg/m
TWA: 2.5 mg/m
TWA: 1 mg/m
(vacated) S*
3
3
3
3
3
3
TWA: 2.5 mg/m3 F
IDLH: 30 ppm
Ceiling: 6 ppm 15 min
Ceiling: 5 mg/m3 15 min
TWA: 3 ppm
TWA: 2.5 mg/m
IDLH: 15 mg/m
TWA: 1 mg/m
TWA: 1 ppm
TWA: 2 mg/m
3
3
3
3
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene
When using do not eat, drink or smoke. Keep away from food, drink and animal feeding stuffs. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Avoid contact with skin, eyes or clothing. Take off all contaminated clothing and wash it before reuse. Wear suitable gloves and eye/face protection. Keep working clothes separately.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical state
Appearance Color Odor Odor threshold
Property Values Remarks • Method
pH Specific Gravity Viscosity
Melting point/freezing point
Flash point Boiling point / boiling range Evaporation rate Flammability (solid, gas)
Flammability Limits in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density
Liquid Colorless Colorless Acidic No Information available
<1
1.06 < 25 cP @ 25°C No Information available
None 99 °C / 210 ° F Degrees No Information available
No data available
No Information available No Information available No Information available No Information available
N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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Water solubility Partition coefficient Autoignition temperature Decomposition temperature
Complete No Information available No Information available No Information available
Other Information
Density Lbs/Gal VOC Content (%)
8.83 Not Applicable
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Exposure to air or moisture over prolonged periods. Extremes of temperature and direct sunlight.
Incompatible materials
Incompatible with strong acids and bases. Incompatible with oxidizing agents. Strong bases. Ammonia. Chlorinated compounds. Contact with metals may evolve flammable hydrogen gas. Metals.
Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating and toxic gases and vapors. Hydrogen chloride. Chlorine gas. Thermal decomposition can lead to release of toxic/corrosive gases and vapors. Hydrogen. Hydrogen fluoride. Ammonia. Nitrogen oxides (NOx).
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Product Information
Inhalation
Eye contact
Skin Contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Hydrochloric Acid 7647-01-0 Nonylphenol Ethoxylate 9016-45-9 Hydrofluoric Acid 7664-39-3 Sulfuric Acid 7664-93-9
The primary effects and toxicity of this material are due to it corrosive nature. Harmful by inhalation. Breathing of vapor can cause respiratory irritation and inflammation.
Breathing of mist or liquid can cause burns to the respiratory tract. Avoid contact with eyes. Corrosive to the eyes and may cause severe damage including
blindness. Toxic in contact with skin. Corrosive. Contact with skin may cause severe irritation and
burns. Contact is irritating and may cause an unusual, skin rash that appears similar to ballooning of the skin. If skin is moist, formation of hydrofluoric acid can cause serious burns. These burns do not appear serious at first, but may cause severe damage if not treated immediately.
Harmful if swallowed. Ingestion causes acute irritation and burns to the mucous membranes of the mouth, trachea, esophagus and stomach.
= 700 mg/kg (Rat) > 5010 mg/kg ( Rabbit ) = 1.68 mg/L ( Rat ) 1 h
= 2590 mg/kg ( Rat ) = 1310 mg/kg
( Rat )
- - = 0.79 mg/L ( Rat ) 1 h
= 2140 mg/kg ( Rat ) - = 510 mg/m3 ( Rat ) 2 h
= 1780 µL/kg ( Rabbit ) = 2 mL/kg (
Rabbit )
-
N-879 Zing® Formula IV Aluminum Pontoon/Boat
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Information on toxicological effects Symptoms
No Information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Corrosivity
Causes burns. Extremely corrosive and destructive to tissue. Risk of serious damage to eyes.
Sensitization Germ cell mutagenicity Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Hydrochloric Acid 7647-01-0 Ammonium Fluoride 12125-01-8 Sulfuric Acid 7664-93-9
ACGIH (American Conference of Governmental Industrial Hygienists)
A2 - Suspected Human Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans Group 3 -Not classifiable as a human carcinogen
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Reproductive toxicity STOT - single exposure STOT - repeated exposure
Chronic toxicity
No Information available. No Information available. The table below indicates whether each agency has listed any ingredient as a carcinogen.
- Group 3 - X
- Group 3 - -
A2 Group 1 Known X
No Information available. No Information available. No Information available. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common. Gastrointestinal disturbances may also be seen. Avoid repeated exposure. Possible risk of irreversible effects.
Target organ effects
Aspiration hazard
EYES, Respiratory system, Skin. No Information available.
Numerical measures of toxicity - Product Information Unknown Acute Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) ATEmix (dermal) ATEmix (inhalation-gas) ATEmix (inhalation-dust/mist)
431.00
526.00 8,040.74
2.76
12. ECOLOGICAL INFORMATION
Ecotoxicity
0.09% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
Hydrochloric Acid
7647-01-0
Ammonium Fluoride
12125-01-8
Nonylphenol Ethoxylate
9016-45-9
Hydrofluoric Acid
7664-39-3
Sulfuric Acid
7664-93-9
Propargyl Alcohol - 1.49 - 1.56: 96 h Pimephales 32: 24 h Daphnia magna mg/L
- 282: 96 h Gambusia affinis mg/L LC50 static
- 364.0: 96 h Pimephales promelas
mg/L LC50 static
- 5: 96 h Fish mg/L LC50 -
- 660: 48 h Leuciscus idus mg/L
LC50
- 500: 96 h Brachydanio rerio mg/L LC50 static
-
-
270: 48 h Daphnia species mg/L
EC50
29: 24 h Daphnia magna mg/L
EC50
N-879 Zing® Formula IV Aluminum Pontoon/Boat
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107-19-7
promelas mg/L LC50 flow-through EC50
Persistence and degradability
No Information available.
Bioaccumulation
Bioaccumulative potential.
Chemical Name Partition coefficient
Other adverse effects
Hydrofluoric Acid
7664-39-3
No Information available
-1.4
13. DISPOSAL CONSIDERATIONS
Waste treatment methods Disposal of wastes
Contaminated packaging
Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
Hydrofluoric Acid
7664-39-3
Propargyl Alcohol
107-19-7
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Do not reuse container.
U134 - - U134 P102 - - -
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Ammonium Fluoride
12125-01-8
Sulfuric Acid
7664-93-9
Toxic
Corrosive
Toxic
Corrosive
14. TRANSPORT INFORMATION
The basic description below is specific to the container size. This information is provided for at a glance DOT information. Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS.
DOT
UN/ID No. Proper shipping name Hazard Class Subsidiary class Packing Group Special Provisions Description
Emergency Response Guide Number
TDG
UN/ID No. Proper shipping name Hazard Class Subsidiary class Packing Group Description
UN2922 Corrosive liquids, toxic, n.o.s. 8
6.1 II B2, IB2, T2, TP2 UN2922, Corrosive liquids, toxic, n.o.s. (contains Hydrochloric Acid and Ammonium Bifluoride), 8, 6.1, II 154
UN2922 Corrosive liquids, toxic, n.o.s. 8
6.1 II UN2922, Corrosive liquids, toxic, n.o.s. (contains Hydrochloric Acid and Ammonium Bisulfide), 8, 6.1, II
N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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15. REGULATORY INFORMATION
International Inventories
TSCA DSL/NDSL
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
Hydrochloric Acid - 7647-01-0 1.0 Ammonium Fluoride - 12125-01-8 1.0
SARA 311/312 Hazard Categories
Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard
Complies Complies
Yes Yes No No No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
Chemical Name CWA - Reportable
Hydrochloric Acid
7647-01-0
Ammonium Fluoride
12125-01-8
Hydrofluoric Acid
7664-39-3
Sulfuric Acid
7664-93-9
Quantities
5000 lb - - X
100 lb - - X 100 lb - - X
1000 lb - - X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
Hydrochloric Acid
7647-01-0
Ammonium Fluoride
12125-01-8
Hydrofluoric Acid
7664-39-3
Sulfuric Acid
7664-93-9
5000 lb 5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
100 lb - RQ 100 lb final RQ
RQ 45.4 kg final RQ
100 lb 100 lb RQ 100 lb final RQ
RQ 45.4 kg final RQ
1000 lb 1000 lb RQ 1000 lb final RQ
RQ 454 kg final RQ
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
Sulfuric Acid - 7664-93-9 Carcinogen
WARNING: This product contains a chemical known to the state of California to cause cancer. WARNING: This product contains a chemical known in the State of California to cause birth defects or other reproduction harm.
N-879 Zing® Formula IV Aluminum Pontoon/Boat
Revision Date 10-May-2017
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U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Hydrochloric Acid
7647-01-0
Ammonium Fluoride
12125-01-8
Hydrofluoric Acid
7664-39-3
Sulfuric Acid
7664-93-9
Propargyl Alcohol
107-19-7
U.S. EPA Label Information
X X X X X X X X X X X X X X X
EPA Pesticide Registration Number
Not Applicable
16. OTHER INFORMATION
NFPA Health hazards 3 Flammability 0 Instability 0 Physical and Chemical
Properties Yes
HMIS Health hazards 3 Flammability 0 Physical hazards 0 Personal protection D Issue Date
Revision Date Revision Note
No Information available
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
10-May-2017 10-May-2017
End of Safety Data Sheet
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