Zep ZUCIT128CA User Manual

SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

Material name

:

ZEP HVY-DTY CITRUS CLEANER CON-CA
Material number

:

ZUCIT128CA

Company

:

Zep Inc.

Address

:

350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone

:

404-352-1680

Emergency telephone numbers

For SDS Information

:

Compliance Services 1-877-428-9937

For a Medical Emergency

:

877-541-2016 Toll Free - All Calls Recorded

For a Transportation
Emergency

:

CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616

Recommended use

:

Cleaner
Degreaser
Drain and Sewer Care
Appearance

liquid

Colour

amber

Odour

characteristic

Eye irritation

:

Category 2A

Hazard pictograms

:

Signal word

:

Warning

Hazard statements

:

H319 Causes serious eye irritation.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Manufacturer or supplier's details

Recommended use of the chemical and restrictions on use

Note: This product is labeled as a consumer product in accordance with the United States
Consumer Product Safety Commission regulations. The warnings presented below in this Safety
Data Sheet (SDS) comply with the 2012 OSHA Hazard Communication Standard (GHS - Globally
Harmonized System of Classification and Labeling). The requirements for the labeling and
warnings of consumer products may differ from those required for GHS based hazard
communication.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS label elements

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

Precautionary statements

:

Prevention:
P264 Wash skin thoroughly after handling.
P280 Wear eye protection/ face protection.

Response:

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Substance / Mixture

:

Mixture

Chemical name

CAS-No.

Concentration [%]

Alcohols, C9-11, ethoxylated

68439-46-3

>= 1 - < 3

Oxirane, methyl-, polymer with oxirane, mono(2­ethylhexyl) ether

64366-70-7

>= 1 - < 5

General advice

:

Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
Get medical attention.

If inhaled

:

If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact

:

Wash off immediately with plenty of water for at least 15
minutes.
Remove contaminated clothing and shoes.
Wash contaminated clothing before re-use.
If skin irritation persists, call a physician.

In case of eye contact

:

Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed

:

Keep respiratory tract clear.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Most important symptoms
and effects, both acute and

:

Effects are dependent on exposure (dose, concentration,
contact time).

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

delayed

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
May cause an allergic skin reaction.
Review section 2 of SDS to see all potential hazards.

Notes to physician

:

Treat symptomatically. Symptoms may be delayed.

Suitable extinguishing media

:

Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Unsuitable extinguishing
media

:

High volume water jet

Specific hazards during
firefighting

:

Do not allow run-off from fire fighting to enter drains or water
courses.

Hazardous combustion
products

:

Carbon dioxide (CO2)
Carbon monoxide
Smoke

Specific extinguishing
methods

:

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Further information

:

Standard procedure for chemical fires.

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Special protective equipment
for firefighters

:

Wear self-contained breathing apparatus for firefighting if
necessary.

Personal precautions,
protective equipment and
emergency procedures

:

Use personal protective equipment.

Environmental precautions

:

Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

:

Neutralise with acid.
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

SECTION 5. FIREFIGHTING MEASURES

SECTION 6. ACCIDENTAL RELEASE MEASURES

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

Advice on safe handling

:

Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and national
regulations.

Conditions for safe storage

:

Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid

:

Oxidizing agents
Do not store near acids.

Engineering measures

:

effective ventilation in all processing areas

Respiratory protection

:

Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material

:

Protective gloves

Remarks

:

The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection

:

Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.
Safety glasses

Skin and body protection

:

Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures

:

When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

Personal protective equipment

Hand protection

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

Appearance

:

liquid

Colour

:

amber

Odour

:

characteristic

Odour Threshold

:

No data available

pH : 11 - 12

Melting point/freezing point

:

No data available

Boiling point

:

No data available

Flash point

:

> 93.3 °C
Method: TCC

Evaporation rate

:

1

Upper explosion limit

:

No data available

Lower explosion limit

:

No data available

Vapour pressure

:

No data available

Relative vapour density

:

No data available

Density

:

1.01 g/cm3

Water solubility

:

soluble

Solubility in other solvents

:

not determined

Partition coefficient: n­octanol/water

:

No data available

Auto-ignition temperature

:

not determined

Thermal decomposition

:

No data available

Viscosity, kinematic

:

No data available

Reactivity

:

Stable

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous
reactions

:

No decomposition if stored and applied as directed.

Conditions to avoid

:

Heat, flames and sparks.

Incompatible materials

:

Oxidizing agents
Acids

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Solubility(ies)

Viscosity

SECTION 10. STABILITY AND REACTIVITY

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

Hazardous decomposition
products

:

Carbon oxides
Nitrogen oxides (NOx)

Aggravated Medical
Condition

:

None known.

Symptoms of Overexposure

:

Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.

IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Acute oral toxicity

:

Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Acute oral toxicity

:

LD50 Oral Rat: 1,400 mg/kg

Remarks: May irritate skin.

Remarks: Severe eye irritation

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Carcinogenicity:

Acute toxicity

Product:

Components:
Alcohols, C9-11, ethoxylated:

Skin corrosion/irritation

Product:

Serious eye damage/eye irritation

Product:

Respiratory or skin sensitisation

No data available

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

Remarks: No data available

Partition coefficient: n­octanol/water

:

Remarks: No data available

Regulation

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances

Remarks

This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

Product:

Mobility in soil

No data available

Other adverse effects

No data available

Product:

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

+ B).

Additional ecological
information

:

No data available

Waste from residues

:

The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.

Contaminated packaging

:

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.

Transportation Regulation: 49 CFR (USA):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IMDG (Vessel):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Cargo Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Passenger Air):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: TDG (Canada):
NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

SECTION 14. TRANSPORT INFORMATION

The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.

SECTION 15. REGULATORY INFORMATION

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

TSCA list

:

No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification
requirements.

Components

CAS-No.

Component RQ

(lbs)

Calculated product RQ

(lbs)

sodium hydroxide

1310-73-2

1000

*

SARA 311/312 Hazards

:

Serious eye damage or eye irritation

SARA 302

:

No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313

:

This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other
reproductive harm.

DSL

All components of this product are on the Canadian DSL

TSCA

On TSCA Inventory

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

*: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

California Prop. 65

The components of this product are reported in the following inventories:

For information on the country notification status for other regions please contact the

manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

SECTION 16. OTHER INFORMATION

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SAFETY DATA SHEET

ZEP HVY-DTY CITRUS CLEANER CON-CA

Version 3.0

Revision Date 10/30/2017

Print Date 04/22/2019

NFPA:

HMIS III:

Hazard pictograms

:

Signal word

:

Warning:

Hazard statements

:

Causes serious eye irritation.

Precautionary statements

:

Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection.
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/ attention.

Version:

3.0

Revision Date:

10/30/2017

Print Date:

04/22/2019

Flammability

Health

Instability

2

1

0

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

0

2

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Further information

OSHA - GHS Label Information:

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®,

Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

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