Zep ZULFFS128EA User Manual

SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Material name
:
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Material number
:
000000000001045769
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616
Appearance
liquid
Colour
colourless, clear
Odour
solvent-like
Skin corrosion
:
Category 1A
Serious eye damage
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H314 Causes severe skin burns and eye damage.
Precautionary statements
:
Prevention: P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS Label element
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
P304 + P340 + P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P363 Wash contaminated clothing before reuse. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local regulation.
IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
Confirmed animal carcinogen with unknown relevance to humans
2-butoxyethanol
111-76-2
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration [%]
2-butoxyethanol
111-76-2
>= 10 - < 20
2-aminoethanol
141-43-5
>= 5 - < 10
General advice
:
Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled
:
If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. Remove to fresh air. If unconscious place in recovery position and seek medical
Potential Health Effects
Carcinogenicity:
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
advice. If symptoms persist, call a physician.
In case of skin contact
:
If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. If on clothes, remove clothes.
Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes.
In case of eye contact
:
Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. Rinse immediately with plenty of water for at least 15 minutes. Keep eye wide open while rinsing.
Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.
If swallowed
:
Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital.
Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital.
Suitable extinguishing media
:
Dry chemical Water spray jet Alcohol-resistant foam Carbon dioxide (CO2)
Unsuitable extinguishing media
:
High volume water jet
Specific hazards during firefighting
:
Do not allow run-off from fire fighting to enter drains or water courses.
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Hazardous combustion products
:
Carbon dioxide (CO2) Carbon monoxide Smoke Nitrogen oxides (NOx)
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Further information
:
Standard procedure for chemical fires.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if necessary.
Personal precautions, protective equipment and emergency procedures
:
Use personal protective equipment. Ensure adequate ventilation. Refer to protective measures listed in sections 7 and 8. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
: Use personal protective equipment.
Environmental precautions
:
Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal.
Neutralise with acid. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.
Advice on safe handling
:
For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Do not breathe vapours or spray mist. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Dispose of rinse water in accordance with local and national regulations. Always replace cap after use.
Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations.
Conditions for safe storage
:
Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.
Materials to avoid
:
Store and keep away from, oxidizing agents and acids.
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
2-butoxyethanol
111-76-2
TWA
20 ppm
ACGIH
TWA
5 ppm 24 mg/m3
NIOSH REL
TWA
50 ppm 240 mg/m3
OSHA Z-1
TWA
25 ppm 120 mg/m3
OSHA P0
2-aminoethanol
141-43-5
TWA
3 ppm
ACGIH
STEL
6 ppm
ACGIH
TWA
3 ppm 8 mg/m3
NIOSH REL
ST
6 ppm 15 mg/m3
NIOSH REL
TWA
3 ppm 6 mg/m3
OSHA Z-1
STEL
6 ppm 15 mg/m3
OSHA P0
TWA
3 ppm 8 mg/m3
OSHA P0
Component
CAS-No.
Control
parameters
Biological specimen
Sampling
time
Permissible
concentration
Basis
2-BUTOXYETHANOL
111-76-2
Butoxyacetic acid (BAA)
Urine
End of
shift (As
soon as
200 mg/g
ACGIH BEI
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Biological occupational exposure limits
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
possible
after
exposure
ceases)
Remarks:
Creatinine
Respiratory protection
:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.
Remarks
:
The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Eye protection
:
Ensure that eyewash stations and safety showers are close to the workstation location. Safety glasses Wear face-shield and protective suit for abnormal processing problems.
Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems.
Skin and body protection
:
impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
Appearance
:
liquid
Colour
:
colourless, clear
Odour
:
solvent-like
Odour Threshold
:
no data available
pH : 11.5 - 12.5
Melting point/freezing point
:
no data available
Boiling point
:
> 100 °C
Flash point
:
> 93.3 °C Method: TCC
Evaporation rate
:
< 1
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Upper explosion limit
:
no data available
Lower explosion limit
:
no data available
Vapour pressure
:
19 hPa (20 °C)
Relative vapour density
:
no data available
Density
:
1 g/cm3
Water solubility
:
soluble in cold water, soluble in hot water
Solubility in other solvents
:
not determined
Partition coefficient: n­octanol/water
:
no data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
no data available
Viscosity, kinematic
:
no data available
Reactivity
:
Stable
No decomposition if stored and applied as directed.
Chemical stability
:
Stable under normal conditions.
No decomposition if stored and applied as directed.
Possibility of hazardous reactions
:
No decomposition if stored and applied as directed.
Vapours may form explosive mixture with air.
Conditions to avoid
:
Heat, flames and sparks. Extremes of temperature and direct sunlight.
no data available
Incompatible materials
:
Acids Oxidizing agents
Hazardous decomposition products
:
Carbon oxides
Acute oral toxicity
:
Acute toxicity estimate : 2,682 mg/kg
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Method: Calculation method
Acute inhalation toxicity
:
Acute toxicity estimate : > 40 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method
Acute dermal toxicity
:
Acute toxicity estimate : 4,585 mg/kg Method: Calculation method
Acute oral toxicity
:
LD50 Oral mouse: 700 mg/kg
LD50 Oral rat: 1,515 mg/kg
Acute inhalation toxicity
:
LC50 mouse: > 1.21 mg/l
Remarks: Extremely corrosive and destructive to tissue.
Remarks: May cause irreversible eye damage.
Components: 2-aminoethanol:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
2-butoxyethanol: 2-aminoethanol:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
no data available
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Remarks: no data available
Partition coefficient: n­octanol/water
:
Remarks: no data available
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological information
:
no data available
Waste from residues
:
Dispose of in accordance with local regulations. Do not contaminate ponds, waterways or ditches with chemical or used container. The product should not be allowed to enter drains, water courses or the soil.
Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container.
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Mobility in soil
no data available
Other adverse effects
no data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
Send to a licensed waste management company.
Contaminated packaging
:
Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.
Transportation Regulation: 49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IMDG (Vessel): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Cargo Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Passenger Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: TDG (Canada): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
2,2'-iminodiethanol
111-42-2
100
*
SARA 311/312 Hazards
:
Acute Health Hazard Acute Health Hazard
SARA 302
:
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SECTION 14. TRANSPORT INFORMATION
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
SARA 313
:
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop 65
WARNING! This product contains a chemical known to the State of California to cause cancer.
2,2'-iminodiethanol
111-42-2
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL.
AICS
On the inventory, or in compliance with the inventory
NZIoC
On the inventory, or in compliance with the inventory
PICCS
On the inventory, or in compliance with the inventory
IECSC
On the inventory, or in compliance with the inventory
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Causes severe skin burns and eye damage.
Precautionary statements
: Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
Flammability
Health
Instability
3
1
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
The components of this product are reported in the following inventories:
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
OSHA GHS Label Information:
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SAFETY DATA SHEET
BZ7578 HD FLR STRP ZULFFS128 4/1 GAL
Version 1.1
Print Date 10/14/2015
hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Wash contaminated clothing before reuse.
Storage: Store locked up. Disposal: Dispose of contents/container in accordance with local regulation.
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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