Zep ZPP1041705 User Manual

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Material name

:

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Material number

:

000000000001041705

Company

:

Zep Inc.

Address

:

1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone

:

404-352-1680

Emergency telephone numbers

For SDS Information

:

Compliance Services 1-877-428-9937

For a Medical Emergency

:

877-541-2016 Toll Free - All Calls Recorded

For a Transportation
Emergency

:

CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616

Appearance

liquid

Colour

colourless, clear

Odour

odourless, mild

Oxidizing liquids

:

Category 1

Skin corrosion

:

Category 1A

Serious eye damage

:

Category 1

Hazard pictograms

:

Signal word

:

Danger

Hazard statements

:

H271 May cause fire or explosion; strong oxidiser.
H314 Causes severe skin burns and eye damage.

Precautionary statements

:

Prevention:
P210 Keep away from heat.
P220 Keep/Store away from clothing/ combustible materials.
P221 Take any precaution to avoid mixing with combustibles.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
P283 Wear fire/ flame resistant/ retardant clothing.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Manufacturer or supplier's details

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS Label element

1 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Response:

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
P306 + P360 IF ON CLOTHING: rinse immediately
contaminated clothing and skin with plenty of water before
removing clothes.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam for extinction.
P371 + P380 + P375 In case of major fire and large quantities:
Evacuate area. Fight fire remotely due to the risk of explosion.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.

IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH

Confirmed animal carcinogen with unknown relevance to
humans

hydrogen peroxide

7722-84-1

OSHA

No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Substance / Mixture

:

Mixture

Chemical Name

CAS-No.

Concentration [%]

hydrogen peroxide

7722-84-1

>= 5 - < 10

Potential Health Effects

Carcinogenicity:

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

2 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

General advice

:

Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled

:

If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact

:

Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
If on skin, rinse well with water.
If on clothes, remove clothes.

In case of eye contact

:

In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.

If swallowed

:

Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Suitable extinguishing media

:

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing
media

:

High volume water jet

Hazardous combustion
products

:

Carbon dioxide (CO2)
Carbon monoxide

Specific extinguishing
methods

:

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Further information

:

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

Special protective equipment
for firefighters

:

Wear self-contained breathing apparatus for firefighting if
necessary.

SECTION 4. FIRST AID MEASURES

SECTION 5. FIREFIGHTING MEASURES

3 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Personal precautions,
protective equipment and
emergency procedures

:

Use personal protective equipment.
Evacuate personnel to safe areas.

Environmental precautions

:

Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for
containment and cleaning up

:

Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

Advice on safe handling

:

Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
To avoid spills during handling keep bottle on a metal tray.
Dispose of rinse water in accordance with local and national
regulations.

Conditions for safe storage

:

Prevent unauthorized access.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid

:

Oxidizing agents
Do not freeze.

Components

CAS-No.

Value type
(Form of
exposure)

Control
parameters /
Permissible
concentration

Basis

hydrogen peroxide

7722-84-1

TWA

1 ppm

ACGIH

TWA

1 ppm

1.4 mg/m3

NIOSH REL

TWA

1 ppm

1.4 mg/m3

OSHA Z-1

TWA

1 ppm

OSHA P0

SECTION 6. ACCIDENTAL RELEASE MEASURES

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

4 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

1.4 mg/m3

Respiratory protection

:

No personal respiratory protective equipment normally
required.
In case of insufficient ventilation, wear suitable respiratory
equipment.

Remarks

:

The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection

:

Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.

Skin and body protection

:

impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures

:

When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Appearance

:

liquid

Colour

:

colourless, clear

Odour

:

odourless, mild

Odour Threshold

:

no data available

pH : 5 - 6

Melting point/freezing point

:

no data available

Boiling point

:

100 °C

Flash point

:

does not flash

Evaporation rate

:

1

Upper explosion limit

:

no data available

Lower explosion limit

:

no data available

Vapour pressure

:

not determined

Relative vapour density

:

no data available

Density

:

1 g/cm3

Water solubility

:

soluble in cold water, soluble in hot water

Personal protective equipment

Hand protection

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Solubility(ies)

5 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Solubility in other solvents

:

soluble

Partition coefficient: n­octanol/water

:

no data available

Auto-ignition temperature

:

not determined

Thermal decomposition

:

no data available

Viscosity, kinematic

:

3.2 mm2/s (20 °C)
Reactivity

:

Stable

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous
reactions

:

No decomposition if stored and applied as directed.

Conditions to avoid

:

Heat, flames and sparks.

Incompatible materials

:

Reducing agents
Cyanides
Organic materials
Oxidizing agents

Hazardous decomposition
products

:

Carbon oxides

Acute oral toxicity

:

Acute toxicity estimate : > 5,000 mg/kg
Method: Calculation method

Remarks: Extremely corrosive and destructive to tissue.

Remarks: May cause irreversible eye damage.

Viscosity

SECTION 10. STABILITY AND REACTIVITY

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Product:

Skin corrosion/irritation

Product:

Serious eye damage/eye irritation

Product:

Respiratory or skin sensitisation

6 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Remarks: no data available

Remarks: no data available

Partition coefficient: n­octanol/water

:

Remarks: no data available

Regulation

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

hydrogen peroxide:

STOT - single exposure

no data available

STOT - repeated exposure

no data available

Aspiration toxicity

no data available

Further information

Product:

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

Product:

Mobility in soil

no data available

Other adverse effects

no data available

Product:

7 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Substances

Remarks

This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological
information

:

no data available
no data available

Waste from residues

:

Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.

Contaminated packaging

:

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

UNRTDG

Not regulated as a dangerous good

IATA-DGR

Not regulated as a dangerous good

IMDG-Code

Not regulated as a dangerous good

49 CFR

Not regulated as a dangerous good

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

SECTION 14. TRANSPORT INFORMATION

International regulation

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable for product as supplied.

National Regulations

Special precautions for user

not applicable

8 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

Components

CAS-No.

Component RQ

(lbs)

Calculated product RQ

(lbs)

sodium hydroxide

1310-73-2

1000

*

SARA 311/312 Hazards

:

Fire Hazard
Acute Health Hazard

SARA 302

:

SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.

SARA 313

:

SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.

California Prop 65

This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.

TSCA

On TSCA Inventory

DSL

This product contains one or several components that are not on the
Canadian DSL nor NDSL.

AICS

Not in compliance with the inventory

NZIoC

Not in compliance with the inventory

PICCS

Not in compliance with the inventory

IECSC

Not in compliance with the inventory

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

*: Calculated RQ exceeds reasonably attainable upper limit.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

The components of this product are reported in the following inventories:

Inventory Acronym and Validity Area Legend:

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

SECTION 16. OTHER INFORMATION

9 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

NFPA:

HMIS III:

Hazard pictograms

:

Signal word

:

Danger:

Hazard statements

:

May cause fire or explosion; strong oxidiser. Causes severe skin burns and eye
damage.

Precautionary statements

:

Prevention: Keep away from heat. Keep/Store away from clothing/ combustible
materials. Take any precaution to avoid mixing with combustibles. Wash skin
thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/
face protection. Wear fire/ flame resistant/ retardant clothing.
Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or
hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/
shower. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/ physician. IF ON CLOTHING: rinse immediately contaminated clothing and skin
with plenty of water before removing clothes. Wash contaminated clothing before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. In
case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk
of explosion.

Storage: Store locked up.
Disposal: Dispose of contents/container in accordance with local regulation.

Flammability

Health

Instability

OX

3

1

0

OX

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

1

3

3

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Further information

OSHA GHS Label Information:

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

10 / 11

SAFETY DATA SHEET

BZ7355 STN RMVR W/PEROXIDE R00701 6QT/CS

Version 1.1

Revision Date 01/09/2015

Print Date 06/01/2015

11 / 11