Zep B2395938 User Manual

SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Material name

:

ZEP FRESHEN DISINFECTANT SPRAY MIST

EPA ID Number:

498-134-1270
Material number

:

000000000001050017

Company

:

Zep, Inc.

Address

:

350 Joe Frank Harris Parkway, SE
Emerson, GA 30137
Telephone

:

404-352-1680

Emergency telephone numbers

For SDS Information

:

Compliance Services 1-877-428-9937

For a Medical Emergency

:

877-541-2016 Toll Free - All Calls Recorded

For a Transportation
Emergency

:

CHEMTREC: 800-424-9300 - All Calls Recorded.
In the District of Columbia 202-483-7616

Appearance

Aerosol containing a liquefied gas

Colour

clear, light yellow

Odour

characteristic

Flammable aerosols

:

Category 1

Gases under pressure

:

Liquefied gas

Eye irritation

:

Category 2A

Hazard pictograms

:

Flame

Gas cylinder

Exclamation

mark

Signal word

:

Danger

Hazard statements

:

H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.

Precautionary statements

:

Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Manufacturer or supplier's details

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

GHS Classification

GHS label elements

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
P264 Wash skin thoroughly after handling.
P280 Wear eye protection/ face protection.

Response:

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/container in accordance with local
regulation.
Substance / Mixture

:

Mixture

Substance / Mixture

:

Chemical Mixture

Chemical name

CAS-No.

Concentration [%]

ethanol

64-17-5

>= 60 - < 80

1,1-difluoroethane

75-37-6

>= 10 - < 30

propane

74-98-6

>= 5 - < 10

butane

106-97-8

>= 5 - < 10

General advice

:

Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled

:

If unconscious, place in recovery position and seek medical
advice.
If symptoms persist, call a physician.

In case of skin contact

:

Wash off with soap and water.
Wash off immediately with plenty of water for at least 15
minutes.
If on clothes, remove clothes.
Wash contaminated clothing before re-use.
If skin irritation persists, call a physician.
In case of eye contact

:

Remove contact lenses.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

The exact percentages of disclosed substances are withheld as trade secrets.

SECTION 4. FIRST AID MEASURES

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Protect unharmed eye.
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed

:

Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.

Most important symptoms
and effects, both acute and
delayed

:

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
Effects are dependent on exposure (dose, concentration,
contact time).
Causes serious eye irritation.
Review section 2 of SDS to see all potential hazards.

Notes to physician

:

Treat symptomatically. Symptoms may be delayed.

Suitable extinguishing media

:

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing
media

:

High volume water jet

Hazardous combustion
products

:

Carbon dioxide (CO2)
Carbon monoxide
Smoke
Fluorine compounds
Hydrogen fluoride
Fluorocarbons

Specific extinguishing
methods

:

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Further information

:

For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.

Special protective equipment
for firefighters

:

Wear self-contained breathing apparatus for firefighting if
necessary.

Personal precautions,
protective equipment and
emergency procedures

:

Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

SECTION 5. FIREFIGHTING MEASURES

SECTION 6. ACCIDENTAL RELEASE MEASURES

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Environmental precautions

:

Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains, inform
respective authorities.

Methods and materials for
containment and cleaning up

:

Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.

Advice on safe handling

:

Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Dispose of rinse water in accordance with local and national
regulations.
Always replace cap after use.

Conditions for safe storage

:

BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.

Materials to avoid

:

Oxidizing agents

Components

CAS-No.

Value type
(Form of
exposure)

Control
parameters /
Permissible
concentration

Basis

ethanol

64-17-5

TWA

1,000 ppm

ACGIH

TWA

1,000 ppm
1,900 mg/m3

NIOSH REL

TWA

1,000 ppm
1,900 mg/m3

OSHA Z-1

TWA

1,000 ppm
1,900 mg/m3

OSHA P0
STEL

1,000 ppm

ACGIH

PEL

1,000 ppm
1,900 mg/m3

CAL PEL

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

1,1-difluoroethane

75-37-6

TWA

1,000 ppm

US WEEL

propane

74-98-6

TWA

1,000 ppm
1,800 mg/m3

NIOSH REL

TWA

1,000 ppm
1,800 mg/m3

OSHA Z-1

TWA

1,000 ppm
1,800 mg/m3

OSHA P0

PEL

1,000 ppm
1,800 mg/m3

CAL PEL

butane

106-97-8

TWA

800 ppm
1,900 mg/m3

NIOSH REL

TWA

800 ppm
1,900 mg/m3

OSHA P0

PEL

800 ppm
1,900 mg/m3

CAL PEL
STEL

1,000 ppm

ACGIH

Engineering measures

:

effective ventilation in all processing areas

Respiratory protection

:

Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Material

:

Protective gloves

Remarks

:

The suitability for a specific workplace should be discussed
with the producers of the protective gloves.

Eye protection

:

Access to clean water to rinse eyes must be available, options
include: eye wash stations or showers, or eye wash bottles
with pure water.
Tightly fitting safety goggles

Skin and body protection

:

Impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures

:

When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

Appearance

:

Aerosol containing a liquefied gas

Colour

:

clear, light yellow

Odour

:

characteristic

Odour Threshold

:

No data available

pH : 10.8

Personal protective equipment

Hand protection

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Melting point/freezing point

:

No data available

Boiling point

:

78.4 °C

Flash point

:

No data available

Evaporation rate

:

No data available

Flammability (solid, gas,
liquid)

:

Flammable aerosol.

Upper explosion limit

:

No data available

Lower explosion limit

:

No data available

Vapour pressure

:

No data available

Relative vapour density

:

No data available

Density

:

0.844 g/cm3Value for liquid concentrate.

Water solubility

:

completely soluble

Partition coefficient: n­octanol/water

:

No data available

Auto-ignition temperature

:

No data available

Thermal decomposition

:

No data available

Viscosity, kinematic

:

No data available

Heat of combustion

:

29.16 kJ/g
Reactivity

:

Stable

Chemical stability

:

Stable under normal conditions.

Possibility of hazardous
reactions

:

No decomposition if stored and applied as directed.

Vapours may form explosive mixture with air.

Conditions to avoid

:

Avoid temperatures above 60°C, direct sunlight and contact
with sources of heat.
Heat, flames and sparks.

Incompatible materials

:

Strong oxidizing agents

Hazardous decomposition
products

:

Carbon monoxide, carbon dioxide and unburned
hydrocarbons (smoke).

Solubility(ies)

Viscosity

SECTION 10. STABILITY AND REACTIVITY

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Aggravated Medical
Condition

:

None known.

Symptoms of Overexposure

:

Effects are immediate and delayed.
Symptoms may include irritation, redness, pain, and rash.
Effects are dependent on exposure (dose, concentration,
contact time).
Causes serious eye irritation.
Review section 2 of SDS to see all potential hazards.
Treat symptomatically. Symptoms may be delayed.

IARC

No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.

ACGIH

Confirmed animal carcinogen with unknown relevance to
humans

ethanol

64-17-5

OSHA

No component of this product present at levels greater than or
equal to 0.1% is on OSHA’s list of regulated carcinogens.

NTP

No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.

Acute oral toxicity

:

LD50 Oral Rat: 7,060 mg/kg

Acute inhalation toxicity

:

LC50 Rat: 124.7 mg/l
Exposure time: 4 h
Test atmosphere: vapour

Acute inhalation toxicity

:

LC50 Mouse: 977,000 mg/l
Exposure time: 2 h

Remarks: May cause skin irritation in susceptible persons.

Remarks: Irritating to eyes.

SECTION 11. TOXICOLOGICAL INFORMATION

Potential Health Effects

Carcinogenicity:

Acute toxicity

Components:
ethanol:

1,1-difluoroethane:

Skin corrosion/irritation

Product:

Serious eye damage/eye irritation

Product:

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Remarks: No data available

Partition coefficient: n­octanol/water

:

Remarks: No data available

Partition coefficient: n­octanol/water

:

Remarks: No data available

Partition coefficient: n­octanol/water

:

Pow: 2.89

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

Carcinogenicity

No data available

Reproductive toxicity

No data available

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

Product:

Components:
ethanol :

butane :

Mobility in soil

No data available

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Regulation

40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances

Remarks

This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).

Additional ecological
information

:

No data available

Waste from residues

:

Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Dispose of in accordance with local regulations.

Contaminated packaging

:

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

Transportation Regulation: 49 CFR (USA):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: IATA (Cargo Air):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: IATA (Passenger Air):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantity

Other adverse effects

No data available

Product:

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

SECTION 14. TRANSPORT INFORMATION

The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

TSCA list

:

No substances are subject to a Significant New Use Rule.

No substances are subject to TSCA 12(b) export notification
requirements.

SARA 311/312 Hazards

:

Flammable (gases, aerosols, liquids, or solids)
Gases under pressure
Serious eye damage or eye irritation

SARA 302

:

No chemicals in this material are subject to the reporting
requirements of SARA Title III, Section 302.

SARA 313

:

This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.

WARNING: This product can expose you to chemicals
including biphenyl-2-ol, which is/are known to the State of
California to cause cancer. For more information go to
www.P65Warnings.ca.gov.

SECTION 15. REGULATORY INFORMATION

This product is regulated under the United States Federal Insecticide, Fungicide and Rodenticide Act
(FIFRA).

Pesticide Labeling Information Required Under U.S. FIFRA Regulations

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject
to certain labeling requirements under federal pesticide law. These requirements differ from the
classification criteria and hazard information required for safety data sheets, and for workplace labels
of non-pesticide chemicals. Following is the hazard information as required on the pesticide label:
WARNING
Causes eye irritation.
Do not get in eyes.
Avoid contact with skin.
Avoid contamination of foodstuff.

EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

California Prop. 65

The components of this product are reported in the following inventories:

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

DSL

All components of this product are on the Canadian DSL

TSCA

On TSCA Inventory

NFPA:

HMIS III:

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

4

0

2

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

FLAMMABILITY

INSTABILITY

HEALTH

4

0

3

0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme

SPECIAL HAZARD.

For information on the country notification status for other regions please contact the

manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)

SECTION 16. OTHER INFORMATION

Further information

OSHA - GHS Label Information:

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SAFETY DATA SHEET

ZEP FRESHEN DISINFECTANT SPRAY MIST

Version 1.0

Revision Date 05/08/2020

Print Date 08/31/2020

Hazard pictograms

:

Flame

Gas cylinder

Exclamation

mark

Signal word

:

Danger:

Hazard statements

:

Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Causes serious eye irritation.

Precautionary statements

:

Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly
after handling. Wear eye protection/ face protection.
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/ attention.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
Disposal: Dispose of contents/container in accordance with local regulation.

Version:

1.0

Revision Date:

05/08/2020

Print Date:

08/31/2020

We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.

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