Zep 92524 User Manual

SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Material name
:
BZ7978 ZEP REACH 092524 4/1G Material number
:
000000000001049220
Company
:
Zep Inc.
Address
:
1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318 Telephone
:
404-352-1680
Emergency telephone numbers
For SDS Information
:
Compliance Services 1-877-428-9937
For a Medical Emergency
:
877-541-2016 Toll Free - All Calls Recorded
For a Transportation Emergency
:
CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616
Recommended use
:
Hand Care Appearance
gel
Colour
green
Odour
characteristic
Eye irritation
:
Category 2A
Hazard pictograms
:
Signal word
:
Warning
Hazard statements
:
H319 Causes serious eye irritation.
Precautionary statements
:
Prevention: P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Manufacturer or supplier's details
Recommended use of the chemical and restrictions on use
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
GHS Classification
GHS label elements
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
attention.
Substance / Mixture
:
Mixture
Chemical name
CAS-No.
Concentration [%]
Distillates (petroleum), hydrotreated light
64742-47-8
>= 30 - < 50
Alcohols, C12-16, ethoxylated
68551-12-2
>= 5 - < 10
Fatty acids, tall-oil, reaction products with isopropanolamine
68440-26-6
>= 1 - < 5 Solvent naphtha (petroleum), heavy aliph.
64742-96-7
>= 1 - < 5
General advice
:
Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.
If inhaled
:
If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.
In case of skin contact
:
This product is formulated for use on skin but should always be immediately washed off with plenty of water. Discontinue use if irritation and redness develop. If conditions persist for more than 72 hours, consult a physician.
In case of eye contact
:
Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes.
If swallowed
:
Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Take victim immediately to hospital.
Most important symptoms and effects, both acute and delayed
:
Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Causes serious eye irritation. Review section 2 of SDS to see all potential hazards.
Notes to physician
:
Treat symptomatically. Symptoms may be delayed.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
The exact percentages of disclosed substances are withheld as trade secrets.
SECTION 4. FIRST AID MEASURES
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Suitable extinguishing media
:
Water spray jet Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical
Unsuitable extinguishing media
:
High volume water jet
Hazardous combustion products
:
Carbon dioxide (CO2) Carbon monoxide Smoke
Specific extinguishing methods
:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Further information
:
Standard procedure for chemical fires.
Special protective equipment for firefighters
:
Wear self-contained breathing apparatus for firefighting if necessary.
Personal precautions, protective equipment and emergency procedures
:
Material can create slippery conditions. Refer to protective measures listed in sections 7 and 8. Use non-slip safety shoes in areas where spills or leaks can occur.
Environmental precautions
:
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and materials for containment and cleaning up
:
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.
Advice on safe handling
:
For personal protection see section 8. Avoid contact with eyes. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations.
Conditions for safe storage
:
Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid
:
Oxidizing agents
SECTION 5. FIREFIGHTING MEASURES
SECTION 6. ACCIDENTAL RELEASE MEASURES
SECTION 7. HANDLING AND STORAGE
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Components
CAS-No.
Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
Distillates (petroleum), hydrotreated light
64742-47-8
TWA
500 ppm 2,000 mg/m3
OSHA Z-1
TWA
400 ppm 1,600 mg/m3
OSHA P0
TWA (Mist)
5 mg/m3
OSHA Z-1
TWA (Mist)
5 mg/m3
OSHA P0
TWA (Mist)
5 mg/m3
NIOSH REL
ST (Mist)
10 mg/m3
NIOSH REL
PEL (particulate)
5 mg/m3
CAL PEL
Engineering measures
:
effective ventilation in all processing areas
Respiratory protection
:
Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Remarks
:
No special protection is required.
Eye protection
:
Eye protection is not required while washing with this product. In the workplace, the use of safety glasses is recommended to avoid eye exposure during the handling of containers or during spill clean-up.
Skin and body protection
:
No special protection is required.
Hygiene measures
:
When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
Appearance
:
gel
Colour
:
green
Odour
:
characteristic
Odour Threshold
:
No data available
pH : 7.5 - 8.5
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Personal protective equipment
Hand protection
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Melting point/freezing point
:
No data available
Boiling point
:
not determined
Flash point
:
not determined
Evaporation rate
:
No data available
Upper explosion limit
:
No data available
Lower explosion limit
:
No data available
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Density
:
0.95 g/cm3
Water solubility
:
emulsifiable
Solubility in other solvents
:
not determined
Partition coefficient: n­octanol/water
:
No data available
Auto-ignition temperature
:
not determined
Thermal decomposition
:
Not applicable
Viscosity, kinematic
:
> 25 mm2/s (40 °C)
Reactivity
:
Stable
Chemical stability
:
Stable under normal conditions.
Possibility of hazardous reactions
:
No decomposition if stored and applied as directed.
Conditions to avoid
:
No data available
Incompatible materials
:
Oxidizing agents
Hazardous decomposition products
:
Heating can release vapours which can be ignited.
Aggravated Medical Condition
:
None known. Symptoms of Overexposure
:
Effects are immediate and delayed.
Solubility(ies)
Viscosity
SECTION 10. STABILITY AND REACTIVITY
SECTION 11. TOXICOLOGICAL INFORMATION
Potential Health Effects
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Symptoms may include irritation, redness, pain, and rash.
IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Acute dermal toxicity
:
Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Acute oral toxicity
:
LD50 Rat: > 5,000 mg/kg
Acute inhalation toxicity
:
LC50 Rat: > 4.6 mg/l Exposure time: 6 h
Acute dermal toxicity
:
LD50 Rat: > 2,000 mg/kg
Result: No skin irritation
Remarks: Severe eye irritation
Carcinogenicity:
Acute toxicity
Product:
Components: Distillates (petroleum), hydrotreated light:
Skin corrosion/irritation
Product:
Serious eye damage/eye irritation
Product:
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
No data available
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Remarks: No data available
Remarks: No data available
Partition coefficient: n­octanol/water
:
Remarks: No data available
Regulation
40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances
Remarks
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Reproductive toxicity
No data available
STOT - single exposure
No data available
STOT - repeated exposure
No data available
Aspiration toxicity
No data available
Further information
Product:
Components: Distillates (petroleum), hydrotreated light:
SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
Product:
Mobility in soil
No data available
Other adverse effects
No data available
Product:
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
Additional ecological information
:
No data available
Additional ecological information
:
No data available
Waste from residues
:
The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer.
Contaminated packaging
:
Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.
Transportation Regulation: 49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IMDG (Vessel): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Cargo Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: IATA (Passenger Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Transportation Regulation: TDG (Canada): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL
Components: Distillates (petroleum), hydrotreated light :
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
SECTION 14. TRANSPORT INFORMATION
The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging for shipment under these alternative transport regulations.
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
TSCA list
:
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
Components
CAS-No.
Component RQ
(lbs)
Calculated product RQ
(lbs)
pentyl acetate
628-63-7
5000
*
SARA 311/312 Hazards
:
Acute Health Hazard
SARA 302
:
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
:
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
California Prop 65
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
TSCA
On TSCA Inventory
DSL
All components of this product are on the Canadian DSL
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
The components of this product are reported in the following inventories:
For information on the country notification status for other regions please contact the
manufacturer’s regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
SECTION 16. OTHER INFORMATION
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SAFETY DATA SHEET
BZ7978 ZEP REACH 092524 4/1G
Version 3.0
Print Date 01/22/2018
NFPA:
HMIS III:
Hazard pictograms
:
Signal word
:
Warning:
Hazard statements
:
Causes serious eye irritation.
Precautionary statements
:
Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention.
Version:
3.0
Revision Date:
09/05/2017
Print Date:
01/22/2018
Flammability
Health
Instability
2
1
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
0
0
2
0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Further information
OSHA - GHS Label Information:
We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, F C Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.
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