Zep A07347 (224) User Manual

SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
Material name
:
ZEP ZEPYNAMIC A II SURFACE DISINFECTANT
EPA ID Number:
33176-5-1270 Material number
:
000000000000351501
Company
:
Zep, Inc.
Address
:
350 Joe Frank Harris Parkway, SE Emerson, GA 30137 Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616
Recommended use
:
Disinfectant Appearance
Aerosol containing a liquefied gas
Colour
colourless, light yellow
Odour
pleasant
Flammable aerosols
:
Category 2
Gases under pressure
:
Liquefied gas
Eye irritation
:
Category 2A
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H223 Flammable aerosol. H280 Contains gas under pressure; may explode if heated. H319 Causes serious eye irritation.
Precautionary statements
:
Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces.
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
No smoking. P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. P403 Store in a well-ventilated place. Disposal: P501 Dispose of contents/container in accordance with local regulation. Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
ethanol
64-17-5
>= 30 - < 50
butane
106-97-8
>= 10 - < 20
propane
74-98-6
>= 1 - < 5
propan-2-ol
67-63-0
>= 1 - < 5
General advice
:
Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled
:
If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact
:
If skin irritation persists, call a physician. Wash off immediately with plenty of water for at least 15 minutes. Wash contaminated clothing before reuse. Remove contaminated clothing and shoes.
In case of eye contact
:
Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a specialist. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
If swallowed
:
Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital.
Most important symptoms and effects, both acute and delayed
:
Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Causes serious eye irritation. Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
Suitable extinguishing media
:
Water spray jet Carbon dioxide (CO2) Alcohol-resistant foam Dry chemical
Unsuitable extinguishing media
:
High volume water jet
Hazardous combustion products
:
Carbon dioxide (CO2) Carbon monoxide Smoke
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Further information
:
For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers.
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if necessary.
Personal precautions, protective equipment and emergency procedures
:
Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
:
Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
container for disposal.
Advice on safe handling
:
Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Do not breathe vapours or spray mist. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Always replace cap after use.
Conditions for safe storage
:
BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards.
Materials to avoid
:
Oxidizing agents
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
ethanol
64-17-5
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm 1,900 mg/m3
NIOSH REL
TWA
1,000 ppm 1,900 mg/m3
OSHA Z-1
TWA
1,000 ppm 1,900 mg/m3
OSHA P0 STEL
1,000 ppm
ACGIH
PEL
1,000 ppm 1,900 mg/m3
CAL PEL
butane
106-97-8
TWA
800 ppm 1,900 mg/m3
NIOSH REL
TWA
800 ppm 1,900 mg/m3
OSHA P0
PEL
800 ppm 1,900 mg/m3
CAL PEL propane
74-98-6
TWA
1,000 ppm
ACGIH
TWA
1,000 ppm 1,800 mg/m3
NIOSH REL
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
TWA
1,000 ppm 1,800 mg/m3
OSHA Z-1
TWA
1,000 ppm 1,800 mg/m3
OSHA P0
PEL
1,000 ppm 1,800 mg/m3
CAL PEL propan-2-ol
67-63-0
TWA
200 ppm
ACGIH
STEL
400 ppm
ACGIH
TWA
400 ppm 980 mg/m3
NIOSH REL
ST
500 ppm 1,225 mg/m3
NIOSH REL
TWA
400 ppm 980 mg/m3
OSHA Z-1
TWA
400 ppm 980 mg/m3
OSHA P0
STEL
500 ppm 1,225 mg/m3
OSHA P0
PEL
400 ppm 980 mg/m3
CAL PEL
STEL
500 ppm 1,225 mg/m3
CAL PEL
Component
CAS-No.
Control
parameters
Biological specimen
Sampling
time
Permissible
concentration
Basis
PROPAN-2-OL
67-63-0
Acetone
Urine
End of shift at end of
workwee
k
40 mg/l
ACGIH BEI
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Material
:
Protective gloves
Remarks
:
The suitability for a specific workplace should be discussed with the producers of the protective gloves.
Eye protection
:
Safety glasses Ensure that eyewash stations and safety showers are close to the workstation location.
Skin and body protection
:
Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures
:
Wash hands before breaks and at the end of workday. When using do not eat, drink or smoke.
Biological occupational exposure limits
Personal protective equipment
Hand protection
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
Appearance
:
Aerosol containing a liquefied gas
Colour
:
colourless, light yellow
Odour
:
pleasant
Odour Threshold
:
No data available
pH : 10 - 11
Melting point/freezing point
:
No data available
Boiling point
:
No data available
Flash point
:
No data available
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Flammable aerosol.
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
0.895 g/cm3
Water solubility
:
soluble
Solubility in other solvents
:
not determined
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
No data available
Viscosity, kinematic
:
No data available
Heat of combustion
:
24.20 kJ/g Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous
:
Vapours may form explosive mixture with air.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
reactions
No decomposition if stored and applied as directed.
Conditions to avoid
:
Extremes of temperature and direct sunlight. Heat, flames and sparks.
Incompatible materials
:
Oxidizing agents Reducing agents
Hazardous decomposition products
:
Carbon oxides
Aggravated Medical Condition
:
None known.
Symptoms of Overexposure
:
Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash.
IARC
Group 2A: Probably carcinogenic to humans
sodium nitrite
7632-00-0
ACGIH
Confirmed animal carcinogen with unknown relevance to humans
ethanol
64-17-5
OSHA
No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Acute oral toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Acute oral toxicity
:
LD50 Oral Rat: 7,060 mg/kg
Acute inhalation toxicity
:
LC50 Rat: 124.7 mg/l Exposure time: 4 h Test atmosphere: vapour
Acute oral toxicity
:
LD50 Oral Rat: 4,396 mg/kg Method: Calculation method
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
Carcinogenicity:
Acute toxicity
Product:
Components: ethanol:
propan-2-ol:
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
Remarks: Irritating to skin.
Remarks: Irritating to eyes.
Remarks: No data available
Partition coefficient: n-
:
Remarks: No data available
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
octanol/water
Partition coefficient: n­octanol/water
:
Remarks: No data available
Partition coefficient: n­octanol/water
:
Pow: 2.89
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological information
:
No data available
Waste from residues
:
Dispose of in accordance with local regulations. Do not contaminate ponds, waterways or ditches with chemical or used container. The product should not be allowed to enter drains, water courses or the soil.
Contaminated packaging
:
Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quantity
Components: ethanol :
butane :
Mobility in soil
No data available
Other adverse effects
No data available
Product:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, FLAMMABLE, 2.1, (LQ), - Limited quantity
TSCA list
:
No substances are subject to TSCA 12(b) export notification requirements.
No substances are subject to a Significant New Use Rule.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
sodium nitrite
7632-00-0
100
*
SARA 311/312 Hazards
:
Flammable (gases, aerosols, liquids, or solids) Gases under pressure Serious eye damage or eye irritation
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.
SECTION 15. REGULATORY INFORMATION
This product is regulated under the United States Federal Insecticide, Fungicide and Rodenticide Act (FIFRA).
Pesticide Labeling Information Required Under U.S. FIFRA Regulations
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION Harmful if inhaled. Causes moderate eye irritation.
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
WARNING: This product can expose you to chemicals including biphenyl-2-ol, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
DSL
All components of this product are on the Canadian DSL
TSCA
On TSCA Inventory
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Warning:
Flammability
Health
Instability
3
3
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
3
2
3
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
California Prop. 65
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
Further information
OSHA - GHS Label Information:
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SAFETY DATA SHEET
A07347 (224) ZEPYNAMIC A II 351501 20N16
Version 3.0
Print Date 06/29/2020
Hazard statements
:
Flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation.
Precautionary statements
:
Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Store in a well-ventilated place. Disposal: Dispose of contents/container in accordance with local regulation.
Version:
3.0
Revision Date:
02/12/2018
Print Date:
06/29/2020
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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