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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Material name
:
ZEP CALCIUM LIME & RST STN REMOVER CON
Material number
:
ZUCAL128
Company
:
Zep Inc.
Address
:
350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Recommended use
:
Bathroom Care Maintenance
Cleaner
Appearance
liquid
Colour
light yellow
Odour
pungent
Skin corrosion
:
Category 1
Serious eye damage
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H314 Causes severe skin burns and eye damage.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
Note: This product is labeled as a consumer product in accordance with the United States
Consumer Product Safety Commission regulations. The warnings presented below in this Safety
Data Sheet (SDS) comply with the 2012 OSHA Hazard Communication Standard (GHS - Globally
Harmonized System of Classification and Labeling). The requirements for the labeling and
warnings of consumer products may differ from those required for GHS based hazard
communication.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Precautionary statements
:
Prevention:
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
urea hydrochloride
506-89-8
>= 10 - < 20
2-hydroxyethanoic acid
79-14-1
>= 1 - < 3
citric acid
77-92-9
>= 1 - < 3
Alcohols, C9-11, ethoxylated
68439-46-3
>= 1 - < 3
General advice
:
Move out of dangerous area.
Get medical attention immediately.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
Move to fresh air.
In case of skin contact
:
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Take off contaminated clothing and shoes immediately.
Wash contaminated clothing before re-use.
If skin irritation persists, call a physician.
Wash off immediately with plenty of water for at least 15
minutes.
Thoroughly clean shoes before reuse.
In case of eye contact
:
Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
If swallowed
:
Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
Take victim immediately to hospital.
Most important symptoms
and effects, both acute and
delayed
:
Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include blistering, irritation, burns, and pain.
Causes severe skin burns and eye damage.
Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.
Unsuitable extinguishing
media
:
High volume water jet
Specific hazards during
firefighting
:
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Nitrogen oxides (NOx)
Chlorine compounds
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
SECTION 5. FIREFIGHTING MEASURES
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
be disposed of in accordance with local regulations.
Standard procedure for chemical fires.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Environmental precautions
:
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
Advice on safe handling
:
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
To avoid spills during handling keep bottle on a metal tray.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage
:
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Oxidizing agents
Keep away from metals.
Store and keep away from bases and alkalies.
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Personal protective equipment
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material
:
Protective gloves
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection
:
Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
liquid
Colour
:
light yellow
Odour
:
pungent
Odour Threshold
:
No data available
pH : < 1
Melting point/freezing point
:
Not applicable
Boiling point
:
100 °C
Flash point
:
does not flash
Evaporation rate
:
No data available
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
1.067 g/cm3
Water solubility
:
soluble
Solubility in other solvents
:
not determined
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Partition coefficient: noctanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
No decomposition if stored and applied as directed.
Conditions to avoid
:
Extremes of temperature and direct sunlight.
Incompatible materials
:
Oxidizing agents
Organic materials
Metals
Bases
Hazardous decomposition
products
:
Carbon oxides
Chlorine
Nitrogen oxides (NOx)
Sulphur oxides
Ammonia gas may be liberated at high temperatures.
Aggravated Medical
Condition
:
None known.
Symptoms of Overexposure
:
Effects are dependent on exposure (dose, concentration,
contact time).
Effects are immediate and delayed.
Symptoms may include blistering, irritation, burns, and pain.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
OSHA
No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Acute oral toxicity
:
Acute toxicity estimate : 4,197 mg/kg
Method: Calculation method
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method
Acute oral toxicity
:
LD50 Oral Rat: 5,400 mg/kg
Acute dermal toxicity
:
LD50 Dermal Rabbit: > 2,000 mg/kg
Acute oral toxicity
:
LD50 Oral Rat: 1,400 mg/kg
Remarks: Extremely corrosive and destructive to tissue.
Remarks: May cause irreversible eye damage.
Acute toxicity
Product:
Components:
citric acid:
Alcohols, C9-11, ethoxylated:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Remarks: No data available
Partition coefficient: noctanol/water
:
Remarks: No data available
Partition coefficient: noctanol/water
:
log Pow: -1.11
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
No data available
Waste from residues
:
Do not dispose of waste into sewer.
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Components:
2-hydroxyethanoic acid :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Transportation Regulation: 49 CFR (USA):
UN3264, Corrosive liquid, acidic, inorganic, n.o.s., (SULFAMIC ACID), 8, II
Transportation Regulation: IMDG (Vessel):
UN3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., (SULFAMIC ACID), 8, II
Transportation Regulation: IATA (Cargo Air):
UN3264, Corrosive liquid, acidic, inorganic, n.o.s., (SULFAMIC ACID), 8, II
Transportation Regulation: IATA (Passenger Air):
UN3264, Corrosive liquid, acidic, inorganic, n.o.s., (SULFAMIC ACID), 8, II
Transportation Regulation: TDG (Canada):
UN3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., (SULFAMIC ACID), 8, II
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification
requirements.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
hydrochloric acid
7647-01-0
5000
*
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
SARA 311/312 Hazards
:
Skin corrosion or irritation
Serious eye damage or eye irritation
SARA 302
:
No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL
NFPA:
HMIS III:
Flammability
Health
Instability
3
0
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
0
0
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
California Prop. 65
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
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SAFETY DATA SHEET
ZEP CALCIUM LIME & RST STN REMOVER CON
Version 4.0
Revision Date 07/20/2018
Print Date 04/26/2019
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Causes severe skin burns and eye damage.
Precautionary statements
:
Prevention: Wash skin thoroughly after handling. Wear protective gloves/ protective
clothing/ eye protection/ face protection.
Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF
INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately
call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER/doctor. Wash contaminated clothing before
reuse.
Storage: Store locked up.
Disposal: Dispose of contents/container in accordance with local regulation.
Version:
4.0
Revision Date:
07/20/2018
Print Date:
04/26/2019
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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