SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
Material name
:
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Material number
:
000000000001041491
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW
Atlanta, GA 30318
Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation
Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616
Appearance
liquid
Colour
colourless, clear
Odour
mild
Acute toxicity (Oral)
:
Category 4
Skin corrosion
:
Category 1A
Serious eye damage
:
Category 1
Hazard pictograms
:
Signal word
:
Danger
Hazard statements
:
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
Precautionary statements
:
Prevention:
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER or doctor/ physician if you feel unwell. Rinse mouth.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS Label element
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P310 IF INHALED: Remove victim to fresh air
and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
IARC
No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP
No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Substance / Mixture
:
Mixture
Chemical Name
CAS-No.
Concentration [%]
orthophosphoric acid
7664-38-2
>= 30 - < 50
Alcohol Ethoxylates
66455-15-0
>= 1 - < 5
General advice
:
Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled
:
If unconscious place in recovery position and seek medical
Potential Health Effects
Carcinogenicity:
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
advice.
If symptoms persist, call a physician.
In case of skin contact
:
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact
:
Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
:
Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
Suitable extinguishing media
:
Dry chemical
Unsuitable extinguishing
media
:
High volume water jet
Hazardous combustion
products
:
Carbon dioxide (CO2)
Carbon monoxide
Smoke
Phosphorus compounds
Specific extinguishing
methods
:
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information
:
Standard procedure for chemical fires.
Special protective equipment
for firefighters
:
Wear self-contained breathing apparatus for firefighting if
necessary.
Personal precautions,
protective equipment and
emergency procedures
:
Use personal protective equipment.
Environmental precautions
:
Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
Methods and materials for
containment and cleaning up
:
Neutralize with chalk, alkali solution or ammonia.
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
Advice on safe handling
:
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
To avoid spills during handling keep bottle on a metal tray.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage
:
Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid
:
Keep away from oxidising agents and strongly acid or alkaline
materials.
Do not freeze.
Components
CAS-No.
Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
orthophosphoric acid
7664-38-2
TWA
1 mg/m3
ACGIH
STEL
3 ppm
ACGIH
TWA
1 mg/m3
NIOSH REL
ST
3 mg/m3
NIOSH REL
TWA
1 mg/m3
OSHA Z-1
TWA
1 mg/m3
OSHA P0
STEL
3 mg/m3
OSHA P0
Remarks
:
The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection
:
Eye wash bottle with pure water
Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Personal protective equipment
Hand protection
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
problems.
Skin and body protection
:
impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures
:
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.
Appearance
:
liquid
Colour
:
colourless, clear
Odour
:
mild
Odour Threshold
:
no data available
pH : 1 - 1.5
Melting point/freezing point
:
no data available
Boiling point
:
107.22 °C
Flash point
:
not applicable
Evaporation rate
:
1
Upper explosion limit
:
no data available
Lower explosion limit
:
no data available
Vapour pressure
:
not applicable
Relative vapour density
:
no data available
Density
:
1.259 g/cm3
Water solubility
:
soluble
Partition coefficient: noctanol/water
:
no data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
no data available
Viscosity, kinematic
:
6.0 mm2/s (20 °C)
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
reactions
:
No dangerous reaction known under conditions of normal use.
Conditions to avoid
:
Extremes of temperature and direct sunlight.
Incompatible materials
:
Alkali metals
Metals
Hazardous decomposition
products
:
Carbon oxides
Phosphorus compounds
Acute oral toxicity
:
Acute toxicity estimate : 1,034 mg/kg
Method: Calculation method
Remarks: Extremely corrosive and destructive to tissue.
Remarks: May cause irreversible eye damage.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
orthophosphoric acid:
Alcohol Ethoxylates:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
Aspiration toxicity
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
Remarks: no data available
Partition coefficient: noctanol/water
:
Remarks: no data available
Regulation
40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks
This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
:
no data available
Waste from residues
:
Dispose of in accordance with local regulations.
Contaminated packaging
:
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
no data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Mobility in soil
no data available
Other adverse effects
no data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
IATA-DGR
UN/ID No.
:
3264
Proper shipping name
:
Corrosive liquid, acidic, inorganic, n.o.s.
(PHOSPHORIC ACID)
Class
:
8
Packing group
:
II
Labels
:
8
Packing instruction (cargo
aircraft)
:
855
Packing instruction
(passenger aircraft)
:
851
IMDG-Code
UN number
:
3264
Proper shipping name
:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(PHOSPHORIC ACID)
Class
:
8
Packing group
:
II
Labels
:
8
EmS Code
:
F-A, S-B
Marine pollutant
:
no
49 CFR
UN/ID/NA number
:
3264
Proper shipping name
:
Corrosive liquid, acidic, inorganic, n.o.s.
(PHOSPHORIC ACID)
Class
:
8
Packing group
:
II
Labels
:
8
ERG Code
:
154
Marine pollutant
:
no
SECTION 14. TRANSPORT INFORMATION
International regulation
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
Special precautions for user
not applicable
SECTION 15. REGULATORY INFORMATION
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
TRIHYDROXIDOOXIDOPHOSPH
ORUS
7664-38-2
5000
*
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313
:
SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL.
AICS
On the inventory, or in compliance with the inventory
NZIoC
Not in compliance with the inventory
PICCS
On the inventory, or in compliance with the inventory
IECSC
On the inventory, or in compliance with the inventory
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
The components of this product are reported in the following inventories:
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
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SAFETY DATA SHEET
BZ7429 CALCM & LM RMVR R11524 4/1 GAL
Version 1.2
Revision Date 10/11/2014
Print Date 06/01/2015
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Danger:
Hazard statements
:
Harmful if swallowed. Causes severe skin burns and eye damage.
Precautionary statements
:
Prevention: Wash skin thoroughly after handling. Do not eat, drink or smoke when
using this product. Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON
SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with
water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/ physician. Wash contaminated clothing before reuse.
Storage: Store locked up.
Disposal: Dispose of contents/container in accordance with local regulation.
Flammability
Health
Instability
3
1
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1
0
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Further information
OSHA GHS Label Information:
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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